Professional Documents
Culture Documents
Exploration For Chromite in India
Exploration For Chromite in India
Government of India
Ministry of Mines
Geological Survey of India
Mission Natural Resources Assessment, Nagpur
Mission-II,
September, 2020
A Brief on Exploration for
Chromite in India - 2020
Contents
Page No.
Abstract 1
1 Introduction 2
2 Geology 3-7
Mineralogy 3
Genetic Aspects 3-4
Deposit Types 5-6
Age Range 6-7
Geochemistry 7
3 Resources & Production in India 8-23
Exploration Efforts 8-10
Exploration Trend 11
Prospects 11-15
Occurrences 15-21
Associated Commodities 21
Resources 21-22
Planning for Next Five Years 22-23
4 Exploration Opportunities 24-26
5 Challenges 27
Extraction 27
Processing and Analysis 27
Beneficiation 28-29
Future Research & Development 29-30
References 31
A Brief on Exploration for
Abstract
1
I - Introduction
2
concentrated in the Sukinda Ultramafic belt, Odisha. The balance is distributed
in several other Indian states such as Karnataka, Jharkhand, Andhra Pradesh,
Maharashtra, Tamil Nadu, Goa and Nagaland. Kashmir and Manipur have small
pockets of Chromite deposits. At the current level of production, the Indian
recoverable chrome ores will last for only 40 years and hence the strategic
importance for intensification of exploration programmes throughout the
country and converting the remaining resources into reserves.
The typical examples of the Indian ultramafic-mafic rocks are within the
Archean greenstone belts such as in the Singhbhum, Dharwar and Aravalli
Bundelkhand cratons and the Proterozoic ultramafic-mafic bodies within these
cratons (e.g., Proterozoic Dhanjori-Dalma-Simlipal-Jagannathpur-Malangtoli
igneous provinces in the Singhbhum craton). Besides, the younger ultramafic-
mafic intrusions within the adjacent mobile belts and the vast basaltic piles of
the Deccan Traps and its syn-volcanic intrusives such as feeder dikes, sills and
conduits are notable examples for targeting exploration for chromite.
The chromite deposits may have associated occurrences or deposits of PGE,
Au, Ni, Cu, Ti-V ores, iron ore (magnetite) etc. thereby enhancing the economic
aspects of the chromite exploitation.
II –Geology
Mineralogy
The mineral chromite belongs to the spinel group. In its purest form the
chromite ore contains 67.9% chromium oxide, 32.1% FeO and Cr:Fe ratio is
1.8:1. Chromites of economic interest have Cr2O3 content of 25 to 65%, though
the revised threshold value for this ore is 10% Cr2O3. Predominantly, Cr2O3
ores range from 30 to 60%.Various gangues occurring within the ores are
generally orthopyroxene, olivine, calcic plagioclase and their alteration
products, serpentine, chlorites and talc. In fact, the hydrous altered magnesian
silicates are probably more commonly present than the original
minerals.Other less common gangue minerals that have been found in various
deposits, include dolomite, magnesite, brucite, uvarovite (chrome garnet),
Kammererite (chromium chlorite), kaolinite, pyrite, mica, magnetite-hematite,
goethite and opaline & crystaline silica.
Genetic Aspects
All chromite deposits are believed to have formed by early crystal settling or
by late gravitative liquid accumulation from magma. These processes aid in
understanding how layered deposits form, but where differential pressures
3
exist, liquid injection is more likely to form podiform deposits. Many authors
believe existence of late magmatic as well as early magmatic formation of
chromite. The basic principles of crystallization ensure that the first formed
spinellids would be relatively rich in MgO and Cr2O3, and would be most stable.
This principle of crystallization completely nullifies the theory of late magmatic
formation of chromite. Based on the study of the structural relations of
chromite with the associated minerals, it is evident that chromite is the
earliest to crystallize or it crystallised only in part simultaneous with olivine
showing cumulate texture. These processes can be briefly described below:
1. Early magmatic segregation deposits - Chromite is believed to be formed
earlier than olivine or contemporaneous with it and partly included in the
grains in olivine. This genetic type includes the layer like segregations of
chromite in the stratiform layered intrusions of platform areas such as
Bushveld, the great dykes of Rhodesia, Skaergaard of New Foundland and
Sukinda-Baula of India.
2. Late magmatic deposits - Chromite is formed at a late magmatic stage and
crystallizing with the last truly magmatic silicates, commonly either bronzite or
plagioclase. In this genetic type, two types are recognized: one occurring as
syngenetic with the surrounding rocks and second injected and developed
during the intrusion of residual ore silicate melts from the lower zones in the
intrusive body. In Bushveld igneous complex, wherein layers of chromite show
relations to the anorthosite indicate late magmatic association. The
Sitampundi Chromite deposits of India also show relations to the anorthosites
indicating late magmatic association.
