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The Discovery of Radioactivity
The Discovery of Radioactivity
Lawrence Badash
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THE DISCOVERY OF
RADIOACTIVITY
O ne hundred years ago,
several remarkable dis-
coveries were crowded into
Chance favored Becquerel with cloudy
days that hid his phosphorescent uranium
Becquerel was immedi-
ately challenged by this
question. In fact, he was
the short space of ten years: salts from the sun. Further experiments ideally suited to answer it.
x rays in 1895, radioactivity Not only was he expert in
the next year, the electron in led him to conclude that the salts emitted the investigation of various
1897, quantum theory in invisible, penetrating rays independent of luminescent effects, a com-
1900 and special relativity in mon activity in physics labo-
1905. Individually, each had their luminescence. ratories of the 19th century,
enormous significance. Col- but he had studied the phos-
lectively, they heralded what phorescence of some ura-
we now know as "modern Lawrence Badash nium compounds in particu-
physics." Practitioners of the lar. He also was skilled in
old "classical physics" had no anticipation of the momen- laboratory applications of photography. And, like most
tous change about to grip their science. Indeed, a few physicists, he sought a better understanding of the na-
even claimed that all the great discoveries had already ture of matter, so perhaps the mechanics of phosphores-
been made and that their profession would be reduced cence would bring him closer to reaching this final,
merely to measurements of greater and greater accu- philosophical goal.
racy. No doubt some discoveries lay in the next decimal
place, as illustrated by the 1894 revelation of the rare gas An expert on uranium phosphorescence
argon during very accurate measurements of the constitu- In the second half of the 19th century, Henri's father,
ents of air. But a career centered only on making increas- Edmond Becquerel, who lived from 1820 to 1891, was the
ingly precise measurements would not have appealed to leading authority in Europe on the subject of the phos-
most physicists. phorescence of solids. It was an important field, made
Of course, they were spared such labor by this second prominent by Robert Wilhelm Bunsen's and Gustav Robert
scientific revolution (the first one having been that Kirchhoff's recent spectroscopic analyses. ("Fluorescence"
sparked by Copernicus, Galileo and Newton). Most of the is defined as the emission of light only during stimulation
discoveries whose centennials we are celebrating in this by external radiation. "Phosphorescence" persists after
ten-year period were immediately recognized as impor- the external radiation ceases. "Luminescence" is the um-
tant, and all their discoverers became Nobel laureates brella term.) Edmond was drawn to the investigation of
(although Einstein was honored for the photoelectric effect, uranium salts because of their exceptionally bright phos-
not relativity). But recognition was not always instanta- phorescence and their interesting spectra. One of his
neous, and in the case of radioactivity even its discov- contributions was to show that the uranic series of salts
erer—Antoine Henri Becquerel—went on to other work is phosphorescent and that the uranous series is not. His
before realizing the implications of his own discovery. son, Henri, began publishing on phosphorescence in 1883.
Born in 1852, Becquerel (see figure 1) was the third and wrote twenty papers on this and related areas of
in a line of Becquerels who held the chair of applied study over the next 13 years, being attracted especially
physics at what is today the National Museum of Natural to the effects of infrared radiation. Like his father, Henri
History in Paris (see Figure 2). Like his grandfather and was fascinated by uranium salts, and he examined their
father before him, he was a member of the French Acad- absorption bands in both infrared and visible regions.
emy of Sciences and customarily attended its weekly Although uranium and its compounds interested the
meetings. It was there, at a session on 20 January 1896, Becquerels, the study of these substances remained in
that he heard mathematical physicist Henri Poincare something of a scientific backwater throughout the 19th
describe the silhouette photographs of living bones taken century. Uranium had been discovered in 1789 by a
recently by German physicist Wilhelm Conrad Rontgen. German analytical chemist, Martin Klaproth, while he
(See the article on Rontgen by Howard H. Seliger in had been examining pitchblendes from Saxony. Its
PHYSICS TODAY, November 1995, page 25.) The invisible name was chosen in honor of William Herschel's discov-
x rays appeared to issue from the area of a glass vacuum ery of the planet Uranus in 1781 (a practice continued
tube made fluorescent when struck by a beam of cathode in the 20th century with the naming of neptunium and
rays. Thinking by analogy was (and still is) common plutonium). Not until 1841, however, was it recognized
practice in science, so Poincare wondered aloud if such that Klaproth had obtained only the oxide. Eugene Peli-
radiation was emitted by other luminescent bodies. got, a noted French chemist, then succeeded in separating
the metal.
