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Construction and Building Materials 212 (2019) 422–430

Contents lists available at ScienceDirect

Construction and Building Materials


journal homepage: www.elsevier.com/locate/conbuildmat

Hydraulic properties of polyurethane-bound permeable pavement


materials considering unsaturated flow
T. Törzs a,⇑, G. Lu b, A.O. Monteiro b, D. Wang b,c, J. Grabe a, M. Oeser b
a
Institute of Geotechnical Engineering and Construction Management, Hamburg University of Technology (TUHH), Harburger Schloßstraße 20, 21079 Hamburg, Germany
b
Institute of Highway Engineering, RWTH Aachen University, Mies-van-der-Rohe-Straße 1, 52074 Aachen, Germany
c
School of Transportation Science and Engineering, Harbin Institute of Technology, Harbin 150090, China

h i g h l i g h t s

 Preparation of innovative polyurethane-bound pavement materials.


 Prediction of the water-retention behaviour based on basic geotechnical properties.
 A laboratory technique to determine the retention behaviour is applied.
 Saturated hydraulic conductivity is determined and modelled.
 Unsaturated hydraulic conductivities are derived from laboratory and modelled data.

a r t i c l e i n f o a b s t r a c t

Article history: Constant urban and infrastructural growth leads to increased sealing of areas in municipal areas. This sur-
Received 26 December 2017 face sealing results in distortions of the natural water cycle, which again can lead to noticeable changes in
Received in revised form 28 February 2019 the natural ecosystem. To counteract the effects of surface sealing, innovative permeable road structures
Accepted 14 March 2019
provide a promising environment-friendly opportunity. An innovative highly permeable road surface
Available online 6 April 2019
material based on alternative binders using polyurethane (PU) to replace the conventionally used bitumi-
nous binders has been developed in the course of an ongoing research project. It is intended that the high
Keywords:
permeability of the road’s surface material and underlying support layers leads to a quick drainage
Open porous pavement
Polyurethane
through the road construction down to the subsoil. The aim of this study is to understand and quantify
Hydraulic properties the relevant hydraulic properties of PU-bound road surface material, i. e. the water retention behaviour
Unsaturated soils and the hydraulic conductivity in saturated and unsaturated states. A predictive model to determine
Water retention behaviour the surface material’s water retention behaviour was used as a first estimation and very low air entry val-
Hydraulic conductivity ues were observed. Results from laboratory experiments on the material’s saturated hydraulic conductiv-
Permeability ity as well as the water retention behaviour in the low suction range are presented. Additionally,
empirical hydraulic models to describe the retention behaviour and models for the saturated and unsat-
urated hydraulic conductivities are outlined and applied.
Ó 2019 Elsevier Ltd. All rights reserved.

1. Introduction materials and technologies. Building permeable road structures


combined with the use of innovative synthetic binders for the
Surface sealing is associated with constant urban and infrastruc- road’s surface material is a promising alternative to the ubiquitous
tural growth. The level of sealed surfaces in Germany can rise up to traditional sealed bituminous pavements. The use of permeable
nearly 50% which is shown in Fig. 1. Sealed surfaces decrease the pavements aims at instantaneous infiltration of water into the
natural retention capacity of an area leading to significant changes underlying layers down to the subsoil. Thus, surface run-off is
in the natural water cycle and consequently in the whole natural reduced and municipal water treatment systems are relieved.
ecosystem. In addition, the global shortage of resources leads to Substituting the bituminous binder in asphalt concrete with a
the need of innovative and environment-friendly construction synthetic PU-based product has already been proved in several
cases [1–4]. The research findings showed that a substitution of
bituminous binders by PU-based binders could significantly
⇑ Corresponding author. improve the performance of a traffic surface. The material showed
E-mail address: tom.toerzs@tuhh.de (T. Törzs).

https://doi.org/10.1016/j.conbuildmat.2019.03.201
0950-0618/Ó 2019 Elsevier Ltd. All rights reserved.
T. Törzs et al. / Construction and Building Materials 212 (2019) 422–430 423

