Safety data sheet "Glue 88"

Revision date 02.02.201

8
Date of filling in 15.02.2006
Page 1 of 6
SAFETY DATA SHEET
Glue 88
In accordance with the requirements of GOST 30333-2007, EU Regulation 1907/2006 and EU Regulation
№1272/2008 (CLP)/EU№453/2010
1. PRODUCT IDENTIFICATION AND SUPPLIER DETAILS
Chemical product name: Glue 88 (88-CA, 88-M, 88-H),
Other names (synonyms) none
Appointment: contact adhesive, designed for bonding rubber to metal, as well as glass,
concrete, polymer materials, ceramics, leather in any combination
Manufacturer: LLC "
AVA Hosting"
Address: Kuzmolovsky Settlement, Vsevolozhsky District, Leningrad Region, 188663, Russia
st. Kapitolovo, zd. bldg. 162-A, p. 39
Phone: +7 (812) 5
65-34-90
Fax: +7 (812)
565-34-90
Emailaddress;
info@avaproviding.ru
Emergency information:
t. +7(812)5
65-34-90
or contact your local poison control center
2. THE COMPOSITION OF THE CHEMICAL PRODUCT. INFORMATION ABOUT ITS COMPONENTS
General Chemical Description-adhesive
Chemical composition: Mixture (solution) from the following substances with the addition of products that are not
dangerous according to
EU criteria for health and the environment: mixtures of rubbers (polychloproprenes with
different molecular weights, # CAS 9010-98-4), resins (thermosetting para-tert-butyl-phenol-
formaldehyde, # CAS 25085-50-1), metal oxides (#CAS 1314-13-2 and # CAS 1309-48-4)
Harmful components: solvents
Chemical name of Formulas
but
#CAS
#EINECS Content
a
nie,%

Hazard classification
Nefras
80-120,
petrol
solvent
A mixture
of
aliphatic
carbohydrates
64742-89-
8
232-453-
7
31,5
F - highly flammable,
R11
Xi-irritant R38,
R67
Ethyl Acetate
With
4
N
8
About
2
141-78-6
205-500-
4
31,5
F - highly flammable,
R11
Xi-irritant
R36, R38, R66, R67
For the text of R phrases, see section 15
3. PRODUCT HAZARD IDENTIFIERS
Fire and explosion hazard:
Class
hazards
3,
subclass
3.1.
Fire
hazard,
Highly flammable liquid. Hazard sign and classification code 3212 according to GOST
19433. Flammable solvents contained in the product evaporate during
the application of glue, their vapors can form explosive mixtures with air.
Safety data sheet "Glue 88"
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Date of filling in 15.02.2006
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Danger to human health, consequences of exposure: low-hazard in terms of exposure to
body product that causes narcotic and irritating effects
Environmental hazards and hazardous effects: pollutes the environment
4. FIRST AID MEASURES
Method of contact of the chemical product: in case of violation of safety measures during storage and
handling of glue - through the respiratory system, skin, mucous membranes of the eyes, in case of accidental
ingestion.
- If inhaled: irritates the mucous membranes of the upper respiratory tract, has
a narcotic effect, dizziness, agitation, dry mouth
- In contact with skin: irritation, dryness, flaking
- In case of contact with eyes: irritation, redness, lacrimation
- If swallowed: cough, vomiting, headache
First aid measures:
Common
recommendations-the use of glue in everyday life and in production strictly for its intended purpose in
a well-ventilated area is safe for consumer health.
By
inhaled
poisoning: pre-medical-fresh air, rest, warmth, give
sedatives. Medical: for severe poisoning-subcutaneously 1 ml of a solution or 20%
camphor solution.
By
impact
on
skin: pre-medical: remove the glue from the skin with a gauze swab, rinse
with running water, wipe dry, lubricate with cream or vaseline. Medicaladvice: for chronic
inflammation, consult a dermatologist
By
a hit
in
eyes: first aid: rinse with running water for 10-15 minutes.
