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Conventional and Special Core Analysis
Conventional and Special Core Analysis
Conventional and Special Core Analysis
Depth Matching
Coring Analysis
* Routine core analysis (rcal).
Porosity, permeability, saturation, lithology, grain density.
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Porosity Controls
Dissolution and leaching out
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Porosity Controls
Fracturing
Diagenetic History
Fissures (Fractures)
Fissures are caused when a rigid rock is strained beyond its
elastic limit - it cracks.
The forces causing it to break are in a constant direction,
hence all the fissures are also aligned.
Fissures are an important source of permeability in low
porosity carbonate reservoirs.
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Vugs
Porosity Controls
Dolomitization
Porosity Controls
Cementation
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Porosity Controls
Cementation
Porosity Controls
Swelling Clay distribution
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Porosity Controls
Sorting and Packing
Pore-Space Classification
Classification of Porosity:
1. Total Porosity
is the ratio of the total pore volume to bulk volume regardless the
continuity of the pores.
2. Effective Porosity
is the ratio of interconnected pore volume to the bulk volume.
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Pore-Space Classification
Vb = Vp + Vg
Porosity
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Porosity
1.Bulk Volume
In all porosity methods a bulk core sample volume
has to be determined and this may be carried out by:
Displacement of liquid (Archimedes mercury immersion
apparatus).
Vb = (Saturated Wt – Immersed Wt) / density of immersed fluid
Porosity
2. Grain Volume (Boyle's law porosimeter)
Involves the compression of a gas into the pore space or the
expansion of gas from the pores of a prepared Sample.
The gas (usually Helium) is admitted into a pre-calibrated
reference cell of known volume “Vr” at a reference pressure “P1”.
The reference cell gas is then vented into a connected chamber
with a volume “Vc” containing a core sample with grain volume
“Vg”.
This venting results in a lower equilibrium pressure “P2”, from
which the grain volume is calculated:
Vr . P1 = (Vc-Vg) . P2 Vg = Vc – (Vr.P1 / P2)
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Porosity
From gas source
Reference
chamber
Vr Pressure
transducer
sample
sample
chamber
Vg
Vc
Boyle's law porosimeter
Helium Pycnometer
Porosity
3. Pore Volume
Simply, the pore volume is calculated by subtracting the Grain
Volume “Vg” from the Bulk Volume “Vb”.
Vp = Vb – Vg
There are other ways to measure the pore volume which can be
summarized as follows:
3.1. Summation of fluids
This method involves the independent determination of oil, gas
and pure water volumes of a fresh core sample.
The oil (650°) and water(120°) can be obtained by retort.
The gas can be obtained by mercury injection (700 psi).
The pore volume is determined by summing the three
independent volumes.
Porosity
Oven retort
Oven retort
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Porosity
3.2. Washburn Porosimeter
Involves the vacuum extraction and collection of the gas
contained in the pores of a prepared sample.
The method measures pore volume.
Porosity
4. Total Porosity
The sample is reduced to grain size after the dry weight and bulk
volume are determined.
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Permeability
1. Single Phase System (absolute permeability)
“It is the ability of the porous media to transmit a single fluid through its
interconnected pores”.
2. Multi phase system
2.1 Effective permeability
“it is the conductivity of each phase at a specific saturation”; when a
second or third phase is present, the obtained permeability of each phase at
a specific saturation is called effective permeability, hence, depends upon
the fluid ratio and its distribution within the pore spaces. Fluid distribution
in turn depends upon the saturation history and wettability of the rock.
2.2 Relative permeability
“it is the ability of the rock to transmit a fluid when there are two or three
phases within the pore spaces”
effective Permeability
Relative Permeability =
specific Permeability
Absolute permeability
Relative permeability
Darcy’s Law
Darcy experimented and developed an empirical relationship for the flow
of fluid through a packed sand , known as Darcy’s low:
q q
A = system cross sectional area, cm2 µ
p2 p1
∆p = differential pressure (p1-p2), atm.
L
One darcy is defined as:
“the ability of the porous rock to transmit fluid of one centipoise viscosity () at
a rate (q) of 1 cm3/s through a cross sectional area (A) of 1cm2 when the
pressure gradient (P / L) is 1 atm/cm”
Darcy’s Law
• Homogeneous rock
• Newtonian fluid
• Laminar flow A
q q
• Steady state µ
p2 p1
• Constant temperature L
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Significant Permeability
Reduction
Migration of Fines
Problem
Carter Sandstone
North Blowhorn Creek Oil Unit
Black Warrior Basin,
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Alabama, USA (Photograph by R.L. Kugler)
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Coarsely Crystalline
carbonates
Permeability
Porosity
Porosity-Permeability Relationships
Permeability can be estimated from porosity, resistivity, Sw and hydrocarbon
density data. However, Sw must equal Swirr, the irreducible water
saturation.
There are two simple formulas for medium gravity oil and dry gas (i.e.
hydrocarbon density is taken into consideration).
