KENDRI

YAVI
DYALAYASANGATHAN,
Ter
m-1Pr
eboar
dExam (
2021-
22)
Cl
ass:
XII
Subj
ect
:Chemi
str
y(043)
Ti
me:
90Mi
nut
es Max.Mar
ks:
35
Gener
alI
nst
ruct
ions:
1.TheQuest
ionPapercont
ainst
hreesect
ions.
2.Sect
ionAhas25quest
ions.At
temptany20quest
ions.
3.Sect
ionBhas24quest
ions.At
temptany20quest
ions.
4.Sect
ionChas6quest
ions.At
temptany5quest
ions.
5.Al
lquest
ionscar
ryequal
mar
ks.
6.Ther
eisnonegat
ivemar
king.

SECTI
ONA
Thi
ssect
ionconsi
stsof25mul
ti
plechoi
cequest
ionswi
thov
eral
lchoi
cet
oat
temptany
20quest
ions.I
ncasemor
ethandesi
rabl
enumberofquest
ionsar
eat
tempt
ed,
ONLY
f
ir
st20wi
l
lbeconsi
der
edf
orev
aluat
ion.

1.Whi
choft
hef
oll
owi
ngi
sanet
wor
ksol
i
d?
(
a)Si
O2
(
b)I
2

(
c)SO2(
sol
i
d)
(
d)H2O(
ice)

2.I
n1962,
Nei
lBar
tl
ettpr
epar
edar
edcol
oredcompoundofXe.I
twas
a)Xe+[ −
( PdF6]
b)Xe+[ −
( PtF5]
c)Xe+[ −
( PtF6]
d)Xe2+[ −
( PtF6]

1
3.Peopl
etaki
ngl
otofsal
texper
iencepuf
fi
nessorswel
l
ingoft
hebodyduet
o:
(
a)Wat
erl
ossf
rom t
hecel
l
sduet
oosmosi
s.
(
b)Wat
err
etent
ioni
nti
ssuecel
l
sandi
nter
cel
l
ularspacesbecauseofosmosi
s.
(
c)Capi
l
lar
yact
ionofwat
ert
hroughski
npor
es.
(
d)Excessi
vet
hir
standdr
inki
ngmor
ewat
er.

4.
Thecr
yst
alsy
stem ofacompoundwi
thuni
tcel
ldi
mensi
ons,
a=0.
387nm,
b=0.
432nm
andc=0.
504nm andα=β=γ=90ᵒ
(
a)cubi
c
(
b)hexagonal
(
c)or
thor
hombi
c
(
d)r
hombohedr
al

5.I
ndehy
drohal
ogenat
ionr
eact
ions,
thepr
efer
redpr
oducti
sthatal
kenewhi
chhast
he
gr
eat
ernumberofal
kyl
groupsat
tachedt
othedoubl
ybondedcar
bonat
oms.Thi
srul
e
i
sknownas:
(
a)Say
tzef
f’
srul
e

(
b)Per
oxi
der
ule

(
c)Mar
kov
nikov
’sr
ule

(
d)Hof
fmannr
ule

6.
Thet
wocy
cli
chemi
acet
alf
ormsofgl
ucosedi
ff
eronl
yint
heconf
igur
ati
onoft
he
hy
drox
ylgr
oupatC1(
theal
dehy
decar
bonbef
orecy
cli
sat
ion)
.α-
for
m andβ-
for
m of
gl
ucosear
ecal
l
ed-
--
--
--
--
--
--
-

(
a)St
ereoi
somer
s
(
b)St
ruct
ural
isomer
s
(
c)Anomer
s
(
d)Epi
mer
s

2
7.Whi
choft
hef
oll
owi
ngcompoundshast
hel
owestboi
l
ingpoi
nt:
(
a)Chl
oropr
opane

(
b)Chl
orobut
ane

(
c)1-
Chl
oro-
2-met
hyl
propane

(
d)2-
Chl
oro-
2-met
hyl
propane

8.Whi
choft
hecompoundswi
l
lactasst
rongestr
educi
ngagent
?
(
a)NH3  
(
b)Bi
H3
(
c)AsH3
(
d)PH3

9.
Theor
derofr
eact
ivi
tyofal
cohol
swi
thLucasr
eagentf
oll
owsor
der
:
(
a)1°>2°
>3°
(
b)2°>1°>3°
(
c)3°>1°>2°
(
d)3°>2°>1°

10.Whi
choneoft
hef
oll
owi
ngwi
l
lshowsamev
aluef
orel
ect
ri
cal
resi
stanceand
r
efr
act
ivei
ndexal
onganydi
rect
ion?
(
a)Napht
hal
ene
(
b)Gr
aphi
te
(
c)Gl
ass
(
d)CommonSal
t

11.Whi
chamongt
hef
oll
owi
nghasl
eastpKav
alue
(
a)o-
cresol
(
b)m-
nit
rophenol
(
c)p-
nit
rophenol

3
(
d)Phenol

12.Whi
choft
hef
oll
owi
ngconcent
rat
iont
ermsi
snotaf
fect
edbyt
emper
atur
e?
(
a)mol
ali
ty
(
b)mol
ari
ty
(
c)nor
mal
i
ty
(
d)w/
v%

13.
Phenol
react
swi
thdi
lni
tr
icaci
dandy
iel
dsami
xtur
eofo-andp-ni
tr
ophenol
.o-
ni
tr
ophenol
isst
eam v
olat
il
e,whi
l
ep-ni
tr
ophenol
isl
essv
olat
il
e,duet
o
(
a)I
ntr
amol
ecul
arH-bondi
ngi
no-ni
tr
ophenol
,whi
l
eint
ermol
ecul
arH-bondi
ngi
np-
ni
tr
ophenol
.
(
b)I
ntr
amol
ecul
arH-bondi
ngi
np-ni
tr
ophenol
,whi
l
eint
ermol
ecul
arH-bondi
ngi
no-
ni
tr
ophenol
.
(
c)WeakVanderWaal
sfor
cei
no-ni
tr
ophenol
.
(
d)WeakVanderWaal
sfor
cei
np-ni
tr
ophenol
.

14.Hotconc.H2SO4 
act
sasmoder
atel
yst
rongoxi
dizi
ngagent
.Itoxi
dizesbot
hmet
als
andnon-
met
als.Whi
choft
hef
oll
owi
ngel
ementi
soxi
dizedbyconc.H2SO4 
i
ntot
wo
gaseouspr
oduct
s?

(
a)Cu
(
b)S
(
c)C
(
d)Zn

15.Whi
choft
hef
oll
owi
ngr
eact
ionsofgl
ucosecanbeexpl
ainedonl
ybyi
tscy
cli
c
st
ruct
ure?

(
a)Gl
ucosef
ormspent
aacet
ate.

4
 (
b)Gl
ucoser
eact
swi
thhy
droxy
lami
net
ofor
m anoxi
me.
(
c)Pent
aacet
ateofgl
ucosedoesnotr
eactwi
thhy
droxy
lami
ne.
(
d)Gl
ucosei
soxi
dizedbyni
tr
icaci
dtogl
uconi
caci
d.

16.Whi
chofthefoll
owingismostr
eact
ivet
owar
dsSN1r
eact
ion?
(
a)C6H5C(
CH3)(C6H5)
Br
(
b)C6H5CH2Br
(
c)C6H5CH(
C6H5)
Br
(
d)C6H5CH(
CH3)
Br

17.
Ident
iyt
het
ert
iar
yal
cohol
amongt
hef
oll
owi
ng:
(
a)CH3C(
CH3)
2CH2OH
(
b)CH2=CHCH2CH2OH
(
c)C6H5CH2CH(
OH)
CH3
(
d)C6H5CH=CHC(
CH3)
2OH