3. Hydrothermal deposits –Though of less important as deposits, the chromite
is formed from hydrothermal solutions, for the most part immediately
preceding to or contemporaneous with serpentinization. Chromite of such
origin form nests and veins.
Though it is difficult to determine any definite process or stage of formation of
different chromite deposits, it is evident that segregation and crystallization of
chromite might have taken place in the early magmatic stage and its
emplacement in the present position may be attributed to either in the late
magmatic or hydrothermal stage. Multiple injection of magmas drawn
periodically from a deeper magma as it differentiates, the mechanism of filter
pressing, magma mixing etc., are plausible explanations for various origin of
chromites.
However, all the early magmatic chromite deposits are of sufficient size to be
of economic interest.
4
Deposit Types
High concentrations of ores very rich in chrome are confined to the most
differentiated massive bodies represented by the dunite-troctolite-
harzburgite, and dunite-harzburgite formations. Besides these natural modes
of occurrence, chromite in varying concentrations occurs in the form of placer
deposits when it is sometimes called “Black Sands”. The placer chromite
deposits along the southern part of Oregon coast, USA, constitute one of the
largest known reserves of chromite in that country. Similarly, the placer
deposits along streams in Maryland, Pennsylvania and North Carolina have
been worked economically. In Japan, sizeable quantity of the country’s
reserves is estimated to be available in the stream placers northern Hokkaido.
The Oregon sands, and for that matter all the placer deposits, are found mixed
up with ilmenite and magnetite in varying proportions. Lateritic iron ores
formed by the weathering of ultrabasic rocks contain an appreciable amount
of chromium in the form of chromite. The Cuban lateritic ores range from 1 to
3 percent Cr, probably, mostly in the form of chromite. This low percentage of
chromite in the laterite added to the costly and complicated method of
extraction of chromium from laterite, may apparently lead one to regard the
lateritic deposits as uneconomic. But the tonnage of ore available is so vast
that they constitute a major proportion of the world reserve. The amount of
chromium in the Cuban laterites alone is believed to be eight to ten times the
reserves of entire deposits in North America.The Indian lateritesaround no
chromite zones of Sukinda area have also analysed Cr of 9900ppm which
signifies its importance like the Cuban laterites.
5
Types of Ore:
Massive Ore: It occur as mono-mineralic chromite bodies, devoid of
any primary/hydrothermal silicates in the matrix. It is hard and lumpy
in aggregates.
Friable ore: The material is extremely friable and crumbles to a fine
granular mass, even when mild pressure is exerted through fingers.
Such ore is quarriable with the aid of crowbars only. These are called
brown ores. Sukinda chromites are mainly of this category.
Banded ore: Typical banded ores with alternations of chromite-rich and
silicate rich layers occurring generally at the wall rocks of the chromite
deposits are banded type.
Spotted ore: In this variety, silicates (Olivine). occur as oval or rounded
spots within chromite (Cumulous structure). Friable ore bodies are
spotted in nature.
Age Range:
The Indian chromite deposits occur with different stratigraphic horizons of
different geological ages. However, The economically important chromite
deposits are mainly restricted within the Archaean greenstone belts.
Archaean Greenstone association: Sukinda and Baula-Nausahi (3.1 Ga) in
Odisha. Sinduvalli and Byrapur in Karnataka, Bhandara and Ratnagiri in
Maharashtra, Roroand Jojohatu in Jharkhand and Ponda-Dudsagar area in Goa.
Auge et al. (2003) determined a zircon age of 3123±5 from the Bangur gabbro
intruding the chromiferrous Baula-Nausahi ultramafics and similar 3123±7 and
3119±6 Ma from the PGE mineralised gabbro matrix of the breccia. Sm-Nd data
on gabbro associated in the Baula ultramafic complex yielded a similar age of
3205±280 Ma.
Neo-Archaean to Proterozoic Granulite association: Sitampundi complex of
Southern Granulite belt in Tamil Nadu and Kondapalli Layered complex in
Andhra Pradesh associated with EGMB rocks.
The co-magmatic rocks of the Sittampundi Complex have a whole rock Sm–Nd
isochron age of ca.2935 ± 60 Ma interpreted as the time of first
metamorphism soon after its emplacement (Bhaskar Rao et al., 1996).
Mesozoic Ophiolite association: Ophiolites of Andaman & Nicobar Islands.