Fig. 1. Level of surfaces sealed by buildings and traffic areas in Germany (satellite data by the European Environment Agency from 2013).

a higher fatigue and deformation resistance against traffic loads retention behaviour of PU-bound pavement of similar composi-
compared to common bituminous open porous asphalt for water- tions to the materials investigated in this research project. Low
permeable road constructions. In addition, Renken and Oeser [5] capillary effects were observed, whereby their importance on the
and Lu et al. [4] showed that the high permeability combined with hydraulic performance of water-permeable pavement still needs
the material’s strength is maintained over the whole range of ser- to be investigated. Besides its mechanical function, the pavement’s
vice temperatures. Further, as petrochemical resources are limited, design must ensure correct drainage under rainfall events. Further-
many efforts have been done in finding alternatives to their appli- more, the passing of vehicles affects the pore air and pore water
cations. The polyol component of polyurethane can be obtained pressures and thus influences the capillary pressure within the
from renewable resources, such as vegetable oils, resulting in an pavement and subsoil [12,13].
environmentally sustainable product [6,7]. Additionally, compared Following these findings, standard tests on the saturated con-
to the heat mixing process using regular bitumen based binders, ductivity as well as tests on the water retention behaviour using
polyurethane-based binders can save energy and significantly a hanging water column apparatus were carried out on two com-
decrease greenhouse gas (GHG) emissions due to the cold mixing positions of PU-bound pavement materials. The latter is not a stan-
process [8]. dard method in asphalt testing. However, the applicability of the
A porous pavement structure, serving in a complex environ- method has been proved in numerous studies in geotechnical
ment, subjected to dynamic vehicle loading, capturing variable and environmental applications [14].
phases (air, liquid and solid) is exposed to mechanical and hydrau- Besides the conducted experiments, the performance of hydrau-
lic loads. With the infiltration and the upward movement of mois- lic models to describe the water retention behaviour as well as a
ture in the sublayer and soil due to changing groundwater levels model for the saturated hydraulic conductivity and a model to
and capillary rise, water-permeable road structures are mostly in derive the unsaturated hydraulic conductivities of both phases,
an unsaturated state. Multi-physical processes in the structure water and air, are presented and evaluated.
include freezing and spalling, drying and shrinkage, hydro diffu-
sion and subsidence, as well as capillary rise and cracking [9]. Each
one of these processes can cause a complex distribution of the 2. Material and methods
phases which exerts significant influence on the pavement beha-
viour. Hence, it is vital to fundamentally clarify the characteristics 2.1. Material’s properties
of pore water and pore air flow in the permeable pavement
structure. The investigated material of this study is the aforementioned
This article focuses on the investigation of the hydraulic proper- PU-bound pavement material, whereby two compositions varying
ties of PU-bound pavement structures. Renken et al. [10] and Törzs in terms of particle size distribution of the aggregates will be inves-
et al. [11] presented first results from experiments on the water tigated. Similar mixtures to the ones investigated in this study
424 T. Törzs et al. / Construction and Building Materials 212 (2019) 422–430

were already used in other studies [1–5,8,10,11] and throughout Table 1


the project funded by the German Research Foundation as part of Properties of the investigated polyurethane-bound road surface materials. The given
parameters for the porous specimens are averaged values for the respective mixtures.
project Nos. GR1024/25-1 and OE514/4-1. Mixture A includes grain Further, a schematic drawing for understanding the different bulk densities is given.
fractions from 0 mm to 8 mm, mixture B from 0 mm to 5.6 mm. The
corresponding particle size distributions as well as bound and Parameter (unit) Mixture

