Date of print: 26/02/2015

EU SAFETY DATA SHEET Rev ision date: 13/01/2015

according to Regulation (EC) No. 1907/2006 and Regulation (EC) No. 453/2010 Date of f irst v ersion: 4/26/2010

Sodium percarbonate
Version 7 / Page 1 of 8

SECTION 1: Identification of the substance/mixture

and of the company/undertaking
1.1 Product identifier
Trade name: Sodium percarbonate
REACH registration No.: 01-2119457268-30-0009

1.2 Relevant identified uses of the substance or mixture and uses advised against
Chemical basic material
Identif ied uses 1. Manufacture, processing and distribution of substances and mixtures
2. Use in Cleaning Agents (Industrial use, Professional use, consumer use)

1.3 Details of the supplier of the safety data sheet

Company name: Zhejiang Jinke Chemicals Co., Ltd.
Street/POB-No.: Hangzhou Bay Fine Chemical Zone
State/city /postal code: Shangyu, Zhejiang, China
Telephone: +86-571-85812235
Telef ax: +86-571-85812333
Dept. responsible f or inf ormation:
NetSun EU B.V. REACH Department,
Telephone: +31 (0)10 842 1148, E-mail reachcompliance@netsun.com

1.4 Emergency telephone number

GIZ-Nord, Germany, Telephone: +49 (0)551-19240

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to EC regulation 1272/2008 (CLP):
Ox. Sol. 3; H272 May intensify fire; oxidiser.
Eye Dam. 1; H318 Causes serious eye damage.
Acute Tox. 4; H302 Harmful if swallowed.
Additional inf ormation Specific concentration limit (SCL):
Eye Dam. 1; H318 >= 25%
Acute Tox. 4; H302 >= 25%
Eye Irrit. 2; H319 >= 10% up to < 25%

Classification according to directive 67/548/EEC:

O; R8 Contact with combustible material may cause fire.
Xn; R22 Harmful if swallowed.
Xi; R41 Risk of serious damage to eyes.

2.2 Label elements

Labelling (CLP)

Signal word Danger

Hazard Statements H272 May intensify fire; oxidiser.
H302 Harmful if swallowed.
H318 Causes serious eye damage.

printed by NetSun EU (en-GB)

 Date of print: 26/02/2015
EU SAFETY DATA SHEET Rev ision date: 13/01/2015
according to Regulation (EC) No. 1907/2006 and Regulation (EC) No. 453/2010 Date of f irst v ersion: 4/26/2010

Sodium percarbonate
Version 7 / Page 2 of 8

Saf ety precautions P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220 Keep/Store away from clothing/.../combustible materials.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P370+P378 In case of fire: Use ... for extinction.
P401 Store in a dry place. Store at temperatures not exceeding 40°C/104°F.

Labelling (67/548/EEC or 1999/45/EC)

O Xn

oxidizing harmful
R phrase(s): R8 Contact with combustible material may cause fire.
R 22 Harmful if swallowed.
R 41 Risk of serious damage to eyes.
S phrase(s): S3 Keep in a cool place.
S8 Keep container dry.
S 17 Keep away from combustible material.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.

2.3 Other hazards

Additional inf ormation Specific concentration limit (SCL):
Xi; R41 >= 25%
Xn; R22 >= 25%
Xi; R36 >= 10% up to < 25%

SECTION 3: Composition/ information on ingredients

3.1 Substances
Chemical characterization (substance)
C2 H6 Na4 O12 = 2 Na2CO3 * 3 H2O2
Disodium carbonate, compound with hydrogen peroxide (2:3)
Sodium percarbonate
CAS-Number: 15630-89-4
EINECS-Number: 239-707-6
RTECS-Number: FG0750000
Additional inf ormation: Impurity:
CAS 497-19-8 Sodium carbonate EU: Xi; R 36. CLP: Eye Irrit. 2. H319 <= 10%

