BOW Guru Antra Goal: Anand Prakash

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JEE Advanced Exam 2019
(Paper & Solution)
PAPER-2
PART-I (PHYSICS)
SECTION – 1(Maximum Marks: 32)
 This section contains EIGHT (08) questions.
 Each question has FOUR options. ONE OR MORE THAN
ONE of these four option(s) is (are) correct option(s).
 For each question, choose(s) corresponding to (all) the correct
answer(s).
 Answer to each question will be evaluated according to the
following marking scheme :
Full Marks: +4 If only (all) the correct option(s) is (are)
chosen.
Partial Marks:+3 If all the four options are correct but ONLY
three options are chosen.
Partial Marks: +2 If three or more options are correct but
ONLY two options are chosen, both of which are correct
options.
Partial Marks: +1 If two or more options are correct but
ONLY one option is chosen and it is a correct option.
Zero Marks: 0 If none of the option is chosen (i.e. the
question is unanswered).
Negative Marks: –1 In all other cases.
1
1. Three glass cylinders of equal height H = 30 cm and same
refractive index n = 1.5 are placed on a horizontal surface
as shown in figure. Cylinder I has a flat top, cylinder II has
a convex top and cylinder III has a concave top. The radii
of curvature of the two curved tops are same (R = 3m). If
H1 , H 2 and H3 are the apparent depth of a point X on the
bottom of the three cylinders, respectively, the correct

statement (s) is / are –
(1)0.8 cm < (H2 – H1) < 0.9 cm (2) H3> H1

(3)H2> H3 (4) H2> H1
Soln.: [3, 4]
For fig. I
It is given that its top is flat or plane. So, R =  for plane
surface,
As we know that
1  2  2  1
  Here 2 =1, 1 =1.5, u = -30 cm, v = - H1
v u R
1 1.5 1  1.5
 
 H1 30 
30
H1 20 cm
1.5
2
For fig. II,
Applying following formula
1  2  2  1
 
v u R
Here 2 =1, 1 =1.5, u = -30 cm, v = - H2, R = - 3m = - 300
cm
1 1.5 1 1.5
H2 30 300
1 15 0.5 1
H2 300 300 600
1 15 1 30 1 29
H2 300 600 600 600
H2 = 20.6 cm
For fig. III
Applying following formula
1  2  2  1
 
v u R
Here 2 =1, 1 =1.5, u = -30 cm, v = - H3, R= 3m = 300 cm
1 1.5 1 1.5 0.5 1

H3 30 300 300 600
1 1 1
H3 20 600
600
H3 19.3
31
Now from above, we get, H1 = 20 cm, H2 = 20.6 cm, H3 =

19.3 cm
H2 – H1 = 20.6 – 20 = 0.6
With above values, we can conclude that
H2> H1, H3< H1, H2> H3
3
p0 ˆ ˆj)
2. An electric dipole with dipole moment (i is held fixed
2
at the origin O in the presence of an uniform electric field
of magnitude E0. If the potential is constant on a circle of
radius R centered at the origin as shown in figure, then the
correct statement (s) is/are : ( 0 is permittivity of free space
R >> dipole size)
(1) Total electric field at point B is EB 0
(2) Total electric field at point A is EA 2E 0 (iˆ ˆj)

1/3
p0
(3) R
4 E0
0
(4) The magnitude of total electric field on any two points

of the circle will be same.
Soln.: [1, 3]
4
At point B, E due to dipole is equatorial. E equatorial at all points
on circle should be zero since the given circle is
equipotential
kp0
EB 0 E0
R3
So, option (1) is correct.
2kp0
Electric field at point A, EA E0 2E0 E0 3E0
R3
1/3 1/3
kp 0 kp p0
E0 R
R3 E0 4 0 E0
So, option (3) is correct.
Because E0 is uniform & due to dipole Electric field is

different at different points, so magnitude of total electric
field will also be different at different points.
So, option (4) is incorrect.
3. A thin and uniform rod of mass M and length L is held

vertical on a floor with large friction. The rod is released
from rest so that it falls by rotating about its contact-point
with the floor without slipping. Which of the following
statement (s) is/are correct, when the rod makes an angle
60º with vertical? [g is the acceleration due to gravity]
(1) The angular acceleration of the rod will be 2gL
(2) The radial acceleration of the rod's center of mass will
be 3g4
3g
(3) The angular speed of the rod will be 2L
5
(4) The normal reaction force from the floor on the rod will
be Mg
16
Soln.: [2, 3, 4]
By applying conservation of energy, we get

1 2 L
I  mg
2 4
1 mL2 2 L
  mg
2 3 4
3g

2L
Now,
L ML2
  I  (mg) sin 60  
2 3
3g 3g 3 3 3g
 sin 60  
2L 2L 2 4L
L L 3 3g 3 3g
Tangential acceleration, aT 
2

2 4L

8
L 2 L 3g 3g
Radial acceleration ac   
2

2 2L 4
Net vertical acceleration of C.M. of rod
3g 3 3g 3g 3 3g 3 3g  3  15g
av  cos 60  sin 600    1   
4 8 8 8 2 8  2  16
Applying Fnet = mav in vertical direction on rod as system
15g Mg
Mg  N  M  N
16 16
6
4. In a Young's double slit experiment, the slit separation d is
0.3 mm and the screen distance D is 1m. A parallel beam of
light of wavelength 600 nm is incident on the slits at angle
as shown in figure. On the screen, the point O is
equidistant from the slits and distance PO is 11.0 mm.
which of the following statement(s) is/are correct?
0.36
(1) For 

degree, there will be destructive interference
at point O
(2) For   0, there will be constructive interference at
point P
(3) For   0.36

degree, there will be destructive interference
at point P.
(4) Fringe spacing depends on .
Soln.: [3]
Given   0.36 deg ree  0.36    1 radian
  180 500
dy
Path difference at p = d sin 
D
(  small, sin  )
dy
 d 
D
 11  103 
 (0.3  103 )   
 1 
7
 1 
3 104   11103  3
=  500   10 [13 103 ]  13
600 109 2 2
 13
  6.5
 2
Destructive interference
 3 104 11103 11
(2)   0,    5.5 (Destructive)
 6 107 2
Fringe width in all the above case remain unchanged. So,
Fringe width does not depend on .
5. A mixture of ideal gas containing 5 moles of monatomic

gas and 1 mole of rigid diatomic gas is initially at pressure
P0, volume V0, and temperature T0. If the gas mixture is
adiabatically compressed to a volume V0/4, then the
correct statement(s) is/are, (Given 21.2  2.3;23.2  9.2 : ; R is gas
constant)
(1) The final pressure of the gas mixture after compression
is in between 9P0 and 10P0.
(2) The work |W| done during the process is 13 RT0.
(3) Adiabatic constant of the gas mixture is 1.6.
(4) The average kinetic energy of the gas mixture after
compression is in between 18RT0 and 19RT0.
Soln.: [1, 2, 3]
Given:
n1= 5 moles of monatomic gas and n2 = 1 mole of diatomic
gas
n1Cp1  n 2 Cp 2
Adiabatic constant of the gas mixture,  mi x 
n1C v1  n 2 Cv 2
3R 5R
Cv1  Cp1 
2 2
5R 7R
Cv 2  Cp 2 
2 2
8
 5R   7R 
5   (1)  
Adiabatic constant of the gas mixture  
2   2   32R / 2  8  1.6
 3R   5R  20R / 2 5
5   (1)  
 2   2 