Attention was again directed to uranium when Dmitri
LAWRENCE BADASH is a professor of history of science at the Mendeleev formulated his periodic table in 1869 and
University of California, Santa Barbara. showed it to be the heaviest element. But in an age of
burgeoning chemical production, few applications for it
several materials—in particular, phosphorescent crystals average of the preceding four days. Indeed, every hourly
of potassium uranyl sulfate—emitted rays that penetrated reading between 0500 and 1900 shows that the nebulosity,
thick black paper and exposed the photographic plate. that is, the fraction of sky covered by clouds, was ten
This exposure was little more than a smudge. To refine tenths (see figure 5).
the results and to make them more attractive to others, A better explanation for Becquerel's activity is that
Becquerel also placed coins and other thin, metallic he wanted to have sufficient material to report at the next
objects under the crystals, producing interesting silhou- day's session of the academy. In previous experiments he
ettes and showing their penetrating power. For example, had already found, or so he believed, that weak illumina-
the bas relief seen in the image of a coin in figure 4 is tion triggered his crystals somewhat. Perhaps he thought
created by the greater penetration through thinner regions that these newly prepared plates had been exposed to
of the object. some diffuse daylight, if not a short period of sunlight,
On Wednesday and Thursday, 26 and 27 February, before he placed them in the dark drawer. Thus, even if
Becquerel prepared several arrays of crystals and photo- he could not describe many additional experiments, he
graphic plates. The Parisian winter, however, brought might furnish evidence of the connection between the
half a week of overcast skies, forcing Becquerel to postpone intensity of the photographic image and the intensity and
the experiments; he felt that he needed strong sunlight. duration of phosphorescence.
The plates rested in a dark drawer until Sunday, 1 March, That he found the plates as blackened as they would
when Becquerel developed them, "expecting to find very have been had the crystals phosphoresced continuously,
weak images. To the contrary," he wrote in his memoirs, and that he recognized the significance of his surprising
"the silhouettes appeared with great intensity." observation, shows that the discovery of radioactivity
The following day, on 2 March 1896, Becquerel re- was not simply a happy accident but also a product of
ported to the Academy of Sciences that the potassium genuine scientific talent. Becquerel's example is comfort-
uranium sulfate crystals could be stimulated to emit the ing to us: His genius emerged because he mistakenly
new rays by diffuse daylight through a thin cloud cover, believed in a connection between the penetrating rays and
as well as by reflected and refracted direct sunlight. He phosphorescence, and because he felt compelled to speak
also described using different thicknesses of copper foil to at the academy's meeting. Folly and pride sometimes are
examine the absorption of the rays. But the most as- rewarded.
tounding result that Becquerel offered was that stimula-
tion of the crystals by sunlight immediately before or Weak hypothesis, strong results
during the experiment was apparently not necessary. Though a major step, this event does not deserve to be
But why had Becquerel bothered to develop those called the discovery of radioactivity. The discovery was a
plates, which he thought were faintly exposed at best? process, not an instantaneous occurrence, for even at this
His behavior has been explained as thoroughness: Jean point Becquerel had not sufficiently localized the phe-
Becquerel has suggested that his father planned to resume nomenon. No doubt Becquerel was a skilled and ingenious
his experiments and wished to use fresh plates, so why experimenter. However, in this early research he was not
not develop the old ones anyway? The explanation prof- sufficiently meticulous to exclude extraneous influences
fered by G. E. M. Jauncey (in a 1946 paper in the Ameri- and to see that some of his experimental results could
can Journal of Physics) is "impatience after waiting four bear more than one explanation. Thus, he often concluded
days for the sun to shine." Yet other reasons, suggested that his experiments proved uranium rays to possess a
by Romer, are "simple thrift... or an overriding curiosity." certain physical property, only to have it shown later that
We can dismiss the belief that Becquerel planned to the effect was due to another cause. Indeed, his investi-
resume his experiments on that Sunday: Meteorological gations are particularly interesting for their many false
records indicate that the day was less sunny than the trails, unreproducible results and misinterpreted effects.