unbound specimens are illustrated in Figs. 2 and 3, respectively. A B


The aggregates in their unbound form are a fine diabase gravel mass fraction (–)
and a limestone filler, which are widely used in regular bituminous aggregates 0.94 0.94
porous asphalt mixtures [15]. In the production of the PU-bound aggregates’ filler content 0.02 0.02
PU-binder 0.06 0.06
road surface material, the unbound grains are mixed in the  
amounts given in Table 1, whereupon the yet liquid PU is added bulk densities qbulk g=cm3
to the mixture creating a thin PU-coating covering the aggregates. aggregates 2.85 2.85
filler 2.80 2.80
Once the PU hardens, the coated grains are bonded together form- PU-binder 1.09 1.09
ing a stable and highly permeable pavement mixture. composed mixtures 2.60 2.60
Polyurethane, as used in the pervious pavement mixtures, is a porous specimens (mean) 1.877 1.849
multifunctional material, which in addition is widely used in many porosity n (–)
different fields, e. g. building and construction materials, furniture, porous specimens (mean) 0.278 0.289
textiles, or electronics. It primarily consists of various polymers
that are made by the polyaddition reaction of a diisocyanate or a
polymeric isocyanate with a polyol. The synthesis is based on the
connection of isocyanates and hydroxyl groups that lead to the cre-
ation of a urethane group [16]. Polyurethane elastomers exist as 2-
component and 1-component binder systems. The 2-component
systems, which are usually used in engineering applications, con-
sist of the components polyol and isocyanate.

In general, the hydraulic conductivity of any porous medium is


highly dependent on properties of the fluid and properties of the
porous medium, respectively, i. e. particle size distribution, particle
shape, void content and pore structure, and the viscosity of water
[17,18]. The drainage performance of a material can be evaluated
by the coefficient of permeability ks , which denotes the speed of
a given quantity of water flowing through a porous structure’s
cross section at a given hydraulic gradient.
As already shown in Renken et al. [10] and Törzs et al. [11], PU-
bound road surface material tends to very low capillary effects,
obviously comparable to a very coarse sand or fine gravel. The
occurrence of different pore types in open porous asphalts is
described by Lin [19], see Fig. 4. Since the drainage direction in
the specimen is downwards, the only option for a fluid is to drain
through type A pores or get stuck in type B pores. Stored water in
type B pores can not drain downwards even when the applied suc-
tion is increased. The larger the specimen height, the higher the
amount of type B pores and the residual water contents. Type C
pores are generally inaccessible for pore water. For the experi-
ments on the water-retention behaviour, a specimen height of
Fig. 2. Particle size distributions of unbound pavement materials of types A and B. 10 mm was chosen. This is based on the results presented in

Fig. 3. PU-bound pavement material from drill cores with a diameter of 50 mm and Fig. 4. Schematic drawing of different pore types after Lin [19] and drainage
a height of 10 mm (left) and unbound pavement material (right). direction.
T. Törzs et al. / Construction and Building Materials 212 (2019) 422–430 425

Renken et al. [10], a predicted low suction range, and high perme-
ability of the material in general. It is crucial to minimise the spec-
imen’s height because saturation Sr is a volume-related property
which highly varies over specimen height when in unsaturated
states. Thus, to derive a representative degree of saturation for a
specimen, it would not be sufficient to average the amount of
water in a much higher specimen. To take account of irregularities,
i. e. non-homogeneous pore distributions, three different speci-
mens for each mixture were tested three times each.

2.2. Working procedure of this research

The working procedure the research and this article is based on


is as follows:

1. Predict the water retention behaviour of PU-bound road surface


material with a model from the literature based on basic
geotechnical properties as an initial estimation.
2. Choose a method for measuring the water retention behaviour
in the soil mechanics laboratory based on the predicted suction Fig. 5. Predicted retention behaviour of polyurethane-bound surface materials of
range and needed accuracy. type A and B using the parameters from Table A.1 showing the influence of capillary
3. Determine the water retention behaviour of PU-bound road force and adhesion force on the saturation Sr .

