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1 Interphase Transfer Packed Columns
1 Interphase Transfer Packed Columns
Topic 3
Lecture Objectives
• To be able to apply the principles of
interphase mass transfer to Gas Absorption
▫ Equilibrium Relations
▫ Graphical Representation
▫ Overall Mass Transfer Coefficients
• To be able to obtain properties of packings
▫ Types of Packings
▫ Packing Characteristics
• To be able to calculate the following for a
packed column:
▫ Flooding Velocity
▫ Column Diameter
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Equilibrium Relations
Graphical Representation
Graphical Representation
At steady state:
NAG = NAL
y1
Operating Line ky(y – yi) = kx(xi - x)
y
y Tie Line
Equilibrium Tie Line Equation:
yi Line
y2 kx y - yi
- =
ky x - xi
x2 x xi x1 = slope of tie line
x
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Graphical Representation
NAG = ky (y – yi)
y
NAG = Ky (y – y*)
yi
NAL = kx (xi - x)
y*
NAL = Kx (x* - x)
x xi x*
Graphical Representation
Relationships:
NAG = ky (y – yi) = Ky (y – y*)
NAL = kx (xi - x) = Kx (x* - x)
From the Graph:
y – y* = (y – yi) + (yi – y*)
y – y*
y Slope EL = m = i
xi - x
yi (yi – y*) = m (xi – x)
y* NAG NAG m NAL
= +
Ky ky kx
x xi x* 1 1 m
= +
Ky ky kx
©UST Ch.E. Department
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Metal
PR
RR BS
Plastic Ceramic IS
PR
Plastic SIS
First and Second Generation Packings ©UST Ch.E. Department
Plastic
CMR
IMTP
Third
Generation
Packings
Metal RSR
Metal NR
©UST Ch.E. Department
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Structured
Packing
Setup
(Flexipac,
Mellapak Plus)
Fourth
Generation
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Flooding Line
CP
• Procedure
1. Obtain liquid density (L) and viscosity(L), gas
density(G) and packing factor(FP)
2. Calculate the ratio of flow of entering liquid to
entering gas (L/G) from problem data.
3. Calculate FLG = (L/G)(G/L)0.5
4. Obtain CP from Fig. 14-55/14-58 (HB) using FLG
and pressure drop of 1.5 in Hg
5. Solve UF =CP[(L- G)/(L FP)]0.5[L/L]0.05 using
appropriate units in the HB
6. GF = UF G
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Example
Solution
y1 x2
y1 .22 Y1 Y1 0.28205 x2 0 X2
1 y1 1 x2
Rec 0.95 r 1.5 Ma 17 Mb 29 Ms 18 X2 0
Y2
Pt 1140 Y2 ( 1 Rec) Y1 Y2 0.0141 y2
1 Y2 y2 0.01391
Solution
Equilibrium Data:
i 1 12 C P 18
Xe
i
i i Xe C xe
i i 1700 i 1 Xe
20 260 i
15 179
10 110
7.5 79.7 P Ye
i i
5 51 Ye ye
4 40.1
i Pt P i 1 Ye
i i
3 29.6
2.5 24.4
2 19.3 9000
q1 q1 0.15 m^3/s
1.6 15.3 60000
1.2 11.5
0 0
ye
i
0.22807 ©UST Ch.E. Department
0.15702
0.09649
0.06991
0.04474
0.03518
0.02596
0.0214
0.01693
0.01342
0.01009
0
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Solution
ye xe
i i
0.22807 0.17476
MV1 y1 Ma ( 1 y1) Mb MV1 26.36
0.15702 0.13706 Pt MV1
T 303 G
0.09649 0.09574 T
.08205760
0.06991 0.07357
0.04474 0.05028 G 1.59043 kg/m^3
0.03518 0.04063
0.02596 0.03079 L 995.647 kg/m^3
0.0214 0.02579 131
L 0.86 0.001 Fp
0.01693 0.02074 3.28
0.01342 0.01666
0.01009 0.01255
0 0
273 Pt 1
V1 q1 3600 V1 32.58045 Kmols/hr
T 760 22.4
Solution
yei
y1
xei
x1e
From Graph: x1e .17 X1e X1e 0.20482 ©UST Ch.E. Department
1 x1e
Solution
Y1 Y2
LVmin M L2 x2 Ma ( 1 x2) Ms
X1e X2
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Solution
0.5
wL2 G
FLG FLG 0.04177 From Flooding Chart:
wv1 L
Cs 1.87
L 2
1000 0.86376
L
Cs
Ut Ut 2.27194 GF Ut G rF 0.62
0.5
G 0.5 0.05
Fp 3.28 GF 3.61337 GV1 rF GF
L G
wv1 4 S
S S 0.10649 D D 0.36822 m
GV1 3600
Exercise
10 m3/min of a gas mixture containing 10%
NH3,90% Air by mole shall be treated in a
packed absorber in order to recover 90% of the
ammonia. The water rate is 40% greater than
the minimum. Operating conditions are 1.4 atm
and 25oC.
Determine the tower diameter if the packing
used is:
a) 25 mm metallic Raschig Rings
b) 25 mm metallic Pall Rings
©UST Ch.E. Department
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