V 
And for adiabatic process P0 V0  P  0  ( adiabatically
 4 
v0
compression = )
4
The final pressure of the gas, P  P0 (4)  P  P0 (4)8/5  9.2P0
V0
P0 V0  (4)8/5 P0
PV P V 4
W 1 1 2 2 
 1 8
1
5
1  43/5  1.92
 P0 V0    P0 V0  2.15P0 V0
 3 / 5  0.6
| W | 2.15(6)RT0  13RT0
5R
Average kinetic energy = nCVT= 6x x2.3 T0= 23 RT0
3
6. A small particle of mass m moving inside a heavy,

hollow and straight tube along the tube axis undergoes
elastic collision at two ends. The tube has no friction and it
is closed at one end by a flat surface while the other end is
fitted with a heavy movable flat piston as shown in figure.
When the distance of the piston from closed end is L = L0
the particle speed is v = v0. The piston is moved inward at
a very low speed V and such that V  dLL
v 0 , where dL is the
infinitesimal displacement of the piston. Which of the

following statement (s) is/are correct?
9
(1) The particle's kinetic energy increases by a factor of 4
when the piston is moved inward from L0 to 12 L0 .
(2) After each collision with the piston, the particle speed
increases by 2V.
(3) The rate at which the particle strikes the piston is v/L.
(4) If the piston moves inward by dL, the particle speed
increases by 2v dL
L
.
Soln.: [1, 2]
(3) The rate at which the particle strikes the piston= 2L

v
(2) Speed of particle after collision = 2V + v0
Change in speed = (2V + v0) – v0
After each collision = 2V
Frequency = v
2L
Change in speed in dt time = 2V × number of collision dt
time
v dL vdL
 dv  2v  
2L V L
On decreasing length to half K.E. becomes ¼

Option (1) and (2)
10
7. A block of mass 2M is attached to a massless spring
with spring-constant k. This block is connected to two other
blocks of masses M and 2M using two massless pulleys and
strings. The accelerations of the blocks are a1 ,a 2 and a 3 as
shown in the figure. The system is released from rest with
the spring in its unstretched state. The maximum extension
of the spring is x 0 . Which of the following option (s) is/are
correct ? [g is the acceleration due to gravity. Neglect
friction]
x0
(1) When spring achieves an extension of 2
for the first
time, the speed of the block connected to the spring is
M
3g
5k
4Mg
(2) x0 
k
x0
(3) At an extension of 4
of the spring, the magnitude of
3g
acceleration of the block connected to the spring is 10
(4) a 2  a1  a1  a 3
Soln.: [4]
11
2a1 = a2 + a3
a 1 – a 3 = a2 – a 1
a 2  a3
ap 
2
or a 2  a1  a1  a 3
Also
m  2m 2m
Reduced mass = m  2m

3
2m1m2 4m
Tension = m1  m2
geff 
3
geff
4m
2T  2  g eff
3
2T 8m

g eff 3
8m 1
.x 0 g   kx 02
3 2
16mg
x0 
3k
Energy conservation
8m x 0 1 x 02 1
g  k  (2m)v2
3 2 2 4 2
2
16mg 4mg 1  16mg  2 4m 2
 k   mv  v
3k 3 8  3k  3
32 m2g 2 7 2
 mv
9 k 3
12
32 mg 2
v2 
21 k
32 mg
vg
21 k
8. A free hydrogen atom after absorbing a photon of

wavelength  a gets excited from the state n = 1 to the state n
= 4. Immediately after that the electron jumps to n = m
state by emitting a photon of wavelength  0 . Let the change
in momentum of atom due to the adsorption and the
emission are pa and pe , respectively. If a  15 , which of the
e
option (s) is/are correct ? [Use hc = 1242 eVnm; 1nm  109 m , h

and c are Planck's constant and speed of light, respectively]
(1) e  418nm
(2) The ratio of kinetic energy of the electron in the state
n = m to the state n = 1 is 14
(3) m = 2
(4) ppa  12
e
Soln.: [2, 3]
The energy level diagram is shown in the figure
13
2
1 1

 a m 2  4  1
It is given that :  
e 1
2 5
1  
4
1 1 1 15 3
   
2 16 5 16 16
m
1 4
2
  m2
m 16
Now,
hc 1 1 
 13.6   
e  4 16 
1240  12 
 13.6  
e  16  4 
1240  16  4
e 
12  13.6
= 487 nm
The ratio of the kinetic energies is also the ratio of the
corresponding total energies  1
4
h h
pa  and pe 
a e
pa  e
Now,  =5
pe  a
14
SECTION – 2 (Maximum Marks: 18)
 This section contains SIX (06) questions. The answer to each
question is a NUMERICAL VALUE.
 For each question, enter the correct numerical value using the
mouse and the on-screen virtual numeric keypad in the place
designated to enter the answer. If the numerical value has
more than two decimal places, truncate/round-off the value
to TWO decimal places.
following marking scheme.
Full Marks: +3 If ONLY the correct numerical value is
entered as answer.
Zero Marks:0 In all other cases.
1. A 10 cm long perfectly conducting wire PQ is moving with
a velocity 1 cm/s on a pair of horizontal rails of zero
resistance. One side of the rails is connected to an inductor
L = 1 mH and a resistance R  1 as shown in figure. The
horizontal rails, L and R lie in the same plane with a
uniform magnetic field B = 1T perpendicular to the plan. If
the key S is closed at certain instant, the current in the
circuit after 1 millisecond is x 103 A , where the value of x is
………. .
[Assume the velocity of wire PQ remains constant (1 cm/s)
after key S is closed. Given: e1  0.37 , where e is base of the
natural logarithm]
15
Soln.: [0.63]
Given: B = 1T, l= 10 cm, v = 1 cm/s
Since velocity of PQ is constant. So emf developed across

it remains constant
E  vlB where l = length of wire PQ
 10 
 (102 m / s)  3
 (1)  10 volt
 100 
Current at any time t is given by
L 103
i  i 0 (1  e  t/  )  
R 1
103  103 /103 
 1  e
1  
 1
 103 1    0.63  103
 e
Therefore,
x= 0.63
16
2. Suppose a 88226 Ra nucleus a rest and in ground state undergoes
  decay to a 86
222
Rn nucleus in its excited state. The kinetic
energy of the emitted a particle is found to be 4.44 MeV.
86 Rn nucleus then goes to its ground state by   decay. The
222
energy of the emitted  photon is ………….. keV. [Given:

atomic mass of 88226 Rn  226.005u , atomic mass of 86222 Rn  222.000u,
atomic mass of  particle = 4.000 u, 1u  931MeV / c2 , c is speed
of the light]
Soln.: [135]
Mass defect m = (226.005) – [222.000 + 4.000]

= 226.005 – 226.000 = 0.005amu
Q = m c2 = 0.005 × 931.5 = 4.6575 MeV = E0
Since momentum is conserved, kinetic energy is in inverse

ratio of masses.
1
PRn   PHe  KE 
m
(KE) Rn m
 
(KE) m Rn
4.000
 (KE) Rn   (KE)
222.000
4
 (KE) Rn   4.44 MeV  0.08MeV  Given (KE)   4.44Mev 
222
Energy of  particle = E  KE 0   KE Rn = 4.65 – [4.44 + 0.08]

= 0.135 MeV = 135 KeV
17
3. A monochromatic light is incident from air on a refracting
surface of a prism of angle 75º and refractive index n 0  3 .
The other refracting surface of the prism is coated by a thin
film of material of refractive index n as shown in figure.
The light suffers total internal reflection at the coated prism
surface for an incidence angle of   60 . The value of n 2 is
…………… .
Soln.: [1.5]
Total internal reflection at the coated prism surface

n
sin c  ...................(i)
3 .
By applying snell,s law
sin   3 sin(75  c )
For limiting condition   60,
sin 60  3 sin(75  c )  c  45
From equation (i), we get

1 n 3 3
  n  n2 
2 3 2 2
n 2  1.50
18
4. An optical bench has 1.5 m long scale having four equal
divisions in each cm. While measuring the focal length of a
convex lens, the lens is kept at 75 cm mark of the scale and
the object pin is kept at 45 cm mark. The image of the
object pin on the other side of the lens overlaps with image
pin that is kept at 135 cm mark. In this experiment, the
percentage error in the measurement of the focal length of
the lens is ……………….. .
Soln.: [1.38 or 1.39]
For the given lens, u = –30 cm and v = 60 cm
By using lens formula, we get

