General Chemistry II (BACH1323 )

Practical Reports

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 Experiment 7: Reactions of amines

Experiment Date: 29 August 2021

Results Table 7
Test Phenylamine Butylamine Ammonia
(a) solubility in water (answer
A. soluble soluble soluble
soluble or insoluble)
(b) pH of solution (one arabic
6 11 9
number)

B. (a) Reaction with hydrochloric phenylammonium

ac chloride is formed
butylammonium chloride is formed
ammonium chloride is formed

(b) Evaporation of water from produ

salt of phenylammonium chloridesalt
is formed
of butylammonium chloride issalt
formed
of ammonium chloride is formed

Reaction with copper(II)

C. copper (II) aniline
a complex
is formed
of [Cu(C4H9NH2)4(H2O)2]2+
a complex
(SO4)2-
of [Cu(NH3)4(H2O)2]2+
is formed (SO4)2- is formed
sulphate solution

D. (a) Reaction with cold nitrous acibenzenediazonium salt is formed

nitrogen gas and water are formed
nitrogen gas and water are formed

(b) Reaction of product from (a) with

(i) phenol A bright-yellow coloured precipitate is formed no reaction no reaction

(ii) naphthalen-2-ol A red coloured precipitate is formed no reaction no reaction

(c) Effect of heat on product from

decomposes
(a to nitrogen gas and phenol no reaction no reaction

E. Reaction with bromine water 2,4,6-tribromophenylamine is formed no reaction no reaction

Questions
1 Are butylamine and phenylamine stronger or weaker bases than anunonia, ?
Answer:
 Butylamine and phenylamine are stronger base than ammonia is because due to the present of ring in phenylamine and

2 How do you account for the different solubility of the amines in water and in dilute hydrochloric acid ?
Answer:

solubility of water is based on number of alkyl group present, and solubility in hcl is same because of acid base reactio

3 Which reactions might enable you to distinguish between a primary alkykmine and primary arylamine ?.
Answer:

The reaction with aqueous bromine (Bromine water, Br2). It produces 2,4,6-tribromophenylamine which seen as white pr

This practical report is

Report prepared by Law Koon Chang 000303-14-1557

End