surface material in the soil mechanics laboratory using an


appropriate method. In the scope of this paper only primary
drainage paths are considered. test setup of the hanging water column apparatus used in this
4. Determine the saturated conductivity of the specimens in labo- study is presented in Fig. 6.
ratory experiments. The test setup consists of a specimen base pedestal, a burette
5. Fit empirical models for the water retention behaviour and the with a scale (capacity: 10 ml, graduation divisions: 0.02 ml) to
saturated conductivity to the experimentally obtained data. measure the water outflow, and a suction supply (vacuum) system
6. Derive unsaturated hydraulic conductivities for water and air implemented using two water reservoirs at different elevations.
phases, respectively. The amount of water flowing in or out of the specimen can be read
from the burette connected to the specimen base pedestal, which is
2.3. Initial prediction of the water retention behaviour furthermore connected to the suction supply system. The burette is
placed horizontally at the same elevation as the bottom of the
This section aims at predicting the water retention behaviour of specimen, allowing to equate the applied vacuum with the suction
two compositions of PU-bound pavement material from its basic inside the specimen.
geotechnical properties using a model from the literature as an ini- This version of a hanging water column apparatus to measure
tial estimation. The prediction of the water retention behaviour of the suction-saturation relationship allows very accurate adjust-
water-permeable PU-bound surface layers using the approach pre- ments in the relative elevation of the water reservoirs and there
sented by Aubertin et al. [20] for soils based on their basic geotech- is no necessity of continuously adjusting the relative elevation of
nical properties is intended to give a first impression on the air the reservoirs in order to maintain a constant applied suction. Air
entry values (aev), the gradients of the retention curves and resid- diffusion in the burette, however, can affect the measurements of
ual states. Also, the results are intended to help in choosing an the water volume flowing in or out of the specimen [14], but was
appropriate method for the planned tests on the water retention neglected herein.
behaviour. Except for the geotechnical properties of the unbound In the beginning of the test, the two water reservoirs are held
grains, i. e. e; D10 ; D60 , and C U , the empirical standard parameters at the same relative elevation resulting in an applied vacuum of
applied by Aubertin et al. [20] have been used. The results in 0.0 kPa. The applied vacuum is identical to the suction s inside
Fig. 5 show the typical sigmoid curve including low air-entry val- the specimen. At this initial point, the water in the fully satu-
ues and a steep gradient. Different parts of the degree of saturation rated specimen and the water already in the tube should be in
Sc and Sa driven by capillary and adhesive forces, respectively, are equilibrium. When lowering one of the reservoirs, the difference
shown as well. Further information on the model and used equa- in the elevation results in an increasing vacuum in the system
tions can be found in Appendix A of this manuscript. which is directly applied to the water phase in the specimen
resulting in drainage of the water inside the specimen into the
2.4. Experimental investigations horizontal burette. The amount of drained water can be read
from the burette after reaching equilibrium, i. e. no water move-
2.4.1. Experimental investigations on the water retention behaviour ment is identifiable in the burette. The applied vacuum pressure
Alongside predicting the water retention behaviour of the PU- is read from an air pressure transducer (type: Kyowa PGM-02KG)
bound surface materials, additional experiments in the soil which is connected to the air system. Another air pressure trans-
mechanics laboratory at Hamburg University of Technology were ducer was used in a previously conducted functional test to ver-
carried out. The previously predicted low suction range between ify the functionality of the used transducer, which is presented in
fully saturated and residual states of the suction-saturation rela- Fig. 7. The unsteady fluctuation in the data results from the vac-
tionship helped to find a suitable laboratory testing method for uum pump used for the preliminary tests. However, good accu-
the determination of the primary drainage curve of the pavement racy in the reference and the suction transducer’s responding
materials. To accomplish accurate measurements in the low suc- qualities is given.
tion range the method of the hanging water column, as presented The investigated specimens are drill cores of PU-bound surface
in ASTM D6836-16 [21], was utilised. A schematic drawing of the materials with a diameter of 50 mm and a height of 10 mm. In
426 T. Törzs et al. / Construction and Building Materials 212 (2019) 422–430

Fig. 6. Schematic drawing of the hanging water column apparatus as proposed in the ASTM D6836-16 [21] in a slightly modified version.