1 1 1 1 1 1
    
v u f 60 30 f
f = 20 cm
Now,
1 1 1
 
f v u
After differentiation both side, we get
df dv du
2
 2

f u2
v
 dv du 
df  f 2  2  2  ………………..(i)
v u 
Here f= 20 cm, dv = du = 0.25+ 0.25 = 0.5cm
Putting values in above equation, we get
19
 0.5 0.5   1 1  10
df  400   2
     2 
 (60)
2
(30)   36 9  36
The percentage error in the measurement of the focal length of

the lens is given by
df 10 / 36 50
 100   100   1.388
f 20 36
5. A ball is thrown from ground at an angle  with horizontal

and with an initial speed u 0 . For the resulting projectile
motion, the magnitude of average velocity of the ball up to
the point when it hits the ground for the first time is V1 .
After hitting the ground, the ball rebounds at the same
angle  but with a reduced speed of u 0 /  . Its motion
continues for a long time as shown in figure. If the
magnitude of average velocity of the ball for entire duration
of motion is 0.8V1 , the value of  is …………… .
Soln.: [4]
2u 0 Sin 
Let g
 T0 and u 0 cos   v1
Total displacement
Vavg 
Time taken
Here, total displacement  v1t1  v 2 t 2  v3t 3...........
Total timeTaken  t1  t 2  t 3...........
Now, we get
20
 u0 u 
 cos  0 sin  
 u 0 cos u 0 sin    
2   2 
 g   g 
  
u0
2 sin 
2u 0 sin 
   ....
g g
 1 1 1 
u 0 cos  1  2  4  ....  2m 
     
1 1 1
1   2  .....  m
  
m
 1 1 
1   2   4  ...... 
 V1  
 1  1  1  ...... 
  2 
 1 
 1   2 
 1    
 V1  2   v  2  1 
 1    
1
 1    1 
 1   
  
 2   1 
Vavg  V1  2  V1
   1     1

0.8V1  V1     0.8  0.8
 1
0.2  0.8
4
21
6. A perfectly reflecting mirror of mass M mounted on a
spring constitutes a spring-mass system of angular
frequency  such that 4M h

 1024 m 2 with h as Planck's
constant. N photons of wavelength   8106 m strike the

mirror simultaneously at normal incidence such that the
mirror gets displaced by 1m . If the value of N is x 1012 , then
the value of x is …………… . [Consider the spring as
massless]
Soln.: [1]
Given that:
-6
A  1m = 10 m N = No. of photons,   8106 m
If v is speed of mirror just after absorption of photons

h
Mv max  2N

h
Ma  2N

h
M(106 )()  2N
8  106
Nh
1012 
4M
 4M  12
N 10
 h 
4M
N  1024 1012  1012 (Given that:  1024 m 2 )
h
X=1
22
 This section contains Two (02) List-Match sets.
 Each List-Match set has TWO (02) Multiple Choice
Questions.
 Each List-Match set has two lists : List-I and List-II
 List-I has Fourentries (I), (II), (III) and (IV) and List-II has
Six entries (P), (Q), (R), (S), (T) and (U).
 FOUR options are given in each Multiple Choice Question
based on List-I and List-II and ONLY ONE of these four
options satisfies the condition asked in the Multiple Choice
Question.
 For each question, marks will be awarded according to the
Full Marks: +3 If ONLY the option corresponding to the
correct matching is chosen.
Zero Marks: 0 If none of the options is chosen (i.e. the
question is unanswered.)
Answer the following by appropriately matching the lists
based on the information given in the paragraph.
1. A musical instrument is made using four different metal
strings, 1, 2, 3 and 4 with mass per unit length ,2,3 and 4
respectively. The instrument is played by vibrating the
strings by varying the free length in between the range
L0and 2L0. It is found that in string-1 () at free length L0and
tension T0the fundamental mode frequency is f0.
23
List-I gives the above four strings while List-II lists the
magnitude of some quantity.
List - I List – II
(I) String – 1 (P) 1
()
(II) String – 2 (Q) 1/2

(2)
(III) String – 3 (R) 1/ 2
(3)
(IV) String – 4 (S) 1/ 3
(4)
(T) 3/16
(U) 1/16
If the tension in each string is T0, the correct match for the
highest fundamental frequency in f0 units will be,
(1) I  Q; II  S; III  R; IV  P
(2) I  P; II  R; III  S; IV  Q
(3) I  P; II  Q; III  T; IV  S
(4) I  Q; II  P; III  R; IV  T
Soln.: [2]
For fundamental mode
Frequency f0  2L1 T
0
1 T0
String (1) f0 
2L0 
P
1 T0 f
String (2) f2 
2L0 2
 0 R
2
24
1 T
String (3) f3 
2L0 3
S
1 T f0
String (4) f4 
2L0
 Q
4 2
I  P, II  R, III  S, IV  Q Option (2)
2. Answer the following by appropriately matching the

lists based on the information given in the paragraph.
A musical instrument is made using four different metal
strings, 1, 2, 3 and 4 with mass per unit length ,2,3 and 4
respectively. The instrument is played by vibrating the
strings by varying the free length in between the range L0
and 2L0. It is found that in string-1 () at free length L0 and
tension T0 the fundamental mode frequency is f0.
List-I gives the above four strings while list-II lists the
magnitude of some quantity.
List – I List – II
(I) String – 1 () (P) 1
(II) String – 2 (2) (Q) 1/2
(III) String – 3 (3) (R) 1/ 2
(IV) String – 4 (4) (S) 1/ 3
(T) 3/16
(U) 1/16
25
The length of strings 1, 2, 3 and 4 are kept fixed at L0,
3L 0 5L 0 7L 0
2
,
4
and 4
, respectively. String 1, 2, 3 and 4 are
vibrated at their 1st, 3rd, 5th, and 14th harmonics, respectively
such that all the strings have same frequency. The correct
match for the tension in the four strings in the units of T0
will be.
(1) I  P; II  Q; III  T; IV  U
(2) I  P; II  Q; III  R; IV  T
(3) I  T; II  Q; III  R; IV  U
(4) I  P; II  R; III  T; IV  U
Soln.: [1]
For string (1)

Length of string = L0
It is vibrating in Istharmonic i.e. fundamental mode.
1 T
f0 
2L 0 
For string (2),

3L 0
Length of string = 2
It is vibrating inIIIrd harmonic but frequency is f0
26
3 T2 1 1 1 T0
f0   
 3L  2 2 L0 2L0 
2 0 
 2 
T
T2  0
2
For string (3)

5L 0
It is vibrating in 5thharmonic but frequency is still f0
5 T3 2 1 T3 1 T0
f0    
 5L  3 3 L0  2L0 
2 0 
 4 
3
T3  T0
16
For string (4),

7L 0
27
It is vibrating in 5thharmonic but frequency is still f0
14 T4 1 T0
f0  
 7L  4 2L0 
2 0 
 4 
T0 T0
4T4   T4 
2 16

In a thermodynamic process on an ideal monoatomic gas,
the infinitesimal heat absorbed by the gas is given by TX ,
where T is temperature of the system and X is the
infinitesimal change in a thermodynamic quantity X of the
system. For a mole of monatomic ideal gas
 T   V 
X  R ln    R ln   . Here, R is gas constant, V is volume of
 T A  V  A 
gas, TA and VA are constants.
The List-I below gives some quantities involved in a
process and List-II gives some possible values of these
quantities.
1
(I) Work done by the system in (P) RT0 ln 2
3
process 1  2  3
1
(II) Change in internal energy in (Q) RT0
3
(III) Heat absorbed by the system in (R) RT0
28
4
(IV) Heat absorbed by the system in (S) RT0
3
process 1  2
(T) 1
RT0 (3  ln 2)
3
5
(U) RT0
6
If the process on one mole of monatomic ideal gas is as

shown in the TV-diagram with P0 V0  13 RT0 , the correct match
is.
(1) I  P; II  R; III  T; IV  P
(2) I  P; II  T; III  Q; IV  T
(3) I  P; II  R; III  T; IV  S
(4) I  S; II  T; III  Q; IV  U
Soln.: [1]
Given that Process 12 is isothermal since temperature is
constant.
Process 2 3 is isochoric since volume is constant
(1) Work done by the system in process 1  2  3
W1-2-3 = W12 + W23
 2V 
W123  nRT ln  0   0
 V0 
T RT0
W123  nR 0 ln 2  0  ln 2
3 3
29
(2) Change in internal energy in process 1  2  3
U123  U12  U 23
 0  nCvdT
3R  T 
 0  1  T0  0   RT0
2  3 
(3) Heat absorbed by the system in process 1  2  3

