MGD GIRLS’ SCHOOL, JAIPUR

ASSESSMENT-2 (2021-2022)

Subject: Chemistry SET-1 answer key Reading Time:10min

Class: XI Time: 90 min
Number of pages: 7 M.M.: 35

General Instructions:
a) The question paper contains three sections.
b) Section A has 21 Questions Attempt any 20 Questions (1/2 mark each) .
c) Section B: has 21 Questions Attempt any 20 Questions (1 mark each)
d) Section C has 6 Questions. Attempt any 5 Questions
e) From multiple choice questions choose the MOST appropriate answer.
f) There is no negative marking.
g) Use of calculators and log tables is not permitted.
h) The answers to the questions have to be written neatly in a notebook or register.
i) On every page write your name class, section, question number and page number.
j) After attempting the questions given, click a clear picture of the answers using any
picture scanner.
k) The pictures should be clicked in sequence. (page wise sequence).
l) Save these images by your name, set and subject as a single PDF on your mobile/pc
m) Go to MS Teams and upload the pdf as Add Work within the submission time and Turn
in/ Hand in your assignment.

Section A
This section consists of 21multiple choice questions with overall choice to attempt any 20 questions. In
case more than desirable number of questions are attempted, ONLY first 20 will be considered for
evaluation. (1/2 mark each)
1. When an electric current is passed through an ionic hydride in the molten state
 Hydrogen is liberated at the anode
 Hydrogen is liberated at the cathode
 No reaction takes place
 Hydride ion migrates towards cathode.
2. Which of the following is incorrect statement?
 S-block elements except Be and Mg form ionic hydrides
 BeH2, MgH2, CuH2, ZnH2,CaH2 and HgH2 are intermediate hydrides
 P-block elements form covalent hydrides
 d and f-block elements form ionic hydrides
3. Which of the following hydride is electron precise hydride
 B2H6
 NH3
 H2O
 CH4
4. Metal hydride are ionic, covalent or molecular in nature. Among LiH, NaH, KH, RbH, CsH,
the correct order of increasing ionic character is:
 LiH>NaH>CsH>KH>RbH
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  LiH<NaH<KH<RbH<CsH
 RbH>CsH>NaH>KH>LiH
 NaH>CsH>RbH>LiH>KH.
5. Atomic hydrogen is called
 Proton
 Deutrium
 Nascent hydrogen
 Tritium
6. Which of the following statement is most applicable to hydrogen? It can act as
 A reducing agent
 An oxidising agent
 Both as oxidising and reducing agent
 Neither as an oxidising nor a reducing agent
7. When a strip of metallic Zn is placed in aquas solution of copper nitrate, the blue colour of
the solution disappears due to the formation of
 Cu+2
 ZnS
 Zn+2 ions
 CuS
8. The oxidation number of Cr in potassium dichromate is
 +6
 −2
 −5
 +2
9. In the following reaction
4P +3KOH +3H2O 3KH2PO2 +PH3
 Phosphorous is both oxidised and reduced
 Only phosphorous is reduced
 Phosphrous is not oxidised
 None of the above
10. Electromagnetic radiation with maximum wavelength is
 Ultra violet
 Radio waves
 X-rays
 Infrared rays.
11. The correct set of quantum numbers for unpaired electron of chlorine atom is
 n=2, l=1, m=0
 n=3,l=1,m=1
 n=2 ,l=1, m=1
 n=3, l=0 , m=0
12. In which of the following pairs , the ions are isoelectronic.
 Na+1 Mg+2
 Al+3, O—1
 Na+1, O—1
 N—3, Cl—1
13. Which has the most stable +2 oxidation state
 Sn
 Pb

