Total Pages -5 UDHB(Sem-IV)-Ch(CC-9)

2021mst iioi
Full Marks:700iioix t
2178)2 fA)
Time: 3 hours

Answer from al the Groups as directed

33121}
The figures in the right-hand margin indicate marks

Candidates are required, to give their answers in their

own words as far as practicable

GROUP-A
(Compulsory )
02 (6
1.. Draw the structure of :
HOH(2x 10

(a) Picric acid

(6) TNT
(c)Ethylmethylamine sioitnislgE
(d) Benzenediazonium bromide

(e) Sym-tribromobenzene

49 Vurn Over)
 2 )
(3)
) Calcium formate
Convert benzenediazonium chloride into
(g) Trichloroacetic acid
) Pheiol
(h) Tartaric acid
(6) Benzoic acid.
) Acetic anhydride
() Succinic acid. 5. Explain different typesoffundamental vibrations.

GROUP-B 6. Write down action of héat on (only chemical

reactions):
Answer any four questions 5x4
a) Oxalic acid
2. Write down the reactions of acetic acid with (b) Malonic acidi
(a) Na
t
(c) Succinic acid
(6) SOCL (d) Glutaric acid
(c)CHOH (e). Adipic acid
() LiAIH, 7. Explain, howhydrogen bonding affects vibrational
(e) NH frequencies with example.

3. Explain which is more basic and why? 8. Explain Kolb's reaction by giving example.
NH,
9 Which is more acidic and why ?
and CH, NH,
a )
CI CHCOOH and F Cu, COOH.

UDHB (Sem-IV)-Ch(CC-9) (Continued) UDHB (Sem-IV)-Ch(CC-9) (Turn Over)

 (5)

GROUP-C (b) Nitrobenzene is metadirecting. Explain.

Answer any fwo questions l5 x 2
13-() State and explain Bear-Lambert's law. 10
10. (a) Prepare acetic acid by using (i) aldehyde
(i) Grignard reagent. (6) Explain the types of electronic transitions
10
that occurs in UV and visible region in brief. 5
(b) Formic acid is stronger than acetic acid.
Explain. 5

H. (a) Write down any two methods for the prepa-

ration of acid chloride. bion aiad 10
(6) Write down the reaction of CH,COCI with
0 CHOH
(ii) Benzene
(i)HLO
(iv) NH
(v) CHMgX. stis titier t19151752 5

12. (a) Complete thereaction with mechanism 10

HNO,/H,SO
60C
UDHB (Sem-IV)-Ch(CC-9) GK-800
(Continued) UDHB (Sem-IV)-Ch(CC-9)