DIACETANIL YELLOW 3 RH 8315C

Safety Data Sheet

according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 11/06/2014 Revision date: 05/05/2015 Version: 1.1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier
Product form : Mixture
Trade name : DIACETANIL YELLOW 3 RH 8315C
Product code : 8315C
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Dyestuff/pigment
1.3. Details of the supplier of the safety data sheet
Cappelle Pigments NV
Kortrijkstraat 153
MENEN, 8930 - België
T 056 / 52.12.40 - F 056 / 52.12.63
msds@cappelle.be - www.cappelle.be
1.4. Emergency telephone number
Emergency number : B.I.G.: Tel. +32 (0)14 58 45 45 - Fax +32 (0)14 58 35 16

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
GHS-US classification
Not classified

2.2. Label elements

Other hazards not contributing to the : Do not breathe dust. Flammable dust clouds may be formed. Use explosion-proof electrical,
classification ventilating, lighting, … equipment.
2.4. Unknown acute toxicity (GHS-US)
Not applicable

SECTION 3: Composition/information on ingredients

3.1. Substance
Not applicable
3.2. Mixture
Full text of H-phrases: see section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
First-aid measures general : Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure.
First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
First-aid measures after skin contact : Wash with plenty of soap and water. Remove/Take off immediately all contaminated clothing.
Wash contaminated clothing before reuse.
First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel
unwell.
4.2. Most important symptoms and effects, both acute and delayed
No additional information available
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : water, carbon dioxide (CO2), powder and foam.

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DIACETANIL YELLOW 3 RH 8315C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixture
Explosion hazard : Avoid dust formation. Avoid dust to spread.
Reactivity : Stable under normal conditions. See Heading 7.
5.3. Advice for firefighters
Precautionary measures fire : Eliminate all ignition sources if safe to do so.
Firefighting instructions : Fight fire remotely due to the risk of explosion.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.
Other information : Avoid (reject) fire-fighting water to enter environment. Do not allow run-off from fire-fighting to
enter drains or water courses.

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
General measures : Do not breathe dust. Avoid contact with skin and eyes.

6.1.1. For non-emergency personnel

Protective equipment : Refer to chapter 8.
Emergency procedures : Absorb spillage to prevent material damage. Avoid dust to spread. Only qualified personnel
equipped with suitable protective equipment may intervene.
Measures in case of dust release : Avoid dust to spread.

6.1.2. For emergency responders

No additional information available
6.2. Environmental precautions
Prevent entry to sewers and public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Methods for cleaning up : Contain and collect as any solid. Avoid dust to spread.
Other information : Spilled product must never be returned to the original container for recycling.
6.4. Reference to other sections
See Heading 8.

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Handle and open container with care. Open only in well ventilated area away from all ignition
sources. Keep away from ignition sources (including static discharges). Proper grounding
procedures to avoid static electricity should be followed. Avoid dust formation. Avoid dust to
spread. Handle product only in closed system or provide appropriate exhaust ventilation. In
case of inadequate ventilation wear respiratory protection.
Hygiene measures : Do not eat, drink or smoke in areas where product is used. Wash hands and other exposed
areas with mild soap and water before eating, drinking or smoking and when leaving work.
Wash contaminated clothing before reuse. Separate working clothes from town clothes.
Launder separately.
7.2. Conditions for safe storage, including any incompatibilities
Storage conditions : Keep only in the original container in a cool,well-ventilated place away from oxidizing agents.
Keep container tightly closed. Keep away from ignition sources (including static discharges).
Keep away from heat and direct sunlight.
Storage area : Store in dry, cool, well-ventilated area.
7.3. Specific end use(s)
Dyestuff/pigment.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters
DIACETANIL YELLOW 3 RH 8315C
ACGIH ACGIH TWA (mg/m³) <= 5 mg/m³ respirable dust
OSHA Not applicable

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DIACETANIL YELLOW 3 RH 8315C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

8.2. Exposure controls

Appropriate engineering controls : SECTION 7.
Personal protective equipment : Dust production: dust mask with filter type P3. Insufficient ventilation: wear respiratory
protection. In case of dust production: protective goggles. In case of dust production: head/neck
protection. In case of dust production: dustproof clothing. Gloves.