Q123  Q12  Q23
RT0
 ln 2  nCv dT
3
RT0
 ln 2  RT0
3
RT0
 (ln 2  3)
3
(4) Heat absorbed by the system in process 1 

2(isothermal)
Q12  W
RT0
 ln 2
3

In a thermodynamic process on an ideal monoatomic gas,
the infinitesimal heat absorbed by the gas is given by TX ,
where T is temperature of the system and X is the
infinitesimal change in a thermodynamic quantity X of the
system. For a mole of monatomic ideal gas
 T   V 
X  R ln    R ln   . Here, R is gas constant, V is volume of
 T
A  V A 
gas, TA and VA are constants.
The List-I below gives some quantities involved in a
process and List-II gives some possible values of these
quantities.
30
1
(I) Work done by the system in (P) RT0 ln 2
3
1
(II) Change in internal energy in (Q) RT0
3
(III) Heat absorbed by the system in (R) RT0
4
(IV) Heat absorbed by the system in (S) RT0
3
process 1  2
1
(T) RT0 (3  ln 2)
3
5
(U) RT0
6
If the process on one mole of monatomic ideal gas is as

shown in the TV-diagram with P0 V0  13 RT0 , the correct match
is.
(1) I  Q; II  R; III  S; IV  U
(2) I  Q; II  S; III  R; IV  U
(3) I  S; II  R; III  Q; IV  T
(4) I  Q; II  R; III  P; IV  U
Soln.: [1]
31
Given that Process 12 is isothermal since temperature is
constant
Process 2 3 is isochoric since volume is constant
Degree of freedom f = 3
(1) Work done by the system in process 1  2  3
Work done in any process = Area under P–V graph
W123  w12  w 23
RT0
 P0 V0 
3
(2) Change in internal energy in process 1  2  3
U123  U12  U 23
 nCv(T3  T1 )
3
 n R(T3  T1 )
2
3
 (RT3  RT1 )
2
3
 (3P0 V0  P0 V0 )  3P0 V0  RT0
2
(3) Heat absorbed by the system in process 1  2  3

Q123  Q12  Q23
 nCp(T2  T1 )  nCv(T3  T2 )
5 3
 (RT2  RT1 )  (RT3  RT2 )
2 2
5 3
 (2P0 V0  P0 V0 )  (3P0 V0  2P0 V0 )
2 2
5 3 4
 P0 V0  P0 V0  4P0 V0  P0 V0
2 2 3
3S
(4) Heat absorbed by the system in process 1  2
5
Q12  5P0 V0  RT0
6
4U
32
(Paper & Solution)
PAPER-2
PART-I (CHEMISTRY)
 Each question has FOUR options. ONE OR MORE
THAN ONE of these four option(s) is (are) correct
option(s).
 For each question, choose(s) corresponding to (all) the
correct answer(s).
chosen.
Partial Marks: +3 If all the four options are correct but
ONLY three options are chosen.
options.
33
 For example, in a question, if (A), (B) and (D) are the
ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 marks;
choosing ONLY (B) will get +1 marks;
choosing ONLY (D) will get +1 marks;
choosing no option (i.e. the question is unanswered) will
get 0 marks; and choosing any other
commination of options will get –1 mark
1. The cyanide process of gold extraction involves leaching
out gold from its ore with CN in the presence of Q in water
to form R. Subsequently, R is treated with T to obtain Au
and Z. Choose the correct options(s)
(1) Z is [Zn(CN)4 ]2 (2) T is Zn
(3) Q is O2 (4) R is [Au(CN)4 ]
Soln.: [1, 2, 3]
Eraction of gold is done by teaching with dil. solution of

NaCN in the pressure of air (CO2).
Au  CN  (aq)  O 2 
2 [Au(CN) ] (aq)  OH 
H O
2
Q

[Au(CN)2 ] (aq)  Zn(s)  [Zn(CN 4 )]2  2Au(s)
(R) (T) (Z)
34
2. Which of the following reactions produce(s) propane as a
major product?
(1)
(2)
(3)
(4)
Soln.: [2, 4]
CH3  CH 2  CH 2  Cl 
Zn
 CH3  CH 2  CH 2 ZnC 
dil.HCl
 CH3  CH 2  CH3
CH3  CH 2  CH 2  C  O Na  
NaOH, CaO
CH3  CH 2  CH3
D
||
O
3. With reference to aqua regia, choose the correct option(s):

(1) Reaction of gold with aqua regia produces NO in the 2
absence of air
(2) Reaction of gold with aqua produces an anion having
Au in +3 oxidation state
(3) The yellow colour of aqua regia is due to the presence
of NOCl and Cl 2
(4) Aqua regia is prepared by mixing conc. HCl and conc.

HNO in 3:1 (v/v) ratio
3
Soln.: [2, 3, 4]
(1) 2Au + 3HNO3 + 11HCl → 2HAuCl4 + 3NOCl + 6H2O
(2) In HAuCl4 or [AuCl4]-, Au is in + 3 oxidation state.
(3) Yellow colour of aqua regia is due to the presence of
NOClorange yellow and Cl (greenish yellow) 2
(4) Aqua regia is mixture of 3HCl(conc.) and 1HNO3.
35
4. The ground state energy of hydrogen atom is –13.6 eV.
Consider an electronic state  of He whose energy,

azimuthal quantum number and magnetic quantum number

are –3.4 eV, 2 and 0, respectively. Which of the following
statement(s) is (are) true for the state  ?
(1) The nuclear charge experienced by the electron in this
state is less than 2e, where e is the magnitude of the
electronic charge
(2) It has 2 angular nodes
(3) It has 3 radial nodes
(4) It is a 4d state
Soln.: [2, 4]
He  (z  2)
Ground state energy is given
z2
E n  13.6  3.4
n2
(2)2
13.6  3.4
n2
n 2  42
n=4
Quantum number are
n = 4, l = 2, m = 0
So, subshell is 4d.
Angular node = l = 2
Radial node = n – l – 1 = 4 – 2 – 1 = 1
Nuclear charge = 2e
36
5. Choose the correct option(s) from the following:
(1) Cellulose has only   D -glucose units that are joined
by glycosidic linkages
(2) Natural rubber is polyisoprene containing trans alkene
units
(3) Nylon-6 has amide linkages
(4) Teflon is prepared by heating tetrafluoroethene in
presence of a persulphate catalyst at high
Soln.: [3, 4]
(1) Cellulose has only   D  glucose units that are joined
by glycosidic linkages.
(2) Natural Rubber units which are joined by C1 – C4
glycosidic linkage is cis-polyisoprene.
(3) Nylon-6 has amide linkages
(4) Teflon is prepared by heating polytetratluro ethene in
presence of a persulphate catalyst.
6. Consider the following reactions (unbalanced)

Zn + hot conc. H SO  G  R  X
2 4
Zn + conc. NaOH  T + Q
G + H2S + NH4OH  Z (a precipitate) + X + Y
Choose the correct option(s)
(1) Bond order of Q is 1 in its ground state
(2) Z is dirty white is color
(3) R is a V-shaped molecule
(4) The oxidation state of Zn in T is +1
Soln.: [1, 2, 3]
37
SO2(R) is V-shaped
ZnS(z) is dirty white gelatinous ppt.
Bond order in H2(θ) is 1.
7. Choose the correct option(s) that give(s) an aromatic

compound as the major product:
(1) (2)
(3) (4)
Soln.: [3, 4]


EtO
 Anti aromatic
(2)
(3)
(4)
38
8. Choose the correct option(s) for the following reaction
sequence
Consider Q, R and S as major products:
(1)
(2)
(3)
(4)
Soln.: [1, 4]
39
entered as answer.
Zero Marks: 0 In all other cases.
1. The amount of water produced (in g) in the oxidation of 1
mole of rhombic sulphur by conc. HNO to a compound with
3
the highest oxidation state of sulphur is _______