18.
Axi
alBr
-Fbondsar
esl
i
ght
lybenti
nthest
ruct
ureofBr
F3.
Iti
sduet
o
(
a)Br
F3i
sani
nter
hal
ogencompound.
(
b)Fi
shi
ghl
yel
ect
ronegat
ive.
(
c)Equat
ori
all
onepai
r-l
onepai
rrepul
sions
(
d)Equat
ori
albondpai
r-l
onepai
rrepul
sions

19.
Acompoundf
ormedbyel
ement
sPandQcr
yst
all
i
zesi
nacubi
cst
ruct
urewher
eP
at
omsar
eatt
hecor
ner
sofacubeandQat
omsar
eatt
hef
acecent
ers.Thef
ormul
aof
t
hecompoundi
s:
(
a)P2Q2
(
b)PQ3
(
c)PQ
(
d)P3Q

5
 20.
Whi
choft
hef
oll
owi
nghy
drogenhal
i
desi
smostv
olat
il
e?
(
a)HF
(
b)HCl
(
c)HBr
(
d)HI

21.
Anucl
eot
ideofDNAonhy
drol
ysi
swi
l
lgi
ve:

(
a)deoxy
ribosesugar
,phosphat
e gr
oupandani
tr
ogen-
cont
aini
ngbaseadeni
ne 
(A)
/
cyt
osi
ne 
(C)/guani
ne 
(G)/t
hymi
ne 
(T)
.
(
b)r
ibosesugar
,phosphat
e gr
oupandani
tr
ogen-
cont
aini
ngbaseadeni
ne 
(A)
/
cyt
osi
ne 
(C)/guani
ne 
(G)/t
hymi
ne 
(T)
.
(
c)deoxy
ribosesugar
,phosphat
e gr
oupandani
tr
ogen-
cont
aini
ngbaseadeni
ne 
(A)
/
cyt
osi
ne 
(C)/guani
ne 
(G)/ur
aci
l
(U)
.
(
d)deoxy
ribosesugar
,phosphat
e gr
oupandani
tr
ogen-
cont
aini
ngbaseadeni
ne 
(A)
/
cyt
osi
ne 
(C)/gl
yci
ne 
(G)/t
hymi
ne 
(T)
.

22.
Whent
wodi
ff
erenthal
ogensr
eactwi
theachot
her
,int
erhal
ogencompoundsar
e
f
ormed.
Whi
chst
atementi
sincor
rectabouti
nter
hal
ogencompounds?
(
a)Thesear
eal
lcov
alentmol
ecul
es.
(
b)Theyar
edi
amagnet
ici
nnat
ure.
(
c)Theyar
emor
ereact
ivet
hanhal
ogensexceptf
luor
ine.
(
d)X-
X’bondi
nint
erhal
ogensi
sst
rongert
hanX-
Xbond.

23.
Anor
gani
ccompoundwi
thmol
ecul
arf
ormul
aC6H6Or
eact
swi
thbr
omi
newat
erand
gi
vesawhi
tepr
eci
pit
ate.TheI
UPACnameoft
hepr
oducti
s:
(
a)2-
bromophenol
(
b)4-
bromophenol
(
c)2-
bromohexanol
(
d)2,
4,
6-Tr
ibr
omophenol

6
24.
Tungst
encr
yst
all
i
zesi
nbccuni
tcel
l
.Ift
heedgeoft
heuni
tcel
li
s316.
5pm,
whati
s
t
her
adi
usoft
ungst
enat
om?
(
a)135pm
(
b)13.
704pm
(
c)137.
04pm
(
d)111.
91pm

25.An 
ethanol
–wat
er 
mixt
ure(
obt
ainedby
 fer
ment
ati
on 
ofsugar
s)on 
fr
act
ional
di
sti
l
lat
ion 
yi
eldsasol
uti
oncont
aini
ngal
most95% byv
olumeofet
hanol
.Whati
s
i
ncor
rectaboutt
heabov
ement
ionedazeot
rope?

