yC3H8= 1

Asumsi produk dalam kesetimbangan termal dengan temperatur reaktor=200degC

Excess udara mencapai 60%
atmospheric pressure Udara:
R= 8,314 J/mol K
Sistem steady state terbuka: ΔH=Q
Basis: 1 mol C3H8

Perhitungan Panas Dari pelepas Panas

Reaksi:
Reaksi 1 C3H8 + 5 O2
m: 1 7.2
rx: 0.9 4.5
s: 0.1 2.7

Reaksi 2 C2H6 + 3.5 O2

m: 0 0
rx: 0 0
s: 0 0

NERACA MASSA
Input Output
KOMPONEN BM
mol massa, gr mol massa,gr
C3H8 44.097 1 44.097 0.1 4.4097
C2H6 0 0 0 0 0
O2 31.999 7.2 230.3928 2.7 86.3973
CO2 44.01 0 0 2.7 118.827
H2O 18.015 0 0 3.6 64.854
N2 28.014 27.0857142857143 758.7792 27.085714285714 758.7792
1033.3 1033.3

ΔH֯ 298 = 25degC

reaksi 1: C3H8 + 5 O2
ΔH֯r = ΔHproduk -
ΔH֯r = 3*(ΔH֯ 298CO2) + 4*(ΔH֯ 298H2O) -
ΔH֯r = -1180527 + -967272 -
ΔH֯r = -2147799 -

ΔH֯ 298rx1 = -2043119 J

reaksi 2: C2H6 + 3.5 O2

ΔH֯ 298rx2 = ΔHproduk -
ΔH֯ 298rx2 = 2*(ΔH֯ 298CO2) + 3*(ΔH֯ 298H2O) -
ΔH֯ 298rx2 = -787018 + -725454 -
ΔH֯ 298rx2 = -1512472 -
ΔH֯ 298rx2 = -1428652 J

ΔH֯ 298 = 0,75* (ΔH֯ 298rx1) + 0,25*( ΔH֯ 298rx2)

ΔH֯ 298 = -1838807.1 + 0
ΔH֯ 298 = -1838807.1 J/mol

ΔHR propane
komp mol A B C
C3H8 1 1.213 0.028785 -8.824E-06
mol*variabel 1.213 0.028785 -8.824E-06
Total 1.213 0.028785 -8.824E-06
T0= 301.15
T= 298.15 R= 8.314 J/mol K
T/T0= τ= 0.990038186950025

(∆ 〖 <𝐶𝑝> 〗 _𝐻)/ 1.213 + 8.62542525 +

𝑅=
ΔHR=R [(∆ 〖 <𝐶𝑝> 〗 _𝐻)/𝑅](𝑇−𝑇_0 )

ΔHR= -225.628090362219 J/mol

ΔHP
komp mol A B C
O2 2.7 3.639 0.000506 0
CO2 2.7 5.457 0.001045 0
H2O 3.6 3.47 0.00145 0
N2 27.0857142857143 3.28 0.000593 0
C3H8 0.1 1.213 0.028785 -8.824E-06
9.8253 0.0013662 0
14.7339 0.0028215 0
mol*variabel 12.492 0.00522 0
88.84114 0.0160618285714 0
0.1213 0.0028785 -8.824E-07
Total 126.0136 0.0283480285714 -8.824E-07
T0= 298.15 K
T= 473.15 R= 8.314
T/T0= τ= 1.58695287606909

(∆(∆〖〖<𝐶𝑝>
<𝐶𝑝>〗〗_𝐻)/
_𝐻)/
𝑅=𝑅=
 (∆(∆〖〖<𝐶𝑝>
<𝐶𝑝>〗〗_𝐻)/
_𝐻)/ 126.013642857143 + 10.932417218572 +
𝑅=𝑅=
ΔHP=R [(∆ 〖 <𝐶𝑝> 〗 _𝐻)/𝑅](𝑇−𝑇_0 )

ΔHP= 196768.109683972 J/mol

Q = ΔH֯ 298 +
Q = -2043119 +
Q = -1922126.27369 J/mol
Qlepas = -1922.12627369 KJ/mol

Perhitungan Panas Dari Penerima Panas (air pendingin)

Q = mol air *
30

Qterima = mol air * 80.092830175 kj/mol

Penyelesaian anggap sistem adiabatik

Qterima = Qlepas
mol air * 80.09283 = 1922.12627369
mol air = 23.99873084132

BM air = 18.016

massa air = 432.3611348373

= 0.432361134837

43.23611348373
21% O2 = 7.2 mol
79% N2 = 27.08571 mol

= 3 CO2 + 4 H2O
0 0
2.7 3.6
2.7 3.6

= 2 CO2 + 3 H2O
0 0
0 0
0 0
O2
N2
Tu1

C3H8
Tp1

= 3 CO2 + 4 H2O
ΔHreaktan
(ΔH֯ 298C3H8) + 5*(ΔH֯ 298O2)
-104680 + 0
-104680

= 2 CO2 + 3 H2O
ΔHreaktan
(ΔH֯ 298C2H6) + 3,5*(ΔH֯ 298O2)
-83820 + 0
-83820
 ΔHR udara
D komp mol
0 O2 7.2
0 N2 27.08571
0
mol*variabel

Total
T0= 373.15
T= 298.15
T/T0= τ= 0.799008

-0.79231465894 + 0
(∆ 〖 <𝐶
𝑝> 〗 _𝐻 115.0419
)/𝑅=
ΔHR=R [(∆ 〖 <𝐶𝑝> 〗 _𝐻)/𝑅]
(𝑇−𝑇_0 )
ΔHR= -75549.76
D
-22700 Total ΔHR= -75775.38 J/mol
-115700
12100
4000
0
-61290
-312390
43560
108342.8571429
0
-221777.1428571

J/mol K
-0.133487712347 + -1.572110709034

ΔHR + ΔHP
-75775.38337369 + 196768.109684

120,2

mol/s

gram/mol

gram/s
kg/s (per satu mol C3H8)
 N2 = 27.08571 mol
Tidak Bereaksi tetapi ada di dalam reaksi

air pendingin
Ta2 = 393.35 K saturated 2 bar
= 120.2 C
= 7.2 mol
= 27.08571 mol C3H8 = 0.1
= 373.15 K O2 = 2.7
= 100 C CO2 = 2.7
H2O = 3.6
Reaktor
N2 = 27.08571

T2 = 473.15
= 1 mol = 200
= 301.15 K air pendingin
= 28 C Ta1 = 303.15 K
= 30 C
na = ?

Q T = 473,15

T = 301,15 T = 373,15

ΔHR ΔHP

T = 298,15 K T = 298,15 K
ΔH298֯
 A B C D
3.639 0.000506 0 -22700
3.28 0.000593 0 4000
26.2008 0.003643 0 -163440
88.84114 0.016062 0 108342.85714
115.0419 0.019705 0 -55097.14286

R= 8.314 J/mol K

+ 6.613993 + 0 + -0.495234

∆ 〖 <𝐶𝑝> 〗 _𝐻)/𝑅]

J/mol
saturated 2 bar

mol
mol
mol
mol
mol

K
C