NAME: IBANEZ, IVAN DAVID S.

SECTION: BSED SCIENCE- 2B

SUBJECT: ORGANIC CHEMISTRY

ACTIVITIES AND EXERCISES

SAQ 1-1-1:
Let us see if you understand the overview of organic chemistry and you know
the reasons for having a large number of organic compounds by matching Column A
with Column B. Write the letter only on the space before each number.
Column A Column B
__H___ 1. CO2 A. structural isomerism
B. stated that organic compounds are
__E___ 2. –C–OH composed of carbon, hydrogen, and
oxygen
__J___ 3. organic compounds C. catenation
__A___ 4. CH3CH2CH2CH3 and H D. stereoisomerism
CH3–C–CH3 E. functional group
CH3 F. example of organic compound and
__I___ 5. Wohler main component of natural gas
__C___ 6. C–C C=C C≡C G. synthesized methane
__F___ 7. CH4 H. example of inorganic compound
__K___ 8. inorganic compounds I. father of organic chemistry
__B___ 9. Lavoisier J. derived from living things
__D___ 10. R R K. derived from minerals
H COOH and HOOCH
H2N NH2
Act 1-2-1
A. Fill up the table below with the required information.
Criteria Inorganic Organic
a. Physical State YES NO

b. Combustibility NO YES

c. Melting LOW HIGH

Point/Boiling Point

d. Solubility in Water NO YES

e. Solubility in YES NO
Organic Solvent

f. Conductivity MOLECULES ION

g. Structure of Solid COMPLEX SIMPLE

COVALENT IONIC

h. Bonding

NO YES
i. Volatility
A. Using your knowledge on bonding and structure of compounds, answer
the following:
1. Ignition Test
a. Flammability
Compound Flammability

a. Ethyl Alcohol FLAMMABLE

b. Water NON-FLAMMABLE

b. Charring

Compound Charring

a. Sugar NEGATIVE

b. Salt NEGATIVE

2. Solubility

Compound Solubility Reasons

Table salt, or Salt {sodium chloride} is
sodium chloride made from positive sodium
{NACl}, the most ions bonded to negative
a. NaCl & H2O common ionic chloride ions. Water can
compound is dissolve salt because the
soluble in water positive part of water
{360 g/L} molecules attract the
negative chloride ions and
 the negative part of the
water molecules attract the
positive sodium ions.

As sodium chloride Non- polar molecules will

is a polar molecule be soluble in non-polar
it will be soluble in solvents and insoluble in
polar solvents like polar solvents. As sodium
b. NaCl & water. And chloride is a polar molecule
Kerosene insoluble in it will be soluble in polar
kerosene { as it is solvent like water. And
non- polar insoluble in kerosene { as it
solvent}. is non-polar solvent }.

Naphthalene is insoluble in
Insoluble water because it is
c. Moth Ball & non-polar. This means that
H2O it cannot participate in
dipole-dipole interactions
or hydrogen bonding
Non polar substances don't
Soluble dissolve in polar solvent. But
nonpolar substances dissolve
in nonpolar solvents like
d. Moth Ball & naphthalene and kerosene.
Kerosene Therefore, we can say that
naphthalene dissolves in
kerosene because both
naphthalene and kerosene are
non polar substances

3. Conductivity
 Electrolyte/ Light or Without
Compound Non-electrolyt Light Reasons
e
Sodium chloride
ELECTROLYTE LIGHT does not have any
free mobile ions in
its solid state which
are responsible for
the conduction of
a. NaCl electricity but in
Solution fused or aqueous
state it conducts
electricity as it has
free mobile ions in
that state.

You might have

NON- heard that adding
sugar to electrolytes
ELECTROLYTE WITHOUT LIGHT boosts hydration -
this isn't false.
Glucose does help
b. Sugar transport sodium,
Solution chloride, and water
across the intestinal
barrier. Because of
this, some claim you
need glucose for
proper hydration.

the acute effect of

NON- ethyl alcohol ingestion
LIGHT is to induce diuresis
ELECTROLYTE
c. Ethyl with excretion of free
Alcohol water and preservation
Solution of electrolytes.
SAQ 1-2-2:
A. Classify each solution as an electrolyte or non-electrolyte.
1. Sugar in Water - NONELECTROLYTE
2. Salt in Water - ELECTROLYTE
3. Alcohol in Water - NONELECTROLYTE
B. Use the solubility rules whether the following compounds are soluble.
4. AgCl - INSOLUBLE
5. AgNO3 - SOLUBLE
6. NaOH - SOLUBLE
C. Determine the intermolecular forces/reason why the given compounds are
soluble in water.
Compound Intermolecular Forces/Reason
7. NaCl ION- DIPOLE
8.Ethanol, DIPOLE - DIPOLE OR H- BONDING
CH3CH2OH
9. Hexane, C6H14 LIKE DISSOLVES LIKE HEXANE- NONPOLAR
WATER- POLAR SOLVENT.
10. Sugar H- BONDING