(Given data: Molar mass of water = 18 g mol–1)
Soln.: [288 gm]
S8  48HNO3 
 8H 2SO4  48NO2  16H 2O
1 mol 16mol
Mole of water = 18
Amount of water produced = 16 × 18 = 288 gm
40
2. Total number of hydroxyl groups present in a molecule of
the major product P is _______
Soln.: [6]
Total 6-OH group present in a molecule of the product.
41
3. Total number of isomers, considering both structural and
stereoisomers, of cyclic ethers with the molecular formula
C H O is ______
4 8
Soln.: [10]
4. The mole fraction of urea in an aqueous urea solution

containing 900 g of water is 0.05. If the density of the
solution is 1.2 g cm , the molarity of urea solution is
3
______
(Given data: Molar masses of urea and water are 60 g mol 1
and 18 g mol , respectively) 1
Soln.: [2.98]
mole fraction urea
n urea
Xurea   0.05
n urea  n water
n urea
 0.05
900
n urea 
18
n urea
 0.05
n urea  50
n urea  0.05n urea  2.5
0.95n urea  2.5
2.5 250
n urea    2.63mol
0.95 95
Mass of urea = 2.63 × 60 (∵ molar mass of urea = 60
g/mol)
= 157.89
42
Mass of solution = 157.8 + 900 = 1057.8g
Volume of solution = 1057.8  881.5 ml
1.2
2.63
Molality of solution =  1000  2.98 M
881.5
5. The decomposition reaction 2N O (g) 2N O (g)  O (g) is

2 5

2 4 2
started in a closed cylinder under isothermal isochoric

condition at an initial pressure of 1 atm. After Y 10 s , the 3
pressure inside the cylinder is found to be 1.45 atm. If the

rate constant of the reaction is 5 10 s , assuming ideal gas
4 1
behaviour, the value of Y is ______
Soln.: [2.30]

2N2O5   2N2O4  O2 ; K  5 104 sec2
Initial pressure (in atm) 1 - -
Pressure after time t sec 1 – 2x 2x x
∴ 1 – 2x + 2x + x = 1.45 atm
∴ x = 0.45 atm
For 1st order reaction (taking into account of reaction
stoichiometry)
a0
2Kt  ln
a0  x
a0  1 and a 0  x  0.1
1 1
t 4
ln  2.3  103 sec
2  5 10 0.1
43
6. Total number of cis N–Mn–Cl bond angles (that is, Mn–N
and Mn–Cl bonds in cis positions) present in a molecule of
cis [Mn(en) Cl ] complex is ______
2 2 (en NH CH CH NH )
2 2 2 2
Soln.: [6]
[Mn(en) 2 Cl 2 ]
Number of cis (Cl – Mn - N) = 6

Questions.
 List-I has four entries (I), (II), (III) and (IV) and List-II has
Question.
44
1. Consider the Bohr's model of a one-electron atom where

the electron moves around the nucleus. In the following.
List-I contains some quantities for the nth orbit of the atom
and List-II contains options showing how they depend on n.
LIST-I LIST-II
(I) Radius of the nth orbit (P)  n 2
(II) Angular momentum of the electron in the nth (Q)  n1

orbit
(III) Kinetic energy of the electron in the nth orbit (R)  n0
(IV) Potential energy of the electron in the nth orbit (S)  n1
(T)  n2
(U)  n1/2
(1) (III), (P) (2) (III), (S)

(3) (IV), (U) (4) (IV), (Q)
45
Soln. [1]
(I) Radius of the nth orbit

n2
r  0.529
z
r  n2
IT
(II) Angular momentum of the electron in the nth orbit
= mvr =  2nh
mvr  n
II  S
(III) Kinetic energy of the electron in the nth orbit.
13.6  z 2
K.E  eV
n2
KE ∝ n-2
III → P
(IV) Potential energy of the electron in the nth orbit.
Z2
P.E  2.KE  27.2  eV
n2
 PE  n 2
 (IV)  (P)
2. Consider the Bohr's model of a one-electron atom where

the electron moves around the nucleus. In the following.
List-I contains some quantities for the nth orbit of the atom
and List-II contains options showing how they depend on n.
46
LIST-I LIST-II
(I) Radius of the nth orbit (P)  n 2
(II) Angular momentum of the electron in the nth (Q)  n1

orbit
(III) Kinetic energy of the electron in the nth orbit (R)  n0
(IV) Potential energy of the electron in the nth orbit (S)  n1
(T)  n2
(U)  n1/2
(1) (I), (P) (2) (I), (T)

(3) (II), (R) (4) (II), (Q)
Soln.: [2]
Radius r  n 2
Kinetic energy  n 2
Potential energy  n 2
 Correct match: (I), (T); (II), (S)
47
3. List-I includes starting materials and reagents of selected
chemical reactions. List-II gives structures of compounds
that may be formed as intermediate products and/or final
products from the reactions of
LIST-I LIST-II
(I) (P)
(II) (Q)
(III) (R)
(IV) (S)
(T)
(U)
48
Which of the following options has correct combination
considering List-I and List-II?
(1) (I), (Q), (T), (U) (2) (II), (P), (S), (U)
(3) (II), (P), (S), (T) (4) (I), (S), (Q), (R)
Soln.: [2]
The above reactions as follows:
49
50
4. List-I includes starting materials and reagents of selected
chemical reactions. List-II gives structures of compounds
that may be formed as intermediate products and/or final
products from the reactions of List-I.
LIST-I LIST-II
(I) (P)
(II) (Q)
(III) (R)
(IV) (S)
(T)
(U)
(1) (IV), (Q), (R) (2) (III), (S), (R)

(3) (IV), (Q), (U) (4) (III), (T), (U)
51
Soln.: [1]
The above reactions as follows:
52
(Paper & Solution)
PAPER-2
PART-I (MATHEMATICS)
 Each question has FOUR options. ONE OR MORE
THAN ONE of these four option(s) is (are) correct
Answer(s).
 For each question, choose(s) corresponding to (all) the
correct answer(s).
chosen.
Partial Marks: +3 If all the four options are correct but
ONLY three options are chosen.
options.
53
 For example, in a question, if (A), (B) and (D) are the
ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 marks;
choosing ONLY (B) will get +1 marks;
choosing ONLY (D) will get +1 marks;
choosing no option (i.e. the question is unanswered) will
get 0 marks; and choosing any other
commination of options will get –1 mark
 
 
 1  2  ...  n
3 3
  54
1. For a  R, | a | 1 , let lim
n   
7/3  1 1 1
n    ...  
 (an  1) (an  2) 2 (an  n) 2  
2

Then the possible value(s) of a is/are

(1) 8 (2) –9 (3) –6 (4) 7
Soln.: [1, 2]
  n
 3
1  2  ....  n
3 3   r1/3
lim    lim r 1
n   
7/3    
1 1 1  n
1
n 7/3  
h
n    ...  2  2 
  (an  1) 2
(an  1) 2
(an  n)   r 1 (an  r) 
 n  r 1/3 
   
n
 lim  n r 1 
n   1 
  
 r 1 (a  r / n)
2

54
1
x
1/3 3 4/3 1 3
dx x
Now, 1
0
 54  4 0
1
 54  4  54
1 1 1
 (a  x)2 dx 
ax 0 a(a  1)
0
⇒ a(a + 1) = 72 ⇒ a2 + a – 72 = 0 ⇒ a = -9, 8
sin x
2. Let f(x) = x2
,x  0
Let x 1  x 2  x 3  ...x n  .... be all the points of local maximum of f

and
be all the points of local minimum of f.
y1  y 2  y3  ...y n  ....
Then which of the following options is/are correct?

 1
(1) x n   2n,2n   for every n (2) x1  y1
 2
(3) | x  y | 1 for every n

n n (4) x n 1  x n  2 for every n
Soln.: [1, 3, 4]
sin x
f (x) 
x2
x 2 cos x  2x sin x
 f '(x) 
x4
 x 
2x cos x   tan x 
⇒ f '(x)   2 
4
x
 x 
2cos x   tan x 
 f '(x)   2 
3
x
For maxima & minima, f′ (x) = 0

⇒ cos π x = 0 or πx/2 = tan π x
⇒ x  (2n 2 1) or 2x  tan x
55
(2n  1)
x , nI
2
f ’(x)
1 0 0  1 0 0  0 1 0 0 1 0
3. Let P1  I   0 1 0  , P2   0 0 1  , P3  1 0 0 , P4   0 0 1  ,
 0 0 1  0 1 0 0 0 1  1 0 0
0 0 1 0 0 1  2 1 3
P5  1 0 0 P6   0 1 0 X   Pk 1 0 2  PkT
6
, and
k 1
0 1 0 1 0 0  3 2 1 
Where P denotes the transpose of the matrix P . Then which

T
k k
of the following options is/are correct?