Ophiolite sequences of Manipur, Nagaland and Ladakh sectors of Himalayan
belt. The age of the Naga Hill Ophiolites (NHO) has previously been estimated
based on the ages of fossils in associated sedimentary strata. Recent reports of
LA-ICP-MS, U/Pb ages for zircons from plagiogranites within the ophiolite
6
(Singh, Chung, et al., 2017) indicate Early Cretaceous (mid-Aptian) ages that
suggest the ophiolitic mélange requires further investigation in order to
resolve its complexity. Two samples analyzed using SHRIMP yielded similar late
Early Cretaceous (mid-Aptian) ages of 116.63 ± 0.30 Ma and 117.55 ± 0.35 Ma.
Maheo et al. (2003) suggested the South Ladakh ophiolites are relics of an
intra-oceanic arc and according to 39Ar/40Ar dating on amphiboles from both
Spontang and Nidar mafic rocks, this arc developed at around 110 – 130 Ma.
Worldwide, chromiferous mafic-ultramafic intrusions are Mesoproterozoic and
older (USGS, Zientek, 2012). The chromite resources also occur in
Paleoproterozoic and Neoarchean intrusions viz: The Bushveld, Great Dyke,
and Stillwater and with the Tertiary intrusions viz: La Perouse in Alaska and
Skaerga ard in Greenland.
Geochemistry:
The behavior of Cr, Ni and Co during fractional crystallization of non-felspathic,
accumulative type layered magmatic rocks is fairly well known from
geochemical studies carried out by various workers. In such bodies, Cr
crystallizes dominantly in the spinel phase, besides entering the early
pyroxenes. Nickel usually occurs in magnesian olivine and pyroxene grains, the
amount of Ni increasing with increase in Mg/Fe ratio, and Co enters in to the
same minerals as Ni.
7
III -Resources & Production in India
Exploration Efforts:
Out of world’s total chromium resources of over 12 billion tonnes, 95% is
geographically concentrated in South Africa, Zimbabwe & Kazakhstan. Indian
chromite resources account to about 2% of the total world resources.
8
State-wise Distribution of Geological Potential Areas (in sq. km) for Chromite
Odisha 7418.9
Jharkhand 5434.9
Manipur 1775.9
Maharashtra 1366.1
Uttar Pradesh 1355.2
Karnataka 1326.8
Nagaland 1304.5
Tamil Nadu 916.5
Madhya Pradesh 856.5
Andhra Pradesh 612.5
Telangana 512.9
Chhattisgarh 398.9
Goa 24.9
All India OGP-2020 for Chromite 23304.98 sq. km
9
Map OGP-2020: Geological Potential Areas of Chromite
Geology Index for the Chromite, OGP-2020
10
Exploration Trend:
0
2012-13 2013-14 2014-15 2015-16 2016-17 2017-18 2018-19 2019-20
Prospects:
The layered mafic-ultramafic sequences exposed/concealed under thick
laterite or soil cover in the greenstone belts of the country offers excellent
scope for prospecting of chromite. The ophiolite associa on of chromite in
Himalyan belts and Andaman & Nicobar Islands also offer opportunity for
exploration. The economically important chromite deposits are mainly
restricted within the mafic-ultramafic belts and occur as massive, disseminated
and granular types. However, the chromites in ophiolites mostly occur as
nodular types.
The distribution of the mafic-ultramafic rocks in various parts of the country
being the target areas for prospecting of the chromite and associated Ni, PGE
and vanadium bearing magnetite are given in the map.
11
Map: Distribution of mafic-ultramafic rocks (please refer next page for index)
12
Geology Index for the mafic-ultramafic rocks
13
Some of the prospective areas for chromite and associated Ni, PGE and
vanadiferrous magnetites in various mafic-ultramafic belts of the country are:
western extensions of Sukinda-Kathapal-Asurbandh and eastern extensions of
Sukinda- Baula- Nausahi-Nilgiri in Odisha, Roroand Jojohatu in Jharkhand,
Sinduvalli and Byrapur in Karnataka, Bhandara and Ratnagiri in Maharashtra,
Ponda-Dudsagar area in Goa, Kondapalli in Andhra Pradesh, Sittampundi
complex in Tamil Nadu.
In Aravali-Delhi fold belt of Rajasthan and parts of Gujrat, several ultramafic
suite of rocks occur along NE-SW trend right from Rikhabdev-Kherwara in
south within Aravalis, Phulad in central within SDFB and Bidasar-Udaipurwati
in north within NDFB. In view of the similar litho-tectonic set up, these three
ultramafic suites of rocks are important prospects for possible chromite and
PGE occurrence. In Rikhabdev, dismembered bodies of serpentinised
ultramafics, meta-gabbro along with chert and probable plagiogranite are
present. The ultramafics occur as isolated lensoid bodies. A major lensoid body
extend for about 10Km length with variable width from a few meters to 3Km.
