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An overview: Natural fiber reinforced hybrid composites, chemical treatments


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Article  in  Materials Today: Proceedings · January 2020


DOI: 10.1016/j.matpr.2020.01.011

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Materials Today: Proceedings xxx (xxxx) xxx

Contents lists available at ScienceDirect

Materials Today: Proceedings


journal homepage: www.elsevier.com/locate/matpr

An overview: Natural fiber reinforced hybrid composites, chemical


treatments and application areas
N. Karthi a,⇑, K. Kumaresan b, S. Sathish a, S. Gokulkumar a, L. Prabhu a, N. Vigneshkumar c
a
Department of Mechanical Engineering, KPR Institute of Engineering and Technology, Coimbatore 641407, India
b
Park College of Engineering and Technology, Coimbatore 641659, India
c
Department of Agriculture Engineering, Sri Shakthi Institute of Engineering and Technology, Coimbatore 641608, India

a r t i c l e i n f o a b s t r a c t

Article history: Application of natural fibre reinforced polymer composites (NFPC) in transportation diligences has
Received 9 August 2019 become inexorable due to light weight, superior properties, less cost of production and suitability to
Received in revised form 27 December 2019 many products. But the main disadvantages of employing these fibers are their poor dimensional stability
Accepted 1 January 2020
and high hydrophilic nature. Interfacial bonding between the fiber and matrix plays a vital role in decid-
Available online xxxx
ing the mechanical characteristics of composites. Various chemical cures are applied for enhancing the
fiber-matrix adhesion which ends up in better mechanical characteristics of the composites. The current
Keywords:
aerospace and automotive industries are looking to change the conventional materials which are high
Natural fibre
Chemical treatment
density material to composite material for reducing the overall weight of the vehicle to increase its per-
Hybrid composites formance. This review paper provides a vast overview on natural fiber reinforced composites, various
Mechanical properties chemical treatments applied and applications of those composites.
Applications Ó 2020 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International conference
on Materials and Manufacturing Methods.

1. Introduction properties of polymers are essentially insufficient for many struc-


tural and constructional purposes. In particular, their rigidity and
Ferrous and non-ferrous metals were used in earlier times to strength is much lower compared to metals and ceramics. Poly-
produce everything from nail to aircraft. Polymers were then mers are strengthened with natural / synthetic fibers on the basis
invented and conventional materials such as metals, for example of their strength properties to overcome these disadvantages.
switches, fasteners and structural components were replaced. Plas- The phase in continuous volume and present in a larger volume
tics are very easy to manufacture complicated components and is called the matrix. They provide composites with ductility and
weigh less than metal counterparts and are even more robust. toughness. Matrix plays an important role in some of the compos-
Because of the need for lightweight and robust materials, compos- ite’s mechanical properties, such as shear properties, compression
ite materials have been developed. A composite material can be and transverse modules. The physical and chemical properties of
defined as a macroscopic combination of two or more matrix and the matrix, such as curing temperature, time, viscosity and fiber
reinforcement materials with enhanced properties than individual bonding behavior, influence the choice of the manufacturing
materials used alone. Composite materials are usually produced by method.
the three most important materials, such as polymers, metals and The matrix in the composites serves the following purpose,
ceramics. The purpose of using composites in different fields is to
increase strength, reduce weight and fulfill the specific properties  To bond the fibers together and transfer the applied loads
of applications. The matrix material may be polymers, metals or between them
ceramics.  To hold the fibers in the desired orientation and location
Polymers are mainly hydrogen, carbon and other non-metallic  To protect the reinforcement from an adverse environmental
elements based organic elements. The physical and mechanical damage like temperature, humidity, chemicals and mechanical
degradation usually by abrasion
⇑ Corresponding author.  Carry interlaminar shear
E-mail address: karthimli@gmail.com (N. Karthi).  Improves transverse properties of composite

https://doi.org/10.1016/j.matpr.2020.01.011
2214-7853/Ó 2020 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International conference on Materials and Manufacturing Methods.

