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Strength of Hardened Concrete - 1: Reinforced Concrete Design Lecture No. 09 - Part 1
Strength of Hardened Concrete - 1: Reinforced Concrete Design Lecture No. 09 - Part 1
1.0—INTRODUCTION 3
fc = ax (3-2)
The strength of concrete is the property most valued by designers and
where a is the intrinsic strength of the material at zero porosity p, and x
quality control engineers. In solids, there exists a fundamental inverse
the solid/space ratio or the amount of solid fraction in the system,
relationship between porosity (volume fraction of voids) and strength.
which is therefore equal to 1 – p. Powers data are shown in Fig. 3.1b;
Consequently, in multiphase materials such as concrete, the porosity of
he found the value of a to be 234 MPa. The similarity of the two curves
each component of the microstructure can become strength-limiting.
in Fig. 3.1 confirms the general validity of the strength-porosity
Natural aggregates are generally dense and strong; therefore, it is the
relationship in solids.
porosity of the cement paste matrix as well as the interfacial transition
zone between the matrix and coarse aggregate, which usually 5.0—FAILURE MODES IN CONCRETE
determines the strength characteristic of normal-weight concrete.
With a material such as concrete, which contains void spaces of various
Although the water-cement ratio is important in determining the size and shape in the matrix and microcracks at the interfacial
porosity of both the matrix and the interfacial transition zone and transition zone, the failure modes under stress are very complex and
hence the strength of concrete, factors such as compaction and curing vary with the type of stress.
conditions (degree of cement hydration), aggregate size and
mineralogy, admixtures types, specimen geometry and moisture Under uniaxial tension, relatively less energy is needed for the initiation
condition, type of stress, and rate of loading can also have an important and growth of cracks in the matrix. Rapid propagation and interlinkage
effect on strength. In this section, the influence of various factors on of the crack system, consisting of preexisting cracks at the interfacial
concrete strength is examined in detail. transition zone and newly formed cracks in the matrix, account for the
brittle failure.
2.0—DEFINITION In compression, the failure mode is less brittle because considerably
more energy is needed to form and to extend cracks in the matrix. It is
The strength of a material is defined as the ability to resist stress
generally agreed that, in a uniaxial compression test on medium- or
without failure. Failure is sometimes identified with the appearance of
low-strength concrete, no cracks are initiated in the matrix up to about
cracks. However, microstructural investigations of ordinary concrete
50 percent of the failure stress; at this stage a stable system of cracks,
show that unlike most structural materials concrete contains many fine
called shear-bond cracks, already exists in the vicinity of coarse
cracks even before it is subjected to external stresses. In concrete,
aggregate. At higher stress levels, cracks are initiated within the matrix;
therefore, strength is related to the stress required to cause failure and
their number and size increases progressively with increasing stress
it is defined as the maximum stress the concrete sample can withstand.
levels. The cracks in the matrix and the interfacial transition zone
In tension testing, the fracture of the test piece usually signifies failure.
(shear-bond cracks) eventually join up, and generally a failure surface
In compression the test piece is considered to have failed even when
develops at about 20 to 30 from the direction of the load, as shown in
no signs of external fracture are visible; however, the internal cracking
Fig. 3.2.
has reached such an advanced state that the specimen is unable to
carry a higher load.
3.0—SIGNIFICANCE
In concrete design and quality control, strength is the property
generally specified. This is because, compared to most other
properties, testing of strength is relatively easy. Furthermore, many Figure 1
properties of concrete, such as elastic modulus, watertightness or Typical failure mode of
impermeability, and resistance to weathering agents including concrete in compression.
aggressive waters, are believed to be dependent on strength and may
therefore be deduced from the strength data. The compressive
strength of concrete is several times greater than other types of
strength, therefore a majority of concrete elements are designed to
take advantage of the higher compressive strength of the material.
Although in practice most concrete is subjected simultaneously to a
combination of compressive, shearing, and tensile stresses in two or
6.0—COMPRESSIVE STRENGTH AND FACTORS AFFECTING IT
more directions, the uniaxial compression tests are the easiest to The response of concrete to applied stress depends not only on the
perform in laboratory, and the 28-day compressive strength of stress type but also on how a combination of various factors affects
concrete determined by a standard uniaxial compression test is porosity of the different structural components of concrete. The factors
accepted universally as a general index of the concrete strength. include properties and proportions of materials that make up the
concrete mixture, degree of compaction, and conditions of curing.