(1) X is a symmetric matrix
1 1
(2) If  
X 1   1 , then   30
1 1
(3) The sum of diagonal entries of X is 18

(4) X – 30I is an invertible matrix
56
Soln.: [1, 2, 3]
We have,
1 0 0  1 0 0  0 1 0 0 1 0 0 0 1
P1  0 1 0  , P2  0 0 1  , P3  1 0 0 , P4   0 0 1  , P5  1 0 0 ,
0 0 1  0 1 0  0 0 1  1 0 0 0 1 0
0 0 1 
P6   0 1 0
1 0 0
2 1 3
X   Pk 1 0 2  PkT
 3 2 1 
2 1 3
Let A  1 0 2 
 3 2 1 
2 1 3
then A  1 0 2 
T
 3 2 1 
 A  AT
 
T
Now, XT  P1AP1T  P2AP2T  ...  P6AP6T X
So X is a symmetric matrix.
1
Let Q  1
1
XQ  P1AP1T Q  P2 AP2T Q  ....  P6 AP6T Q

 1 0 0  1 
     
 P1AQ  P2 AQ  ....  P6 AQ  P1T Q  0 1 0  1  Q 
 0 0 1  1 
 (P1  P2  ...  P6 ) AQ,
57
 2 2 2  6  30    2 1 3  1 6  
  2 2 2   3   30   30Q       
 AQ  1 0 2  1   3 
 2 2 2  6  30    3 3 1  1 6  
⇒XQ = 30Q ⇒ (X – 30I) Q = 0

So, |X – 30I| = 0 has non-trivial solution.
So |X - 30 I|is not invertible.
Where trace (Pk A PTk) = 3
⇒ Trace X = 3 × 6 = 18.
1 1 1  2 x x
4. Let x R and let P  0 2 2  , Q   0 4 0  and R  PQP1 . Then
0 0 3   x x 6 
which of the following options is/are correct?

(1) For x = 1, there exists a unit vector î  ˆj  kˆ for which a
  0
R    0 
   0 
(2) There exists a real number x such that PQ = QP

2 x x
(3) det R = det 0 4 0   8 , for all x R

 x x 5 
1  1 
(4) For x = 0, if R a   6 a  , then a + b = 5
   
 b   b 
Soln.: [1, 4]
We have, R = PQP-1
 1 
⇒det(R) = det(PQP-1) = (det P) (det Q)  
 det P 
= det Q
58
2 x x
det (Q)  0 4 0
x x 6
= 2(24) – x(0) + x(-4x)

= 48 – 4x2
⇒ det R = det Q = 48 – 4x2
(i) for x = 1, det (R) = 48 – 4x2 = 48 – 4 = 44 ≠ 0

⇒ (det R) ≠ 0
  0
 for equation R     0 
    0 
We will have trivial solution

⇒α = β = γ = 0
(2) PQ = QP
PQP-1 = Q
R=Q
No value of x.
2 x x
(3) det  0 4 0   8 = (40 – 4x2) + 8 = 48 – 4x2 = det R  x
 x x 5 
R
For x = 0
2 4 6  6 3 0 
 
PQ   0 8 12  and P  0 3 2 
1
 0 0 18  0 0 2 
59
 2 1 2 / 3
R   0 4 4 / 3
 0 0 6 
Now R  PQP 1
 2 4 6  6 3 0 
  0 8 12  0 3 2 
1
6
 0 0 18  0 0 2 
1  1 
We have,  
R  a   6  a 
 b   b 
1 
(R  6l)  a   O
 b 
2b 4b
 4a   0 and  2a  0
3 3
 a  2 and b  3
ab5
5. Let f : R  R be a function. We say that f has

PROPERTY 1 if lim f (h)  f (0) exists and is finite, and
h 0 |h|
f (h)  f (0)
PROPERTY 2 if lim
h 0 h2
exists and is finite.
(1) f (x)  x has PROPERTY 1
2/3
(2) f(x) = x|x| has PROPERTY 2

(3) f(x) = sin x has PROPERTY 2
(4) f(x) = |x| has PROPERTY 1
60
Soln.: [1, 4]
(1) We have, f (x)  x 2/3
h 2/3  0
= lim
h 0
 0 (finite)
|h|
(2) We have f(x) = x|x|

h | h | 0 |h|
lim 2
 lim
h 0 h h  0 h
|h| 
Case  I : lim 1 
h 0 h 
  limit does not exist
|h|
Case  II : lim  1 
h 0 h 
(3) We have, f(x) = sin x

sinh  0
= lim
h 0 h2
 limit does not exist
(4) We have f(x) = |x|

= lim | h | 0  0  finite
h 0 |h|
So, correct option is (1, 4)
6. Three lines
L : r  î,   R , L : r  kˆ  ˆj,   R and L : r  î  ˆj  vk,
1 2 3
ˆ v  R are given. For
which point(s) Q on L can we find a point P on L and a

2 1
point R on L so that P, Q and R are collinear?

3
1 1
(1) kˆ  ˆj (2) kˆ  ˆj
2 2
(3) k̂ (4) kˆ  ˆj
61
Soln. [1, 2]
Let P  (λ, 0, 0), Q(0, μ, 1), R(1, 1, v)
P, Q, R are collinear PQ  kPR
  0 0   0 1
 
 1 0 1 0  v
1
  and     
v
1 
 v  and  
  1
   0,   1
ˆ Q  kˆ  ˆj
 Q  k,
7. Let f :R  R be given by f(x) = (x – 1) (x – 2) (x – 5). Define

x
F(x)   f (t)dt ,x>0
0

(1) F has a local minimum at x = 1
(2) F has two local maxima and one local minimum in
(0, )
(3) F has a local maximum at x = 2

(4) F(x)  0 for all x  (0,5)
Soln.: [1, 3, 4]
We have,
f(x) = (x - 1) (x - 2) (x - 5)
x
F(x)   f (t) dt, x  0
0
F'(x)  f (x)  (x  1)(x  2)(x  5), x  0
x = 1, 5 is point of focal minima for x > 0
62
x = 2 is point of local maxima for x > 0
f(x) = x3 – 8x2 + 17x – 10

x
 F(x)   (t 3  8t 2  17t  10) dt
0
4
x 8x 3 17x 2
F(x)     10x
4 3 2
2
Also F(2)   f (t)dt  0
0
 F(x)  0  x (0, 5)
n
 k 1  k2 
 sin  n  2   sin  n  2  
8. For non-negative integers n, let f (x)  k 0
n
 k 1 
 sin
k 0
2

n2 

Assuming cos x takes values in 1

[0, ] which of the following
options is/are correct?
3
(1) f (4) 
2
(2) sin(7cos1 f (5))  0
1
(3) If   tan(cos1 f (6)) , then 2  2  1  0 (4) lim f (n) 
n  2
Soln.: [1, 2, 3]
n
  K 1  K2 
  2sin  n  2   sin  n  2   
K 0
f (x)  n
 K 1 
 2sin 2  n  2  
K 0
n
     2k  3  
  cos  n  2   cos  n  2   
⇒ f (x)  k 0

n
 2k  2  
 1  cos 
k 0

n  2  
63
 n3  n 1 
cos   .sin  
    n  2  n2
(n  1) cos  
n2      
sin   (n  2)cos  
 n2   (n  2) 
 n 1  n2
cos .sin  
(n  1)  n2
  
sin  
n2
     
(n  1)cos    cos  
n 2 n 2   
 = cos  
(n  1)  1 n2
  
Hence, f (x)  cos  
n2
    3
Now, (1) f (4)  cos    cos 
42 6 2
     
(2) sin  7 cos 1  cos    sin  7   sin   0
  7   7

2 tan
 1      8 1  2
  tan  cos  cos    tan Also tan 
(3)   8  8 4 1  tan 2  1  2
8
   2  1  0
2
  