Please cite this article as: N. Karthi, K. Kumaresan, S. Sathish et al., An overview: Natural fiber reinforced hybrid composites, chemical treatments and
application areas, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2020.01.011
2 N. Karthi et al. / Materials Today: Proceedings xxx (xxxx) xxx

 Improves impact and fracture resistance of composite Table 1 shows the comparison between natural and glass Fibers
[1].
The needs or desired properties of the matrix which are impor- Natural fibers are classified into different types based on their
tant for a composite are as follows, origins such as cotton, pulp, bark, wood, nut shells, corncobs, bam-
boo, bagasse and vegetables. These natural fibers are mainly com-
 Low shrinkage posed of cellulose, hemicelluloses, pectin’s, lignin and small
 Dimensional stability quantity of extractives. Fig. 1 shows the structural organizations
 Better chemical resistance of the three major constituents in the fiber cell wall. Fig. 2 shows
 Low coefficient of thermal expansion classification of natural fibers.
 Reduced moisture absorption Natural fibers provide many advantages over synthetic fibers
 Strength at elevated temperature are easily availability and low cost, recyclability, renewability,
 Must be elastic to transfer load to fiber biodegradability, low density, desirable aspect ratio and moderate
 Excellent flow characteristics so that it penetrates the fiber bun- strength. Table 2 shows the physical and mechanical Properties of
dles completely and eliminate voids during the compacting various natural fibers. The natural fiber composites can be cost
process effective material especially automobile body panels, interiors,
 Should be easily processable into final composite shape storage devices, building and industrial panels, partition boards
and false ceilings. Aircraft wings and wind turbine blades are con-
Among the various materials that can be developed, plastics stantly pushing the limits on size and requiring advanced materi-
holds major share as wood substitutes. Plastics are almost used als, designs and fabrication techniques. In the further days,
in all fields from home appliances to complicated engineering com- composites will utilize processed fiber and resin, fillers incorpo-
ponents. But the plastics are non-renewable and non- rated materials. The research activities will be refined to use
biodegradable. Due to daily price hike and crisis of petroleum- improved materials and steps to fabricate them into products.
based materials, there is a need to use suitable alternatives to con-
cern an environmentally friendly.
2. Overview of natural fiber reinforced hybrid polymer
The enhancement in mechanical and thermal properties of fab-
composite
ricated polymer composites depends on the following factors are
Hybrid composites are the combination of two or more rein-
 Type of fiber
forced elements in single matrix or a mixture of different matrices
 Type of matrix
merged with a single reinforcing element. The physical and
 Type of fillers (if used)
mechanical properties of the hybrid composites is dependent on
 Percentage of fibers in the composites
the aspect ratio of fiber, properties of individual fiber, orientation
 Aspect ratio and orientation of fiber
of fiber, length of individual fiber, adhesion between fiber and
 Shape of the fiber (which may be cylindrical, spherical or rect-
matrix and stacking sequence of both fibers [2]. The properties of
angular cross sectioned prisms or platelets)
the hybrid composites of two elements can be estimated through
 Manufacturing method/techniques
the rule of mixtures [3] as shown in Eqs. (1) and (2).

Issues such as biodegradability and recyclability are vital role in PH ¼ P1 V1 þ P2 V2 ð1Þ


the introduction of materials and products. Natural fibers have a
number of techno economic and ecological advantages over syn- V1 þ V2 ¼ 1 ð2Þ
thetic fibers. Table 1 shows the comparison between natural and
glass fibers. Where, PH is the property to be analyzed, P1 the corresponding
Synthetic fibers like carbon and glass fibers are widely used as property of the first element and P2 the corresponding property of
reinforcement materials, but their non-bio degradability and the second element. V1 and V2 are the volume fraction of first and
non-recyclability becomes a significant drawback at the end of second element respectively. Most of the investigation on natural
their lifetime. During processing, they are also found to hazardous fibers reinforced hybrid composite involves studies of strength
to health. In recent days, research and development interest has property as function of fiber loading, length of fiber, fiber disper-
been shifting from monolithic materials to natural fiber reinforced
composites. Carbon dioxide neutrality of plant fibers is mostly fas-
cinating. The combustion of elements derived from petroleum-
based products releases enormous quantities of carbon dioxide
into the environment, which is believed to be the root cause of
the greenhouse effect and, by extension, the global climate change.

