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MM435 CDP-1 6 Kinetics 1
MM435 CDP-1 6 Kinetics 1
MM435 CDP-1 6 Kinetics 1
Fall-2021
By
➢ Kinetics of Passivity
➢ Corrosion Testing
Metal Surface
potential varies linearly with
distance
For example,
➢ io for H+ / H2 reaction on platinum
-2
is about 10 A/cm2 and
➢ io for H+ / H2 reaction on mercury
-13 2
is about 10 A/cm ,
➢ This means it is easier to reduce
hydrogen ions from acidic
electrolyte on a platinum
electrode unlike on mercury,
which possesses a high
Hydrogen-overvoltage. MM-435_Corrosion Degradation and Protection 10
Faraday’s Laws and corrosion rate calculation:
1st Law
The mass of primary products formed at an electrode by electrolysis is directly proportional to the
quantity of electricity passed
I = current in amperes
t = time in seconds
m = mass of the primary product in grams
Z = constant of proportionality (electrochemical equivalent). It is the mass of a substance liberated by 1 ampere-second of a current (1
coulomb).
nd
2 Law
The masses of different primary products formed by equal amounts of electricity are
proportional to the ratio of molar mass to the number of electrons involved with a
particular reaction:
Solution
(a) What is the corrosion
rate of zinc in mdd (mg/dm2/day)?
Current density
Penetration
rates
Mass/Weight loss
(in mpy)
Objectives:
➢ASTM Standards
most commonly used
➢NACE Standards
➢API Standards
➢British Standards
Laboratory Tests:
Immersion Test
Immersion Test
Immersion Test
Immersion Test
Immersion Test
It is given by:
η = E − Erev
where:
η is the Polarization or deviation of the potential,
E is applied/measured potential and
Erev is the reversible potential.
Types of Polarization:
Sub Types:
1. Activation Polarization (Over Potential)
2. Concentration Polarization
Total Polarization: