WK 8

Dalton'sLaw of Partial Pressure

Total pressure 7 Pt P t Pe t Patty

partial pressure 7 gas present in the container
mole fraction Xi
Xgas at Xgas 13 1
Example
mixture of oxygengas Nitrogen
p
Oxygen xi 0.26
mole fraction of Xna 1 0.26
0.74 1
Partial Pressure Pi XiPt
Example
given p 2.5 atm Required
Nz 0.67 Individualpressure or
partialpressuresofNa H2
Equation Formula
XgasAt XgasB 1 Pi xi Pt
solution
A Nr D H2
PN2 XyzPT 10.67 2.5 atm 1.7 atm PiofNz
XHz 1 XN2 1 O 67 0 33 molefraction H2

PH2 XH2PT 10.33 2.5atm 0 8 atm

check
p prat pit 1.7 atm t 0.8atm
2.5 atmy
Gas stoichiometry
withmole PV net w o mole
PhymRT
Example 2 He 02 2420
Given Mass Hao 1869 Required
PHz I 00 atm volume of Hr
MM420 101121 16 T 230C f 273 296K
202 16 Equation
18.02
MMHa 1.0112
iv mm at mass ax Immolmax Mm
MM
Imot
 solution
mass of Ha 186g
yg.fi moaox mmI
Y Mitt
Mass of H2 20 85 9 Has

4
RT RT
V'Fy
Mmm

3 get 10.8214511129614
00 atm 1
v 250 84 L u
try it 2064Hlo t 1302 7 08102 t 10420
Given Required
MM of 64410 5812 Mass of Cattio I kg 12,000g
MM of 102 4401 Pt 2.0 Atm volume of CO2 in L
T 3500 273 308 K
Equation
mass at Imanol t mm Ba t MMB
MMA

timmass
Y nd
of con 12,000
gcultiotgg.mgmjitii 1mmIEH
mass of 102 36346.87 9 102
v 3 130810
14.89 10 084m44s
Ratt
V 10441.90

Effusion P Diffussion 7 Thomas Graham

KEI KEI
1m
I v mav2
Me
mma or
EE MY1 Itn t Mmm

Example
Given Required
mm yo yy o g mo MM 2
time 31 secs
 ez 39 secs
Equation
CMMI
t.IT iTm tmmsMmnmt.fftmet
Commit Emmetmmi
Eiht
mm
Solution 144.0191m01
43412 6966glmole