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RESEARCH ARTICLE
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Shukla et al. / Indian Journal of Science and Technology 2021;14(30):2472–2482
1 Introduction
Groundwater quality is governed by Chemical, biological and physical parameters. It is less prone to biological pollution than surface water
which is always in contact with soil, rocks and foreign materials. But freedom from biological pollution itself does not make it eligible for
drinking purposes. Various materials and minerals could be present in it either in the dissolved or dispersed form. These materials and
minerals are very hard to detect from the naked eyes and most of it doesn’t affect the human body are even beneficial up to some extent. But
some of them are highly toxic and if taken in higher concentration could be fatal for the living being.
Groundwater is susceptible to soil properties and aquifer level. The property of groundwater is dependent on depth of the water into the
ground and surrounding soil strata (1) . Also, the water quality of groundwater depends on the rainfall, as after every rainfall the percolation
through the soil layers from pores and cracks occurs causing the change in water quality as percolation of water takes the contaminants and
soil pollutants along with it.
IS code 10500:2012- “Drinking water specification” provides acceptable and permissible values of various water quality parameters for
drinking purposes. The electrical conductivity does not affect the drinking water quality but is used for irrigation purposes. BIS have
mentioned irrigation standards for electrical conductivity, which have been used in this paper (2) . The water having the quality parameters
under acceptable levels is the best for drinking purposes. In the absence of other sources, the water source containing parameters within
permissible limits is accepted as water sources for drinking purposes. Water having quality parameters crossing permissible values are not
chosen for drinking purposes.
In a research by Central Ground Water Board, 2013, it has been mentioned that all the values of water are under the permissible limit
and the Gorakhpur city, which is very prone to flood and water logging during the monsoon season, the quality parameters are susceptible
to change since past 6 years. The growing population and industries have increased the water consumption, generation of wastewater and
effluent to rivers that have become the source of contamination for the groundwater. Therefore, to determine the quality of groundwater from
India Mark II pumps and pumps at shallow depth of less than 50 m, it was found that the pumps at shallow depth had 25% more total dissolved
solid (TDS) and hardness (3) . This study was done in an urban area of Gorakhpur and a semi-urban area of Khorabar. In the same year i.e.,
2014, the water quality index (WQI) was too calculated for different locations of the Gorakhpur City to compare the quality of the water by
standard methods as it is the best tool to classify the different areas according to their water qualities (2) . Earlier, WQI and weighted overlay
analysis were used as imperative tools for classifying the Lucknow sector into regions of safe and unsafe water thus, (2) .
It has been found that the increment in the level of physical and chemical parameters of the groundwater raises significantly in the urban
areas. In a study TDS, turbidity, alkalinity and hardness exceeded the acceptable limits but were below the permissible limits (4) .
Observing the role and significance of WQI in assessing the water quality, we determined the groundwater quality of Gorakhpur city was
by calculating WQI for respective locations. We used this water quality data for creating and publishing the spatial distribution maps. The
determined water quality data was compared with the guidelines for drinking water provided by BIS (IS: 10500-2012).
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• Identification of 150 water samples uniformly distributed over the study area
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• Collection of groundwater samples from hand pumps of 150 locations in Polyethylene bottles. The bottles used were clean and neat
and as per IS: 3025 (Part-1) (1987).
• Collection of GPS coordinates of the collection sites and plotting of points using QGIS Software.
• All the samples were tested in a laboratory for quality parameters and designated by a sample number (SMN). The laboratory facility
was provided by the Public Health Engineering Laboratory of Madan Mohan Malviya University of Technology, Gorakhpur.
• WQI was calculated for the comparison of groundwater quality between different locations of the city.
• Based on the spatial distribution maps, safe and unsafe zones of water quality were demarcated by taking in account water quality
parameter and water quality index
5 Parameters studied
There are large numbers of physical and chemical parameters of water, which need to be observed while determining the water quality and
classifying water into the different categories like drinking purposes, irrigation etc. In the study, the seven physical and chemical parameters
were tested, Table 1 shows the list of parameters used in studying the water quality with information on testing methods adopted according
to the reference Additionally, Table 2 shows the water quality specification for different physical and chemical parameters of water with
information on acceptable limit, permissible limit according to the reference.