4.0—STRENGTH-POROSITY RELATIONSHIP From the standpoint of strength, the relationship between water-
cement ratio and porosity is undoubtedly the most important factor
In general, there exists a fundamental inverse relationship between because, independent of other factors, it affects the porosity of both
porosity and strength of solids. For simple homogeneous materials, it the cement mortar matrix and the interfacial transition zone between
can be described by the expression the matrix and the coarse aggregate.
–kp
S = S0 e (3-1) The actual response of concrete to applied stress is a result of complex
interactions between various factors which fall under three categories:
(1) characteristics and proportions of materials, (2) curing conditions,
where S = strength of the material which has a given porosity p and (3) testing parameters.
S0 = intrinsic strength at zero porosity
k = constant
6.1—Characteristics and Proportions of Materials
The ratio S/S0 plotted against porosity follows the same curve and is
Before making a concrete mixture, the selection of proper component
applicable to a very wide range of materials.
materials and their proportions is the first step toward obtaining a
Powers found that the 28-day compressive strength fc of three product that would meet the specified strength. The composition and
different mortar mixtures was related to the gel/space ratio, or the properties of concrete-making materials were already discussed in in
ratio between the solid hydration products in the system and the total our previous lectures; however, some of the aspects that are important
space: from the standpoint of concrete strength are considered here. It should
be emphasized again that, in practice, many mixture design parameters (especially tensile strength) at early ages than a corresponding concrete
are interdependent, and therefore their influences cannot really be containing smooth or naturally weathered aggregate of similar
separated. mineralogy. Also, with a given cement content, somewhat more mixing
water is usually needed to obtain the desired workability in a concrete
6.1.1—Water-Cement Ratio. In 1918, as a result of extensive testing at mixture containing rough-textured aggregates; thus the small
the Lewis Institute, University of Illinois, Duff Abrams found that a advantage due to a better physical bonding may be lost as far as the
relation existed between water-cement ratio and concrete strength. overall strength is concerned.
Popularly known as Abrams’ water-cement ratio rule, this inverse
relation is represented by the expression 6.1.5—Mixing Water. Impurities in water used for mixing concrete,
when excessive, may affect not only the concrete strength but also
k1 setting time, efflorescence (deposits of white salts on the surface of
fc = (3-3)
k2w / c concrete), and the corrosion of reinforcing and prestressing steel. In
general, mixing water is rarely a factor in concrete strength, because
where w/c represents the water-cement ratio of the concrete mixture many specifications for making concrete mixtures require that the
and k1 and k2 are empirical constants. quality of water used should be fit for drinking, and municipal drinking
waters seldom contain dissolved solids in excess of 1000 ppm (parts per
Compressive strength of concrete is a function of the water-cement
million).
ratio and degree of cement hydration. At a given temperature of
hydration, the degree of hydration is time dependent and so is the
As a rule, water that is unsuitable for drinking may not necessarily be
strength.
unfit for mixing concrete. Slightly acidic, alkaline, salty, brackish,
colored, or foul-smelling water should not be rejected outright. This is
6.1.2—Air Entrainment. For the most part, it is the water-cement ratio important because of the water shortage in many areas of the world.
that determines the porosity of the cement paste matrix at a given Also, recycled waters can be safely used as mixing waters for concrete.
degree of hydration; however, when air voids are incorporated into the The best way to determine the suitability of a water of unknown
system, either as a result of inadequate compaction or through the use performance for making concrete is to compare the setting time of
of an air-entraining admixture, they also have the effect of increasing cement and the strength of mortar cubes made with the unknown
the porosity and decreasing the strength of the system. water with reference water that is clean. The cubes made with the
It has been observed that the extent of strength loss as a result of questionable water should have 7- and 28-day compressive strengths
entrained air depends not only on the water-cement ratio of the equal to or at least 90 percent of the strength of reference specimens
concrete mixture, but also on the cement content. made with clean water; also, the quality of mixing water should not
affect the setting time of cement to an unacceptable degree.
6.1.3—Cement Type. The degree of cement hydration has a direct Seawater, which contains about 35,000 ppm dissolved salts, is not
effect on porosity and consequently on strength. At ordinary harmful to the strength of plain concrete. However, with reinforced
temperature ASTM Type III Portland cement, which has a higher and prestressed concrete it increases the risk of steel corrosion;
fineness, hydrates more rapidly than other types; therefore, at early therefore, the use of seawater as concrete-mixing water should be
ages of hydration (e.g., 1, 3, and 7 days) and a given water-cement avoided under these circumstances. As a general guideline, from
ratio, a concrete containing Type III Portland cement will have a lower standpoint of the concrete strength, the presence of excessive amounts
porosity and correspondingly a higher strength. On the other hand, of algae, oil, salt, or sugar in the mixing water should send a warning
compared to ASTM Type I, Type II, and Type III Portland cements, the signal.
