Data in brief 29 (2020) 105121

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Data in brief
journal homepage: www.elsevier.com/locate/dib

Data Article

Data supporting the elemental composition, the

morphological and thermal properties of
MnPhos/waterborne poly(urethane)(WPU)
coatings for carbon steel
P. Salazar-Bravo a, A.M. Torres-Huerta a, b, *,
D. Del Angel-Lo pez c, M.A. Domínguez-Crespo a, b,
D. Palma-Ramírez d, A.B. Lo  pez-Oyama e
a
Instituto Polit
ecnico Nacional, CICATA-Altamira, Km. 14.5 Carretera Tampico-Puerto Industrial Altamira,
89600, Altamira, Tamps, Mexico
b
Instituto Polit
ecnico Nacional, UPIIH, Carretera Pachuca e Actopan k 1þ500 Ciudad del Conocimiento y la
Cultura, 42162, HGO, Mexico
c
Tecnologico de Monterrey, Escuela de Ingeniería y Ciencias. Ave Eugenio Garza Sada 2501, C.P. 64849,
Monterrey NL, Mexico
d
Instituto Polit n Ma
ecnico Nacional, Centro Mexicano para la Produccio s Limpia (CMPL), Av. Acueducto s/n,
la Laguna Ticoma n, C.P. 07340, M
exico City, Mexico
e
CONACYT Research Fellow-CICATA-Altamira, Ave. Insurgentes Sur 1582, Col. Cr edito Constructor, Del.
Benito Juarez, C.P. 03940, Ciudad de M exico, Mexico

a r t i c l e i n f o a b s t r a c t

Article history: The data set presented here offers evidence of the elemental
Received 30 August 2019 composition related to a SEM micrograph of [Mn5(PO3(OH))2(-
Accepted 3 January 2020 PO4)2,4H2O] (MnPhos) powders, known as hurealite, and syn-
Available online 10 January 2020
thesized by the reflux method. In addition, it contains additional
information of the glass transition, melting and decomposition
Keywords:
temperatures and their weight loss percent of coatings based on
Hureaulite
MnPhos incorporated into waterborne poly(urethane) (WPU).
MnPhos/WPU coatings
Thermograms These data are complementing of the article “Corrosion investi-
Elemental composition gation of new hybrid organic/inorganic coatings for carbon steel
SEM micrographs substrates: electrochemical and surface characterizations”.
© 2020 The Authors. Published by Elsevier Inc. This is an open
access article under the CC BY license (http://creativecommons.
org/licenses/by/4.0/).

DOI of original article: https://doi.org/10.1016/j.porgcoat.2019.05.038.

* Corresponding author.
E-mail address: atorresh@ipn.mx (A.M. Torres-Huerta).

https://doi.org/10.1016/j.dib.2020.105121
2352-3409/© 2020 The Authors. Published by Elsevier Inc. This is an open access article under the CC BY license (http://
creativecommons.org/licenses/by/4.0/).
2 P. Salazar-Bravo et al. / Data in brief 29 (2020) 105121

Specifications Table

Subject area Materials Science

More specific subject area Surfaces, Coatings and Films
Type of data Figures, Table and images
How data was acquired Scanning Electron Microscopy (SEM) (Quanta 3D FEG FEI Co.)
Simultaneous Differential Scanning Calorimetry(DSC)/Thermogravimetric analysis (TGA)
equipment (Labsys Evo, Setaram instrument)
Data format Raw and analyzed
Experimental factors Samples for SEM analysis were sputter coated with AuePd for 30 s on a Quorum Q150T ES
sputter coater system.
Experimental features MnPhos/WPU films were analyzed by their elemental composition as well as the morphological
and thermal properties.
Data source location Centro de Investigacion en Ciencia Aplicada y Tecnología Avanzada (CICATA) IPN Unidad
Altamira, Tamaulipas, M exico.
Data accessibility Data are with the article.
Related research article P. Salazar-Bravo, A.M. Torres-Huerta, D. Del Angel-Lopez, M.A. Domínguez-Crespo, D. Palma-
pez-Oyama. Corrosion investigation of new hybrid organic/inorganic coatings
Ramírez, A.B. Lo
for carbon steel substrates: electrochemical and surface characterizations. Progress in Organic
Coatings. In press [1].

Value of the Data

 These data are useful to compare the results consisting on elemental composition and the morphology of MnPhos par-
ticles synthesized by another types of physical and chemical routes.
 Data set are valuable for informing to the research community the thermal transitions that occur when MnPhos is
dispersed into a waterborne poly(urethane) (WPU) and subsequently degraded at high temperatures.
 Data will be a guide to decide the correct wt.% of MnPhos incorporation into polymeric system similar to WPU.
 It will benefit to the environment to understand how the morphology and thermal properties can be managed while
retarding the corrosion of metallic substrates.

1. Data

A possibility to retard the corrosion of carbon steel (AISI 1018) is to produce hybrid coatings by
combining the properties of an inorganic and an organic phase such as the MnPhos and waterborne
poly(urethane)(WPU), which subsequently can be sprayed onto the metallic substrates [2,3].
The dataset of this work shows additional micrographs of the morphology of MnPhos powders
synthesized by reflux method. Fig. 1 displays the SEM micrographs of MnPhos. Also, the EDS spectrum
showed in Fig. 2 shows the number of counts (y-axis) and the energy of the X-rays (x-axis). The
elemental composition, detected from a selected area of the micrographs, is reported in Table 1.
Similarly, the thermogravimetric analysis is showed as TGA thermograms in Fig. 3. The glass
transition temperature, melting temperature (Tm), decomposition temperature (Td) and the weight
loss % (wt.%) in different stages of degradation are reported in Table 2 (see Fig. 4).