Table 1
Comparison between Natural and Glass Fibers [1]

S. No Natural fiber Glass fiber


1 Density Low
2 Cost Low
3 Renewability Yes
4 Recyclability Yes
5 Energy consumption Low
6 Distribution Wide
7 CO2 neutral Yes
8 Abrasion to machines No
9 Health risk No
Fig. 1. Structural Organizations of the Three Major Constituents in the Fiber Cell
10 Biodegradability Yes
Wall.

Please cite this article as: N. Karthi, K. Kumaresan, S. Sathish et al., An overview: Natural fiber reinforced hybrid composites, chemical treatments and
application areas, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2020.01.011
N. Karthi et al. / Materials Today: Proceedings xxx (xxxx) xxx 3

Fig. 2. Classification of Natural Fibers.

sion, fiber orientation, stacking sequence of fiber arrangements, mechanical properties of the composite were found for longitudi-
effect of various chemical treatments of fibers, use of coupling nal direction rather than transverse direction. The interfacial
agents, matrix selection and fiber/matrix interaction. strength between natural fiber and rubber matrix was found to
The mechanical properties of sisal/oil palm fiber reinforced nat- increase on alkali treatment of fibers. Therefore, the alkali treated
ural rubber hybrid composites as function of fiber loading, ratio fibers exhibited maximum tensile strength than untreated fiber
and chemical treatment had investigated [4]. The maximum composites.

Please cite this article as: N. Karthi, K. Kumaresan, S. Sathish et al., An overview: Natural fiber reinforced hybrid composites, chemical treatments and
application areas, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2020.01.011
4 N. Karthi et al. / Materials Today: Proceedings xxx (xxxx) xxx

Table 2
Physical and Mechanical Properties of Natural Fibers.

Fiber type Density (g/cm2) Tensile strength (MPa) Specific strength (MPa) Youngs modulus (GPa) Specific modulus (GPa) Elongation (%) Specific gravity
Bast Fibers surrounds the central core of plant
Flax 1.4 340–1600 535–1000 25–81 16.7–54 1.1–3.3 1.5
Hemp 1.48 550–900 372–608 70 – 0.8–3 1.5
Remie 1.5 200–1000 147–625 41–130 27–81 1.5–4 1.6
Kenaf 1.2 223–1191 641 11–60 10–42.9 1.6–4.3 1.3
Jute 1.46 385–850 269–548 9–31 6.9–20.7 1.4–2.1 1.3–1.5
Leaf Fibers extracted from the leaf of plant
Sisal 1.33 400–700 366–441 8.5–40 6.5–30.8 1.9–15 1.3
Abacca 1.5 980 – – – – –
Fruit Fiber collected from the fruits
Coir 1.25 170–230 146 3.0–7.0 2.5–5.0 14–30 1.2–1.4
Banana 1.35 711–789 444 4.0–32.7 3.6–27.3 2.4–3.5 1.1–1.2
Betelnut 0.2–0.4 120–166 – 1.3–2.6 1.0–1.9 22–24 1.3–1.4
Stalk Fibers collected from the stake of plant
Wheat 1.45 – – – – – –
Grass Fibers are sclerenchyma elongated cells that occurs in various parts of plants
Elephant 0.817 185 – 7.4 – 3 –
Sea 1.5 453–692 – 3.1–3.7 – 13–26.6 –
Cane Natural fiber obtained from fiber rich parts of the plants
Bagasse 1.5 170–350 – 5.1–6.2 3.6–4.1 6.3–7.9 1.4–1.5
Bamboo 1.1 500–575 454 27–40 50–67.9 1.9–3.2 0.4–0.8