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hydrologists use GIS technology for integration of various data applications into one and manageable system (9) . QGIS too includes a function
to interpolate the data and find out the value of any parameter at any GPS coordinate. We used QGIS for creating and publishing the spatial
distribution and weighted overlay map of the water quality variables. Figure 2: Flowchart of the methodology for determining water quality
and classifying areas from excellent to unsuitable for drinking.
For computing the water quality index, the following three steps were adopted.
Step 1: Each physical and chemical parameter of water was acknowledged with a weight Wi according to its relative importance in the overall
water for drinking purposes. Table 3 presents the details on the weight and relative weight of each parameter.
Step 2: Relative weights were for each parameter was computed using the following equation,
Wir = Wi /∑ni=1 Wi
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where quality rating is denoted by qi, Ci represents concentration of each parameter in water sample in mg/l, Si is the acceptable value for the
chemical parameter in sample of water represented by Si in mg/l according to guidelines of IS: 10500-2012 (Indian drinking water standards).
WQI Equation:For each physical and chemical parameter, SI value was determined in mg/l, which was used to determine water quality index
according to the equation given below:
SIi = qi × Wir
WQI = ∑ SIi
SIi = Wi *qi , WQI =∑ SIi , SIi represents sub-index of the ith parameter, ith parameter concentration denotes qi rating, the number of
parameters is represented by n.
The computed water quality index values were classified into 5 types from “excellent water” to “water unsuitable for drinking” as depicted
in Table 4.
Where,
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Table 5. Descriptive statistics and concentration standards and guidelines of groundwater quality parameters
Standard Limit (BIS)
Parameter Max Min Mean Mode Median S.D.
Acceptable Permissible
pH 6.5-8.5 No Relaxation 150 8.0 6.0 7.25 7.5 7.5 0.404
TU (NTU) 1 5 150 0.5 0.1 0.11 0.1 0.1 0.05
CH (mg/l) 250 1000 150 204 45 110.53 138 104 41.96
EC (µ S/cm) 2000 Not Specified 150 1342 478 848.5 856 856 136.46
TA (mg/l CaCO3) 200 600 150 259 90 184.16 198 186 35.14
TH (mg/l CaCO3) 200 600 150 315 80 193.49 205 190 46.85
TDS (mg/l) 500 2000 150 1007 359 636.38 642 642 102.34
Further, the statistical analysis of the errors associated with computed data of 30 samples was done and Table 6 shows the descriptive
statistics of these samples for each parameter with information on error associated with each parameter.
Table 6. Descriptive statistics of errors b/w test data andderived data from QGIS
Parameter N Min Max Mean Absolute Error Standard Deviation Root Mean Square Error
pH 30 0.001 0.861 0.298 0.227 0.372
TU (NTU) 30 0.000 0.121 0.022 0.032 0.038
CH (mg/l) 30 0.07 79.04 29.118 20.968 35.677
EC (µ S/cm) 30 3.27 258.90 99.604 80.211 127.045
TA (mg/l CaCO3) 30 1.17 54.61 24.204 14.699 28.190
TH (mg/l CaCO3) 30 3.05 70.23 27.979 18.052 33.134
TDS (mg/l) 30 1.25 194.77 75.067 60.105 95.537
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Fig 3. (a) Spatial Distribution Map for pH, (b) Spatial Distribution Map for Chloride, (c) Spatial Distribution Map for Turbidity, (d) Spatial Distribution Map
for Electrical Conductivity
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Fig 4. (a) Spatial Distribution Map of WQI, (b) Spatial Distribution Map of Total Alkalinity, (c) Spatial Distribution Map of TDS, (d) Spatial Distribution Map
for Total Hardness
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11 Discussion
1. PH
The value of pH varied from 6.0 to 8.0 with the mean value of 7.25 ± 0.404. According to BIS (IS: 10500-2012), the acceptable and
permissible limits for pH are ‘6.5-8.5’ and ‘no relaxation’respectively. The observed values are within the permissible limit, so the
water quality is safe.
2. Turbidity
The value of turbidity varied from 0.1 NTU to 0.5 NTU with the mean value of 0.11 ± 0.05 NTU. According to BIS (IS: 10500-2012),
the acceptable and permissible limits for turbidity are 1 NTU and 5 NTUrespectively. The observed values are within the permissible
limit, so the water quality is safe.
