Components

Molar
No. Formula Mass Name Constant Value

1 C3 H 6 O 58.08 Acetone
Temperatur
(C)
2 C3 H 8 O 60.096 2 -propanol

Parameters for Antoine Eq.

Data Bahan
A B C
1 Acetone 14.3145 2756.220 228.060
2 2 -propanol 16.6796 3640.200 219.610

EXPERIMENT
X1 Y1 Y2
T (°K) T (°C) X2 (mol/mol)
(mol/mol) (mol/mol) (mol/mol)
355.45 82.30 0 1 0 1
354.75 81.60 0.05100 0.9490 0.09000 0.9100
354.05 80.90 0.08400 0.9160 0.14100 0.8590
352.30 79.15 0.19800 0.8020 0.29200 0.7080
351.50 78.35 0.25500 0.7450 0.35700 0.6430
350.75 77.60 0.31200 0.6880 0.41600 0.5840
349.95 76.80 0.38600 0.6140 0.48500 0.5150
349.35 76.20 0.45400 0.5460 0.54800 0.4520
348.85 75.70 0.53100 0.4690 0.59600 0.4040
348.65 75.50 0.60500 0.3950 0.64100 0.3590
348.60 75.45 0.675 0.325 0.675 0.325
348.650 75.5 0.70400 0.2960 0.69100 0.3090
349.000 75.85 0.81200 0.1880 0.75000 0.2500
349.250 76.1 0.85400 0.1460 0.77100 0.2290
349.850 76.7 0.91200 0.0880 0.80000 0.2000
349.600 76.45 0.96300 0.0370 0.86100 0.1390
354.750 81.6 1.00000 0.0000 1.00000 0.0000
 Kurva Experiment

𝐺𝐸/𝑥1𝑥2𝑅𝑇
0.0000
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8
-5.0000 f(x) = 25.2552514114844 x − 19.6031158369317
R² = 0.50487427674682
-10.0000

-15.0000

-20.0000

-25.0000

-30.0000

-35.0000

x1
 Vapor-Liquid Equ
Antoine Eq.
Constant Value

25

Sumber Data γ1 dan γ2 Pers 12.1

App. B.2
S. Van Ness
S. Van Ness

EXPERIMENT
P1 Sat P2 Sat
γ1 γ2 ln γ1 ln γ2 𝐺𝐸/𝑅𝑇
(kPa) (kPa)
229.0135 101.7343 #DIV/0! 0.2457 #DIV/0! -1.4035 #DIV/0!
224.4618 98.9232 0.1965 0.2423 -1.6268 -1.4174 -1.4281
219.9806 96.1772 0.1908 0.2438 -1.6567 -1.4116 -1.4322
209.0810 89.5895 0.1763 0.2463 -1.7354 -1.4010 -1.4672
204.2404 86.7061 0.1714 0.2489 -1.7639 -1.3909 -1.4860
199.7818 84.0738 0.1668 0.2524 -1.7907 -1.3767 -1.5059
195.1099 81.3400 0.1610 0.2578 -1.8264 -1.3556 -1.5373
191.6622 79.3389 0.1574 0.2609 -1.8487 -1.3438 -1.5730
188.8255 77.7029 0.1486 0.2771 -1.9065 -1.2832 -1.6142
187.7001 77.0565 0.1411 0.2949 -1.9582 -1.2212 -1.6671
187.4195 76.8956 0.1334 0.3251 -2.0145 -1.1236 -1.7249
187.7001 77.0565 0.1307 0.3387 -2.0346 -1.0827 -1.7528
189.6731 78.1907 0.1217 0.4252 -2.1059 -0.8553 -1.8707
191.0922 79.0094 0.1181 0.4963 -2.1361 -0.7006 -1.9265
194.5320 81.0036 0.1127 0.7014 -2.1827 -0.3546 -2.0219
193.092942 80.1676 0.1158 1.1715 -2.1563 0.1583 -2.0706
224.4618 98.9232 0.1114 #DIV/0! -2.1948 #DIV/0! #DIV/0!