4.4
* Timur Equation (1968): K 0.136*
(S wirr ) 2
2
3
* For medium gravity oil: K 250 Wyllie and Rose (1950)
S wirr
2
3
K 79
* For Dry Gas:
S wirr Wyllie and Rose (1950)
Gas Permeameter
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Klinkenberg Effect
Klinkenberg (1941) stated that permeability to gas is relatively higher than
that to water. He attributed this phenomenon to a slip flow between the gas
molecules and the solid walls. The error introduced is significant for values less
than 1 md.
where:
kg is the apparent permeability calculated from gas flow tests; md,
kL is the true absolute permeability measured from liquid flow tests; md,
̅P is the mean flow pressure of the gas in the flow system; atm, and
b is the Klinkenberg’s factor for a given gas in a particular porous medium.
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Core analysis forms a base for the calibration and verification of log
analysis in the evaluation of petrophysical parameters for the static and
dynamic description of reservoirs.
The proof of a log analysis is the degree to which the porosity matches
core analysis porosity.
The easiest way to check this is to plot the core analysis porosity on
top of the log analysis on the same depth plot.
If the core is off depth to the log porosity, shift the core depths
appropriately and re-display the results.
Advanced Carbonate Reservoirs Characterization & Scal Analysis - Bassem S. Nabawy 23.08.2017 52
Choice 1: Adjust shale, matrix, and fluid parameters in the log analysis model
until a better match is achieved. This may take several attempts and may
require choosing a different mathematical model or mineral assemblage.
Choice 2: Cross-plot core porosity vs log analysis porosity, and find a
regression line that corrects the log result to the core, in the form:
corr = a * e + b
The regression should be the reduced major axis (RMA) method (not a simple
least squares regression.
Choice 3: Perform the regression on a single input log curve instead of on
e, or separately on several curves. Pick the regression with the least standard
deviation or highest R-squared.
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Permeability
2. Multi Phase System
2.1 Effective Permeability
“It is the permeability to a particular fluid , i.e. oil, gas, or water (ko, kg,
or kw) in the presence of another phase”.
0 ≤ k o, k g, k w ≤ k
Where:
k = absolute permeability
ko = oil effective permeability
kw = water effective permeability
oil
kg = gas effective permeability
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Permeability
2. Multi Phase System
2.2 Relative Permeability
“It is the fractional ratio of the effective permeability of certain phase to
the absolute permeability”.
Kro = ko/k,
krw = kw/k, 0 ≤ kro, krg, krw ≤ 1
krg = kg/k
Where:
k = absolute permeability
kro = oil relative permeability
krw = water relative permeability
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Permeability
2. Multi Phase System
2.2 Relative Permeability
Laboratory measurement of end points
1. Clean the core; evacuate all fluids.
2. Saturate with water; then Sw = 1 and Krw = K and absolute permeability
can be measured.
3. Inject oil , (non-wetting, drainage) until no further Water is produced,
water saturation now = Swirr, at this point Ko could be measured .
4. Now inject water (wetting, imbibition) until no further oil is produced,
oil saturation is equal to Soirr (the equilibrium point), at this point Kw
could be measured .
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Effect of Wettability
for Increasing Sw
Wettability
Wettability:
“it is the tendency of one fluid to spread on or adhere to a
solid surface in the presence of other immiscible fluids”.
Wettability refers to interaction between fluid and solid
phases.
Wettability
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Nature of Wettability
Petrophysical Studies
- 1.0
- 0.8
- 0.6
- 0.3
0.0
0.3
0.6
0.8
1.0
Wettability Concepts
Water-Wet Rock
ow Oil
Water
os ws os
Solid
If an oil-wet rock saturated with water is placed in oil, it will imbibe oil
into the smallest pores, displacing water.
Oil-Wet Rock
ow
Water
Oil
The adhesion tension between water and the rock surface is less than
that between oil and the rock surface.
WATER-WET OIL-WET
Air
OIL Oil OIL
WATER WATER
< 90
WATER WATER > 90
SOLID (ROCK) SOLID (ROCK)
FREE WATER
OIL
GRAIN GRAIN
OIL
RIM
BOUND WATER FREE WATER
WATER
SILICA SURFACE
WATER
CALCITE SURFACE
From Amyx Bass and Whiting, 1960; modified from Benner and Bartel, 1941
From Tiab and Donaldson, 1996 CONTACT ANGLE: Triber et al. CONTACT ANGLE:
-Water-wet = 0 – 75 degrees -Water-wet = 0 – 80 degrees
-Intermediate-wet = 75 – 105 degrees -Intermediate-wet = 80 – 100 degrees
-Oil-wet = 105 – 180 degrees -Oil-wet = 100 – 180 degrees
* Wettability Affects:
Capillary Pressure.
Irreducible water saturation.
Residual oil and water saturations.
Relative permeability.
Electrical properties.
* Implications of Wettability:
Oil moves easier in water-wet rocks than oil-wet rocks.