SECTION 4: First aid measures

4.1 Description of first aid measures
Af ter inhalation: Provide fresh air. If you feel unwell, seek medical advice.
In case of skin contact: Remove residues with soap and water. Change contaminated clothing. In case of skin
reactions, consult a physician.
Af ter ey e contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids apart.
Subsequently consult an ophthalmologist.
Af ter swallowing: Rinse mouth. Seek medical attention.

printed by NetSun EU (en-GB)

 Date of print: 26/02/2015
EU SAFETY DATA SHEET Rev ision date: 13/01/2015
according to Regulation (EC) No. 1907/2006 and Regulation (EC) No. 453/2010 Date of f irst v ersion: 4/26/2010

Sodium percarbonate
Version 7 / Page 3 of 8

4.2 Most important symptoms and effects, both acute and delayed
No data available
4.3 Indication of any immediate medical attention and special treatment needed
No special measures are required.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media:
Co-ordinate fire-fighting measures to the fire surroundings.
5.2 Special hazards arising from the substance or mixture
Not combustible. May decompose slowly if local heating up above 50 °C.
Formation of: Sodium carbonate and hydrogen peroxide.
In case of fire may be liberated: Carbon monoxide and carbon dioxide, NaOx
5.3 Advice for firefighters
Special protectiv e equipment f or f iref ighters:
Wear self-contained breathing apparatus. Wear suitable protective clothing.
Additional inf ormation: Hazchem-Code: 1Y
Cool endangered containers with water jetspray. Do not allow fire water to penetrate into
surface or ground water.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment. Avoid generation of dust. Do not breathe dust. Provide
adequate ventilation. Avoid contact with skin and eyes.
6.2 Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.
6.3 Methods and material for containment and cleaning up
Take up dust-free and set down dust-free. Place in appropriate containers for disposal.
6.4 Reference to other sections
not required

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Adv ices on saf e handling Avoid generation of dust. In case of dust: Provide adequate ventilation, and local exhaust as
needed. Avoid contact with skin and eyes. Do not breathe dust.
Precautions against f ire and explosion:
Keep away from sources of ignition and heat.

7.2 Conditions for safe storage, including any incompatibilities

Requirements f or storerooms and containers:
Keep container dry, tightly closed and store at cool and aired place. Keep away from heat
sources, sparks and open flames. Protect from humidity and water.
Hints on joint storage Do not store together with highly inflammable or combustible materials.
Storage class: 5.1 A = Oxidising substances

printed by NetSun EU (en-GB)

 Date of print: 26/02/2015
EU SAFETY DATA SHEET Rev ision date: 13/01/2015
according to Regulation (EC) No. 1907/2006 and Regulation (EC) No. 453/2010 Date of f irst v ersion: 4/26/2010

Sodium percarbonate
Version 7 / Page 4 of 8

7.3 Specific end use(s)

No data available

SECTION 8: Exposure controls/personal protection

All exposure relev ant inf ormation (human health and env ironment) is summarised in annexes to this saf ety data sheet.

8.1 Control parameters

Additional inf ormation: Contains no substances with occupational exposure limit values.
DNEL DNEL Acute, workers, dermal: 12,8 mg/cm².
DNEL Long Term, workers, inhalative: 5 mg / m³.
DNEL Acute, consumers, dermal: 6,4 mg/cm².
PNEC PNEC stp: 16 mg/L.
The product hydrolyses quickly in the presence of water to: Sodium carbonate and hydrogen
peroxide (H2O2).
Hydrogen peroxide (H2O2):
PNEC water: 0,01 mg/L.

8.2 Exposure controls

In the case of the formation of dust: Withdraw by suction.

Occupational exposure controls

All information for relevant exposure scenarios including operational conditions and risk management measures are
listed in 'Annex I: Worker Exposure and Risk Assessment'.
Respiratory protection: In case of dust: Particulates filter P3 according to EN 143.
Hand protection: Protective gloves according to EN 374.
Glove material: Nitrile rubber
Breakthrough time: >480 min.
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Ey e protection: Tightly sealed safety glasses according to EN 166.
Body protection: Wear suitable protective clothing.
General protection and hy giene measures:
Change contaminated clothing. Wash hands before breaks and after work. Provide a
conveniently located eye rinse station. Do not breathe dust. Avoid contact with skin and eyes.
When using do not eat, drink or smoke.

consumer exposure controls

All information for relevant exposure scenarios including operational conditions and risk management measures are
listed in 'Annex II: Consumer Exposure and Risk Assessment'.