(
a)I
tisaconst
antboi
l
ingmi
xtur
e.
(
b)Thei
rcomposi
ti
oni
sunchangedbysi
mpl
edi
sti
l
lat
ion
(
c)Whent
heabov
eazeot
ropei
sboi
l
ed,
thev
apourhast
hedi
ff
erentpr
opor
ti
onsof
const
it
uent
sast
heunboi
l
edmi
xtur
e.
(
d)I
tshowsgr
eat
erposi
ti
vedev
iat
ionf
rom 
Raoul
t'
slaw.

SECTI
ONB
Thi
ssect
ionconsi
stsof24mul
ti
plechoi
cequest
ionswi
thov
eral
lchoi
cet
oat
tempt
any20quest
ions.I
ncasemor
ethandesi
rabl
enumberofquest
ionsar
eat
tempt
ed,
ONLYf
ir
st20wi
l
lbeconsi
der
edf
orev
aluat
ion.
–1
26.Anel
ementwi
thmol
armass27gmol for
msacubi
cuni
tcel
lwi
thedgel
engt
h
300pm.I
fit
sdensi
tyi 6gcm–3,
s6. thenat
ureofcubi
cuni
tcel
li
s
(
a)si
mpl
e
(
b)bcc
(
c)f
cc
(
d)endcent
red

27.Whi
choft
hef
oll
owi
ngi
snotanal
l
yli
chal
i
de?
(
a)4-
Bromopent
-2-
ene
(
b)3-
Bromo-
2-met
hyl
but
-1-
ene
(
c)1-
Bromobut
-2-
ene
7
 (
d)4-
Bromobut
-1-
ene

28.
Nit
rogeni
sunabl
etof
orm pent
ahal
i
desbecauseof
:
(
a)Tr
ipl
ecov
alentbondi
spr
esentbet
weent
woni
tr
ogenat
oms.
(
b)Theabsenceofdor
bit
als.
(
c)Ni
tr
ogenhashal
f-
fi
ll
edpor
bit
al.
(
d)Thepr
esenceofsandpor
bit
als.
29.Whi
chr
eagenti
srequi
redf
oronest
epconv
ersi
onofchl
orobenzenet
ophenol
?
( H+,
a)NaOH/ 623K,
300at
m
( H+,
b)NaOH/ 443K
(
c)KOH(
al /H+
c)
(
d)War
m/wat
er

30.Anorgani
ccompound( A)havi
ngmol ecularf
ormul
aC6H6Ogi v
esacharact
eri
sti
c
colourwit
haqueousFeCl 3 
sol
uti
on.(A)ont r
eatmentwi
thCO2 andNaOHat400Kunder
pressuregi
ves(B),whichonacidi
fi
cati
ongi v
esacompound( C).Thecompound(C)
reactswit
hacetylchlori
detogi
ve(D)whi chisapopul
arpai
nkill
er.
Compound( A)and( D)are
(a)Cycl
ohexanolandBenzoicaci
d
(
b)Phenol
and2-
Acet
oxy
benzoi
caci
d
(
c)Phenol
and4-
Hydr
oxy
benzoi
caci
d
(
d)Sal
i
cyl
i
caci
dand4-
Hydr
oxy
benzoi
caci
d

31.
whenanel
ementAi
sbur
nti
nai
r,i
tgi
vesacol
orl
essgasBwhi
chi
susedf
or
bl
eachi
ngwool
andsi
l
k.Thegasi
s:
(
a)CO2
(
b)SO3
(
c)NO2
(
d)SO2

32.
Alkal
imet
alhal
i
desar
ecol
oredduet
o:
(
a)met
aldef
ici
encydef
ect
.
(
b)met
alexcessdef
ectduet
othepr
esenceofext
racat
ionsati
nter
sti
ti
alsi
tes.

