Department of Chemistry

University of Bahrain
Chemy 332 – practical physical – Data sheet

Exp no. 1: Date :____

The Acid – Catalyzed Iodination of Acetone:

Preparation of solutions: (show calculations):

Aim:

Preparation of solutions: (show calculations):

1.Preparation of 250 mL 0.010 M Na2S2O3 from the stock solution of 0.1 M

solution

2.Preparation of 0.4 M NaAc [CH3COONa] in 250 mL volumetric flask

 DATA 1 SEC :1

Data: Record volumes according to the specified timing in each run.

A (10 mL 1 M HCl) B (20 mL 1 M HCl)

Time (min) Volume of Na2S2O3 Time (min) Volume of Na2S2O3

for the specified for the specified
intervals of time intervals of time

(mL) (mL)

10.0 23.0 6.0 14.5

20.0 21.0 12.0 13.9

30.0 19.5 18.0 13.0

40.0 19.2 24.0 12.8

50.0 16.5 30.0 11.5

60.0 14.0 36.0 8.5

RUN A
Time (min) V S2O32- Mole of Mole of I2 = [I2]=
𝒎𝒐𝒍𝒆 𝒐𝒇𝑺𝟐𝑶𝟑𝟐 − 𝒎𝒐𝒍𝒆 𝒐𝒇 𝑰𝟐.
(L) S2O32- 𝟐 𝑽
VxM
NOTE : Same calculation for B,C,D

Data: Record volumes according to the specified timing in each run.

C (5 mL 1 M Cl2CHCOOH) D (10 mL 1 M Cl2CHCOOH)

Time (min) Volume of Na2S2O3 Time (min) Volume of Na2S2O3

for the specified for the specified
intervals of time intervals of time

(mL) (mL)

10.0 15.6 6.0 21.5

20.0 14.0 12.0 17.5

30.0 14.2 18.0 15.5

40.0 13.8 24.0 12.0

50.0 12.0 30.0 11.5

60.0 11.5 36.0 8.0

NOTE : Plot graph between [I2] and time for A, B, C, D and find
out slope . Slope= Kobs
 Sample graph Mention graph title, Axis title, unit

Calculation catalytic constant

RUN A To calculate KH1 +
1. Kobs = slope of the graph
2. Vol .of HCl = 10 mL
3. Molarity of HCl = 1M
4. [H+] in 100 mL =
5. Kobs = KH1+ [H+]
6. KH1+ =

RUN B To calculate KH2 +

1. Kobs = slope of the graph
2. Vol .of HCl = 20 mL
3. Molarity of HCl = 1M
 4. [H+] in 100 mL =
5. Kobs = KH2+ [H+]
6. KH2+ =

KH+ = KH1+ + KH2+

RUN C To calculate KHA1 +.

Note Cl2CHCOOH is weak acid represented as HA

1. Kobs = slope

2. Vol. of HA = 5 mL

3. Molarity of HA = 1M

4. [HA] in 100 mL. = 1M x 5/100 = 0.05 M

5. Ka for [HA] = 0.055

HA ⇌ H+ +A–

0.05 -𝛼. ⇌ 𝛼. 𝛼
["#][%&] ' )'
Ka = = use quadratic equation and solve
["%] *.*,&'

6. 𝛼 = [H+] = [A-]
7. [𝐻𝐴] = 0.05 - 𝛼
8. K obs =. KH+ [H+] + KHA1 [HA]
- ./0 & -1# [1#]
9. KHA1. =
["#]

RUN D To calculate KHA2 +.

Note Cl2CHCOOH is weak acid represented as HA

1. Kobs = slope

2. Vol. of HA = 10 mL

3. Molarity of HA = 1M

4. [HA] in 100 mL. = 1M x 10/100 = 0.1 M

5. Ka for [HA] = 0.055

HA ⇌ H+ +A–

0.1 -𝛼. ⇌ 𝛼. 𝛼
["#][%&] ' )'
Ka = = use quadratic equation and solve
["%] *.2&'

6. 𝛼 = [H+] = [A-]
7. [𝐻𝐴] = 0.1 - 𝛼
8. K obs =. KH+ [H+] + KHA2 [HA]
- ./0 & -1# [1#]
9. KHA2. =
["#]

3"%2#3"%4
KHA =
4

Discussion

Conclusion

Sources of Error

Mention how to avoid the Errors

Reference