t/min 0 2 4 8

[A]/[M] 0.1 0.09 0.08 0.07

ln[A] -2.3 -2.4 -2.5 -2.7

ln[A]thdt

ln [A] vs t
-2.1
0 1 2 3 4 5 6 7 8 9
-2.2

-2.3
f(x) = − 0.044530521425562 x − 2.31802302073227
ln[A]

-2.4 R² = 0.981065744155468

-2.5

-2.6

-2.7
t (min)

k = -slope=-(-0,04453025)= 0,04453025 s-1

t1/2 = 0,693/k 15.5623603766585
[A]=[A]0 e^{-kt}
ln[A] = ln [A]0-kt
t= (ln[A]-ln[A]0)/-k
8 9
 Time (s)
[PP] (M) ln[PP] t/[PP]
0.005 -5.29831736655 200 0
0.0045 -5.40367788221 222.2222222222 10.5
0.004 -5.52146091786 250 22.3
0.0035 -5.65499231049 285.7142857143 35.7
0.003 -5.80914299031 333.3333333333 51.1
0.0025 -5.99146454711 400 69.3
0.002 -6.21460809842 500 91.6
0.0015 -6.50229017087 666.6666666667 120.4
0.001 -6.90775527898 1000 160.9
0.0005 -7.60090245954 2000 230.3
0.00025 -8.2940496401 4000 299.6
0.00015 -8.80487526387 6666.666666667 350.7
0.0001 -9.21034037198 10000 391.2

ln[PP] vs t
[PP] vs t 1/[PP] vs t
0
0.006 0 50 100 150 200 250 300 350 400 450 12000
-1
0.005 -2 10000
-3
0.004 -4 8000
f(x) = − 1.17047981796982E-05 x + 0.003804762918638
[PP]
R² = 0.829812439591053 -5 f(x) = 20.6969679493051 x − 878.873635172511
0.003 6000
[PP]

[PP]
f(x) = − 0.009999100784582 x − 5.29842508459088 R² = 0.830946324059669
-6
R² = 0.999999961330541
0.002 -7 4000
-8
0.001 2000
-9
0 -10 0
0 50 100 150 200 250 300 350 400 450 0 50 100 150 200 250 300 350 400 450
t(s)
t(s) t(s)

jadi reaksi antara PP dan basa berlebih mengikuti kinetik reaksi orde 1 semu.
karena basanya excess

k=-slope=-(-0,01) = 0,01 s-1

rate law = 0,01 s-1 [PP]
t1/2=0,693/k
69.3
 1/[PP] vs t

) = 20.6969679493051 x − 878.873635172511
= 0.830946324059669

100 150 200 250 300 350 400 450

t(s)