8
 (
c)I
mpur
it
ydef
ect
s.
(
d)met
alexcessdef
ectduet
oani
oni
cvacanci
es.
33.
Anal
kyl
hal
i
de,
RXr
eact
swi
thKCNt
ogi
vepr
opaneni
tr
il
e.RXi
s:
(
a)C3H7Br
(
b)C4H9Br
(
c)C2H5Br
(
d)C2H4Br
34.
Whi
choneoft
hef
oll
owi
ngi
scor
rect
:
(
a)XeOF4:
Squar
epy
rami
dal
,XeO3:
Pyr
ami
dal
,XeF4:
Squar
epl
anar
(
b)Cl
F3:
BentTshaped,
BrF5:
squar
epy
rami
dal
,I
F3:
Pyr
ami
dal
(
c)XeF2:
Linear
,XeO3:
Tri
gonal
planar
,XeOF4:
Squar
epy
rami
dal
(
d)XeF6:
Oct
ahedr
al,
XeF2:
Linear
,XeF4:
Tet
rahedr
al

35.18gofgl
ucosei
sdi
ssol
vedi
n1kgofwat
er.Atwhatt
emper
atur
ewi
l
lwat
erboi
lat
-
1
1.
013bar
?Kbf
orwat
eri
s0.
52Kkgmol
(
a)373.
15K
(
b)0.
052K
(
c)373.
202K
(
d)100.
202K
36.
Whi
chamongt
hegi
venαami
noaci
dsi
sopt
ical
l
yinact
ive?
(
a)Al
ani
ne
(
b)Val
i
ne
(
c)Gl
yci
ne
(
d)Leuci
ne

37.
WhenMnO2i
sheat
edwi
thconcHCl
,apungentcol
oredgas(
A)i
sev
olv
ed.(
A)r
eact
s
wi
thexcessofNH3t
ogi
veacol
orl
essgas(
B).Howev
er,
whenexcess(
A)i
sreact
ed
wi
thNH3i
tgi
vesanexpl
osi
ve(
C).(
A),
(B)and(
C)r
espect
ivel
yar
e
(
a)Cl
2,N2,
NH4Cl
(
b)Cl
2,N2,
NCl
3

(
c)MnCl
2,NH4Cl
,NCl
3

9
 (
d)MnCl
2,N2,
NCl
3

38.
Theuni
tofebul
l
ioscopi
cconst
anti
s
-1
(
a)Kkgmol
( kgK-1
b)mol
-1 -1
(
c)kgmol K
(
d)Kmol
kg
39.
Thecor
rector
derofhy
dri
desoft
he15t
hgr
oupi
ndecr
easi
ngor
derofboi
l
ingpoi
nti
s:
(
a)NH3>PH3>AsH3>SbH3>Bi
H3
(
b)NH3<PH3<AsH3<SbH3<Bi
H3
(
c)Bi
H3>SbH3>NH3>AsH3>PH3
(
d)NH3>Bi
H3>SbH3>AsH3>PH3

40.
Thepr
oductf
ormedi
nar
eact
ioni
s2-
Met
hyl
propan-
2-ol
.Fort
her
eact
iont
he
r
eact
ant
sar
e:
(
a)Pr
opanal
andmet
hyl
magnesi
um br
omi
de
(
b)Pr
opanoneandmet
hyl
magnesi
um br
omi
de
(
c)Et
hanal
andet
hyl
magnesi
um br
omi
de
(
d)Pr
opanoneandet
hyl
magnesi
um br
omi
de

41.Whi
choft
hef
oll
owi
ngi
sthecor
rector
derofi
ncr
easi
ngboi
l
ingpoi
nts:
(
a)Pent
an-
1-ol
>But
an-
1-ol
>Et
hoxy
ethane>But
ane
(
b)Et
hoxy
ethane<But
ane<Pent
an-
1-ol
<But
an-
1-ol
(
c)Et
hoxy
ethane<But
ane<But
an-
1-ol
<Pent
an-
1-ol
(
d)But
ane<Et
hoxy
ethane<But
an-
1-ol
<Pent
an-
1-ol

42.
Amongt
heoxoaci
dsofCl
whi
chonei
sthest
rongestaci
d:
(
a)HOCl
(
b)HCl
O4
(
c)HCl
O3
(
d)HCl
O2

10
43.
Ani
sol
eunder
goesFr
iedal
-Cr
aft
sacy
lat
ionr
eact
ion.Themaj
orpr
oducti
s
(
a)2-
Met
hoxy
acet
ophenone
(
b)4-
Met
hoxy
acet
ophenone
(
c)2-
Met
hoxy
tol
uene
(
d)4-
Met
hoxy
tol
uene