Environmental exposure controls

All information for relevant exposure scenarios including operational conditions and risk management measures are
listed in 'Annex III: Environmental Exposure and Risk Assessment'.

SECTION 9: Physical and chemical properties

9.1 information on basic physical and chemical properties
Phy sical state: solid
Colour white
Odour: odourless
Boiling temperature / boiling range In case of heating: Decomposition
Melting point / melting range In case of heating: Decomposition
Flash point / f lash point range: not combustible

printed by NetSun EU (en-GB)

 Date of print: 26/02/2015
EU SAFETY DATA SHEET Rev ision date: 13/01/2015
according to Regulation (EC) No. 1907/2006 and Regulation (EC) No. 453/2010 Date of f irst v ersion: 4/26/2010

Sodium percarbonate
Version 7 / Page 5 of 8

Autof lammability : In case of heating: Decomposition

Explosiv e properties: Product is not explosive.
Vapour pressure: at 25 °C: negligible
Density : 2,01-2,16 g/cm³
pH v alue: at 25 °C, 1%: 10,4-10,6
Water solubility : at 25 °C: 140 g/L
Thermal decomposition: In case of heating: Decomposition

9.2 Other information

Molecular weight: 314.06 g/mol

SECTION 10: Stability and reactivity

10.1 Reactivity
No data available

10.2 Chemical stability

Product is stable under normal conditions.

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

Humidity, warmness. Protect from light.

10.5 Incompatible materials

Strong reducing agents, strong acids, Organic materials, powdered metals

10.6 Hazardous decomposition products

May decompose slowly if local heating up above 50 °C.
Formation of: Sodium carbonate and hydrogen peroxide.
In case of fire may be liberated: Carbon monoxide and carbon dioxide, NaOx
Thermal decomposition: In case of heating: Decomposition

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity : LD50 Rat, oral: 1034-2000 mg/kg
LD50 Rabbit, dermal: > 2000 mg/kg
Af ter swallowing: Harmful.
The following symptoms may occur: Cough, shortage of breath, Headache, Nausea, vomiting
In case of skin contact: Irritant.
Specific symptoms in animal studies (Rabbit): Mild irritant.
Af ter ey e contact: Risk of serious damage to eyes.

printed by NetSun EU (en-GB)

 Date of print: 26/02/2015
EU SAFETY DATA SHEET Rev ision date: 13/01/2015
according to Regulation (EC) No. 1907/2006 and Regulation (EC) No. 453/2010 Date of f irst v ersion: 4/26/2010

Sodium percarbonate
Version 7 / Page 6 of 8

SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity : Algae toxicity:
EC50 Anabaena sp.: 8 mg/L/140 h.
Daphnia toxicity:
EC50 Daphnia pulex: 4,9 mg/L/48h.
Fish toxicity:
LC50 Pimephales promelas: 70,7 mg/L/96h.
source: IUCLID.
Water Hazard Class: 1 = slightly hazardous to water (WGK catalog number 1364)

12.2. Persistence and degradability

Further details: Methods for the determination of biodegradability are not applicable to inorganic substances.

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

No data available

12.6 Other adverse effects

General inf ormation: Do not allow to enter into ground-water, surface water or drains.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Product
Waste key number 0613 = Wastes from inorganic chemical processes not otherwise specified
Recommendation: Special waste. Dispose of waste according to applicable legislation.

Contaminated packaging
Recommendation: Dispose of waste according to applicable legislation. Handle contaminated packages in the
same way as the substance itself.
Non-contaminated packages may be recycled.