See an ophthalmologist if necessary
Contraindications: epinephrine, adrenomimetic drugs, emetics
If swallowed: first aid: rinse mouth, give a drink of water, do not induce
vomiting. Medical information consult a doctor if necessary
4
sheets
5.MEASURES AND MEANS TO ENSURE FIRE AND EXPLOSION SAFETY
Recommended extinguishing media: dry sand, asbestos cloth, PSV-3 powder,
air-mechanical and chemical foam, carbon dioxide
Not recommended extinguishing media: compact water jet
Hazardous components released from the chemical substance during its combustion,
combustion products, gases: carbon oxides, combustion products
Personal protectiveequipment: rubber gloves, respiratory protection
6. MEASURES TAKEN IN CASE of AN EMERGENCY (not intentional
release to the environment)
Collective and personal protection measures:
- industrial premises must be equipped with supply and exhaust ventilation or
local vents, fire extinguishing equipment, personal protective equipment in accordance
with standard industry standards
- when carrying out small work - work in a well-ventilated area, if
necessary, use rubber gloves.
Measures to prevent environmental pollution: do not allow spills,
product to enter the sewer system. In case of contact with water bodies or sewers, inform the relevant
competent administrative and official services.
 Methods and measures for the assembly and neutralization of the chemical substance: the spilled glue
must be carefully collected in a separate container observing safety measures, fill the place of spillage
with sand or chalk, followed by cleaning in a transport container.
7. RULES FOR HANDLING AND STORING PRODUCTS
Safety data sheet "Glue 88"
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Requirements and recommendations for use: work should be carried out in a well-ventilated
area, do not smoke, do not perform welding operations, avoid open flames. Do not drain waste
into the sewer system. When using a large amount of glue, use an intrinsically
safe tool, take measures to prevent the formation of static electricity
Requirements for protection against explosion and fire –work should be carried out away from sources of open fire,
sparks, do not smoke, do not perform welding work.
Storage requirements: in domestic conditions, store in the original packaging at a temperature of 0
up to +40
about
C, keep away from children; store glue in a tightly closed container in the factory and warehouses.
a room intended for storing flammable materials at a temperature not exceeding 40 degrees Celsius.
0
C

at a distance of at least 1 m from heating systems.

Unsuitable (incompatible) chemicals for storage:
self-igniting substances, do not keep together with food
Notes on the maximum amount of chemical that can be stored under the
specified conditions: none
Chemical / product packaging requirements: sealed metal packaging
(tube, jar, drum, barrel)
8. EXPOSURE CONTROLS AND
PERSONAL PROTECTIVE EQUIPMENT.
Maximum amount of chemical preparation in the air: Fire-hazardous and toxic
properties of the adhesive are determined by the properties of solvents: The maximum permissible concentration of
vapors
in the working area for gasoline is 100 mg / m
3
, for ethyl acetate -200 mg / m
3
, Hazard class 4, Content
harmful substances in the air of the working area must meet the requirements of GOST 12.1.005.
Technical means: ensure good ventilation or local extraction at the workplace.
Respiratory protection: in case of insufficient ventilation
, use respiratory protection equipment (gas mask).
Hand and skinprotection: wear protective clothing in accordance with industry
standards
Eye protection: not required, use glasses if necessary
Personal hygieneproducts: avoid contact with glue on the skin, eyes, clothing; keep the glue
separate from food, before a break, and at the end of the working day, wash your hands,
store work clothes separately
9. PHYSICAL AND CHEMICAL PROPERTIES
Color
From gray-green to beige
Uniformity
Uniform in consistency
Mass fraction of dry residue,%, within the limits of
24 ± 3
Conditional viscosity, c, within the limits of
Boiling point, temperature range,
about
With
Combustibility
Flash point, °C
Gasoline
Ethyl Acetate
Explosion limit (Petrol):
Lower, % of volume
Top, % of volume
Explosion limit (Ethyl Acetate):
Lower, % of volume
Top, % of volume
Solubility :
in water
in organic solvents
10 – 40
80-120
Lit when applied to a fire source
-17
-3
1,1
5,4
3,2
16,8
It does not mix with water
Soluble in toluene, mixture (1:1)