3. Chloride
Concentration of chloride mostly lied from 45 mg/l to 204 mg/l with the mean value of 110.53 ± 41.96 mg/l. According to BIS (IS:
10500-2012), the acceptable and permissible limits for chloride are 250mg/l and 1000mg/lrespectively. The observed values are within
the permissible limit, so the water quality is safe.
4. Electrical Conductivity
The value of electrical conductivity varied from 478 µ S/cm to 1342 µ S/cm with the mean value of 848.5 ± 136.46 µ S/cm. According to
BIS (Irrigation Standard), the acceptable and permissible limits for electrical conductivity are 2000 mg/l and ‘Not Specified’respectively.
The observed values are within the permissible limit, so the water quality is safe.
5. Total Alkalinity
The Concentration of total alkalinity varied from 90 mg/l to 259 mg/l as CaCO3 with the mean value of 184.16 ± 35.14 mg/l as
CaCO3 . According to BIS (IS: 10500-2012) the acceptable and permissible limit for total alkalinity are 200 mg/l and 600 mg/l as
CaCO3 respectively. The observed values are within the permissible limit, so the water quality is safe.
6. Total Hardness
The value of total hardness varied from 80 mg/l to 315 mg/l as CaCO3 with the mean value of 193.49 ± 46.85 mg/l as CaCO3. Accord-
ing to BIS (IS: 10500-2012), the acceptable and permissible limit for total hardness is 200 mg/l and 600 mg/l as CaCO3 respectively.
The observed values are within the permissible limits, so the water quality is safe.
12 Conclusion
The present study assessed the Ground Water Quality of the Gorakhpur City by analyzing the 150 groundwater samples for which the tests
were completed as per the guidelines laid down by BIS (IS: 3025). Out of 150 samples only one sample was found whose pH was of poor quality.
The total alkalinity, total hardness and total dissolved solid of groundwater raised issues because about one-third of the samples crossed the
acceptable limits, but not the permissible limits as per guidelines of BIS (IS: 10500-2012). The turbidity, chloride, and electrical conductivity
of groundwater for all the samples were below the acceptable limit. As per WQI, out of 150 samples, only 3 samples were found showing Poor
Groundwater for drinking purposes sampled inwards Purdilpur (Ward 42), Dilejakpur (Ward 38) and Alhadadpur (Ward 55) with WQI of
103.54, 100.17 and 100.11, respectively. The best water sample is that whose WQI is the least. Shaktinagar (Ward 37) is found to have best
results with a WQI of 59.05 i.e., good water. None of the samples were found as ‘Excellent’.
Hence the overall water quality of groundwater of Gorakhpur City is within permissible limits for all the measured seven parameters and
the water quality is safe corresponding to these seven parameters.
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References
1) Integration of Remote Sensing and GIS in Ground Water Quality Assessment and Management. Ibrahim. Shakak, Nadia Babiker. In: The International Archives of the
Photogrammetry, Remote Sensing and Spatial Information Sciences, Vols. XL-7/W3. 2015. doi:10.5194/isprsarchives-XL-7-W3-1483-2015.
2) Konkey S, Chitranshi UB, Garg RD. Ground water quality analysis and mapping using GIS techniques. International Journal of Engineering Science and Technology. 2014;6(8):474–
488.
3) Verma A, Pandey G. A Study of Groundwater Quality in Urban and Peri-urban Areas of Gorakhpur City in India. International Research Journal of Environment Sciences.
2014;3(1):6–8.
4) Kumar GM, Pandey G. International Journal for Scientific Research & Development. 2015;3:614–615. Available from: http://ijsrd.com/Article.php?manuscript=IJSRDV3I70136.
5) CIDC. City Development Plan, Gorakhpur. 2014. Available from: www.cidc.in.
6) Gorakhpur. 2019. Available from: http://gorakhpur.nic.in/.
7) Indikosh. 2019. Available from: https://indikosh.com/city/200198/gorakhpur.
8) RCUES. 2019. Available from: http://www.rcueslucknow.org/AMRUT/SLIPWaterUP/Amrut%20SLIP%20Water%20-%20Gorakhpur.pdf.
9) ESRI, California USA : Environmental Systems Research Institute (ESRI). What is GIS ?. 2012.
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