The ultramafic body around Masaron-ki-Obri around Rikhabdeb shows avg. Ni
content of 1927ppm and Cr-2457ppm. Raghunandan and Chattopadhyay
(1972) collected ultramafic and associated bed rock samples from Rikhabdev
area, which gave Ni, Co, and Cr content from 700 to 3000 ppm, 50 to 600 ppm
and 8.11 to 0.27% respectively. GSI during 2015-16 identified several grains of
Ni-sulphide such as millerite, heazlewoodite and polydymite through EPMA
studies.
Ophiolite association of chromite occurrences in Manipur, Nagaland, Andaman
& Nicobar Islands and Jammu & Kashmir are also prospects for more detailed
work.
14
Occurrences:
On a cursory glance on the chromite resource map of India (Fig. 3) five clusters
of deposits/ occurrences can be visualized.
visualized These are: 1.Jharkhand and Odisha,
2. Andhra Pradesh, 3. Tamil Nadu,
adu, 4.
4 Karnataka and Goa, and 5. Maharashtra.
In the first cluster, Odisha has the largest resource, Jharkhand contributing a
small percentage. In the second and third clusters, the chromiferous
ultramafics have been emplaced into granulite litho-package
litho and are
associated with anorthosite and pyroxenite.
pyroxenite In the fourth and fifth clusters,
the host ultramafics are intrusive into a granite-greenstone
granite litho-ensemble of
low metamorphic grade.
15
Chromite Resource map of India
1. ODISHA
Major share (98.6%) of chromite resources in the country is located in Odisha.
The major chromite deposits associated with ultramafic complexes are in
Sukinda and Baula Nausahi region. Minor occurrences have been reported in
ultramafic rocks at Bhalukasoni and Ramgiri respectively in Balasore and
Koraput districts.
16
A. OTHER OCCURRENCES AROUND SUKINDA:
1. Kathpal, Jajpur district: The ultramafic body covers an area of 0.4 sq km
with lenses of lumpy chromite within serpentinised dunite and unaltered
orthopyroxenite. The chromiferous ultramafic body occurs as xenolith within
granophyre in the WSW of main Sukinda valley. A total of 1.12 m.t. of lumpy
chromite reserve has been established up to 60 m depth. The area was earlier
mined by FACOR and OMC.
2. Birasal, Dhenkanal district: At about 2.5 km NNE of Birasal, lenses of
chromite ore body occur within altered serpentinised dunite. The altered
chromiferous ultramafic body also possibly occurs as a xenolith within the
granophyre.
3. Maulabhanj Parbat, Dhenkanal district : At about 1.5 km SSE of
Maulabhanj hill near Bhuban several lenses of lumpy chromite ore occurs
within altered dunite alternating with bands of pyroxenite and secondary silica
derived from leached ultramafics in a set up similar to that seen in Sukinda
valley. Extension of such pockets is seen over more than 1 km.
4. Asurbandh - Dhenkanal district: About 6 km ESE of Maulabhanj chromite,
low grade chromite occurs as pockets associated with ultramafic bodies which
have been extensively lateritised. Concentration of pockets of chromite is seen
within chert bands.
5. Ghotringa - Dhenkanal district: North of the village along the western foot
hills of quartzite hill, occurrences of chromite are reported in form of thin
bands and layers within greenish quartzite. This occurrence is thought to be
sedimentary type.
6. Kendragadia - Jajpur district: Low grade chromite ore of irregular
disposition is seen enclosed in silicified and lateritised ultramafic rocks
occurring SW of Kathpal.
17
scree of dunite, serpentinite, chromite strewn around it. Chromite occurs
within the altered dunite and peridotite in form of sugary disseminations and
massive laminae. From the drill hole data, a narrow zone of ultramafic rocks
comprising serpentinised dunite, peridotite, pyroxenite interspersed with thin
zones of gabbroic rocks has been encountered with cumulative thickness
varying from 10.85 m to 11.75 m. This zone thins out westward and occurs as
detached bodies.
The DGM, Orissa identified two small lodes – a western lode having a
dimension of 50 m x 3.5 m x 4.5 m and a very small eastern lode with a
dimension of 5.5 m x 2 m x 3.3 m. The DGM, Orissa estimated a total reserve
of the order of 1550 tonnes for both massive and spotted variety of chromite
with Cr2O3 content from 25.77 to 54.76%.