(4) lim f (n)  lim cos   1
n  n 
 n 2

64
entered as answer.
Zero Marks: 0 In all other cases.
 n n

 k  n
Ck k 2 
1. Suppose det  n 0 , holds for some positive integer
k 0 k 0
 n n

  Ck k  n
Ck 3k 
 k 0 k 0 
n
n. Then  k C 1 equals …..
n
k
k 0
Soln.: [6.20]
n n 1
  k 2  k  k  n G c   (k  1) k . k  1
n n n
n
n c
G c2   k n 1
Ck 1
k 0 k 0 r 0 k
= n (n - 1) . 2n-2 + n 2n-1
= n . 2n-2 [(n-1)+2]
= n(n + 1) 2n-2
n
n
 k k n 1Cn 1  n2n 1
k 0
n
 3k n 1Cn 1  n C0  31 (n C1 )  (32 )n e  ....3n (n Cn )
k 0
n(n  1)
n(n  1)2n 2
Now 2 0
n2n 1 4 n
2 2n
 0 22n 1  n.22n 1
n2n 1 4n
=n=4
65
4
4
C1c 4 C0 4 C1 4C2 4 C3 4 C4
 k 1

1

2

3

4

5
k 0
 1  2  2  1  1/ 5
31

5
 6.20
2. Let a  2iˆ  ˆj  kˆ
and b  î  2ˆj  kˆ be two vectors. Consider a vector
c  a  b ,  R . If projection of c on the vector (a  b) is 3 2 ,
then the minimum value of (c  (a  b)).c equals…..

Soln.: [18]
c  (2iˆ  ˆj  k)
ˆ  (iˆ  2jˆ  k)
ˆ
c  (2  )iˆ  (  2)ˆj  (  )kˆ
c  (a  b)
Pr ojection of c on the vector (a  b) 
ab
c.(a  b)
3 2
|a b|
9(  )  18
  2
Now,  c   a  b  .c   2
 
| a |2   2 | b |2 2 a  b  a  b .c  6( 2  2  4)
Minimum value = 18
66
/ 2
3 cos 
3. The value of the integral  d equals……
( 0 cos   sin  )5
Soln.: [0.5]
 /2
3 cos  d
Let I  
 
5
0 cos   sin 

2
d
 2I  3 
 
4
0 cos   sin 
3 /2 sec 2 d

2 0 2  tan 
I
 
4
1
Let 1  tan   t  sec 2  d  dt
2 tan 
  when   0, then t  1 
3  2(t  1) 3 2 2  
I  dt   
2 1 t4 2 2t 2 3t 3 1  and   , then t   
 2 
3 2 2 1
      0.5
2 2 3 2
4. Five persons A, B, C, D and E are seated in a circular

arrangement. If each of them is given a hat of one of the
three colors red, blue and green, then the number of ways
of distributing the hats such that the persons seated in
adjacent seats get different coloured hats is .......
Soln.: [30]
67
Possibilities are
1R, 2B, 2G; 1B, 2R, 2G; or 1G, 2R, 2B
⇒ Total number of ways = 5C1 × 2 + 5C1× 2 + 5C1× 2 = 10
× 3 = 30
So total no. of ways = 3 × 10 = 30
 1 10  7  k   7  (k  1)  
5. The value of sec 1   sec    sec    in the interval
 4 k  0  12 2   12 2 
  3 
 4 , 4  equals……
 
Soln.: [0]
 1 10  7  k   7  (k  1)   
We have, sec 1   sec    sec   
 k  0  12 2   12
4 2 
 1 10  7 K    7 (k)  
 sec1   sec    sec    
 4 K 0  12 2   2 12 2 
 1 10  7  k   7  k  
 sec 1    sec    cos ec   
 4 k  0  12 2   12 2  
 
 1 10 2 
 sec1    
 4 k 0 sin  7   k  
  
 6 
 
 1 10 1 
 sec   
1


 2 k 0 (1)k 1 sin 
 6
 sec1 (1)  0
68
6. Let |X| denote the number of elements in a set X. Let S =
{1, 2, 3, 4, 5, 6} be a sample space, where each elements is
equally likely to occur. If A and B are independent events
associated with S, then the number of ordered pairs (A, B)
such that 1 | B || A | , equals ....
Soln.: [422]
A and B are independent events
P(A  B)  P(A).P(B)
| AB| | A| | B|
  .
|S| |S| |S|
 | S || A  B || A | . | B |
 6.| A  B || A | . | B | ...(i)
|| B || A |
So, possible values of |A| can be 2, 3, 4 or 6

|A| ≠ 5; because |A| = 5 cannot satisfy the equation (i)
Case I
If |A| = 2 then |B| = 1 (it is also not satisfying equation (i))
Case-2 :
If |A| = 3 then |B| = 2 and |A  B| = 1
Number of ways = 6C3. 3C1. 3C1 = 180
Case-3 :
If |A| = 4 then |B| = 3 and |A  B| = 2
Number of ways = 6C4. 4C2. 2C1 = 180
Case-4 :
If |A| = 6 then |B| may be any number between 1 to 5
Number of ways = 6C6. [ 6C1 + 6C2 + ... + 6C5 ] = 62
Total number of ordered pairs (A, B) = 180 + 180 + 62
= 422
69
Questions.
 List-I has Four entries (I), (II), (III) and (IV) and List-II has
Question.
1. Let f (x)  sin( cos x) and g(x)  cos(2sin x) be two functions defined
for x > 0. Define the following sets whose elements are
written in the increasing order:
X  {x : f (x)  0}, Y  {x : f '(x)  0}
Z  {x : g(x)  0}, W  {x : g'(x)  0}
70
List-I contains the sets X, Y, Z and W. List-II contains
some information regarding these sets.
List-I List-II
(I) X (P)    , 3 ,4,7
2 2 
(II) Y (Q) an arithmetic

progression
(III) Z (R) NOT an arithmetic
progression
(IV) W (S)    , 7 , 13 
6 6 6 
(T)   2 
  , , 
3 3 
(U)   3 
 , 
6 4 
Which of the following is the only CORRECT

combination?
(1) (II), (Q), (T) (2) (I), (P), (R)
(3) (II), (R), (S) (4) (I), (Q), (U)
Soln.: [1]
X  {x : f (x)  0}
f (x)  0  sin(  cos x)  0
  cos x  n, n  I
 cos x  n
So cos x = – 1, 0, 1
 3    
x   , , , 2, .... X  n. ,n  I 
 2 2   2 
Also, Y  {xf '(x)  0}
Now, f '(x)  0
71
 f '(x)   cos( cos x) sin x  0
 cos( cos x)( sin x)  0
 cos( cos x)  0 or ( sin x)  0


  cos x  (2n  1) or x  n
2
1
 cos x  (2n  1) or x  n
2

 x  n  or x  n
3
  2 3 4 5 6  
Y , , , , , , ,...
3 3 3 3 3 3 3 
Z  {x : g(x)  0}
g(x)  0  cos(2 sin x)  0


 2 sin x  (2n  1) , n  I
2
2n  1
 sin x 
4
1 3
 sin x   , 
4 4
 1 3 
 Z  n  sin 1 ,n  sin 1 ,n  I 
 4 4 
W  {x : g '(x)  0}
g '(x)  0   sin(2 sin x)(2 cos x)  0
 sin(2 sin x)  0 or 2 cos x  0


 2 sin x  n or x  (2n  1)
2
n n
 sin x  or x  (2n  1) , n  I
2 2
1 
 sin x  0,  ,  1 or x  (2n  1)
2 2
   
