JOAQUIN Maria Katrina A.

,
2020-11082

1. Ka Of Formic Acid : 1.78×10-4

A) pH of a 0.1M solution of formic acid ?

nii
"
[ Ht ][ A I
78×10-4 :[ Ht ]
-

Ka : = g. = > [ Ht ] : 4.130943246×10 -3M

[ HA ] 0.1M -

ltlt ]
in

0.1M [ A- ] -

pH log [ Ht ] =
log [4.130943×10-3]=2.383950772--2.38
-
:
-

b) 150mL Of 0.1M NaOH is added to 200mL Of 0.1M formic acid is added to What is the pH of the final 501h ?
,
and water give a final volume of 1L .

HCOOH ,
'
Htt HCOO -
°
HCOOH 1- OH '
HCOO
-

t 1-120
,
,

From a) [1-1-1] :[ ] 4.1309433×10 -3M [ HCOOH ] 0.1M 4.130943×10 -3mi 0.09586905675M

-

HCOO
'

= : -
. .

[ HCOO ]
-

[ OH ] 11-11001-17 Initially ,

thot b) 0 015m01 c) 1.917×10 1m01 4.130943246×10-3 MOYL 8-261886492×10 4m01 8.262×10 4m01
- - -

I 9) 8.262×10 0.200L
-

0
-

a)
=
I

( t D. 015m01 d. 015m01 O 015m01 Mol

/L D. 015m01
-

b) 0.1 0,15L
'
-
=
-

E 1.58262×10
"
0 4.17381135×10-3 c) 0.09586905675 moth -0.200L : 0.01917381135 MOI = 1.917×10
-

2m01

[ " COO ) '

' '

1-58262×10
pH :p Kat log :
log (1.78×10-4) +
log -3=4-328423832 I 4.33
-

[ HCOOH ] 4. 1,3g , ,zg× , ,

2. Given : 0.1M CHZCOOH ,

0.1M NACHZCOO , pKa : 4-76
, Mwa, , coop, i 60
-05196g / MOI , MWNacnz.co ,
i
82.03379 91m01

Required : Prep 1L of 0.1M acetate buffer at pH 5.4 ?

using HHE : ] [ Ctlzcoo ]

10%4-4^6
-

[ ( " 3100 ] " " 3100

' "

pH :
pkat log 5.4--4.76 1- log = > i =
4.365158322
[4-131001-1] [01-136001-1] [ cµ , goop, ,

0.1M :[ sum of all acetate species ] =

[01-13100] 1- [ CHZCOOH ] ,
ICH } COOH ] :
0.01863877895M I 0.018639M

=
4.365158322 ICH } COOH ] 1- ICHZCOOH ] :
5- 3651583221GHz COOH ] ✓ [ CH } COO
-

] :
0.1M -0.01863877895M =
0.08136122105M

I 0.0814M
calculating the mass :

mass NACHZCOO =
0.0814m¥ ✗ 1L X 82.03379 91m01 =
6.678g
"
V01 CH , COOH : 0.01863877895 Mx IL ✗ / 0.1 moi =
0.18639L : 186.39mL

Preparation :

prepare 6.678,9 of NaCl-13100 and 186.4 .no/-CHzCOOH and mix them w/ distilled water in a beaker until all solid particles are dissolved .

the pH if 0.1M HCl drop wise until needed if pH is lower desired , add 0.1M NaOH drop wise
Measure , pH is
higher than target pH , add . than

until needed .

Transfer to 1L volumetric flask and fill w/ distilled water until it reaches 1L .

3. Given : pkg = 8.3 ,

1L
of 0.05M Bicine
pkb
Bicinetlt-P-%13icine.tt/tBicinetHz0--BicineHttOH- pkb pkw : -

pKa -14-8.3--5.7
.

initially :
[ OH ][ Bicinetlt ] [ OH ] :[ Bicinetlt ]
-

:X
-

Kai
[ Bicine ] [ Bicine ] : 0.05 X
-

,
2
"
10-5
✗
: = > × : 3.148569414×10 -4M '

[ Bicine ] : 0.05-3.148569414×10 -4M :

4.968514306×10 -2M 14.9685×10 2m01
-

og ×
. .

o
-

↳ 3.148569414×10 4m01
-

↳ given 1L Of buffer so In

using HHE :

[ Bicine ] " " ""}

[ Bicine ] "" " "
PH :p Kat log
= 10 = 10 :
0.1584893192 =) 0.1584893192 [ Bicinetlt ] :[ Bicine ]
[ Bicineiyt ] [ Bicinetit ]

0.05 :[ Bicinetlt ] t [ Bicine ] :[ Bicinetlt ] 1- 0.1585 [ Bicinetlt ] :

1.1585 [ Bicinetlt ]

[ Bicinetlt ] :
0.04315965557M I 0.0432 MOI

-3
3m01
-

[ Bicine ] : 0<05-0.0431596557--6.84034443×10 MI 6.84×10

2m01 6.84×10 3m01 4.28×10 2m01

-

Amo , [ Bicine ] 4.9685×10 is needed

- -

=
Of Ht 428.46mL of 0.1N HCl
-

: =
4. Given : 50mL Of 0.01M Hat 100mL of 0.05M phosphate buffer @ pH :
7.2 , pKa -7-2
-

Required IHPOYZ
-

pH ? ?
of Hzpoy
-

: :
conc
,

[ HPOYZ ] [ Ht ] ]
-

[ Hzpoy
-

Initially :
I b) 5×10 4m01
-

a) 0.0025 MOI c) 0.0025 MOI

a) ( 0.025M )( 0.14--0.002 5m01

4m01 4m01 4m01

- -

C 5×10 5×10 1-5×10

-

b) 10.01M ) / 0.054=5×10-4 MOI

-
-

3m01 3m01
-

3×10
-

E 2×10 0
10.025M )( 0.14=0.0025
MOI
c)

)
" 002

a) PHI 7.2 flog / 0.003

= 7.023908741 I 7.02

0.002
b) [1-110042] [ 1-121004 ] 0.003
-

: :
MOI
i
0.013g µ = 0.02M
0.15L
0.15L

5. Given : 50mL 0.01M NaOH t 100mL 0.05 Phosphate Buffer ( pH : 7.2 , pKa 7. 2)
-

, ,

Reqd : pH ? [ Hzpoy ] & [ HPOY ]

- -

[ Hzpoy ] [ OH ] [ HPO ;] Initially :

-

Solution :

I 9) 0.0025 b) 5×10-4 c) 0.0025 9) ( 0.025M )( 0.054--0.0025 MOI

C -
5×10-4 -
5×10-4 1-5×10-4 b) 10.01M ) / 0.054=5×10-4 MOI

E 0.003 0 C) 10.025M ) / 0.054--0.0025 MOI

0.002

(°¥%)
0.002
b) [ Hzpoy ] M
i
0.0133
a) pH
'

7.21-109
: :
0.1g ,

"
0.003
= 7.376091259=7.38 [ HPOY ] :
0.1g ,
=
0.02M

6. alanine ionic dissociation

11° PK ' : ? -4
1,0 pkz -9.7
1,0
.

µ, , ' H3C H3C Pkitpkz 2.41-9.7

PI
'
OH , O
-

O
-

: = i 6.05
µ µ
,
µ 2 z
NH , NH , NH
,

given that PI <

pH ,
the alanine will travel towards pI ( downward )
,
it will be gaining Ht

and will be attracted to the negative electrode / cathode )