The hybrid composites prepared with three different fibers such The effect of stacking sequence on tensile and flexural proper-
as sisal, jute and glass with epoxy resin with weight ratio of fiber to ties of luffa cylindrica and glass fiber reinforced epoxy-based
matrix as 30:70. Different combination of composites was fabri- hybrid composites investigated. All composite samples were made
cated to the ASTM standard and tested for mechanical properties with a total of four plies by varying the number and position of
such as tensile and impact strength. The maximum tensile and glass fiber. From the results, it was found that the maximum ten-
impact strength were found for sisal/glass/epoxy hybrid composite sile and flexural strength are obtained from hybrid composite by
compared to other combinations [5]. placing of two luffa cylindric fiber mats at the middle when sup-
The small amount of glass fiber in silk fabric reinforced epoxy ported by two glass fiber mats on either side [11].
composites and has been analyzed by mechanical properties. The The production and mechanical properties of composites from
addition of small content of glass fabric to the silk fiber reinforced natural and man-made fibers such as hemp, kenaf, lyocell and cot-
composites enhanced the mechanical properties. The results ton were described. Tensile strength, impact strength and elonga-
showed that the mechanical properties increased with increase tion at break were improved significantly compared to lyocell/PLA
in weight fraction of fiber content to the maximum extent. They composites by using a combination of lyocell and hemp [12].
also found that the water absorption of composites decreased by
the process of hybridization [6].
The tensile and flexural strength of sisal and glass fibers rein- 3. Treatment by chemical agents
forced unsaturated polyester hybrid composites were studied as
a function of fiber content [7]. They noticed that the tensile and Natural fibers inherently possess high amount moisture and
flexural strength of sisal/glass fibers reinforced hybrid composite more water absorption capability. This ends up in poor interface
was higher than sisal fiber reinforced composite, but lower than between the matrix and reinforcement. To convert the fibers into
the glass fiber reinforced composite. hydrophobic from hydrophilic nature, chemical treatment of fibers
In the evaluation of physical, mechanical and dynamic mechan- is necessary. There are many chemical treatments available in that
ical properties of glass/ramie fibers reinforced polyester hybrid best chemical treatment is finding out based upon the environ-
composites were fabricated by resin transfer moulding as function mental aspects and cost factor.
of fiber content [8]. The impact and interlaminar shear strength of The main drawbacks of using bio fibers are their poor dimen-
the composites were improved by using higher fiber content. The sional stability and its moisture absorption level getting increase
high interfacial strength between fiber and matrix was observed from the environment which leads to poor adhesion with matrix
during the SEM analysis. materials. The lignocellulosic natural fibers are composed of cellu-
The luffa fiber and ground nut reinforced epoxy hybrid compos- lose, hemicelluloses, lignin, pectin and waxy elements. Cellulose is
ites prepared by hand lay-up techniques as function of volume the main element of the bio fiber configuration which provides
fraction of fiber. They found that composites with 40% treated fiber high strength, stiffness and structural stability of the fiber [13].
content exhibited maximum mechanical properties than luffa Fig. 1 shows structural organization of the three major constituents
groundnut polymer composites with 30% and 50% fiber contents. in the fiber cell wall.
The lowest strength was found at 50% fiber content due to insuffi- Lignin and pectin are linked with cellulose-hemicellulose chain
cient wetting between fiber and the matrix [9]. and provides the bonding quality to hold the molecules together.
Tensile test on oil palm empty fruit bunches/jute fibers rein- This bonding quality is the cause for strength properties of the fiber
forced epoxy matrix hybrid composites has been conducted. Signif- [14].
icant improvement in tensile strength and modulus of the oil palm The main problems with the use of natural fiber composites
empty fruit bunches/jute fiber hybrid composites were observed stem from the hydrophilic nature of the matrix’s fiber and
while compare to oil palm empty fruit bunches fibers alone used. hydrophobic nature. The fiber-matrix interfaces are chemically
Finally, the hybrid composites showed excellent adhesion to combined in the reaction zone. The adhesion between fiber and
matrix than pure oil palm empty fruit bunches fiber composite matrix plays a major part to improve the mechanical properties
during SEM analysis [10]. of the composites. Poor adhesion across the reaction zone which