SECTION 14: Transport information

14.1 UN number
ADR/RID, IMDG, IATA: 3378

14.2 UN proper shipping name

ADR/RID, IMDG, IATA: UN 3378, SODIUM CARBONATE PEROXYHYDRATE

14.3 Transport hazard class(es)

ADR/RID: Class 5.1, Code: O2
IMDG: Class 5.1, Code -
IATA: Class 5.1

printed by NetSun EU (en-GB)

 Date of print: 26/02/2015
EU SAFETY DATA SHEET Rev ision date: 13/01/2015
according to Regulation (EC) No. 1907/2006 and Regulation (EC) No. 453/2010 Date of f irst v ersion: 4/26/2010

Sodium percarbonate
Version 7 / Page 7 of 8

14.4 Packing group

ADR/RID, IMDG, IATA: III

14.5 Environmental hazards

Marine Pollutant No

14.6 Special precautions for user

Land transport (ADR/RID)
Warning board: ADR/RID: Kemmler-number 50, UN number 3378
Hazard label 5.1
Limited quantities 5 kg
EQ E1
Contaminated packaging: Instructions P002 IBC08 LP02 R001
Contaminated packaging: Special prov isions B3
Special prov isions f or packing together MP10
Portable tanks: Instructions T1 BK1 BK2
Portable tanks: Special prov isions TP33
Tank coding SGAV
Tunnel restriction code: E

Sea transport (IMDG)

EmS: F-A, S-Q
Special prov isions 967
Limited quantities 5 kg
EQ E1
Contaminated packaging: Instructions P002, LP02
Contaminated packaging: Prov isions -
IBC: Instructions IBC08
IBC: Prov isions B3
Tank instructions: IMO -
Tank instructions: UN T1, BK2, BK3
Tank instructions Prov isions TP33
Stowage and segregation Category A. Keep as dry as reasonably practicable. "Separated from"
permanganates. "Away from" any sources of heat.
Properties and observ ations White crystals or powder. Soluble in water. Mixtures with combustible material
are readily ignited. Decomposes in contact with water and acids, forming
hydrogen peroxide. Risk of decomposition when exposed to continuous heat
(exothermic decomposition >= 60°C). When involved in a fire or exposed to high
temperatures, it may decompose, yielding oxygen and steam. Irritating to skin,
eyes and mucous membranes. Harmful if swallowed.

Air transport (IATA)

Hazard Oxidizer
EQ E1
Passenger Ltd.Qty .: Pack.Instr. Y546 - Max. Net Qty/Pkg. 10 kg
Passenger: Pack.Instr. 559 - Max. Net Qty/Pkg. 25 kg
Cargo: Pack.Instr. 563 - Max. Net Qty/Pkg. 100 kg
ERG 5L

14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
No data available

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
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 Date of print: 26/02/2015
EU SAFETY DATA SHEET Rev ision date: 13/01/2015
according to Regulation (EC) No. 1907/2006 and Regulation (EC) No. 453/2010 Date of f irst v ersion: 4/26/2010

Sodium percarbonate
Version 7 / Page 8 of 8

National regulations - Great Britain

Hazchem-Code: 1Y
National regulations - Germany
Storage class: 5.1 A = Oxidising substances
Water Hazard Class: 1 = slightly hazardous to water (WGK catalog number 1364)
Inf ormations on working limitations:
Observe employment restrictions concerning young persons.
Observe employment restrictions for expectant or nursing mothers.
National regulations - USA
TSCA Inventory: listed
TSCA HPVC: not listed
Hazard rating sy stems NFPA Hazard Rating:
Health: 2 (Moderate)
0 Fire: 0 (Minimal)
2 2 Reactivity: 2 (Moderate)
HMIS Version III Rating: HEALTH 2

Health: 2 (Moderate) FLAMMABILITY 0

Flammability: 0 (Minimal) PHYSICAL HAZARD 2
Physical Hazard: 2 (Moderate) X
Personal Protection: X = Consult your supervisor
15.2 Chemical Safety Assessment
For this substance a chemical safety assessment has been carried out.

SECTION 16: Other information

Further remarks
Reason of change: CADR 2015, IATA 2015

Group that issues data sheet

Contact person: see chapter 1, department responsible for information.

The information in this data sheet has been established to our best knowledge and was up-to-date at time of revision.
It does not represent a guarantee for the properties of the product described in terms of the legal warranty regulations.

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