rates of hydration and strength development with Type IV and Type V
cements, and with Portland-slag and Portland-pozzolan cements are 6.1.6—Admixtures. The adverse influence of air-entraining admixtures
slower up to 28 days; however, the differences usually disappear on concrete strength has already been discussed. By their ability to
thereafter when they have achieved a similar degree of hydration. reduce the water content of a concrete mixture, at a given consistency,
the water-reducing admixtures can enhance both the early and the
6.1.4—Aggregate. In concrete technology, an overemphasis on the ultimate strength of concrete. At a given water-cement ratio, the
relationship between water-cement ratio and strength has caused presence of water-reducing admixtures in concrete generally has a
some problems. For instance, the influence of aggregate on concrete positive influence on the rates of cement hydration and early strength
strength is not generally appreciated. It is true that aggregate strength development. Admixtures capable of accelerating or retarding cement
is usually not a factor in normal strength concrete because, with the hydration obviously would have a great influence on the rate of
exception of lightweight aggregates, the aggregate particle is several strength gain; however, the ultimate strengths may not be significantly
times stronger than the matrix and the interfacial transition zone in affected.
concrete. In other words, with most natural aggregates the strength of
the aggregate is hardly utilized because the failure is determined by the For ecological and economic reasons, the use of pozzolanic and
other two phases. cementitious by-products as mineral admixtures in concrete is
There are, however, aggregate characteristics other than strength, such gradually increasing. When used as a partial replacement for Portland
as the size, shape, surface texture, grading (particle size distribution), cement, mineral admixtures usually have a retarding effect on the
and mineralogy, which are known to affect concrete strength in varying strength at early ages. However, the ability of a mineral admixture to
degrees. Frequently the effect of aggregate characteristics on concrete react at normal temperatures with calcium hydroxide (present in the
strength can be traced to a change of water-cement ratio. From hydrated Portland cement paste) and to form additional calcium silicate
theoretical considerations it may be anticipated that, independent of hydrate can lead to significant reduction in porosity of both the matrix
the water-cement ratio, the size, shape, surface texture, and and the interfacial transition zone. Consequently, considerable
mineralogy of aggregate particles would influence the characteristics of improvements in the ultimate strength and watertightness of concrete
the interfacial transition zone and therefore affect concrete strength. are achievable by incorporation of mineral admixtures. It should be
noted that mineral admixtures are especially effective in increasing the
A change in the maximum size of well-graded coarse aggregate of a tensile strength of concrete.
given mineralogy can have two opposing effects on the strength of
concrete. With the same cement content and consistency, concrete 6.1.7—Curing Conditions. The term curing of concrete involves a
mixtures containing larger aggregate particles require less mixing water combination of conditions that promote the cement hydration, namely
than those containing smaller aggregate. On the contrary, larger time, temperature, and humidity conditions immediately after the
aggregates tend to form weaker interfacial transition zone containing placement of a concrete mixture into formwork.
more microcracks. A change in the aggregate grading without any
change in the maximum size of coarse aggregate, and with water- At a given water-cement ratio, the porosity of a hydrated cement paste
cement ratio held constant, can influence the concrete strength when is determined by the degree of cement hydration (Fig. 2.10, case A).
this change causes a corresponding change in the consistency and Under normal temperature conditions some of the constituent
bleeding characteristics of the concrete mixture. compounds of Portland cement begin to hydrate as soon as water is
added, but the hydration reactions slow down considerably when the
It has been observed that a concrete mixture containing a rough- products of hydration coat the anhydrous cement grains. This is
textured or crushed aggregate would show somewhat higher strength because hydration can proceed satisfactorily only under conditions of
saturation; it almost stops when the vapor pressure of water in strength. On the other hand, as explained below, it has been observed
capillaries falls below 80 percent of the saturation humidity. Time and that the higher the casting and curing temperature, the lower will be
humidity are therefore important factors in the hydration process the ultimate strength.
controlled by water diffusion. Also, like all chemical reactions,
The influence of time-temperature history on concrete strength has
temperature has an accelerating effect on the hydration reactions.
several important applications in the concrete construction practice.