44.AnOr
gani
ccompoundwi
thmol
ecul
arf
ormul
aC6H7Nr
eact
swi
thNaNO2+HCl
/273
–278Kgi
ve‘
X’.Xonr
eact
ionwi
thcupr
ouschl
ori
degi
ves‘
Y’.I
dent
if
y‘X’
and‘
Y’.
(
a)X–Hexanami
ne Y–Chl
orohexane
(
b)X–Ni
tr
obenzene Y–1,
2–di
chl
orobenzene
(
c)X–Benzenedi
azoni
umhal
i
de Y-Chl
orobenzene
(
d)X-Benzy
lchl
ori
de Y-Tol
uene

45.Gi
venbel
owar
etwost
atement
slabel
l
edasAsser
ti
on(
A)andReason(
R)
Asser
ti
on(
A):
SN2r
eact
ionpr
oceedswi
thi
nver
sionofconf
igur
ati
onwhi
l
eSN1r
eact
ions
ar
eaccompani
edbyr
acemi
zat
ion.
Reason(
R):
SN2t
akespl
acei
nsi
ngl
est
epwhi
l
eSN1occur
sint
wost
eps.
Sel
ectt
hemostappr
opr
iat
eanswerf
rom t
heopt
ionsgi
venbel
ow:
(
a)Bot
hAandRar
etr
ueandRi
sthecor
rectexpl
anat
ionofA
(
b)Bot
hAandRar
etr
uebutRi
snott
hecor
rectexpl
anat
ionofA.
(
c)Ai
str
uebutRi
sfal
se.
(
d)Ai
sfal
sebutRi
str
ue.

46.Gi
venbel
owar
etwost
atement
slabel
l
edasAsser
ti
on(
A)andReason(
R)
Asser
ti
on(
A):
Par
ti
alhy
drol
ysi
sofXeF6gi
vesoxy
fluor
ides.
Reason(
R):
Hydr
oly
sisofXeF6i
sar
edoxr
eact
ion.
Sel
ectt
hemostappr
opr
iat
eanswerf
rom t
heopt
ionsgi
venbel
ow:

11
(
a)Bot
hAandRar
etr
ueandRi
sthecor
rectexpl
anat
ionofA
(
b)Bot
hAandRar
etr
uebutRi
snott
hecor
rectexpl
anat
ionofA.
(
c)Ai
str
uebutRi
sfal
se.
(
d)Ai
sfal
sebutRi
str
ue.

47.Gi
venbel
owar
etwost
atement
slabel
l
edasAsser
ti
on(
A)andReason(
R)
Asser
ti
on(
A):
Ami
xtur
eofchl
orof
orm andacet
onef
ormsasol
uti
onwi
thposi
ti
ve
dev
iat
ionf
rom Raoul
t’
slaw.
Reason(
R):
Chl
orof
orm mol
ecul
efor
mshy
drogenbondwi
thacet
onemol
ecul
e.
Sel
ectt
hemostappr
opr
iat
eanswerf
rom t
heopt
ionsgi
venbel
ow:
(
a)Bot
hAandRar
etr
ueandRi
sthecor
rectexpl
anat
ionofA
(
b)Bot
hAandRar
etr
uebutRi
snott
hecor
rectexpl
anat
ionofA.
(
c)Ai
str
uebutRi
sfal
se.
(
d)Ai
sfal
sebutRi
str
ue.

48.Gi
venbel
owar
etwost
atement
slabel
l
edasAsser
ti
on(
A)andReason(
R)
Asser
ti
on(
A):
Irononr
eact
ionwi
thHCl
giv
esFeCl
2andnotFeCl
3.

Reason(
R):
Hydr
ogengaspr
oduceddur
ingt
her
eact
ionpr
event
sthef
ormat
ionofFeCl
3.