2. Experimental design, materials, and methods

MnPhos powders were obtained by the reflux method as follows: 30 mmoles of Manganese(II)
Dihydrogen Phosphate [Mn(H2PO4)2,2H2O] were dissolved in 100 mL of deionized water. 1.7 mL of a
phosphoric acid (H3PO4) solution were added and refluxed under magnetic stirring at 100  C for 12 h.
Thereafter, 2 mL of sodium hypochlorite (NaClO) (>99.99%, Sigma-Aldrich) were added and stirred for
other 20 min. The suspension was filtered, rinsed and dried at 60  C for 12 h.
The morphology and the elemental composition of the MnPhos powders were studied by Energy
Dispersive Spectroscopy (EDS) and Scanning Electron Microscopy (SEM) on a Quanta 3D FEG equip-
ment from FEI Co. equipped with a field emission electron source. High vacuum and a secondary
electron detector were used during the study to acquire the images. Micrographs were obtained at
 P. Salazar-Bravo et al. / Data in brief 29 (2020) 105121 3

Fig. 1. SEM micrograph of MnPhos powders showing a prismatic morphology.

Fig. 2. EDS spectrum of MnPhos powders.

magnifications of 5000 X and 10,000 X with a working distance (WD) of 3.6 mm at 5.0 Kv of accel-
erating voltage. Elemental composition was analyzed with an Apollo X Sillicon Drift Detector (SDD) at
9126 counts per second (CPS), Dead time 20.6 s, 17.6 Lsec (spectrum acquisition time in live seconds).
A waterborne poly(urethane) (WPU) (U-5510®) was provided by COMEX® company. Hybrid
coatings were synthesized by dispersing 2, 4 and 6 wt.% of MnPhos powders into a mixture of resin
(component A, 10 g) and demineralized water (1 mL) by using the sonication method during 30 min. A
component B, the catalysts was added into the mixture to complete the polymerization. This solution
was sprayed onto a carbon steel substrate (AISI 1018). To study the thermal properties of these coatings,
simultaneous thermal analysis was carried out in a Labsys Evo, Setaram equipment in the Differential
Scanning Calorimetry (DSC)/thermogravimetric analysis (TGA) configuration using aluminium crucible
of 80 mL of capacity. An amount of 10 mg was used; the samples were firstly heated at 30  C and hold for
2 min and subsequently, the measurements were carried out in the range of 30e500  C to evaluate

Table 1
Elemental composition of MnPhos powders detected from EDS analysis.

Element Weight (%) Atomic (%) Error (%)

O 59.43 77.84 5.18

Mn 17.93 6.84 7.76
p 22.64 15.32 7.42
4 P. Salazar-Bravo et al. / Data in brief 29 (2020) 105121

Fig. 3. TGA thermograms of MnPhos/WPU coatings showing three stages of decomposition.

thermal degradation under argon atmosphere with a heating rate of 10  C/min. Then, the samples were
hold at 500  C for 2 min followed by a cooling with the same rate. The heating until 500  C was
configured intentionally to evaluate the total degradation of the samples.

Fig. 4. DSC thermograms of MnPhos/WPU coatings.

 P. Salazar-Bravo et al. / Data in brief 29 (2020) 105121 5

Table 2
TGA/DSC measurements of MnPhos/WPU coatings, indicating Tg, Tm and Td temperature ranges in each degradation phase,
weight loss % per stage and weight loss % at 500  C.

Tg ( C) Tm ( C) Tdi_I ( C) Wt.%_df_I Tdi_II ( C) Wt.% df _II Tdi_III ( C) Wt.% at 500 C

WPU 78 175 145 21 300 53 438 93

WPU/2 wt.% Hureaulite 103 240 145 7 252 44 439 98
WPU/4 wt.% Hureaulite 103 177 145 5 239 35 443 86
WPU/6 wt.% Hureaulite 105 181 145 6 218 42 444 88

Tg glass transition temperature, Tm (Melting temperature), Tdi (Initial temperature of decomposition), Tdi_I (Initial temperature
of decomposition of stage I), Wt%df_I (weight loss % of final decomposition in stage I), Tdi_II (Initial temperature of decomposition
of stage II), Wt%df_II (weight loss% of final decomposition in stage II), Tdi_III (Initial temperature of decomposition of stage III), Wt
%df_III (weight loss%of final decomposition in stage III), Wt% at 500  C (weight loss% at 500  C).

Acknowledgments

P. Salazar Bravo is grateful for postgraduate fellowship through CONACyT. The authors are also
grateful for the financial support provided by the CONACYT Research Fellowship-IPN-CICATA Altamira
agreement, 2014e1905 and CONACYT CB2015-252181 projects; Instituto Polite cnico Nacional (IPN)
through the SIP2019-6650, SIP2019-6670, SIP2019-6718 projects; as well as SNI-CONACyT.

Declaration of interests

The authors declare that they have no known competing financial interests or personal relation-
ships that could have appeared to influence the work reported in this paper.

References

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