ethyl acetate with gasoline, not included
dissolves (does not mix) with
gasoline, ethyl acetate, and acetone
10. STABILITY AND CHEMICAL ACTIVITY.
Safety data sheet "Glue 88"
Revision date 02.02.201
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Date of filling in 15.02.2006
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Chemical stability and hazardous chemical reactions: if properly stored
and used, the product does not boil due to thermal decomposition. When
stored below 0
about
C possible crystallization of the polymer component of the adhesive,
causing a violation of the homogeneity of the solution. When heated to room temperature and
mixed, the homogeneity of the adhesive and all its properties are restored
Decomposition products: No hazardous products are released if properly stored and used
. During combustion, the combustion products of hydrocarbons, carbon oxides are released.
Stabilizers: other than those contained in the glue are not required
Exothermic reaction: does not occur
Unstable decomposition products: not formed
11. TOXICOLOGICAL INFORMATION.
Human exposure: low-hazard product,
belongs to class 4 (low-hazard compounds according to GOST 12.1.007-76), causes
narcotic and irritating effects. The use of glue in accordance with
the intended use and recommended method of application is safe for
the consumer
Acute toxicity to experimental animals:
If swallowed, LD
50
– 4.4 g / kg
Through the skin, LD
50
- there is no irritating effect with a single application
If inhaled, LC
50
- no toxic effect has been established
Irritation – irritating effect on the mucous membranes of the eyes and upper eyelids.
respiratory systems
paths
(protocol
tests
LLC
PolymerTest,
FEZ
No. 78.01.05.251. P. 008262. 04. 08)..
Chronic exposure to experimental animals: leads to lethargy, emaciation
Kancerogenicity: none
Mutagenicity: none
Reproductive toxicity: none
12. ENVIRONMENTAL IMPACT INFORMATION
Environmental properties: pollutes water bodies, soil;
do not allow access to water bodies, soil.
Ecotoxicity (toxicity to aquatic and terrestrial organisms, plants and animals):
MPC
reservoir
= 0.1 mg / l, MPC
soils
= 0.1 mg / kg, for biological treatment facilities of harmless
the concentration is 100 mg / l
Preservation and decomposition (biodegradation) in the medium: BOD
full
= 0.11, COD=3.54
Bioaccumulation: none
Data on other impacts: none
13. RECOMMENDATIONS FOR DISPOSAL (waste management)
Requirements not to dispose of waste in the environment: waste is collected in a special container, it is forbidden
to dump it into the sewer, etc.
Glue waste is neutralized by disposing of it in special places for
disposal and disposal of waste.
Types of chemical product, waste, and packaging disposal (burning, recycling, etc.): waste can
be incinerated in specialized facilities in compliance with local regulations
14. TRANSPORT INFORMATION
Title
regulatory level
report form
Title
chemical
of the drug/
substances
№
substances
by list
UN
Class
hazards
JT Number
Packaging Group
Glue 88
1133
3
-
-
Glue is transported by any type of transport that provides transportation conditions
Safety data sheet "Glue 88"
Revision date 02.02.201
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Date of filling in 15.02.2006
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for flammable goods in compliance with the rules of transportation established for this type
of transport, When transporting at subzero temperatures, the adhesive must
be kept at room temperature until a uniform consistency is restored. After
restoration, the adhesive completely retains its properties.