Slope = 1.2397 Kurva T-xy

Intercept = 0.2238 358.00

356.00

354.00

352.00
 358.00

356.00

354.00

352.00

C
(°
T

)
A'12 = 0.683293
350.00
A'21 = 4.468275
348.00

346.00

344.00
0 0.2 0.4 0.6 0.8 1

x1, y1
or-Liquid Equilibrium Data
`

𝐺𝐸/𝑅𝑇 Experiment Pers 12.6 Persamaan Van Laar :

𝐺𝐸/x1x2𝑅𝑇 Experiment Pers 12.6 Persamaan Van Laar :

PARAMETER VAN LAAR

𝐺𝐸/𝑥1𝑥2𝑅𝑇 A'12 A'21 ln γ1 ln γ2 γ1 γ2

#DIV/0! 0.6833 4.4683 0.6833 #DIV/0! 1.9804 #DIV/0!

-29.5071 0.6833 4.4683 0.6722 0.0003 1.9586 1.000297
-18.6130 0.6833 4.4683 0.6645 0.0009 1.9436 1.000855
-9.2397 0.6833 4.4683 0.6345 0.0059 1.8861 1.005931
-7.8222 0.6833 4.4683 0.6170 0.0111 1.8534 1.011116
-7.0152 0.6833 4.4683 0.5975 0.0188 1.8177 1.01897
-6.4864 0.6833 4.4683 0.5687 0.0344 1.7660 1.034968
-6.3457 0.6833 4.4683 0.5378 0.0569 1.7123 1.058512
-6.4815 0.6833 4.4683 0.4965 0.0973 1.6430 1.102219
-6.9759 0.6833 4.4683 0.4486 0.1609 1.5661 1.174591
-7.8629 0.6833 4.4683 0.3936 0.2596 1.4823 1.296446
-8.4116 0.6833 4.4683 0.3674 0.3178 1.4440 1.374149
-12.2546 0.6833 4.4683 0.2478 0.7070 1.2812 2.027846
-15.4513 0.6833 4.4683 0.1904 0.9961 1.2097 2.707728
-25.1928 0.6833 4.4683 0.1023 1.6797 1.1077 5.364173
-58.1128 0.6833 4.4683 0.0276 2.8540 1.0279 17.35708
#DIV/0! 0.6833 4.4683 #DIV/0! 4.4683 #DIV/0! 87.20834

a T-xy Kurva P
10.0000

0.0000
0 0.2 0.4 0.6

-10.0000

-20.0000
y1

y2

x1
x2
E/

E/
G

G
T,
ln

ln

R
T
,

,
 Kurva P
10.0000

0.0000
0 0.2 0.4 0.6

-10.0000

-20.0000

y1

y2

x1
x2
E/

E/
G

G
T,
ln

ln

R
T
,

,
-30.0000

-40.0000

-50.0000

-60.0000
0.6 0.8 1 1.2
-70.0000
y1
x1
Persamaan Van Laar :
Pers 13.43

EDISI 8

Pers 13.44

Persamaan Van Laar :

Pers 13.42

LAAR

𝐺𝐸/𝑅𝑇 𝐺𝐸/𝑥1𝑥2𝑅𝑇 Error

0 0.6833 #DIV/0!
0.034564 0.698367232 -43.2515
0.056603 0.709234626 -27.2438
0.130371 0.752240386 -13.2829
0.165575 0.776809007 -11.0696
0.199364 0.803554056 -9.7303
0.240621 0.841608921 -8.7072
0.275222 0.878862924 -8.2204
0.309284 0.927636524 -7.9872
0.334945 0.976522723 -8.1437
0.350049 1.02374639 -8.6805
0.352747 1.041396707 -9.0772
0.334142 1.079376028 -12.3534
0.308019 1.064481866 -15.5153
0.241088 0.961996756 -27.1881
0.13213 0.651186022 -90.2414
0 #DIV/0! #DIV/0!

Kurva Persamaan Van Laar

0.4 0.6 0.8 1 1.2

ln y1
ln y2
GE/x1x2RT
 Kurva Persamaan Van Laar

0.4 0.6 0.8 1 1.2

ln y1
ln y2
GE/x1x2RT
GE/RT
ln y1 Van Laar
ln y2 Van Laar
GE/X1X2RT Van Laar
GE/RT Van Laar

x1
`
Pers 13.42
 Components
Molar
No. Formula Name Constant Value
Mass
1 C3 H 6 O 58.08 Acetone Temp. (°K) 323.15
2 C3 H 8 O 60.096 2 -propanol Temp. (°C) 50

Parameters for Antoine Eq. Sumber Data

Data Bahan
A B C App. B.2
1 Acetone 14.3145 2756.220 228.060 S. Van Ness
2 2 -propanol 16.6796 3640.200 219.610 S. Van Ness