Fig. 8. Specimen base pedestal with a fully saturated specimen of PU-bound surface
material (mixture A).
Fig. 7. Accuracy and functionality verification of air pressure transducers (Kyowa
Electronic Instruments Co., Ltd.).

2.4.2. Experimental investigations on the saturated conductivity


total, 18 tests were conducted: three specimens of mixture A and The saturated hydraulic conductivity was tested in vertical per-
mixture B were tested three times each. For each test, a specimen meability tests at RWTH Aachen University on specimens of the
is put on the specimen base pedestal and is drained through a same compositions as given in Table 1 and following the instruc-
microporous membrane with a pore diameter of 0:8 lm (Pall Corp., tions in DIN EN 12697-19 [25]. The coefficient of permeability ks
[22]) induced by the applied vacuum. The membrane is placed on in the vertical direction was determined by quantifying the water
top of a porous disk made from sintered metal enabling a dis- flow Q v (m3 =s) through specimens with a diameter of 100 mm and
tributed drainage over the specimen’s cross section. The mem- a height of 40 mm in a defined time at a constant effective hydro-
brane has a high air entry value to ensure that nothing but water static head of 300 mm. The corresponding vertical permeability
is drained from the specimen into the horizontal burette. The out- apparatus is shown in Fig. 9. The specimen heights correspond to
flown water volume is then read from the scale on the burette. To typical pavement thicknesses as used in road construction practice.
take into account slightly fluctuating porosities of the different
specimens, the outflown amount of water at the end of a test 2.5. Modelling of hydraulic properties
was used to derive the specific specimen’s effective porosity. The
functionality of the specimen base pedestal has been successfully When taking into account unsaturated states in numerical anal-
tested in numerous tests on the water retention behaviour of sands yses, the fundamental relationship between suction s and satura-
by Törzs [23] and Milatz et al. [24]. The specimen base pedestal tion Sr (in soil mechanics also referred to as soil-water
equipped with a fully saturated specimen before a test run is pre- characteristic curve, SWCC) is a key function on which a lot of
sented in Fig. 8. Throughout the experiments, a perforated cling research has been carried out [17]. This relationship has been used
film is placed above the specimen to minimise evaporation while for the estimation of the hydraulic conductivity, shear strength,
ensuring hydraulic contact to the atmospheric air phase. volume change, and aqueous diffusion functions of unsaturated
In this study, however, only the drainage behaviour beginning soils [26].
from fully saturated specimens was investigated. Any hysteretic To better understand the retention behaviour as well as the
effects in the water retention curve resulting from changes in the pore water and pore air flow in PU-bound pavement material,
flow direction due to changing weather conditions or dynamic the most commonly established models to describe the water
effects for example from repetitive tire loadings were not further retention behaviour of soils are used to fit the laboratory-
investigated herein. determined data for both materials. Further, saturated hydraulic
T. Törzs et al. / Construction and Building Materials 212 (2019) 422–430 427

the Kozeny-Carman model (KCM). Contrary to the Hazen model


based on the effective aggregate diameter d10 , the KCM integrates
the entire particle size distribution as well as void ratio and a shape
factor to achieve a prediction of ks . Thus, the accuracy of KCM
highly surpasses that of the Hazen model [33]. As a result, the
KCM is widely adopted for modelling the hydraulic conductivity
ks in porous material and pavements [34] and is given by Eqs. (5)
and (6):

cW 2 1 e3eff
ks;KCM ¼ D ð5Þ
lW C KC eff S2F 1 þ eeff
and
100 %
Deff ¼ X   ð6Þ
f i = D0:5 0:5
li Dsi
i

