1.The solubility of Ba (OH)2 .8H2 O in water at 288 K is 5.6 g per 100 g of water.

What is the
molality of hydroxide ion in saturated solution of Ba (OH)2 .8H2 O at 288 K.
a.) 0.456 b.)0.442 c.)0.356 d.)0.302

2.The vapour pressure of pure benzene at a certain temperature is 0.850 bar. A non-volatile,
non-electrolyte solid weighing 0.5 g when added to 39.0 g of benzene (molar mass 78 g mol–1),
then vapour pressure of the solution is 0.845 bar. What is the molar mass of the solid
substance?
a.)165 g mol-1 b.)170 g mol-1 c.) 180 g mol-1 d.)185 g mol-1

3.)Calculate the molal elevation constant of water, it being given that 0.1 molal aqueous solution
of a substance boiling at 100.052 ºC.
a.)0.520C molal-1 b.) 0.600C molal-1 c.) 0.700C molal-1 d.) 0.650.C molal-1

4.A 6.90 M solution of KOH in water contains 30% by

mass of KOH. Calculate the density of the KOH solution.
(Molar mass of KOH = 56 g mol–1)
a.)2.04 g mL-1 b.)1.288 g mL-1 c.)3.214 g mL-1 d.) 4.56g mL-1

5.Calculate the moles of methanol in 5 litres of its 2 m

solution, if the density of the solution is 0.981 kg L–1
(Molar mass of methanol = 32.0 g mol–1).
a.)7.58 mol b.) 8.98 mol c.) 9.22 mol d.)8.76 mol

6.A 0.118 molal solution of LiCl has a freezing point of

–0.415 ºC. What is the van’t Hoff factor for this solute
at this concentration ?
a.)1.21 b.)1.67 c.)1.89 d.)1.43

7.Ethylene glycol (C2

H6O2) is used as an antifreeze. What
mass of ethylene glycol should be added to 5.00 kg of
water to lower the freezing point to –5.0 ºC ? Given that
Kf = 1.86 ºC molal–1. Consider ethylene glycol to be a
non-electrolyte.
a.) 678 b.)837 c.)865 d.)729

8.A solution prepared by dissolving 1.25 g of oil of winter

green (methyl salicylate) in 99.0 g of benzene has a
boiling point of 80.31ºC. Determine the molar mass of
this compound. (Boiling point of pure benzene
= 80.10 ºC and Kb for benzne = 2.53 ºC molal–1.)
a.)148.59 g mol-1 b.)150.09 g mol-1 c.)152.11 g mol-1 d.) 155.78 g mol-1
9.In an aqueous solution, KCl undergoes complete
dissociation into K+ and Cl– ions. What is the value
of osmotic pressure of a 0.525M solution of KCl at 300
K ? (Use R = 0.0821 L atm K–1)
a.)25.86 atm b.)28.24 atm c.)30 atm d.) 32 atm

10.The vapour pressure of water at 293 K is 2338 Pa and

the vapour pressure of an aqueous solution is 2295.8
Pa. If density of solution is 1010 Kg/m3 at 313 K,
calculate the osmotic pressure at 313 K. Molecular
weight of solute = 60.
a.) 5*106Pa b.) 1.6*106Pa c.)2.53 * 106Pa d.) 3.2*106Pa

11.A sample of naphthalene has freezing point, 80.6ºC.

When 0.512g of a solute is dissolved in 7.03g of
naphthalene, the solution has a freezing point of
75.2ºC. Calculate the molecular mass of the solute.
(Kf for naphthalene = 6.8ºC kg/mol)
a.)91.7 g mol-1 b.) 88 g mol-1 c.)90 g mol-1 d.) 95 g mol-1

12.Calculate the vapour pressure lowering caused by addition of 50 g of sucrose (molecular

mass = 342) to 500 g of water if the vapour pressure of pure water at 25°C is 23.8 mm Hg.
a.)0.156 mm Hg b.) 0.124 mm Hg c.)0.180 mm Hg d.) 0.456 mm Hg

13.0.15 g of a substance dissolved in 15 g of solvent boiled at a temperature higher by 0.216°C

than that of the
pure solvent. What is the molecular weight of the substance. [Kb solvent = 2.16°C]
A.100 b.)120 c.) 110 d.)130

14.The rise in boiling point of a solution containing 1.8 g glucose in 100 g of a solvent is 0.1°C.
The molal elevation constant of the liquid is –
a.)2 b.)3 c.)1 d.)4

15.If freezing point of a solution prepared from 1.25 g of a non electrolyte and 20 g of water is
271.9 K, the molar mass of the solute will be –