Professional Documents
Culture Documents
Hóa Lý Bài 2
Hóa Lý Bài 2
Hóa Lý Bài 2
CO + 2H2 CH3OH
548,15
=
298 298 298 T
1
− ∫ (−90,13 ) + ∫ ∆ C dT 2 dT
[ R
]
548,15
8,314 ×10,815 ×10−3 ( 2 1
¿
−24,79
298
∫
298
[ −90,13 ×8,314 ×7,663 × ( T −298 ) +
2 ]
× T −2982 ) ×10−3 2 dT
T
k y =1
k f =k=7,8366 × 10−4
⇔
CO + 2H2 CH3OH
200 420 α
α 2α α
200 – α 420 – α α
−2
α 60
7,8366∗10−4 =
( 200−α ) × ( 420−α )2
×
620−2 α ( )
α =90,919 (mol)
e quilibriumCO ¿ 109,081 (mol) ; H2 ¿ 238,162 (mol) ; CH3OH ¿ 90,919 (mol)
∑ n=438,162 (mol)
109,081
PCO = × 60=14,937 atm (PC = 3,5 MPa ; TC = 133K)
438,162
14,937 ×101325
PC = =0,432
CO
3,5 ×106
T C =4,1214
CO
γ CO =1
238,162
PH = × 60=32,607 atm (Pc = 1,3 MPa ; TC = 33,3K)
2
529,081
PC =2,5414
H2
T C =16,61
H2
γ H =1
2
90,919
PCH OH = ×60=12,45 atm (Pc = 7,95 MPa ; TC = 513,2K)
3
529,081
PC CH3 OH
=0,189
TC CH3 OH
=1,068
γCH 3 OH =0,95
γ C H OH
¿> k γ = 3
=0,95
γ H × γ CO
2
¿> k y =0,95
7,836 × 10−4 −2
α 60
k p=
0,95
= ×
(200−α )×(420−2 α ) 620−2 α ( )
α =92,76 (mol)
CO = 92,76 (mol) ; H2 = 234,48 (mol) ; CH3OH = 92,76 (mol)
∑ n=434,48 (mol)
107,24
PCO = × 60=14,8 atm
434,48
PC =0,42846
CO
T C =4,1214
CO
γ CO =1
P H2 =32,38 atm
PC =2,524
H2
T C =16,61
H2
γ H =1
2
PC H OH =12,81 atm
3
PC C H 3 OH
=0,163
TC C H3 OH
=1,068
γCH 3 OH =0,95
¿> k γ =k γ =0,95
old new
92,76 2 × 92,76
¿> X CO = =0,4638 ; X H 2= =0,22
200 420