where f i denotes the fraction of particles between two adjacent


sieve sizes: Dl (larger sieve size) and Ds (smaller sieve size). Further,
lW denotes the viscosity of water, which is approximately
Fig. 9. Vertical permeability testing apparatus in accordance to DIN EN 12697-19
1  106 kPa s at 20  C, cW represents the unit weight of water, C KC
[25], see Lu et al. [8].
is the Kozeny-Carman empirical coefficient for which a value of 5
conductivity is determined utilising a widely used model. From is suggested, SF represents the shape factors of the aggregate: (a)
there, the unsaturated hydraulic conductivities for both phases, spherical grains: 6.0, (b) rounded grains: 6.1, (c) worn grains: 6.4,
water and air, are derived by another model. (d) sharp grains: 7.4 - 7.5 and (e) angular grains: 7.5 - 8.4. For the
investigated PU-bound surface material a shape factor of 7.4 (corre-
2.5.1. Water retention behaviour sponding to diabase) was selected.
Empirical models to describe the water retention behaviour of
soils were presented by Brooks and Corey [27], van Genuchten 2.5.3. Unsaturated hydraulic conductivities
[28], and Fredlund and Xing [29]. The corresponding formulations From the semi-empirical relationship firstly proposed by Brooks
given in Eqs. (1)–(3) were used to model the retention behaviour of and Corey [27], the partial permeability of the water phase kw can
the investigated materials. Furthermore, best fit analyses using be described as follows:
least squares were carried out to find the appropriate parameters
kw ¼ ks Sð2þ3k
e
p Þ=kp
ð7Þ
for the different models. For the determination of parameter mVG
in Eq. (2) the simplified approach by Mualem [30] was used, i. e. In Eq. (7), ks denotes the coefficient of permeability at satura-
mVG ¼ 1  1=nVG . tion of porous media, Se represents the effective degree of water
 saturation and kp gives the value of pore-size distribution index
Sr;max for s 6 saev
Se ðsÞ ¼ ð1Þ determined as the average gradient of the retention curve in this
ðaBC sÞnBC for s > saev research. Similarly, the partial permeability of the air phase ka
can be calculated by Eq. (8):
1  
Se ð s Þ ¼  m ð2Þ ka ¼ ks ð1  Se Þ2 1  Sð2þkp Þ=kp
ð8Þ
1 þ ðaVG sÞnVG VG e

1
Se ð s Þ ¼  h  nFX imFX ð3Þ 3. Results and discussion
ln e þ asFX
3.1. Water retention behaviour
Eq. (4) allows the conversion from the normalised or effective
saturation Se to the actual saturation Sr , which is mainly used in The compiled results from several test runs on the suction-
this study. saturation relationship of the PU-bound surface materials of type
Sr ¼ Se ðSr;max  Sr;res Þ þ Sr;res ð4Þ A and B are presented in Fig. 10. The air entry values of mixtures
A and B are located between 0 kPa and 0.1 kPa. The average gradi-
ent of the data points can be taken from linear regression line fits
2.5.2. Saturated hydraulic conductivity given in the legends of the corresponding datasets. The quick drai-
Pore structure characteristics are usually adopted for the esti- nage of the pavement materials is indicated by the gradient of the
mation of the saturated and unsaturated hydraulic conductivity, curve. A higher gradient corresponds to a quicker drainage. Fur-
also referred to as the coefficient of permeability in porous media. ther, the application of the most common hydraulic models for
The most common relationships are established based on pore fac- the description of the suction-saturation relationship from the lit-
tors in terms of particle size distribution or measured pore indices erature was feasible even for this very low suction ranges. The fit-
[31]. Due to the high complexity in measuring different pore ted curves and corresponding parameters are presented in Fig. 10
indices regarding to pore structure, pore shape factor and tortuos- and Table 2 respectively.
ity, models are mostly constructed on varied types of assumptions,
while models integrated from the particle size distribution present 3.2. Saturated conductivity
more empirical and convenient results [32]. Two famous
approaches for predicting the saturated hydraulic conductivity ks The results from the laboratory tests (Section 2.4.2) as well as
based on the particle size distribution are the Hazen model and results from modelling the saturated hydraulic conductivity
428 T. Törzs et al. / Construction and Building Materials 212 (2019) 422–430

Fig. 11. Saturated permeabilities ks in PU-bound pavements of mixture A (light


grey) and mixture B (dark grey). The permeabilities from laboratory tests are
compared to the modelled permeabilities.