The ultramafic body at Brahmahuli is lensoidal spreading over an area of
1.5km x 0.5km in a NE-SW trend.
OCCURRENCES AROUND SOUTHERN ODISHA
8. Ramagiri Chromite:
Located in Jeypore of Koraput district, the country rock is granite gneiss with
thin bands and lenses of hornblende schist and chlorite-sericite-quartz schist.
These lithounits form isolated outcrops in an otherwise soil covered area.
Several chromiferous altered ultrabasics (at present an aggregate of talc and
tremolite and/or talc-schist) are exposed occurring as intrusives into the
country rocks. The chromiferous bodies are not continuous in outcrops and
are mostly patchy, bouldery type in soil covered area. Largest individual body
exposed in a nala section has a dimension of 10 m x 4 m.
Detailed mapping reveal that the chromite bearing altered ultrabasics occur as
discontinuous patches over a length of 200 mtrs. in N-S direction. Chromite
forms neither distinct bands nor pockets but is distributed throughout the
altered ultrabasics as disseminated grains.
18
2. JHARKHAND
Chromite deposits of erstwhile Bihar had a pioneering role in the early history
of chromite exploitation in India. Small deposits of chromite ore are confined
to the southern part of Singhbhum district of Jharkhand. Such deposits are
exposed around Jojohatu, Hatmagariya, Keshargariya, Roroburu, Chitungburu,
Kimsiburu, Kittaburu. Small occurrences of chromite are also found at Kusmita
(22o05’: 85 o45’), Gurgaon (22 o25’: 85o10’03"), Tonto (22 o20’: 85 o35’) and
Janoa-Ranjrakocha (22 o31’: 85o38’) areas. Many of the deposits have been
prospected by private parties but abandoned afterwards. The deposits are
rather small, scattered, and the grade is generally inferior (30-40% Cr2O3).
Total chromite reserve of Jharkhand is 0.736 million tones (IMYB, 2015).
3. MAHARASHTRA
Bhandara – Nagpur, Sindhudurg and Chandrapur are three important chromite
producing belts of Maharashtra.
4. ANDHRA PRADESH
In this State, chromite deposits occur as lenses and pods of small dimension in
two distinct geological environments viz. (1) associated with the ultramafics of
the metamorphosed, layered Chimalpad gabbro-anorthosite complex,
intrusive into the Archaean high grade schists and gneisses in Khammam
district, and (2) as lenses and disseminations in orthpyroxenite emplaced
within charnockite and quartzo-feldspathic gneisses of the Proterozoic Eastern
Ghats Supergroup in Kondapalli Hills of Krishna district. The chromite of
Khammam district is of low grade with average Cr2O3 content less than 40%,
the other oxides being within the permissible limits of refractory grades. The
Kondapalli chromite ore has high Cr2O3 content (upto 52%) as also high Fe2O3
(about 18-35%).
5. KARNATAKA
19
Chikkonahalli and Tagadur.
6. GOA
Large ultramafic pluton in Dudhsagar belt near Ponda has been recently
confirmed to be chromiferous, though ore deposits are yet to be discovered in
this Archaean greenstone association.
7. TAMIL NADU
Chromite occurs in Salem and Coimbatore districts in Tamil Nadu associated
with high grade metamorphic rocks hosted in ultramafic complexes.
8. JAMMU AND KASHMIR
Chromite occurs in Brown Hill at Dras, Kargil District and Kyun Tso-Shurok
Sumdo, Leh District and Kyun Tso-Shurok Sumdo, Leh District.
9. CHROMITE DEPOSITS OF ARAKAN SUTURE LINE
Ophiolitic ultramafics occurring in a broadly N-S trend along the Indo-
Myanmar frontier coinciding with Arakan Yoma suture line down to the
Andaman and Nicobar Islands, are studied for chromites and their incidences
to form ore deposits in areas such as Nagaland, Manipur and the Andaman.
10. MANIPUR
Chromite occurs in Manipur as small pockets, lenses and pods in Ukhrul and
Chandel districts and is similar to those of Alpine type in its mode of
occurrence, physical and chemical characters. They are associated with the
meta-ultramafic rocks of the ophiolite suite. The host rocks are harzburgite,
dunite, serpentinite and combination of these. Physically the chromites are of
massive, granular, inter-banded and podiform types. Besides, chromite is
disseminated in dunite and peridotite in which it occurs as highly fractured,
granulated and very rarely as idomorphic grains in serpentinised and bastitised
pyroxenite. Important occurrences have been observed at Sirohi-Gamnom
areas of Ukhrul district, and Moreh area of Chandel district. Although no large
deposit has been found so far, small occurrences of up to a few meters in
extent have been prospected and worked by surface pitting. The chromite is of
high grade with Cr2O3content varying from 44 to 59%. Chemically, these are
comparable with Alpine type chromite in high Cr2O3 content (44-59%) and low
TiO2 (trace), Cr/Cr+Al (0.59 to 0.88) and Mg/Mg+Fe2 (0.46 to 0.74) content.
