100 题目 comments

12.
NaClO3 target <10 g/l

13. Feed brine: 300~310g/l，return brine :200+/-10g/l。

19. In normal operation, what is H2 and Cl2 pressure, and differential pressure?

Cl2 pressure：350 mmH2O (35mbar)

H2 pressure：850 mmH2O (85mbar)

Differential pressure: H2 pressure 500 mmH2O (50mbar) higher than Cl2 pressure.

20. What is the quantity of CA9 bipolar element / electrolyzer? How many electrolyzer?
113 pcs elements /electrolyzer, 2 sets electrolyzer in total.

21. What is the effective area for CA9 membrane? What is the current for full load at initial start
up and maximum design current?
Membrane effective area is 3.276m2, full load at initial is 19.2kA and maximum design 19.7kA.

22. What is the CA9 electrolyzer product and the maximum capacity?

Cl2：132.3 MTPD as 100% Cl2

H2：3.8 MTPD as 100% H2

NaOH ： 150 MTPYD as 100%NaOH

23. H2 in Cl2 < 0.2%

25. List the increasing production procedure.

(1) Increase flow rate of feed brine and demi water to NaOH accordingly.

(2) Increase the current as speed 0.3~1kA/min and check overflow keep normal.

(3) Adjust the temperature of NaOH out of electrolyzer accordingly.

(4) Always keep differential pressure 500mmH2O (50mbar).

25. List the decreasing production procedure.

(1) Decrease the current as speed 0.3~1kA/min and check overflow keep normal.

(2) Decrease flow rate of feed brine and demi water to NaOH accordingly.

(3) Adjust the temperature of NaOH out of electrolyzer accordingly.

(4) Always keep differential pressure 500mmH2O (50mbar).

29. Which situation will trip the interlock to shut down the rectifier in Cell Room?

-Feed brine flow rate LL for more than 90 S

-NaOH circulation flow rate LL for more than 300 S

- Elements voltage HH or Deviation H (6 elements in one group)

- Instrument air pressure LL

- H2/Cl2 differential pressure HH or LL

- Cl2 pressure HH

30. What interlock action will automatically happen when interlock rectifier stopped?

- N2 on-off valve at end of outlet manifold both anode and cathode open to start N2 purge.

- Polar rectifiers switch on

- N2 on- off valve at end of H2 header piping will open to start N2 purge.

- HCl injection to anolyte tank stops

- Demineralized water to NaOH stops

- Steam to NaOH heating stops

- Control valve of Cl2 gas to product close, to hypo open.

- Control valve of H2 to product close.

31. Procedure for filling electrolyzer after assembly.

(1) Open manual valves to H2 off gas and Cl2 off gas

(2) Connect the portable humidifier seal pot to supply N2 to H2 side, keep anode about
0mmH2O and cathode side about 500mmH2O.

(3) Check NaOH and feed brine within specification.

(4) Filling 26~32% NaOH to cathode side, after 3mins filling anode side with 200g/l brine
(diluted with demi. water to electrolyzer).
Open and adjust the gas sampling valve if pressure high during filling.

(5) Check all elements overflow in about 30 minutes.

(6) Disconnect portable humidifier seal pot. Open XV-1, XV-2 starting N2 purge at end of outlet
manifold.

(7) Chang the feed brine and NaOH circulation flow rate per operation manual flow chart.

38, 39

Fail Open (FO): cooling water for NaOH cooling, Cl2 off gas to hypo

Fail Close (FC): feed brine, feed NaOH, recycle brine, HCl to anolyte tank,
anolyte/catholyte/individual catholyte level control, Demi water to NaOH, Steam for NaOH
heating, Cl2 to product, H2 to product, H2 off gas to vent, N2 purge.

51. Purpose of tightness test for electrolyzer and test pressure.

To check the tightness of all elements flanges, piping flanges and all connections between
electrolyzer and the first the manual valves.

Pressure keeps 20kPaG at both anode and cathode, pouring soapy water over all connections
visually check for leakage.

52. How to do membrane pinhole test?

(1) After membrane installed, keep 200mmH2O for cathode by pressure regulator with
200mmH2O seal pot.

(2) Use manometer connecting outlet nozzle of anode side for 30s and if reading rising, try
3minutes. If increase more than 30mm in 3mintues, consider replace the membrane.
87. Procedure for maintenance (drain electrolyzer for disassembly)

(1) Purging free Cl2 in anolyte with polar rectifier on about 90 minutes (free Cl2<20ppm). Switch
off polar rectifier after purging.

(2) Cooling the electrolyzer <45 degree-C.

(3) Diluted brine 200g/l feeding to electrolyzer at least 1 hour. NaOH keep circulation.

(4) Stop N2 purge via XV-1, XV-2 to outlet manifold. Open Cl2 sampling (S1, S2). Cl2 gas to off gas
valve open, H2 gas to off gas valve open.

(5) Connect portable humidifier seal pot and keep H2 pressure 500mmH2O

(6) Drain anolyte first, after 5mins to drain catholyte.

(7) Filling 3% NaOH to cathode side, 3mins later start filling DW to anode side per operation
manual flow chart.

(8) After over flow, drain anode side first, 5mins later, drain cathode side

91. N2 purging for Cl2 after rectifier shut down.

Each electrolzyer set N2 on-off valve XV-1 for purging at end of anode outlet manifold, it will
purge via PV-2011 to hypo unit. If need additional air suction, one manual valve can be open at
end of Cl2 header piping.

92. N2 purging for H2 after rectifier shut down.

Each electrolzyer set N2 on-off valve XV-1 for purging at end of cathode outlet manifold, also on-
off valve XV-2001 at end of H2 header piping, which will purge to vent stack.