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  Fe
 Ag
14. The chemistry of Li is very similar to Mg, even though they are placed in different groups.
The reason is:
 Both are found together in nature
 Both have nearly the same size
 Both have similar electronic configuration
 The ratio of their charges and size is nearly the same.
15. Carbon tetrachloride has no net dipole moment because of
 Its planar structure
 Its regular tetrahedral structure
 Similar sizes of C and Cl atoms,
 Similar electron affinities of C and Cl.
16. Amongst H2O, H2S, H2Se and H2Te, the one with the highest boiling point is
 H2O because of hydrogen bonding.
 H2Te because of higher molecular weight.
 H2S because of hydrogen bonding.
 H2Se because of lower molecular weight
17. In which of the following species all the bonds are not equal
 BF4—1
 CO3—2
 PF5
 SF6
18. In the lewis structure of nitrate ion, the number of bond pairs and lone pairs around nitrogen
are respectively
 4,0
 2,0
 3,1
 3,2
19. The condition to form a molecular orbital from atomic orbital is
 Atomic orbitals must have comparable energies and proper symmetry.
 Only atomic orbitals must be in proper symmetry
 Only atomic orbitals must be of comparable energies.
 None of the above
20. In the following chemical reaction
MnO4—1 + I–1 MnO2 +I2
The oxidation half reaction is
 MnO4−1 MnO2
I -1
I2
I2 I -1
 None of the above
21. The correct order of electronegativity is
 Cl>F>O>Br
 F>O>Cl>Br
 F>Cl>Br>O
 O>F>Cl>Br
Section B

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This section consists of 21 questions with overall choice to attempt any 20 questions. In case
more than desirable number of questions are attempted, ONLY first 20 will be considered for
evaluation (1 mark each)
22. The amount of lime required to remove the hardness in 20 L of pond water, containing 3mg
of calcium bicarbonate per 100ml water is
 0.27g
 0.027g
 27g
 2.7g
23. The density of a solution prepared by dissolving 120g of urea (molecular mass=60u) in
1000g of water is 1.15g/ml. The molarity of the solution is
 1.78M
 1.02M
 2.05M
 0.05M
24. Which has the maximum number of molecules among the following:
 44g of carbon dioxide
 48 g of ozone
 8g of hydrogen
 64g of sulphurdioxide
25. If the velocity of an electron in Bohrs’ first orbit is 2.19X106 m/s,the de Broglie wavelength
associated with it is
 33.2pm
 332pm
 3.32pm
 3320pm
26. In an atom, an electron is moving with a speed of 600 m/s with and accuracy of 0.005%.
certainty with which the position of the electron can be located is:
 1.92 ✕10-3 m
 19.2 ✕ 10-3 m
 192 ✕ 10-3 m
 1.82 ✕ 10-3 m
27. The geometry and the type of hybrid orbital present about the central atom in BF3 is
 Linear, SP
 Trigonal planar, SP2
 Tetrahedral, SP3
 Pyramidal, SP3
28. The magnetic quantum number specifies
 Shape of the orbital
 Orientation of the orbital
 Size of the orbital
 Nuclear stability
29. The number of unpaired electrons present in the ground state of Chromium is
3
4
5
6
30. The compound of the type ECl3, where E = B, P, As or Bi, the angles Cl-E-Cl in order is:

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  B>P=As=Bi
 B>P>As>Bi
 B<P=As=Bi
 B,P,As<Bi
31. According to the molecular orbital theory
 O2+1 is paramagnetic and the bond order is greater than O2
 O2+1 is paramagnetic and bond order is less than O2
 O2+ is diamagnetic and bond order is less than O2
 O2+ is diamagnetic and bond order is greater t has O2
32. The bond orders of O2+1 O2—1 ,O2—2 respectively are,
 2.5, 1, 5,1
 2.5,1,1.5
 1,2.5,1.5
 1.5,1,2.5
33. The correct decreasing order of C—H bond lengths in a molecule C2H6, C2H2 and C2H2 is
 C2H6>C2H4>C2H2
 C2H4>C2H2>C2H6
 C2H2>C2H6>C2H4
 C2H6>C2H2>C2H4
34. In a chemical reaction A+B AB ,if B the limiting reagent ,then choose the correct
option.
A B
 50 atoms 100 atoms
 100 atoms 200atoms
 50 atoms 30 atoms
 50 atoms 200 atoms
35. The amount of Barium sulphate precipitate on mixing barium chloride (0.5M) with sulphuric
acid (1M) will correspond to
 0.5M
 0.1 M
 1.5 M
2
36. The IUPAC name of:

 3-oxo-butanoic acid
 1,4-dihydroxybutanol
 3-carboxybutan-1-ol
 4-oxopentanoic acid
37. The correct order of decreasing stability of the following cations is
CH3-C+H-CH3 (I) , CH 3-C + H-OCH3 (II) ,CH3-C +H -CH2-CH3(III)
 II> I >III
 II>III>I
 III>I>II
 I>II.> III
38. The following reaction (CH3)3Br H2O (CH3)3-C-OH is
 Elimination reaction
 Substitution reaction
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  Free radical reaction
 Addition reaction.
39. Assertion (A): Though the central atom of both NH3 and H2O molecule sp3 hybridized, yet
H—N—H bond angle is greater than that of H—O—H
Reason(R): Nitrogen atom has 1 lone pair and oxygen atom has two lone pairs.
 Both A and R are correct and R is the correct explanation of A
 Both A and R are correct but R is not the correct explanation of A
 A is correct and R is incorrect
 Both A and R are incorrect.
40. Assertion (A): Hydrogen has one electron in its orbit.
Reason( R): There are many energy levels available.
 Both A and R are correct and R is the correct explanation of A
 Both A and R are correct but R is not the correct explanation of A
 Both A and R are not correct
 A is not correct but R is correct
41. Assertion(A): Noble gases have highest first ionization energy in their respective periods.
Reason(R): Noble gases have stable electronic configuration
 Both A and R are correct and R is the correct explanation of A
 Both A and R are correct but R is not the correct explanation of A
 Both A and R are correct
 A is not correct but R is correct
42. Assertion(A)Molarity of pure water is 55.5 M
Reason (R)Molarity is temperature dependent parameter.
 Both A and R are correct and R is the correct explanation of A
 Both A and R are correct but R is not the correct explanation of A
 Both A and R are not correct
 A is not correct but R is correct.
Section C
This section consists of 6 questions with overall choice to attempt any 5 questions. In case more
than desirable number of questions are attempted, ONLY first 5 will be considered for evaluation
(1 mark each)
Read the following passage and answer the following questions:
A reagent that brings an electron pair is a nucleophile, the reaction is nucleophilic reaction. A
reagent that takes away an electron pair is called an electrophilic. During a polar organic
reaction, a nucleophile attacks an electrophilic centre, of the substrate which is that specific atom
or part of the electrophile that is electron deficient. Similarly, the electrophiles attack at
neucleophillic centre, which is electron rich centre of the substrate. Thus, the electrophiles
receive electron pair from neucleophile when the two undergo bonding interaction.
43. Which of the following statement is not correct for a nucleophile
 Ammonia is a nucleophile
 Nucleophile attack low electron density sites
 Nucleophiles are not electron seeking
 Nucleophile is a lewis acid
44. Which of the following is an electrophile
 H2O
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  NH3
 AlCl3
 C2H5 NH2
45. For I—1 , Cl—1 ,Br—1 ,the increasing order of nucleophilicity would be:
 Cl—1 <Br—1 < I—1
 I-1 ,<Cl—1 < Br—1
 Br—1 <Cl—1 <I-1
 I—1 < Br—1 < Cl-1
46. Nucleophile is a species that should have:
 A pair of electron to donate
 Positive charge
 No charge
 Electron deficient species
47. Which of the following behave as a nucleophile and as an electrophile:

•
 CH3OH
 CH2=CH-CH3
 CH3NH2
48. The correct order of electronegativity of C in ethane, ethene, ethyne is
 ethane <ethene<ethyne
 ethyne<ethene<ethane
 ethene<ethyne<ethane
 ethene<ethane<ethyne