20
11. NAGALAND
Minor chromite occurrences are located in the ophiolite belt in Reguri and
Washello areas of Phek district and Pang, Pokphu and Wui areas of Tuensang
district. PGE concentration in ophiolite suite of Naga Hills is likely to be of low
in view of the absence of massive chromite or chromitite.
21
and accounts for 30 per cent share in the global trade in chromite ore.
ore With
the recent increase in world demand for chromite, India has stepped up its
production to become third largest chromite producer in the world. In India,
97% of the total chromite deposits occur in association with Iron Ore Group
and other 3% deposits belong to Proterozoic Eastern Ghat Group and Tertiary
Ophiolite formation. About 95% of the total chromite resources i.e.
i 203 MT is
located in Sukinda and Boula-Nuasahi
uasahi belt in Odisha.
Odisha Against this resource
base, and at annual rate of production of chrome ore of around 3.73 MT,the
resources are expected to last for several years.
years
22
Chromite mines at Sukinda Valley are going deeper with opencast
mines already reached up to a depth of about 120m down from the
surface. The six chromite ore bands are sub-vertical (about 700-800
dips) in nature and the exploration carried out by the lessee has proved
chromite up to 250m depth. Hence, underground mining technology
needs to be promoted for exploring the deep seated ore bodies.
Exploration of deep-seated ore bodies needs to be carried out and
efforts need to be intensified to identify more deposits of chromite in
the country.
Besides taking up exploration programmes in the known deposits for
assessing strike and depth continuity, thrust should be given in other
mafic-ultramafic belts of the country.
In India there is no reported occurrence of large chromite deposit of
typical ‘Bushveld type’. Though the occurrence of stratiform
chromitites in Archean greenstone belts (e.g., Nuggihalli, Nuasahi,
Sukinda) and in high-grade terrains (e.g., Sittampundi, Kondapalli) are
presumably genetically linked with high-Mg parent melts that
characterized the Archaean magmatism, search for their potentiality
for Bushveld type deposit need to be intensified.
Suitable technology needs to be developed for beneficiation of low-
grade, friable chromite ore (30% Cr2O3) fines which are available in
sizeable quantity in India. R & D is required for development of suitable
technology for extraction of nickel from the laterite/latsols which are
available in huge quantity as overburden during mining of chromite
ores.
The Sittampundi Complex of Salem district is a major source of
chromite in Tamil Nadu. Further investigations can be planned in this
complex.
In Karnataka, chromite rich belts show presence of layered complexes
in association with greenstone belts represented by Sargurs. More
exploration programmes can be planned with integrated approach.
In Singhbhum district, Jharkhand along Jojohatu-Roro belt, small
chromite ore bodies occur as bands in altered ultramafics, intrusive
into the Precambrian Iron Ore Group. These areas can be revisited
using the modern exploration techniques for finding a good deposit.
Chromite deposits in Maharashtra occur in Bhandara-Nagpur belt,
Sindhudurg belt and Chandrapur belt in association with the
ultramafics of Sakoli and older Groups. These areas also need further
exploration using the modern exploration techniques
Vast resources/reserves of chromite are confined to leasehold areas
and therefore, a proper re-assessment has to be carried out by the
exploring agency.
23
IV - Exploration Opportunities
Chromite resources are located to the extent of 95% in Odisha,
predominantly in Sukinda Valley. There is immense scope for search of
this mineral in the eastern extensions between Sukinda and Baula-
Nuasahi and further east which are mostly covered with thick laterites.
Presently GSI is carrying out G4 stage explora on between the gap
areas of Sukinda and Baula and the field work has shown existence of
ultramafic rocks beneath the lateri c cover in a deep nala sec on.
Hence more nos. of systema c explora on coupled with high end
explora on techniques, MT survey, DSRS etc. need to be intensified in
this large gap areas. The western extensions of the Sukinda deposit,
though patchy occurrence of chromite bodies and magne te (possibly
with Ti & V) are found up to Bhuban-Asurbandh area and beyond,
there is immense scope for detailed explora on for assesing depth and
strike con nuity of chromite and proving other important associated
commodi es viz.: PGE, Ni, Ti and vanadium.
