2.3 Electron Configurations

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Learning
Objectives

Each level contains


different number of
This strict order begins to break
down, further down the pTable, as sub-levels
orbitals become close in energy.
Principal energy
levels
Lowest energy sub-
levels are occupied first

Aufbau Principle
Four sub-levels exist

Labelled in order of
increasing energy -> s,
Sub-levels p, d, f
An orbital can contain
maximum of two
electrons Each holds different
number of electrons
The electrons spin in
Pauli Exclusion 🏛
opposite directions Energy level -> number
⬇ ⬆
Principle Rules of
First electron to enter Electron Orbitals Sub-level -> letter Characteristics of
orbital is drawn as , standard electron
second as Notation Number of electrons configuration
occupying orbitals ->
superscript
Electrons which occupy
orbitals of equal energy
Note: some scientific material
(p - 3, d - 5, f - 7) -> will write in numerical order (1,
2, 3, 4 etc.)
must be entered into States the location of
each orbital, before a every electron in the
second is added Hund’s Rule atom Obtainable up to Vanadium (Z = 23)

Full electron
configuration Begins at 1s and
continues until no
electrons left

States previous noble


Electrons are
gas, then remaining
arranged in energy outer electrons
levels

Condensed notation
Main energy levels ->
referred to as
2.3 Electron
‘principal energy Configurations 🧩
levels’
Configurations
Each sub-level filled (or
partially filled) last
Evidence of energy aligns with location on
levels supported by periodic table
ionisation energy
graphs Layout on periodic
table


All principal energy Energy Levels
levels contain one (or
more) sub-levels

Memorisation
strategy
Evidence of sub-
levels also supported
by ionisation energy
graphs

Orbital Filling

Diagram
Representation
Configuration of Ions

If two electrons enter


Chromium (Z=24), Cr 🙅 same orbital ->
Exceptions repulsion between them
Copper (Z=29), Cu

Most stable
Stability configuration -> single
electrons in different
orbitals

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