Sel
ectt
hemostappr
opr
iat
eanswerf
rom t
heopt
ionsgi
venbel
ow:
(
a)Bot
hAandRar
etr
ueandRi
sthecor
rectexpl
anat
ionofA
(
b)Bot
hAandRar
etr
uebutRi
snott
hecor
rectexpl
anat
ionofA.
(
c)Ai
str
uebutRi
sfal
se.
(
d)Ai
sfal
sebutRi
str
ue.

49.Gi
venbel
owar
etwost
atement
slabel
l
edasAsser
ti
on(
A)andReason(
R)

12
Asser
ti
on(
A):
Whenur
eai
sdi
ssol
vedi
nwat
er,
theboi
l
ingpoi
ntofwat
eri
slower
ed.
Reason(
R):
Thev
apourpr
essur
eoft
hesol
ventdecr
easesi
nthepr
esenceofnon–
v
olat
il
esol
ute.
Sel
ectt
hemostappr
opr
iat
eanswerf
rom t
heopt
ionsgi
venbel
ow:
(
a)Bot
hAandRar
etr
ueandRi
sthecor
rectexpl
anat
ionofA
(
b)Bot
hAandRar
etr
uebutRi
snott
hecor
rectexpl
anat
ionofA.
(
c)Ai
str
uebutRi
sfal
se.
(
d)Ai
sfal
sebutRi
str
ue.

SECTI
ONC
Thi
ssect
ionconsi
stsof6mul
ti
plechoi
cequest
ionswi
thanov
eral
lchoi
cet
oat
tempt
any
5.I
ncasemor
ethandesi
rabl
enumberofquest
ionsar
eat
tempt
ed,
ONLYf
ir
st5wi
l
l
beconsi
der
edf
orev
aluat
ion.
50Mat
cht
hef
oll
owi
ng
I I
I
(
i)Mal
tose (
A)Coagul
ati
onofegg
(
ii
)My
osi
n (
B)DNA
(
ii
i)Denat
urat
ion (
C)Reduci
ngsugar
(
iv)Nucl
eot
ide (
D)Pr
otei
ns
(
v)Pept
idebond
Whi
choft
hef
oll
owi
ngi
sthebestmat
chedopt
ion?
(
a)i
)-
D,i
i
)-C,
ii
i)
-A,
iv)
-B

(
b)i
)-
B,i
i
)-C,
iv)
-D,
ii
i)
-A

(
c)i
)-C,
ii
)-D,
ii
i)
-A,
iv)
-B

(
d)i
)-B,
ii
i)
-D,
iv)
-C,
v)-D,

51Whi
choft
hef
oll
owi
nganal
ogi
esi
scor
rect
:
(
a)NH3–Lewi
sbase : PH3-Lewi
saci
d

(
b)Nobl
egases–Maxi
mum negat
iveel
ect
rongai
nent
hal
py :Hal
ogens-

13
 Maxi
mum posi
ti
veel
ect
rongai
nent
hal
py.

(
c)Br
F3–Tr
igonal
planar
:XeO3–Py
rami
dal

(
d)He–Fi
l
li
ngbal
l
oons:
Ne-
Indi
schar
get
ubes

52Completet
hefoll
owinganal
ogy:
Mixt
ureoftwoenanti
omersinequal
proporti
on,havezer
oopti
calr
otat
ion–A
I
somerswhichrotat
ethepl
anepolar
izedl
ight–B( i
denti
fyAandB)
(
a)A-I
nver
sion B-Stereoisomers
(
b)A-
Racemi
cmodi
fi
cat
ion B–Opt
ical
isomer
s
(
c)A-
Ret
ent
ion B-Geomet
ri
cal
isomer
s
(
d)A-
Ster
eoi
somer
s B-r
acemi
cmodi
fi
cat
ion

CASE1:
Readt
hepassagegi
venbel
owandanswert
hef
oll
owi
ngquest
ions53-
55

“
Thechal
l
engeofaer
ospacemedi
cinel
i
esi
nsaf
eguar
dingt
heheal
thofi
ndi
vi
dual
swho
wor
kinady
nami
cat
mospher
eofl
ower
ingpr
essur
eandoxy
gencont
ent
,coupl
edwi
th
i
ncr
easi
ngal
ti
tude.I
tisessent
ial
tocompr
ehendt
hephy
sical
changest
hatoccuraswe
ascendf
rom seal
evel
toaddr
esst
hemedi
cal
needsoft
hepi
l
ot,
air
crew,
andai
rcr
aft
passenger
s.Henr
y’sLawi
soneoft
hemostper
ti
nentoft
hesegasl
awst
othepr
act
ice
ofaer
ospacemedi
ci
ne.Thi
slawdef
inest
her
elat
ionshi
pbet
weent
hepar
ti
alpr
essur
e
ofgasesov
erl
yi
ngasol
uti
onandt
hegases’
abi
l
ityt
odi
ssol
vei
nthatsol
uti
on.Aper
son
exper
iencesHenr
y’sl
awi
nact
ionwhent
heyopenanewbot
tl
eofsodapop.y
ourbl
ood
i
sasol
uti
oncont
aini
ngmul
ti
plegases.Atseal
evel
,thosegasesr
emai
ninsol
uti
on(
i.
e.,
bl
ood)
.Thi
sisbecause,
atseal
evel
,ai
randar
ter
ial
bloodcont
ainappr
oxi
mat
elyt
he
samepar
ti
alpr
essur
eofgases,
pri
mar
il
yni
tr
ogen.Asoner
isesi
ntheat
mospher
e,t
he
par
ti
alpr
essur
edecr
eases,
andt
heamountoft
hesegaseshel
dinsol
uti
on(
i.
e.,
blood)
necessar
il
ymustdecr
ease.Thi
sresul
tsi
ngasev
olv
ingi
nthebl
oodst
ream.Asar
esul
t,
t
heot
her
wisei
ner
tni
tr
ogensuper
sat
urat
esi
nthebl
oodst
ream or“
bubbl
esout
”li
ket
he
sodapopexampl
e.

Sour
ce:
htt
ps:
//www.
ncbi
.nl
m.ni
h.gov
/books/
NBK544301/

53.Thev
alueofHenr
y’sconst
antKH 
i
s__
___
___
___
__.

14
(
a)gr
eat
erf
orgaseswi
thhi
ghersol
ubi
l
ity
.
(
b)gr
eat
erf
orgaseswi
thl
owersol
ubi
l
ity
.
(
c)const
antf
oral
lgases.
(
d)notr
elat
edt
othesol
ubi
l
ityofgases.

54.
Mount
aineer
sathi
ghal
ti
tudesuf
ferf
rom al
i
fet
hreat
eni
ngcondi
ti
on…….
whi
chi
sdue
t
o…….
.
(
a)anoxi
a,l
owconcent
rat
ionofoxy
geni
nbl
ood.
(
b)anoxi
a,hi
ghconcent
rat
ionofoxy
geni
nbl
ood.
(
c)bends,
lowconcent
rat
ionofoxy
geni
nbl
ood.
(
d)bends,
for
mat
ionofni
tr
ogenbubbl
eswhi
chcausesbl
ockageofcapi
l
lar
ies.

55.
H2​
S 
atox
icgaswi
thr
ott
ene
ggl
i
kes
mel
l
,isus
edf
ort
hequal
i
tat
iv
eanal
ysi
s.I
fthe
s
olubi
l
it
yof
 
H2​
S 
i
nwat
erat
 STP 
i
s 0.
195 
m,He
nry
'sl
awc
ons
tantwi
l
lbe
:
(
a)2.
82at
m
(
b)28.
2at
m
(
c)0.
282at
m
(
d)282at
m

ENDOFPAPER

15
S.
No UNI
T SECTI
ON SECTI
ONB SECTI
ONC TOTAL
A QUESTI
O
MCQ M ASSERTI
ON MCQ CASE NS
C REASON BASED
Q

16