MO APPROACH: 1, YOU ALWAYS END UP WITH AS MANY ORBITALS AS YOu STARTED WITH 2. BONDING CAN BE ACCOUNTED FOR BY PUOITING ELECTRONS INTO THE MOS BY HOUNDS ROLE ANO PALLI EXCLUSION PRINCIPLE 3. BOND_ORDER: ff BONDING — y ANTI-BONDING 22” ELECTRONS ELECTRONS 4. MOLECULAR CONFIGURATION: ti, lot N, 107 20%? §9 307° lot 20%? 3o% int 2ne4MOLECULAR ORBITALS AND BONDING jp Ly “stk is “4b ee : ATOMIC ELECTRONIC STRUCTURE Is? 2g? Zp* 35? see SG OF ELECTRONS ATOMIC ORBITAL MOLECULAR ELECTRONIC STRUCTURE log 2og30, Youn, dh Sa or Evecrrons Sime yy “TH —____— norecurae lo? Jot? 3q74o%2 W!... ORBITAL A, we Mo BO. Ran B.S, dH; \ Q;' 08 100A 255 Se Hy 2 o; 1 Off 432 Het 3 Igid! oS 108 322 He, 4 pis Oo °oo eel _ yh 1 ao tt ava ap AL. 2p ja 4" Fp kW ara Aa___te Mo CONFIG. BS i 3 7 B 105 ney iz 6 Isa'lsotzsey | 267A Yon Be, g asog 2s o. Oo 2 Ls 239 B, «10 290g 2so 2PM \ gq bey Oe 2 7 4,2 1.09% 94 N, 1 2PM PhO oo 2 1.20% 449% oO le FL oo wn Bp Zp Zp! \ 1.430 1SHETERONUCLEAR DIATOMICS H a x ‘ede. A —L— “oF Op Yo ? Cn is, + Celp t Cp 2p +Cr 2p, Don's INTERACT WITH H1sS Yo = -33ls, + 4 2p, POLAR, oO ORBITAL %, = any ' 2Pey NON- BONDING You? .Wisy -332p, PocarR o* ORBITALDIPOLE MOMENT ot aoe = 2 oo ter BL Gae DISTRIBUTION OF SEPARATION OF CENTER CHARGE OF Positive ANDO NEGATIVE CHARGE ON AVERAGE THE ELECTRON > —sCDENSITY 16 ON F St &- DIPOLE HOMENT OPERATOR: — Ea NN dure [ Wuvae = [etzeit bar wf , ™ Pox s2,%Ya2,o") INTEGRATE OVER ALL ELECTRONS, ” be $07) OG OG) -- Te (X,Y 8 XaYasteo )