Please cite this article as: N. Karthi, K. Kumaresan, S. Sathish et al., An overview: Natural fiber reinforced hybrid composites, chemical treatments and
application areas, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2020.01.011
N. Karthi et al. / Materials Today: Proceedings xxx (xxxx) xxx 5

leads to relative weak dispersion of load occurs and results in less applications because of its high mechanical properties and less cost
mechanical properties [15]. [27-34].
The connections between fibers and matrix are challenging and Products made of bio fibers have been increased and used in
the chemical structures of both are different, which cause ineffec- window frame, decking, dashboards, parcel shelves, door panels,
tive load transfer across the composite interface region. Due to the seat cushions, backrests and cabin linings. The using of natural
presence of hydrophilic hydroxyl groups in natural fibres, compat- fiber over petroleum based fiber have been increased in various
ibility with the matrix is reduced. In order to improve the interface industries like automotive, aerospace, marine, electrical and elec-
connection between fibers and matrix, the outer surface of fibers tronics, sports, recreation equipments and machinery office equip-
and hydroxyl groups must be changed with different chemical ments due to light weight, recyclability, biodegradability, low
treatments, couplers and reactive fillers. Chemical treatments processing cost, good relative mechanical properties and resistance
expose more reactive groups across the fiber surface and provide to corrosion and fatigue [22].
an efficient matrix coupling [16]. The effect of chemical treatments on the mechanical and ther-
The functional mechanisms of coupling in materials are follow- mal properties of the natural fibers reinforced thermoplastic and
ing namely (a) Elimination of weak outer boundary layers (b) pro- thermoset composites has addressed and demonstrated the appli-
duction of thin and flexible layer (c) formation of cross linked inter cations of Natural Fiber Composites (NFC) in automobile and con-
phase compression region with a modulus intermediate between struction industries [35]. It was found that, the physical and
the substrate and the polymer (d) improvement in wettability mechanical properties of NFC can be further improved through
between matrix and substrate (e) development of covalent bonds the surface modification, while moisture absorption of the NFC
with both phases and (f) alteration of the substrate surface. The can be reduced through chemical treatment on fibers such as alka-
main objective of surface treatments on bio fibers is to maximize lization with addition of curing agents. Volkswagen company used
the interfacial strength between reinforcement and matrix so as natural fibers to make boot lid finish panel, seatback, boot liner and
the stress transferability in the composites. The influences of sur- door panel in passat variant, A4, golf and Bora model. Daimler Benz
face treatments on natural fibers that are used as reinforcement used natural fibers to develop the dashboards and centre armrest
in the composites are studied. The different chemical agents for consoles along with seat shells. Moreover, it increased the usage
the treatments include alkali, silane, acetylation, acrylation, of NFC in few automobiles by approximately 98% over earlier mod-
maleated coupling agent, benzoylation, permanganate, peroxide, els by using cellulose fibers, for example flax and abaca. Table 4.
isocynate, sodium chlorite and stearic acid. As a result, significant shoes applications of natural fibers in automobile field. As per
improvements in the strength properties of the composites can European guidelines 2000/53/EC provided by the European com-
be achieved through chemical treatment. mission, 85% of the weight of products especially automobiles
Hence it is perceived that there are problems like poor bonding had to be recyclable by 2005. This percentage of recyclable will
between fibers and matrix, and hydrophilic nature of the natural be increased to 95% by 2015. In order to face balancing sustainabil-
fibers, which limit their applications. A literature reveals that ity and cost, the automakers are invited to use bio fibers in com-
chemical treatment on natural fibers would lead to enhanced fiber posites [36].
matrix bonding, increase in the hydrophobicity, improved fiber Composites have become a prominent material for commercial
wetting, removal of hemi cellulose and lignin. Table 3 shows the aircrafts such as the Airbus A380 used 25% of composites and
effect of various chemical treatments on mechanical properties Boeing 787 ‘‘Dreamliner” used 50% of composites while A350
[17-26]. used 53%. Weight reduction in composites is crucial factor for
improving fuel efficiency [37]. The development of natural fibers
4. Applications of natural fiber composite reinforced composites in aircrafts reduces the overall weight of
the aircraft by 35%. The E-class Mercedes Benz introduced the
NFPC can replace glass in various applications in which the load first NFRC for inner door panel which containing flax and sisal
bearing capacity is considered as a major factor. Fiber reinforced with epoxy polymer shown remarkable weight reduction of about
composites are better than polymer resins in case of structural 20% [38].

Table 3
Effect of various chemical treatments on mechanical properties.