Exploration of deep seated ore bodies needs to be carried out through
multidisciplinary surveys keeping in tune with the modern trends of
mineral exploration. The proving of chromite beyond 250m depth in
the Sukinda belt and re-assessment of resource need to be carried out.
The Multi-sensor Aero-geophysical Survey of the Geological Potential
Area is in progress since 2017in the selected sectors of the country by
GSI with close (300m) line spacing and 80m flight height. The data
generated shall have a great impact on mineral search.
The ongoing ambitious programmes like RMT and Project: Uncover
(India) taken up by GSI shall generate potential mineralised blocks for
further detailed exploration.
The small deposits in Sittampundi complex, Tamil Nadu, Sargur schist
belt, Karnataka, Bhandara-Nagpur belt, Sindhudurg belt and
Chandrapur belt, Maharashtra, Jojohatu-Roro belt, Jharkhand need
reappraisal and revisit in the light of new scientific developments in
latest sophisticated analytical instruments to prove major chromite
bodies in the extensions and other affiliated commodities.
All the mafic-ultramafic complexes of the country whether with known
occurrences or not yet reported or under explored, need continued
checking and revisit.
The enormous extent and thickness of Deccan flood basalts having
picritic composition at the basal flows need detailed and extensive
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exploration, R & D activities for search for many important
commodities including chromite. The Muscox intrusion of Canada is an
excellent example of having layered chromite deposits underneath a
thick pile of basaltic lava at top (copper mine flood basalt, Mackenzie
large igneous province, Day et al., 2013). The funnel shaped feeder
dykes contain picrite which has given rise to a layered complex in the
upper parts of the magma chamber. These layered complexes are in
turn overlain by the thick basaltic flows.
The following target areas of mafic-ultramafic complexes offer
opportunity for further detailed exploration and revisit. (Please refer
prospects map of chromite)
i. Sittampundi and Mettuppalaiyam M-UM complex, TN
ii. Satyamangalam-Attapadi area, Kerala
iii. Hanumalpura and Nuggihali schist belt, Karanataka
iv. Usagaon Complex, Goa
v. Gondipipri and Heti, Maharastra
vi. Kondapalle layered UM complex
vii. Noto pahar Gabbro-anorthosite complex, Odisha
viii. Dibang valley, Arunachal Pradesh
ix. Ophiolite belts of Ladakh
x. Phulad Ophiolite Suite, Rajasthan
xi. Rikhabdeb UM belt, Rajasthan
xii. Bidasar Ophiolites, Rajasthan
xiii. Naga Hill Ophiolite Complex, Nagaland
xiv. Andaman ophiolites, A & N Island.
Appraisal of the Indian laterites in the ultramafic fields of the country can be
an opportunity for exploration for low grade chromite in line with the
occurrence of chromite in Cuban laterite.
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26
V - Challenges
Exploration:
The India is endowed with good mineral wealth, and there may be
many mineral deposits, which are yet to be discovered .There is also a
great need to develop intensive and extensive integrated methods of
exploration in conjunction with geological, geophysical and
geochemical techniques for discovering world-class concealed
Chromite deposits which might have remained undetected so far by
conventional methods of exploration.
Though emphasis was given for the need of detailed exploration in all
the potential areas with a view to estimate resources to a depth of
500m in Sukinda belt and estimation of resources in all other potential
areas of the country, exploration efforts need intensification to identify
more deposits of chromite in the country.
omite orehr Because of friable nature of cin Sukinda Valley at shallow
levels, exploration of deep seated ore bodies needs to be carried out
on priority basis.
Structurally, all the chromite fields are highly complex .Transverse and
dip faults of various trends and magnitude, with numerous folding and
intrusions of various dykes in chromite ore bodies are common
features, posing difficulty in mining, development and exploration at
depths.
R & D is required for development of suitable technology for extraction
of Nickel from the Chromite overburden from the Sukinda area of
Odisha.
Appropriate exploration techniques to be adopted based on their
genetic types. In stratiformiden fica on of the layered nature ,type
and cumulate por ons of the intrusions is important for targe ng the
ultramafic complexes of -not reported chromite occurrences in mafic
,For podiform type .the countryall dunitic portions of Alpine-type
peridotites )Harzburgite Dunite components of ophiolite complexes (
.need careful and detailed study
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Beneficiation:
Chromite ore is a combination of chromite minerals and gangue minerals that
are separated through the beneficiation process after mining. Gangue minerals
affect the performance of chromite products, because beneficiation does not
completely separate them from chromite ore. Metamorphosis of ore can
result in the Cr2O3 reporting to the gangue minerals stream (tailings) during
beneficiation (Greico, 2010).