3.3. Unsaturated hydraulic conductivity

Fig. 10. Retention data of PU-bound surface material from tests with the hanging Based on the unsaturated permeability model (Section 2.5.3),
water column and fitted models from the literature.
the pore water and pore air flow in PU-bound pavement surface
can be characterised. The unsaturated hydraulic conductivities of
water kw and air ka were modelled from the laboratory data as well
as simulated from the models presented in Sections 2.5.1 and 2.5.2.
(Section 2.5.2) are shown in Fig. 11. Laboratory determined mean
As shown in Fig. 12, the development of simulated permeabilities
coefficients of permeability at saturation are ks;A ¼ 5:25  103
fits almost well to those using reference parameters. The reference
m=s and ks;B ¼ 3:67  103 m=s for specimen of type A and B, respec- parameters were derived from the experimentally obtained satu-
tively. From a geotechnical point of view and corresponding to DIN rated permeabilities and retention data of PU-bound pavement
18130-1 [35] both can be categorised as ”highly permeable”. This is specimens investigated in the soil mechanics laboratory. This
in good agreement with the requirements for water-permeable applies for mixture A and B, respectively. However, minor devia-
road constructions given in FGSV [15], where ks P 5:4  105 m=s tions resulting from the slight deviations between tested and mod-
is demanded. Modelled mean coefficients of permeability at satu- elled saturated hydraulic conductivities (DA and DB in Section 3.2)
ration are ks;KCM;A ¼ 6:06  103 m=s and ks;KCM;B ¼ 4:61  103 m=s, are visible. In general, the coefficient of permeability of pore water
respectively. Reasonably good agreement between tested and kw increases with the degree of saturation Sr , while that of pore air
modelled behaviour becomes evident. However, the modelled per- ka decreases. During vertical saturation processes the effective void
meabilities are slightly higher (DA ¼ 0:81  103 m=s
and content can quickly be filled by infiltrating water, while the avail-
3 able air is squeezed out. With increasing degree of saturation in the
DB ¼ 0:94  10 m=s) but therefore in line with the trend. This
porous structure, more pore water flow can be detected, whereas
slight deviation might be based on the fact that the Kozeny-
the flow of pore air dissipates quickly. The results were also consis-
Carman equation was initially formulated for unbound granular
tent with the aforementioned experimental saturated permeability
materials.
tests on PU-bound pavement specimens, wherein a steady vertical
outflow velocity was achieved averagely after 15 s of infiltration.

Table 2
Hydraulic Parameters for the models by Brooks & Corey, van Genuchten and Fredlund 4. Conclusion
& Xing for mixtures A and B, see Fig. 10. In the calculation of the degree of saturation
Sr with Eq. (4), the residual saturation Sr;res has been set to the minimum saturation The hydraulic performance of polyurethane-bound road pave-
value from the conducted experiments. Sr;max was set to 1.
ment material as it is used in water permeable road constructions
Hydraulic model Parameter Unit Mixture was investigated. The suction-saturation relationship of this mate-
A B rial is a vital property and of major interest when investigating
Brooks & Corey aBC 1=kPa 5.656 4.945 unsaturated states in numerical analyses. The goal of this study
nBC – 3.460 3.582 was to give insights into the hydraulic properties, i. e. the
Van Genuchten aVG 1=kPa 4.792 4.255
suction-saturation relationship, from an initial prediction to labo-
nVG – 5.526 5.546 ratory experiments up to the expression of this relationship with
mVG – 0.819 0.820 empirical models. Additionally, models for the determination of
Fredlund & Xing aFX kPa 0.746 0.315 the hydraulic conductivities in saturated as well as unsaturated
nFX – 3.208 4.711 states were successfully applied.
mFX – 90.414 4.973 The presented results show that the water retention behaviour
and the corresponding air entry values of PU-bound pavement
T. Törzs et al. / Construction and Building Materials 212 (2019) 422–430 429