Transport marking-is carried out in accordance with GOST 14192 with the application of manipulative signs
"protect from sunlight". "Top", danger sign (drawing) according to GOST 1 9433 and
classification code
15. INFORMATION ON NATIONAL AND INTERNATIONAL LEGISLATION
Letter marking and hazard identification of the product:
Hazard signs and text: flammable, work should be carried out in a well-ventilated area
List of R phrases and numeric characters:
R11-highly flammable
R36-irritates the eyes,
R36 / 37 irritates the eye mucosa and respiratory system.
R67-Fumes may cause drowsiness and dizziness.
List of S phrases and numeric characters:
S-23 – do not breathe vapors,
S-24/25 – avoid contact with eyes and skin
S-26 – in case of contact with skin or eyes, rinse with plenty of water
S 36/37/39 - wear suitable protective clothing
S45 – in case of accident, if you feel unwell, contact your doctor
S61 – avoid to throw out into the environment. Refer to
special safety instructions
Xi-irritant
F - Highly flammable
Regulatory documentation regulating requirements for glue parameters, marking,
storage and transportation requirements, etc.:
TU2384-024-44297874-03 Glue 88M
TU38. 1051
061-87 Glue 88,
TU38. 105540-85 Glue 88 N
Information indicated on the label of the package (container): areas of application, method
of application, composition, precautions, storage conditions, technical specifications, volume,
date of manufacture, expiration date, barcode, manufacturer's address.
This information reflects the current level of knowledge. The
safety data sheet describes the product in terms of safety requirements. The above
information does not guarantee the quality of the product or its properties.
16. OTHER INFORMATION
When reissuing the Safety Data Sheet, changes were made to sections 1, 2, 15, 16
List of data sources used in drawing up the passport:
1. GOST 30333-2007. International standard. Chemical product Safety Data Sheet.
General requirements
2. Regulation EC No 1907/2006
3. Regulation EC No 1272/2008 (CLP)/EU No 453/2010
4. Requirements of the REACH/CLP Regulation for safety data sheets for products imported into the Russian Federation
EU countries. 2010
5. TU2384-024-44297874-03 Glue 88M
Safety data sheet "Glue 88"
Revision date 02.02.201
8
Date of filling in 15.02.2006
Page 6 of 6
6. TU38. 105176
1-87 Glue 88 ,
7. TU38. 105540-85 Glue 88 NP
8. GOST 8981-78. Ethyl and butyl acetic acid esters. Technical specifications
9. TU 38.401-67-106-92. Gasoline is a solvent for the rubber industry. Technical specifications
conditions.
10. Safety Data Sheet 0711580/09. Bayprene 330. Bayer.
11. Safety Data Sheet (MSDS). Skyprene. Toson Corporation.
12. GN 2.2.5.1313-03/2.2.5.2308-07. MPC/ELIMINATION of harmful substances in the air of the working area.
Hygiene standards.
13. GN 2.1,6.1338-03/2.1.6..2309-07. MPC/MONITORING of harmful substances in the air of localities.
Hygiene standards.
14. GOST 19433-88. Dangerous cargo. Classification and marking
15. GOST 14192-96. Cargo marking.
16. Recommendations for the transport of dangerous goods. Model Regulations, UN, New York and Geneva,
2011
17. GOST 12.1.004-91 Fire safety. General requirements.
18. Fire Safety Regulations in the Russian Federation (PPB 01-03)
19. Personal protective equipment. Spravochnik. L. Khimiya [Chemistry]. 1989
20. SanPiN 2.1.7.1322-03. Hygienic requirements for waste disposal and disposal
 production and consumption. Ministry of Health of the Russian Federation, 2003.
21. GOST 12.1.007-76. SSBT. Harmful substances. Classification and general requirements, Moscow, 1984
22. Test report of PolymerTest LLC, No. SG-1155-08-88M, 2008
23. Test report of LLC "PolymerTest", No. SG-1156-08 - SA, 2008
24. Test report of LLC "PolymerTest", No. SG-1157-08 - 88NP, 2008
25. Sanitary and epidemiological conclusion No. 78.01.05.251. P. 008262. 04. 08