EXPERIMENT

X1 X2 Y1 P1 Sat
P (kPa) T (°C) Y2 (mol/mol)
(mol/mol) (mol/mol) (mol/mol) (kPa)
5.906 25 0 1 0 1 30.6592
13.332 25 0.17500 0.8250 0.59900 0.4010 30.6592
18.612 25 0.33900 0.6610 0.73500 0.2650 30.6592
22.291 25 0.51400 0.4860 0.79800 0.2020 30.6592
25.331 25 0.66900 0.3310 0.85500 0.1450 30.6592
29.554 25 0.83900 0.1610 0.91000 0.0900 30.6592
30.198 25 1.00000 0.0000 1.00000 0.0000 30.6592

Kurva Experiment
𝑥1𝑥2/GE/𝑅𝑇

Slope =
1.2
Intercept =
f(x) = − 0.55232763330144 x + 1.11165268573262
1 R² = 0.826562218117884

0.8

0.6
 Kurva Experiment

𝑥1𝑥2/GE/𝑅𝑇
1.2
f(x) = − 0.55232763330144 x + 1.11165268573262
1 R² = 0.826562218117884

0.8

0.6 A'12= 1/intercept

0.8995232526761
0.4 A'21=1/slope + intercept
0.2
1.7876296031462

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8

x1
 Vapor-Liquid Equil
`

Antoine Eq. 𝐺𝐸/𝑅𝑇 Experiment

γ1 dan γ2 Pers 12.1 𝐺𝐸/x1x2𝑅𝑇 Experiment

Temp.
Range
Memenuh
i

EXPERIMENT

P2 Sat
γ1 γ2 ln γ1 ln γ2 𝐺𝐸/𝑅𝑇 𝐺𝐸/𝑥1𝑥2𝑅𝑇 𝑥1𝑥2/Ge/𝑅𝑇
(kPa)
6.0373 0.9783 -0.0220
6.0373 1.4884 1.0734 0.3977 0.0708 0.1280 0.8866 1.1278951414
6.0373 1.3162 1.2359 0.2747 0.2118 0.2332 1.0405 0.9610588363
6.0373 1.1288 1.5346 0.1211 0.4283 0.2704 1.0825 0.9237875564
6.0373 1.0559 1.8380 0.0544 0.6087 0.2379 1.0742 0.9308855419
6.0373 1.0455 2.7365 0.0445 1.0067 0.1994 1.4764 0.677336359
6.0373 0.9850 -0.0152

Kurva P-xy
35

30

25

20
(k

a)
P

15
-0.5523
1.1117
10

5
 a)
(k
P

P
15

10

0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
slope + intercept x1, y1
uid Equilibrium Data
Experiment Pers 12.6 Persamaan Van Laar :
Pers 13.43

EDISI 8

Pers 13.44

Experiment Pers 12.6 Persamaan Van Laar :

PARAMETER VAN LAAR

A'12 A'21 ln γ1 ln γ2 γ1 γ2 𝐺𝐸/𝑅𝑇 𝐺𝐸/𝑥1𝑥2𝑅𝑇 Error

1.1847 0.7196 1.1847 3.2697 1 0 1.1847 -1.0000

1.1847 0.7196 0.6508 0.2133 1.9171 1.2378 0.1536608003 0.47616904 0.8620
1.1847 0.7196 0.3483 0.3010 1.4166 1.3512 0.2177549155 0.34254779 2.0376
1.1847 0.7196 0.1577 0.3834 1.1708 1.4673 0.222143541 0.23858078 3.5372
1.1847 0.7196 0.0633 0.4717 1.0653 1.6027 0.1831468741 0.15575297 5.8971
1.1847 0.7196 0.0129 0.5867 1.0130 1.7981 0.1037612664 0.07280564 19.2783
1.1847 0.7196 0.7196 1.0000 2.0536 0

1.60

1.40

1.20

1.00

0.80

0.60
 1.00

0.80

0.60

0.8 0.9 1
0.40

0.20

0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7

-0.20
Pers 13.42

ln γ1
ln γ2
𝐺𝐸/𝑅𝑇
𝐺𝐸/𝑥1𝑥2𝑅𝑇
ln γ1
ln γ2
𝐺𝐸/𝑅𝑇
 ln γ1
ln γ2
𝐺𝐸/𝑅𝑇
𝐺𝐸/𝑥1𝑥2𝑅𝑇
ln γ1
ln γ2
𝐺𝐸/𝑅𝑇
𝐺𝐸/𝑥1𝑥2𝑅𝑇

0.6 0.7 0.8 0.9 1