Wettability affects the shape of the relative permeability curves.
Wettability
• Almost all reservoirs are initially water wet because of the natural
sedimentological mechanism involving in aqueous processes.
• When rock is water wet, water tends to occupy the smaller pores and
contact most of the rock surface.
• The opposite is true in oil wet rocks, the rock is preferentially in contact
with oil and fills the small pores.
• When rock has no strong preference for either oil or water the rock is said
to be neutral or intermediate wettability.
• The early saturation history for a petroleum reservoir may include:
• Connate water fills the void spaces in a reservoir during sedimentation and
trap development.
• Oil accumulates, water is expulsed from larger pores and retained in smaller
pores by capillary forces.
• Water is retained as a thin film on pore surfaces overlain by oil.
Wettability Classification:
Strongly oil- or water-wetting
Neutral wettability
- No preferential wettability to either water or oil in the pores.
Fractional wettability
- Reservoir that has local areas are strongly oil-wet, whereas most of
the reservoir is strongly water-wet.
- Occurs where reservoir rock have variable mineral composition and surface
chemistry.
Mixed wettability
- Smaller pores are water-wet and filled with water, whereas larger
pores are oil-wet and filled with oil.
- Occurs where oil with polar organic compounds invades a water-wet rock
saturated with brine.
* Wettability
* Core Wettability Can Be Altered By:
1- Invasion of coring fluids and filtrates during coring.
2- Asphaltene and/or wax precipitation by change in reservoir pressure
and temperature.
3- Improper well site handling and preservation procedures (drying and
oxidation must be avoid).
1- Contact angle
If a liquid wets a surface, it tends to spread and cover
that surface.
Observed on a microscopic scale, the edge of the
liquid has a characteristic shape.
A knife edge shape indicates wetting, while a beaded
edge shape indicates nonwetting.
The measurements are generally made on a polished
surface that simulates the reservoir material. For
sandstones, glass slides or polished quartz are often
used. Polished marble is usually chosen to simulate a
carbonate reservoir.
An adaptation of the technique uses a drop of liquid
confined between two surfaces.
Contact angle measurements can be precise, but even
for ideal systems, measurements can show significant
variation.
2- Amott Technique
Wettability measurements by the Amott method give a guide to the relative oil or brine
wetting tendencies of reservoir rocks.
The Amott method involves four basic measurements.
(i) The amount of water or brine spontaneously imbibed, AB.
(ii) The amount of water or brine forcibly imbibed, BC.
(iii) The amount of oil spontaneously imbibed, CD.
(iv) The amount of oil forcibly imbibed, DA.
2- USBM Technique
This method is very similar to the Amott method, but measures the work required to do
the imbibitions. It is usually done by centrifuge, and the wettability index W is calculated
from the areas under the capillary pressure curves A1 and A2:
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R=rA/L
Where; R: is the resistivity of the sample, ohm-m.;
r : is the resistance of the sample, ohm;
A : is the cross-sectional area, m2; and
L : is the length of the sample, m.
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Wettability Dolomitization
Channel diameter Silicification
Electrical Resistivity
- The resistivity of porous rocks is controlled mainly by:
1) the pore phase (its volume, geometry and distribution),and
2) the resistivity of saline solution within the pore spaces.
* Apparent Electric Resistivity (RO)
“It is the resistivity of the porous rock fully saturated with saline”
* True Electric Resistivity (Rt)
“It is the resistivity of the porous rock partially saturated with
saline at the irreducible water saturation”.
* Irreducible Water Saturation (Swirr)
“It is ratio of the water
retained inside the pore spaces”.
a . Rw
Sw = n m
F Rt
Saturation Exponent
Porosity Uninvaded Zone Resistivity
a R
F= = m
Rw F
F.R w = R
R n F .R w
Sw = n =
Rt Rt
a . Rw
Sw = n m
F Rt
Saturation Exponent
Porosity Uninvaded Zone Resistivity
Electrical Resistivity
In fact, the resistivity „RO‟ of saturated porous sedimentary rocks is
mainly of electrolytic origin, because resistivity of the solid matrix is much
larger than that of the saline solution „Rf‟.
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This equation was developed frequently through the study of a large number of
sandstone samples. It has the effect of approximating the Archie equation with m =
1.5 for high porosity unconsolidated sandstone samples and approximating m = 2
for low porosity well consolidate sandstone samples.
Shell Oil Company generalized the former equation keeping for low
porosity (9 %) not fractured carbonate rocks keeping ‘a’ equals 1, and
processing ‘m’ as a variable value as follow.
1.0
a * Rw Ro
SWn
m * Rt Rt
Ro/Rt in (ohmm)
Ro
0.1
n log SW log( )
Rt
Ro
log( ) n log SW b
Rt 0.01
n = Slope
Tortuosity of Channels
“It is the ratio between the tortoise (actual) length, La, and the length of the
straight line between the two ends of the channel, L”.
T = La/L
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