Fig. 12. Unsaturated permeabilities of pore water kw and pore air ka in PU-bound pavement type mixture A (left) and mixture B (right) as a function of Sr . The permeabilities
derived from laboratory data are compared to the modelled permeabilities.

material are very low and seem to be negligible. However, the water at 20  C; a is a shape factor varying from 6 to 18, and e is the
investigated properties might influence the hydraulic performance, void ratio. DH is taken from Eq. (A.2) by Aubertin et al. [36,20]:
i. e. drainage behaviour, of a real road structure. The observed
DH ¼ ½1 þ 1:7 log ðC U ÞD10  ðA:2Þ
instantaneous desaturation induced by small changes in air pres-
sure, e. g. induced by passing vehicles, could result in high satura- wherein C U ¼ D60 =D10 is the coefficient of uniformity wherein again
tion changes in a pavement under real load scenarios. Further, D60 and D10 are the diameters corresponding to 60 % and 10 % of
driving comfort and safety could be affected by surface spray dur- passing particles on the particle size distribution, respectively, see
ing rain events depending on the degree of saturation Sr . Noise Fig. 2.
reduction effects of porous pavements might be influenced by Kovács [37] describes that the main driving forces in a porous
the water retention behaviour, especially the degree of saturation medium to retain water are capillary forces, resulting in capillary
Sr , as well. This, however, still needs to be assessed in future saturation Sc , and adhesive forces, resulting in saturation by adhe-
research. sion Sa , leading to the following Eq. (A.3) for the degree of satura-
tion Sr .
Acknowledgements h
Sr ¼ ¼ Sc þ ð1  h1  Sa iÞð1  Sc Þ ðA:3Þ
n
This work was supported by the German Research Foundation
(Deutsche Forschungsgemeinschaft, DFG) as part of project Nos. wherein h i are Macaulay brackets. The parts of the degree of sat-
GR1024/25-1 and OE514/4-1. The support is greatly uration resulting from capillary and adhesive forces as functions of
acknowledged. the capillary height h and the current matric suction s are shown in
Eqs. (A.4) and (A.5):
" 2 #m "  2 #
Appendix A. Utilised equations from the Aubertin model to h h
Sc ¼ 1  exp m ðA:4Þ
predict the SWCC s s

Originally, the model by Aubertin [20] is capable of predicting h2=3


the water retention behaviour for granular and for plastic cohesive Sa ¼ ac C s s
 1=6 ðA:5Þ
soils for the case of drying. In agreement to the particle size distri- e1=3 s
sn
butions of the unbound materials, the formulas corresponding to
granular soils are presented subsequently. The model calculates with
the equivalent capillary rise above the water table derived from  
an expression for capillary rise in tubes with a given diameter. Cap- ln 1 þ sres
s

illary rise in a granular soil is calculated by Eq. (A.1): Cs ¼ 1    ðA:6Þ


ln 1 þ ssres0
rw cos bw a
h¼ ðA:1Þ
cw e DH wherein e is Euler’s number, m and ac are model parameters, and sn
is a normalisation parameter. The parameter C s is given by Fredlund
where rw is the surface tension of water at 20  C; bw is the contact and Xing [29] and forces the water content to zero at a suction s of
angle between water and the tube surface, cw is the unit weight of 106 kPa. The suction sres is the residual suction described by the fol-
430 T. Törzs et al. / Construction and Building Materials 212 (2019) 422–430

Table A.1 6th Asia-Pacific Conference on Unsaturated Soils (AP-UNSAT 2015), 2015, pp.
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