24 11 Apr
Downloaded FEBRUARY 1996 ThisPHYSICS
2013 to 200.233.31.241. TODAY
article is copyrighted as indicated in the abstract. Reuse of AIP content is subject to the terms at: http://www.physicstoday.org/about_us/terms
P A R J S ..(. PARS-. >E. CLOUD COVER IN PARIS was very heavy from Wednesday
«n _
afternoon through Sunday (26 February to 1 March 1896), a
..NEBUL051IE-, _
period when Becquerel wanted to expose his uranium
SuiJ VEB" ftr SOT suH • Tuts" - •
?: 0. 0 V, ^ AQ. Wo 4O 4o c 10 < 9
were kept in darkness for months. And at the University Becquerel, it turns out, had opened a new branch of
of Cambridge, C. T. R. Wilson, a student of J. J. Thomson's science.
who was already building the first cloud chamber, showed
that uranium rays would produce nuclei for the conden- The legacy of nuclear physics
sation of water. Because these nuclei were swept away Since the discovery of radioactivity evolved into the study
by an electric field, Wilson reasoned that they must be of nuclear physics almost a century ago, the applications
charged particles, or ions. that have flowed from the work of Becquerel and others
In the two years after Poincare had speculated at the are primarily nuclear medicine, nuclear reactors and nu-
Academy of Sciences meeting attended by Becquerel about clear weapons. In the field of medicine, diagnostic proce-
whether all luminous bodies emit penetrating radiations, dures, such as tracer techniques, and therapeutic appli-
there were perhaps no more than a dozen other original cations, such as the treatment of cancer by radiation, have
research contributions in addition to the nine papers on proven to be highly valuable and no doubt will continue
radioactivity written by Becquerel. X rays, which pro- to be worthwhile. But the future of nuclear reactors and
duced far sharper photographic images in less time, were weapons is more problematic. Electric utilities in the US
overwhelmingly more popular. (Figure 6 contrasts the ceased buying nuclear power plants some two decades ago,
quality of images produced by the two types of rays. I amid fears of meltdown and skyrocketing costs, while
Laboratories were more likely to have glass vacuum tubes, reactors for ship propulsion seem to be viable only in naval
spark coils and high-voltage sources than various uranium vessels, where cost is less important than convenience.
compounds. Indeed, in 1896 alone, 49 books and 1040 Similarly, nuclear weapons, which ranked terribly high in
papers were published on x rays. the developed world's consciousness until the recent end
Beyond the competition with the immensely popular of the Cold War, have an uncertain future. They seem to
x rays, other phenomena served to suppress interest in be unusable, except for deterrence, and the world commu-
radioactivity. The end of the century was a period of nity increasingly seeks to contain them (as reflected in
excitement about numerous kinds of radiation, both real the recent renewal of the NonProliferation Treaty). No
and spurious. There were not only the familiar cathode doubt, such weapons will remain part of our society in
rays but also dia- and para-cathodic varieties. There were the future, but their significance in the scheme of things
canal rays, discharge rays from sparks, Finsen rays, Hertz- will likely be less. The centennial of radioactivity's dis-
ian waves, emissions from freshly cleaned metallic sur- covery thus celebrates in several ways also the demise of
faces and a host of radiations from other substances. its own influence.
Among this plethora of rays, those from uranium did not
stand out. For further reading:
In early 1898, Curie in Paris and Rutherford in L. Badash, Archives Internationales d'Histoire des Sciences 18, 55
Cambridge began their own investigations of uranium, (1965).
which enabled Becquerel to see the significance of his own L. Badash, Am. J. of Phys. 33, 128 119651.
discovery. It was a major new phenomenon of nature! L. Badash, Isis 57, 267 (19661.
These fresh inquiries were marked by a more systematic L. Badash, Isis 63, 48 11972).
approach—Curie's survey of the periodic table for other L. Badash, Radioactivity in America: Growth and Decay ofa Science
(Johns Hopkins University Press, Baltimore, 1979).
active sources—and more quantitative techniques—elec- Henri Becquerel, Recherches sur une propricte nouvelle de la
trometers largely replaced electroscopes and photographic matiire, memoires de l'Academie des Sciences de l'lnstitut de
plates. In 1903, five years before he died, Becquerel France, vol. 46 I Firmin-Didot, Paris, 1903). In his only book on
shared the Nobel Prize in Physics with Pierre and Marie the subject, Becquerel organized and reviewed his work on
Curie for the discovery of radioactivity. radioactivity.
New and exciting results came quickly, and still others Helmut Gernsheim, The History of Photography (Oxford Univer-
flowed in over the next dozen years: The activity of sity Press, London, 1955).
thorium, new elements polonium and radium, the break- E. Newton Harvey, A History of Luminescence (American Philo-
down of the radiation into alpha, beta and gamma com- sophical Society, Philadelphia, 1957).
Alfred Romer, ed., The Discovery of Radioactivity and Transmuta-
ponents and the recognition of their particulate or elec- tion (Dover, New York, 1964). Many of the early papers in
tromagnetic natures, the explanation of radioactivity as radioactivity are translated into English here.
atomic transmutation, the recognition of isotopy, and the Glenn Seaborg, "Uranium," Encyclopaedia Britannica 22. 888
transformation of radioactivity itself into nuclear physics. (1957). •