Professional Documents
Culture Documents
Chapter 3: The Structure of Crystalline Solids: Energy and Packing
Chapter 3: The Structure of Crystalline Solids: Energy and Packing
ISSUES TO ADDRESS...
• How do atoms assemble into solid structures?
(for now, focus on metals)
Chapter 3 - 1
typical neighbor
bond length
typical neighbor r
bond energy
typical neighbor
bond length
typical neighbor r
bond energy
1
10/15/2020
Si Oxygen
Noncrystalline materials...
• atoms have no periodic packing
• occurs for: -complex structures
-rapid cooling
"Amorphous" = Noncrystalline noncrystalline SiO2
Adapted from Fig. 3.22(b),
Callister 7e.
Chapter 3 - 3
7 crystal systems
14 crystal lattices
2
10/15/2020
vs.
Chapter 3 - 6
3
10/15/2020
• Coordination # = 6
(# nearest neighbors)
4
10/15/2020
2a
Close-packed directions:
Adapted from
R length = 4R = 3 a
Fig. 3.2(a), Callister 7e.
a
atoms volume
4
unit cell 2 π ( 3a/4) 3
3 atom
APF =
volume
a3
unit cell Chapter 3 - 10
5
10/15/2020
6
10/15/2020
A
• FCC Unit Cell B
C
Chapter 3 - 13
7
10/15/2020
Chapter 3 - 15
Theoretical Density, ρ
nA
ρ =
VC NA
Chapter 3 - 16
8
10/15/2020
Theoretical Density, ρ
• Ex: Cr (BCC)
A = 52.00 g/mol
R = 0.125 nm
n=2
R
a a = 4R/ 3 = 0.2887 nm
atoms
g
unit cell 2 52.00 ρtheoretical = 7.18 g/cm3
mol
ρ= ρactual = 7.19 g/cm3
a3 6.023 x 1023
volume atoms
unit cell mol Chapter 3 - 17
5
Ceramics have... 4
Titanium
Al oxide
Diamond
• less dense packing 3 Si nitride
Aluminum Glass -soda Glass fibers
• often lighter elements Concrete
Silicon PTFE GFRE*
2
Polymers have... Magnesium Graphite
Silicone
Carbon fibers
CFRE*
Aramid fibers
PVC
• low packing density PET
PC
AFRE*
1
(often amorphous) HDPE, PS
PP, LDPE
• lighter elements (C,H,O)
0.5
Composites have... 0.4
Wood
9
10/15/2020
Chapter 3 - 19
Polycrystals Anisotropic
• Most engineering materials are polycrystals.
10
10/15/2020
Chapter 3 - 21
Single vs Polycrystals
• Single Crystals E (diagonal) = 273 GPa
Data from Table 3.3,
-Properties vary with Callister 7e.
(Source of data is R.W.
direction: anisotropic. Hertzberg, Deformation
and Fracture Mechanics
-Example: the modulus of Engineering
Materials, 3rd ed., John
of elasticity (E) in BCC iron: Wiley and Sons, 1989.)
Chapter 3 - 22
11
10/15/2020
Chapter 3 - 23
12