6.1.8—Time. It should be noted that the time-strength relations in Since the curing temperature is far more important to the strength
concrete technology generally assume moist-curing conditions and than the placement temperature, ordinary concrete mixtures that are
normal temperatures. At a given water-cement ratio, the longer the placed in cold weather must be maintained above a certain minimum
moist curing period the higher the strength, assuming that the temperature for a sufficient length of time. Concrete cured in summer
hydration of anhydrous cement particles is still going on. In thin or in a tropical climate can be expected to have a higher early strength
concrete elements, if water is lost by evaporation from the capillaries, but a lower ultimate strength than the same concrete cured in winter
air-curing conditions prevail, and strength will not increase with time. or in a colder climate. Compared to the strength of the specimens
cured at normal laboratory temperature, the in situ concrete strength
The curing age would not have any beneficial effect on the concrete will be higher at early ages and lower at later ages.
strength unless curing is carried out in the presence of moisture.
6.2—Testing Parameters
The evaluation of compressive strength with time is of great concern to
It is not always appreciated that the results of concrete strength tests
structural engineers. ACI Committee 209 recommends the following
are significantly affected by parameters involving the test specimen
relationship for moist-cured concrete made with normal Portland
and loading conditions. Specimen parameters include the influence of
cement (ASTM Type I):
size, geometry, and the moisture state of concrete; loading parameters
fcm(t) = fc28
t include stress level and duration,
(3-4) and the rate at which stress is applied.
4 0 .8 5t
6.3.1—Specimen Parameters. The standard specimen for testing
For concrete specimens cured at 20C, the CEB-FIP Models Code (1990)
the compressive strength of concrete is a 15- by 30-cm cylinder. While
suggests the following relationship:
maintaining the height/diameter ratio equal to 2, if a concrete mixture
28 is tested in compression with cylindrical specimens of varying diameter,
fcm(t) = exp s 1 fcm (3-5) the larger the diameter the lower will be the strength. For laboratory
t t1
experiment purposes, however, a 10- by 20-cm cylinder may be used.
where fcm(t) = mean compressive strength at age t days In general, the greater the ratio of the specimen height to diameter,
fcm = mean 28-day compressive strength the lower will be the strength. For instance, compared to the strength
s = coefficient depending on the cement type of the standard specimens (height/diameter ratio equal to 2), the
s = 0.20 for high early strength cements, specimens with the height/diameter ratio of 1 showed about 15
s = 0.25 for normal hardening cements; percent higher strength.
s = 0.38 for slow hardening cements
t1 = 1 day Because of the effect of moisture state on the concrete strength, the
standard procedure requires that the specimens continue to be in a
moist condition at the time of testing. In compression tests it has been
6.1.9—Humidity. The influence of the curing humidity on concrete observed that air-dried specimens show 20 to 25 percent higher
strength is obvious, which show that after 180 days at a given water- strength than corresponding specimens tested in a saturated condition.
cement ratio, the strength of the continuously moist-cured concrete The lower strength of the saturated concrete is attributed to the
was three times greater than the strength of the continuously air-cured disjoining pressure within the cement paste.
concrete. Furthermore, probably as a result of microcracking in the
interfacial transition zone caused by drying shrinkage, a slight 6.3.2—Loading Conditions. The compressive strength of concrete is
retrogression of strength occurs in thin members of moist-cured measured in the laboratory by a uniaxial compression test (ASTM C
concrete when they are subjected to air drying. The rate of water loss 469) in which the load is progressively increased to fail the specimen
from concrete soon after the placement depends not only on the within 2 to 3 min. In practice, most structural elements are subjected to
surface/volume ratio of the concrete element but also on temperature, a dead load for an indefinite period and, at times, to repeated loads or
relative humidity, and velocity of the surrounding air. to impact loads. It is, therefore, desirable to know the relationship
between the concrete strength under laboratory testing conditions and
A minimum period of 7 days of moist-curing is generally recommended
actual loading conditions. The behavior of concrete under various
with concrete containing normal Portland cement; obviously, with
stress states is described in the next section. From this description it
concrete mixtures containing either a blended Portland cement or a
can be concluded that the loading condition has an important influence
mineral admixture, longer curing period is desirable to ensure strength
on the strength.
contribution from the pozzolanic reaction. Moist curing is provided by
spraying or ponding or by covering the concrete surface with wet sand,
To appreciate at a glance the complex web of numerous variables that
sawdust, or cotton mats. Since the amount of mixing water used in a
influence the strength of concrete, a summary is presented in Fig. 3.12.
concrete mixture is usually more than needed for Portland cement
hydration (estimated to be about 30 percent by weight of cement),
proper application of an impermeable membrane soon after the
concrete placement provides an acceptable way to maintain the
strength development at a satisfactory rate. However, moist-curing
should be the preferred method when control of cracking due to
autogenous shrinkage or thermal shrinkage is important.