Mineral beneficiation of chromite ore is the exploitation of physical properties,
such as density and chemical, magnetic, and surface characteristics, to
produce concentrates. Current chromite ore beneficiation practice is to
separate chromite ore from gangue minerals via dense media separation or
gravity separation, which take advantage of the higher density of chromite
minerals [4.3 to 4.5 grams per cubic centimeter(g/cm3)] compared to that of
silicates (the gangue minerals) (2.6 to 4.0 g/cm3). The purpose of beneficiation
is to render the ore physically (granulometry) and chemically suitable for
subsequent treatments. Operations typically serve to separate and
concentrate mineral values from waste materials, remove the impurities or
prepare the ore for further refinement. Beneficiation activities do not change
the mineral values themselves other than by reducing (crushing and grinding)
or enlarging (pelletising and briquetting) particle size to facilitate further
processes. Chromite ore is beneficiated for processing using several methods.
Though gravity techniques are well established and widely accepted for the
concentration of chromite ore, such techniques become inefficient and
complex while treating fine size particles of less than 75 µm. Recovery is a
concern particularly in finely disseminated ores due to its inherent
complexities. Each gravity separation technique delivers its maximum
efficiency under specific operating conditions and particle size range (Murthy
et al., 2011). Heavy medium and gravity concentration methods are the most
commonly used beneficiation processes. Heavy medium separation is the most
economical method when coarse particles ranging between 10-100 mm need
to be treated. In the case of finer particles, jigs, spirals and shaking tables are
used. Spirals are, however, the most important among gravity concentrator
sand are currently the preferred choice.
All chromites are paramagnetic at room temperature. Their magnetic capacity
is dependent on the Fe2+content (Owada & Harada, 1985). It has been
speculated that this ferromagnetism is predominantly present in the sections
more concentrated with Fe2+because of the non-uniform distribution of
magnetic ions in the crystalline structure. Low-intensity magnetic separation
(about 0.1 T) is used to reject the magnetite from paramagnetic chromite
material, but is inefficient in separating the chromites that are present in fine
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intergrowths with other materials. In a high-intensity magnetic field (about 1
T) chromite can be extracted as a magnetic product from the gangue material
(Gu & Wills, 1988; Nafziger, 1982).
Since the host rock for chromite is a store house of many other affiliated Cu-
Ni-PGE, magnetite, V, Ti etc. metals, more research need to be carried out
through experimental petrology, EPMA, SEM studies in respect of their genetic
aspects and accumulation at the critical phase of the fractional crystallization,
critical temperature of sulphide immiscibility phase, sulphide saturation etc.
for targeting the exploration methodology for all associated commodities
along with chromite.
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Serpentinised dunite-peridotite with chromite bands
Emplaced in to IOSG, thick laterite cover
6 chromite seams, strike length: 200m to 2km (up to 7km)
Depth continuity: 250m. Thickness: 1 to 40m
Mostly friable ores except the southern Mahagiri band.
Significant Contributors:
1 Pradeep Kumar Jena, Director, Regional Mission-II, GSI, ER
2 Smt. Sradhanjali Subhadarshini, Sr. Geologist, SU: Odisha, GSI, ER
3 Director of Mission-II, GSI Nagpur for editing, formatting.
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References
1. Auge et al.(2003): Age of the Baula PGE mineralization (Odisha, India) and its
implications concerning the Singhbhum Archaean nucleus, Precambrian
Research 121, pp-85-101.
2. Bhaskar Rao, Y.J., Chetty, T.R.K., Janardhan, A.S., Gopalan, K. (1996): Sm–Nd
and Rb–Srages and P–T history of the Archean Sittampundi and Bhavani
layered meta-anorthosite complexes in Cauvery shear zone, South India:
evidence for Neoproterozoic reworking of Archean crust. Contributions to
Mineralogy and Petrology 125, 237–250.
3. Day, James et al. (2013): Highly siderophile element behavior during flood
basalt genesis and evidence for melts from intrusive chromitite formation in
the Mackenzie large igneous province, Lithos 182-183: 242-258.
4. Day, James et al. (2013): Rhenium-Osmium Isotope and Platinum-Group
Element Constraints on the Origin and Evolution of the1.27 Ga Muskox
Layered Intrusion, Journal of Petrology, Vol. 49, pp 1255-1295.
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Tethys, Chemical Geology 203 (2004) 273 – 303.
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