S. Fiber Applied Chemical Treatments Results on Mechanical Properties Ref.


No Treated No
1 Coir 20% alkali treated followed by grafting The mechanical properties of the composites were increased significantly after treatment of the 17
with 50% ethylene dimethylacrylate fiber.
2 Aspen fiber Alkaline Treatment The tensile strength has been improved 18
3 Flax Maleic Anhydride, Mercerization The tensile strength of MAH-PP treated flax/PP composites has improved by 50% compared to 19
Treatment untreated and mercerized fiber composites.
4 Ramie fiber 15% Alkaline Treatment The tensile strength of treated ramie fiber has been improved by 4 to 18% higher than that of 20
the untreated ramie fiber.
5 Flax fiber Alkaline Treatment The young’s modulus and tensile strength of the flax/epoxy composites were found to be 21
increased with decreasing fiber shrinkage
6 Different Alkaline Treatment Alkaline treatment was found to be most effective method to improve interfacial bonding 22
fibers between fiber and matrix, while other treatment methods exhibited either no effect or
reduction on the fiber strength.
7 Doum Alkaline Treatment After alkaline treatment, a significant improvement was observed in flexural modulus, young’s 23
Fibers modulus and flexural modulus
8 Pineapple Alkaline Treatment & Silane Treatment The mechanical and thermal properties were found to be high for alkaline treatment 24
Leaf Fibers
9 Vetiver 5% Alkaline Treatment The maximum tensile strength for raw vetiver fiber composite and chemically treated fiber 25
Fiber composite was found to be 11.9 MPa and 13.59 MPa respectively.
10 Sisal Fiber Treated Vs Untreated fibers The dynamic mechanical property like storage modulus has been increased for treated fiber 26
composites compared to untreated fiber composites

Please cite this article as: N. Karthi, K. Kumaresan, S. Sathish et al., An overview: Natural fiber reinforced hybrid composites, chemical treatments and
application areas, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2020.01.011
6 N. Karthi et al. / Materials Today: Proceedings xxx (xxxx) xxx

Table 4
Applications of Natural Fibers in Automobile Field.

Manufacturer Model Components


Audi A2, A3, A4, A4 Avant, A6, Audi Seat back, side and back door panel, boot lining,
A8 Road star, Coupe hat rack, spare tyre liner
Citroen C5 Interior door paneling
BMW 3, 5, 7 series Door panels, headliner panel, bootlining, seat back,
noise insulation panels, molded foot well linings
Lotus Eco Elise Body panels, spoiler, seats, interior carpets
Fiat Punto, Brava, Marea, Door panel
Alfa Romeo 146, 156
Opel Astra, Vectra, Zafira Instrumental panel, headliner panel, door panels,
Pillar cover panel
Peugeot 406 Front and rear door panels
Rover 2000 and others Insulation, rear storage shelf/panel
Toyota Raum, Brevis, Harrier, Celsior Door panels, seat backs, floor mats, spare tier cover
Volkswagen Golf A4, Passat, Variant, Bora Door panel, seat back, boot-lid finish panel, boot-
liner
Mitsubishi Space star, Colt Cargo area floor, door panels, instrumental panels
Renault Clio, Twingo Rear parcel shelf
Daimler-Benz Mercedes A, C, E, S class, Trucks Door panels, windshield/dashboard, business table,
EvoBus (exterior) Piller cover panel, glove box, instrumental panel
support, insulation, molding rod/apertures, seat
backrest panel, trunk panel, seat surface/backrest,
internal engine cover, engine insulation, sun visor,
bumper, wheelbox, roof cover
Honda Pilot Cargo area
Volvo C70, V70 Seat padding, natural foams, cargo floor tray
General Motors Cadillac Deville, Chevrolet, Seat backs, cargo area floor
Trial Blazer
Saturn L3000 Package trays and door panel
Ford Mondeo CD 162, Focus, freestar Floor trays, door panels, B-piller, boot liner

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Please cite this article as: N. Karthi, K. Kumaresan, S. Sathish et al., An overview: Natural fiber reinforced hybrid composites, chemical treatments and
application areas, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2020.01.011
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