W  n, (2n  1) , n  ,n  I 
 2 6 
Option (1) is correct.
72
2. Let f (x)  sin( cos x) and g(x)  cos(2sin x) be two functions defined
for x > 0. Define the following sets whose elements are
written in the increasing order:
X  {x : f (x)  0}, Y  {x : f '(x)  0}
Z  {x : g(x)  0}, W  {x : g'(x)  0}
List-I contains the sets X, Y, Z and W. List-II contains

some information regarding these sets.
List-I List-II
(I) X (P)    , 3 ,4,7
2 2 
(II) Y (Q) an arithmetic

progression
(III) Z (R) NOT an arithmetic
progression
(IV) W (S)    , 7 , 13 
6 6 6 
(T)   2 
  , , 
3 3 
(U)   3 
 , 
6 4 

combination?
(1) (III), (P), (Q), (U) (2) (IV), (P), (R), (S)
(3) (III), (R), (U) (4) (IV), (Q), (T)
Soln.: [2]
f(x) = 0 ⇒ sin(π cosx) = 0
⇒ π cosx = n π ⇒ cosx = n
⇒ cos x = -1, 0, 1 ⇒ x = (nπ, (2n + 1)π/2)
73
= (n π/2, n)
f’(x) = 0 ⇒ cos (π cos x) (-π sin x) = 0
⇒ π cos x = (2n + 1) π/2 or x = nπ
   
 cos x  1, 0, 1  x  (n(2n  1) )   n , n 
2  2 
f '(x)  0  cos( cos x)(  sin x)  0
1
 cos x  n  or x n
2
1
 cos x   of x  n
2
  2 
 y  an  2r  , nn 
 3 3 

g(x)  0  cos(2x sin x)  0  2  sin x  (2n  1)
2
2n  1 1 3
 sin x   
2 2 2
1 1
 cos x  n  or xn  cos x   or x  n
2 2
  2 
 y  2n  , 2n  , n, n 1
 3 3 
g(x)  0  cos(2 sin x)  0
 2n  1 1 3
 2 sin x  (2n  1)  sin x   
2 4 4 4
 1 3 
 Z  n  sin1 , n  sin1 , n 1
 4 4 
g '(x)  0   sin(2 sin x) (2 cos x)  0
 n 1 
 2 sin x  n or x  (2n  1)
 sin x   0,  , 1 or x  (2n  1)
2 2 2 2
   
 W  n,(2n  1) , np , n 1
 2 6 
74
3. Let the circles C : x  y  9 and C : (x  3)  (y  4)  16 , intersect at
1
2 2
2
2 2
the points X and Y. Suppose that another circle

C : (x  h)  (y  k)  r satisfies the following conditions.
3
2 2 2
(i) center of C is collinear with the centers of C and C ,

3 1 2
(ii) C and C both lie inside C , and

1 2 3
(iii) C touches C at M and C at N.

3 1 2
Let the line through X and Y intersect C at Z and W, and let 3
a common tangent of C and C be a tangent to the parabola

1 3
x  8y .
2
There are some expressions given in the List-I whose

values are given in List-II below:
List-I List-II
(I) 2h + k (P) 6
(II) Length of ZW (Q) 6
Length of XY
Area of triangle MZN 5
(III) (R)
Area of triangle ZMW 4
21
(IV)  (S)
5
(T) 2 6
10
(U)
3
Which of the following is the only INCORRECT

combination?
(1) (IV), (U) (2) (I), (P)
(3) (IV), (S) (4) (III), (R)
75
Soln.: [3]
(I) Diameter of circle C3will lie on line MN  2r  MN

= MO + OQ + QN
2r  3  3  4  4 = 3 + 5 + 4 = 12
2 2
 r6
Centre C of circle C3 lies on line y  43 x

4h
Let co-ordinates of C(h, k) where K
3
OC = MC – OM
OC = 6 – 3 = 3
16 2 25h 2 5h
 h2  h 3 3 3
9 9 3
9
 h
5
4 4 9 12
 k'  h  
3 3 5 5
18 12
 2h  k   6
5 5
(II) Equation of line ZW

C1  C2  0
76
⇒ 6x + 8y – 19 = 0
 3x  4y  9
Perpendicular distance of ZW from (0, 0) is

9 9
 
9  16 5
2
9 24
Length of XY 2 9  
5 5
 9 12 
Perpendicular distance of ZW from C3  ,  is
5 5 
9  12 
3   4    9
5  5 
6
9  16 5
2
6 36  1  24 6
Length of ZW = 2 36     2 36   2 36 1   
5 25  25  5
 9 12 
length of ZW from  , 
 5 5   6
length of XY, from (0, 0)
1 1 1 
(III) Area of MZN  ZP  MN  NM  ZW 
2 2 2 
1 1 1 
Area of ZMW  ZW  MP  NM  ZW 
2 2 2 
Area of MZN 5
 
Area of ZMW 4
3
(IV) Slope of tangent to C1 at M
4
 Equation of tangent y  mx  3 1  m2
3 9
y   x  3 1
4 16
 y
3x 15
4

4
…… (i)
Tangent to parabola is
x 2  8y
 y  mx  2m2 ……(ii)
77
Compare (i) & (ii)
3 15
m   and 2m   2
4 4
 9  15
 2   
 16  4
10
 
3
So, correct option (3) (IV) - (S)
4. Let the circles C : x  y  9 and C : (x  3)  (y  4)  16 , intersect at

1
2 2
2
2 2
the points X and Y. Suppose that another circle

C : (x  h)  (y  k)  r satisfies the following conditions.
3
2 2 2
(i) center of C is collinear with the centers of C and C ,

3 1 2
(ii) C and C both lie inside C , and

1 2 3
(iii) C touches C at M and C at N.

3 1 2
Let the line through X and Y intersect C at Z and W, and let 3
a common tangent of C and C be a tangent to the parabola

1 3
x  8y .
2
There are some expressions given in the List-I whose

values are given in List-II below:
List-I List-II
(I) 2h + k (P) 6
(II) Length of ZW (Q) 6
Length of XY
Area of triangle MZN 5
(III) (R)
Area of triangle ZMW 4
21
(IV)  (S)
5
78
(T) 2 6
10
(U)
3

combination?
(1) (II), (Q) (2) (II), (T)
(3) (I), (S) (4) (I), (U)
Soln.: [1]
Refer solution of above Question
The correct Option (1) length of zw
length of xy
 6
So, II → Q
79
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bottom of the three cylinders, respectively, the correct

(1)0.8 cm < (H2 – H1) < 0.9 cm (2) H3> H1

1 1.5 1 1.5 0.5 1

Now from above, we get, H1 = 20 cm, H2 = 20.6 cm, H3 =

(1) Total electric field at point B is EB 0

(2) Total electric field at point A is EA 2E 0 (iˆ ˆj)

(4) The magnitude of total electric field on any two points

So, option (3) is correct.

Because E0 is uniform & due to dipole Electric field is

3. A thin and uniform rod of mass M and length L is held

By applying conservation of energy, we get

5. A mixture of ideal gas containing 5 moles of monatomic

6. A small particle of mass m moving inside a heavy,

infinitesimal displacement of the piston. Which of the

(3) The rate at which the particle strikes the piston= 2L

On decreasing length to half K.E. becomes ¼

8. A free hydrogen atom after absorbing a photon of

option (s) is/are correct ? [Use hc = 1242 eVnm; 1nm  109 m , h

The energy level diagram is shown in the figure

Given: B = 1T, l= 10 cm, v = 1 cm/s

Since velocity of PQ is constant. So emf developed across

energy of the emitted  photon is ………….. keV. [Given:

Mass defect m = (226.005) – [222.000 + 4.000]

Since momentum is conserved, kinetic energy is in inverse

Energy of  particle = E  KE 0   KE Rn = 4.65 – [4.44 + 0.08]

Total internal reflection at the coated prism surface

From equation (i), we get

For the given lens, u = –30 cm and v = 60 cm

By using lens formula, we get

Putting values in above equation, we get

The percentage error in the measurement of the focal length of

5. A ball is thrown from ground at an angle  with horizontal

constant. N photons of wavelength   8106 m strike the

If v is speed of mirror just after absorption of photons

(II) String – 2 (Q) 1/2

(III) String – 3 (R) 1/ 2

(IV) String – 4 (S) 1/ 3

I  P, II  R, III  S, IV  Q Option (2)

2. Answer the following by appropriately matching the

(IV) String – 4 (4) (S) 1/ 3

For string (1)