STUDY GUIDE: Chemistry 2

NAME:
GRADE LEVEL GRADE 12
TOPIC/TITLE Methodology
WEEK/S: WEEK 1 and 2

Refer to your Book Exploring Life Through Science and open on page 143-145.

Answer Test Yourself A and B.

Test Yourself
A.
1. Which of the following is correct about a chemical reaction?
a. All chemical reactions are reversible.
b. A reaction is complete when it has reached equilibrium.
c. There are no reactants left at equilibrium;only products.
d. if the forward reaction is exothermic, the reverse is also exothermic.

2. Which of the following is incorrect about the condition in equilibrium?

a. The concentration of the reactants and products are constant.
b. The rate of the forward reaction is equal to the rate of the diverse reaction.
c. The ratio between the concentrations of the reactants and products is
constant.
d. The rate of the forward reaction is the reciprocal of the rate reverse
reaction.

3. Consider the reaction

A( g )+2 B( g) ⇄2C (g) + D(g)
If Q < K, which of the following is true about the reaction system?
a. There are equal amounts of the substances.
b. There is less substance D than at the start of the reaction.
c. there is more substance B than at the start of the reaction.
d. there is more substance C than at the start up the reaction.

4. which of the following values for equilibrium constants reflects favor for the
formation of products?
 a. 1.8 ×10−27
b. 0.0021
c. 0.90
d. 10.4

5. What is the equilibrium constant expression for the reaction below?

2 NO(g) +O 2 ( g) ⇄2 NO (g)
2
a. K= [ NO ] [ O2 ]
[ NO ] [ O2 ]
b. K=
[ NO2 ]
[ NO2 ]
c. K=
[ NO ] [ O2 ]
2
[ NO2 ]
d. K= 2
[ NO ] [ O2 ]

6. What is the equilibrium constant expression for the reaction below?

C(s )+CO 2 ( g )+ 2Cl 2 (g)⇄ 2 COCl 2( g)
[ C ] [ CO2 ][ Cl2 ]
a. K= ❑
[ COCl 2 ]
[ C ] [ CO2 ][ Cl2 ] 2
b. K= 2
[ COCl 2 ]
❑
[ COCl2 ]
c. K=
[ CO 2 ][ Cl 2 ]
2
[COCl 2 ]
d. K= 2
[ CO 2 ][ Cl 2 ]

7. Which condition favors the forward direction love a reversible reaction?

a. Q = K
b. Q < K
c. Q > K
d. Q = 0

8. For a reaction in equilibrium, which the following is incorrect is the forward action
is endothermic?
a. The reverse reaction is exothermic.
 b. Decreasing the temperature will favor the reverse reaction.
c. Increasing the temperature will favor the reaction.
d. Only the forward reaction will be affected by changes in temperature.

9. Which of the following will not affect systems in equilibrium?

a. Adding a catalyst.
b. Changing the pressure.
c. Changing the temperature.
d. Changing the volume.

10. Which of the following reactions in equilibrium can be affected by changes in

pressure?
a. AgCl( s) ⇄ Ag (aq) +Cl (aq ) ¿ ¿
+¿ −¿

b. SO3 ( g ) + H 2 O ( l ) ⇄ H 2 SO4 ( aq )
c. P4 O 10 ( s )+6 H 2 O ( l ) ⇄ 4 H 3 PO 4 ( aq )
+ ¿ ( aq ) ¿

d. CH 3 COOH ( aq ) ⇄ CH 3 COO−¿ (aq )+ H ¿

11. The composition of phosphorus pentachloride ( PCL5 ) to Phosphorus trichloride

( PCL3 )and chlorine gas is a reversible process represented below.
PCL5 ( g ) ⇄ PCL3 ( g )=Cl 2( g)
The equilibrium constant K c For the reaction was found to be 0.024 at 523 K. if
the equilibrium concentrations of PCL5 and PCL3 gases are 0.037 M and 0.012
M, respectively, what is the equilibrium concentration of the Cl 2 gas?

a. 0.0078 M
b. 0.019 M
c. 0.074 M
d. 1.2 M

12. The reaction below has an equilibrium constant K p of 19.9 at 1000 K. if the
equilibrium pressure of the CO 2 gas is 0.725 atm, what is the equilibrium
pressure of CO gas?
Fe2 O3 ( s ) +3 CO ( g ) ⇄ 2 Fe( s) +3 CO2 ( g )
a. 0.0191 atm
b. 0.268 atm
c. 3.74 atm
d. 52.2 atm
B. Critical Thinking. Answer the following items in separate sheets of paper.

1. Chemical reactions do not go to completion; they only reach equilibrium. In

industries, it is important to maximize the yield of a reaction. What can be
done to increase the yield a reaction even if the reaction does not go to
completion?

2. Equilibrium also established phase changes. during melting, for instance, an

equilibrium is established between the solid and liquid phases a substance. At
the triple point of water, what states of equilibrium exist? explain this condition
in terms of the concepts learned in the chapter.

3. For a general reaction A=B ⇄ AB

The rate of the forward reaction is equal to the rate of the reverse reaction.
kf
Starting with the rate law, show the K= where k f and k r are the rate
kr
constants of the forward and the reverse reactions, respectively.

4. For a general reaction aA=bB ⇄ AB

Show that K p =K c (RT ) ∆ n .(Hint :Usethe ideal gas equation .) In what instance(s)
will K p be equal to K c ?

5. For the reaction: N 2 ( g )+ 3 H 2 ( g) ⇄2 NH 3 ( g)

PNH 2
Show that K p = 3

PN PH 3
2 2