Act 1-3-2 Qualitative Elemental Analysis

A. Fill up the table below. Consider the formula of the tested compound as
your guide.
1. Ferrox Test for Oxygen

Test Compound Formula (Research) Color Change

a. acetone POSITIVE IN THE PRESENCE OF

OXYGEN A DEEP RED
COLOR RED IS
 DISTRIBUTED IN THE
FILTER PAPER
b. benzene NEGATIVE IN THE PRESENCE OF
OXYGEN A DEEP RED
COLOR RED IS
DISTRIBUTED IN THE
FILTER PAPER
c. ethyl alcohol POSITIVE IN THE PRESENCE OF
OXYGEN A DEEP RED
COLOR RED IS
DISTRIBUTED IN THE
FILTER PAPER
d. kerosene NEGATIVE IN THE PRESENCE OF
OXYGEN A DEEP RED
COLOR RED IS
DISTRIBUTED IN THE
FILTER PAPER

2. Test Compound
Name of Test Color Change
e. monochloroacetic SILVER NITRATE SILVER CHLORIDE -
acid TEST WHITE PRECIPITATE
f. albumin (egg white) LEAD ACETATE TEST ACETATE IS A WHITE
CRYSTALLINE
SUBSTANCES MADE
BY TREATING
LITHARGE
g. CO2 + lime water SODA- LIME TEST RED INTO BLUE

B. Question
1. How will you prepare ferrox paper?

Ferrox paper is prepared by soaking filter paper in methanol containing

equal amounts of ferric chloride and ammonium thiocyanate.
2. What is the role of CuO in the given reaction in the 3.1.1 topic?
The results revealed that CuO acted as a reactant, while as - formed
copper carbonate could act as a catalyst in this reaction- the
electrolytes influence CuO phase change and product selectivity,
helping to elucidate the ways in which the Co2 photoreduction process
was assisted this materials.

SAQ 1-3-3
Match Column A with Column B. Write the letter only on the space provided.

COLUMN A COLUMN B

__F___ 1. Ferrox Test A. detects the presence of sulfur

__E___ 2. CuO B. predominant elements in organic
compounds
__H___ 3. Silver nitrate Test C. decompose organic compound into
inorganic
__C___ 4. Sodium Fusion ions
__J___ 5. Lime Water Test D. it is also known as sodium fusion
extract
__K___ 6. Sodium nitroprusside TestE. serves as catalyst
__B___ 7. Carbon and Hydrogen F. test for oxygen
__D___ 8. Lassaigne Extract G. indicates the presence of hydrogen
__A___ 9. Lead acetate Test H. identify the presence of chlorine
__I___ 10. Chlorine, Bromine, Iodine I. signify the formation of CO2
J. test for nitrogen

Act 1-3-3 Quantitative Elemental Analysis

1. A hydrocarbon weighing 0.1647 g was heated to produce 0.4931 g CO2
and 0.2691 g H2O. Determine the masses of carbon and hydrogen and
also the percentages of these elements in the hydrocarbon.
A gaseous hydrocarbon gives upon combustion, 0. 72g of water and 3. 08
g of CO [2] this tells you that all the carbon that was initially a part of the
hydrocarbon will now be part of the carbon dioxide. Likewise , all the
hydrogen that was initially a part of the hydrocarbon is now a part of the
water.
This means that you can use the number of moles of water and carbon
dioxide , respectively to determine how many moles of carbon and of
hydrogen were originally present in the hydrocarbon.

2. What is the %S in an organic compound weighing 0.157 g that gives

0.4813 g BaSO4?
Weight of sulphur is 32 u
And weight of BaSo4 IS 233 u
So weight of sulfur in BASO4=23332=0.4813
Percentage of sulfur= 23332 x 0.1570.4813 x 100= 42.12%

3. In the Carius method, find the %Cl in an organic compound that weighs
0.15 g and gives 0.12 g AgCl.

Here , the mass of the substances taken = 0.15

Mass of AgBr formed = 0.12 g
Now 1 mole of AgBr = 1g atom of Br or 188 [ 108 plus 88 ]g of AgBr = 80g
of Br .., 188 of AgBr contain bromine =80g .., 0.12g of AgBr will contain
bromine [ 80 ] [ 188 ] x 0.12g
But this much amount of bromine is present in 0.15 g of the organic
compound. Percentage of bromine = [ 80 ] [ 188 ] x [ 0.12 ][ 0.15 ] x 100=
34.04.

SAQ 1-3-4
1. Glucose weighing 0.1014 g was burned to produce 0.1486 g CO2 and
0.0609 g of H2O. Since glucose contains carbon, hydrogen and oxygen,
determine the masses of C, H and O in the sample and the percentages
of these elements.
1. wt. of C = 0.4055 g
2. wt. of H = 0.0068 g
3. %C = 39.99%
4. %H = 6.72%
5. wt. of O = 0.0540 g
%O = 3.2%