Hand protection : Chemical resistant gloves (according to European standard NF EN 374 or equivalent).
Eye protection : Wear tight fitting safety glasses or face shield. Safety glasses with side guards should be worn
to prevent injury from airborne particles and/or other eye contact with this product.
Skin and body protection : Wear suitable protective clothing, gloves and eye or face protection. Impervious footwear must
be worn. Separate work clothes from street clothes.
Respiratory protection : Wear appropriate mask. Wear appropriate breathing apparatus if air renewal not sufficient to
maintain dust/vapour under TLV.
Environmental exposure controls : Avoid direct discharge into drains. Avoid release to the environment.
Other information : To our knowledge, this product does not present any particular risk, provided it is handled in
accordance with good occupational hygiene and safety practice. Avoid dust formation. Avoid
dust to spread.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Solid
Appearance : Dry powder.
Colour : Yellow
Odour : None
Odour threshold : No data available
pH : No data available
pH solution : 5 - 7 50 g/l
Relative evaporation rate (butylacetate=1) : Not applicable
Relative evaporation rate (ether=1) : Not applicable
Melting point : > 200 °C Decomposes without melting
Freezing point : Not applicable
Boiling point : Not applicable
Flash point : Not applicable
Auto-ignition temperature : No data available
Decomposition temperature : No data available
Flammability (solid, gas) : No data available
Vapour pressure : Not applicable
Vapour pressure at 50 °C : Not applicable
Relative vapour density at 20 °C : No data available
Relative density : No data available
Density : 1,5 g/cm³
Solubility : Water: Insoluble
Ethanol: Insoluble
Ether: Insoluble
Acetone: Insoluble
Organic solvent:Insoluble
Log Pow : No data available
Log Kow : No data available
Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosive properties : No data available
Oxidising properties : No data available

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DIACETANIL YELLOW 3 RH 8315C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

Explosive limits : No data available

9.2. Other information
Minimum ignition energy : 1 - 3 mJ
Sublimation point : Not applicable
Saturation concentration : Not applicable
Fat solubility : Insoluble

SECTION 10: Stability and reactivity

10.1. Reactivity
Stable under normal conditions. See Heading 7.
10.2. Chemical stability
Stable under normal conditions. See Heading 7.
10.3. Possibility of hazardous reactions
No dangerous reactions known.
10.4. Conditions to avoid
See Heading 7.
10.5. Incompatible materials
No dangerous reactions known.
10.6. Hazardous decomposition products
See Heading 5. Thermal decomposition may produce : 3,3'-dichlorobenzidine.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Not classified

(Conclusive but not sufficient for classification)
DIACETANIL YELLOW 3 RH 8315C
LD50 oral rat >= 2000 mg/kg bodyweight
LD50 dermal rat > 2000 mg/kg bodyweight
LC50 inhalation rat (mg/l) Not determined.
Skin corrosion/irritation : Not classified
(Conclusive but not sufficient for classification)
Serious eye damage/irritation : Not classified
(Conclusive but not sufficient for classification)
Respiratory or skin sensitisation : Not classified
(Conclusive but not sufficient for classification)
Germ cell mutagenicity : Not classified
(Conclusive but not sufficient for classification)
Carcinogenicity : Not classified
(Lack of data)
Reproductive toxicity : Not classified
(Conclusive but not sufficient for classification)
Specific target organ toxicity (single exposure) : Not classified
(Conclusive but not sufficient for classification)
Specific target organ toxicity (repeated : Not classified
exposure) (Conclusive but not sufficient for classification)
Aspiration hazard : Not classified
(Lack of data)

SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : Material insoluble in water. Not classified.

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DIACETANIL YELLOW 3 RH 8315C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

12.2. Persistence and degradability

DIACETANIL YELLOW 3 RH 8315C
Persistence and degradability Not established. Material insoluble in water. Not readily biodegradable.

12.3. Bioaccumulative potential

DIACETANIL YELLOW 3 RH 8315C
Bioaccumulative potential Not established. Material insoluble in water. Insoluble in oils/fats. Practically not
bioaccumulable.

12.4. Mobility in soil

DIACETANIL YELLOW 3 RH 8315C
Ecology - soil Not established. Material insoluble in water. Ultimate destination of the product : soil and
sediment.

12.5. Other adverse effects

Effect on ozone layer : No known ecological damage caused by this product.

Effect on the global warming : No known ecological damage caused by this product.

Effect on the global warming : No known ecological damage caused by this product.

SECTION 13: Disposal considerations

13.1. Waste treatment methods
Sewage disposal recommendations : Material insoluble in water. physico-chemical treatment.
Waste disposal recommendations : This material and its container must be disposed of in a safe way, and as per local legislation.
Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber.
Recycling is preferred to disposal or incineration. Recycle or dispose of in compliance with
current legislation.
Additional information : This material and its container must be disposed of as hazardous waste.

SECTION 14: Transport information

In accordance with DOT
Not regulated for transport
Additional information
Other information : No supplementary information available.

ADR
No additional information available
Transport by sea
No additional information available
Air transport
No additional information available

SECTION 15: Regulatory information

15.1. US Federal regulations
No additional information available

15.2. International regulations

CANADA
No additional information available

EU-Regulations
No additional information available
Classification according to Regulation (EC) No. 1272/2008 [CLP]
Not classified
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]
15.2.2. National regulations
\

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DIACETANIL YELLOW 3 RH 8315C
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations

15.3. US State regulations

SECTION 16: Other information

Revision date : 05/05/2015

SDS US (GHS HazCom 2012)

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product

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