Total Pages-7 UDHB(Sem-IV)-Ch (CC-8)

EE oisis, 2021 o vii196i (

8A2
Full Marks :70olgiot
Time:3 hours
Answer from allthe Groups as directed
Thefigures in the right-hand margin indicate marks
Candidates are required to give their answers in their
own words as far as practicable

GROUP-A
(Compulsory)
1. Answerthe following:
o 2x10
( Which of the following is not a correct
statement ?
(a) Cu2* ion behaves as aharder acid than
Mn2t
to) Cs* ion is harder acid.than Li" ion

NH, is harderthan CHNH,

)(CH)NH is a soft base

( Turn Over)
 (2
3)

(ii) Identify the wrong statement among the (6) Nat

following cases of application of HSAB
principle.
(BF
(4) CO,
a stable compounds
4a Agl, exists as
whereas AgF, does not. (v)Which ofthe following is an aprotic solvent?
(b) [CoF 1 is more stable the [Col ()HO
C). [SCN ] co-ordinates through N-atom (6) HF
toform [Co(NCS),1 (e) CHOH
(a) [SCN co-ordinates through S atom to
form [Pd(SCN),1
(vi) Which one of the following is solvolysis
(iii) The correct order of strength of halogen acid reaction ?
is
(a) Cuso,+5H,0->Cuso,5HLO
(a) HI<HBr< HCI< HF CN +H,O>HCN+OH
b)
HF< HCI <HBr<HI (c) CaCl+4CHOH CaCl4CH,OH
(c) HI<HBr<HF <HCI
(d) HCI < HF <HBr< HI
(d)BF,+NH,>BF,NH

(iv) Which of the following is not a Lewis acid? (vii) Which of the following has greatest value
of dielectric constant ?
ka) NH
UDHB(Sem-IV)-Ch (CC-8) 2-3 (Turn Over)
UDHB(Sem-IV)-Ch (CC-8) (Continued)
 (4) 5)

(6)-0-6A
(6)NH -1-2A
(c)HCN (d)-0-44g
d)So
GROUP-B
(vii) EDTA is a_ -ligand.
Answer any four questions: 5x4
(a) Monodentate
(6) Bidentate 2. Discuss the solvent system ofacid base concept.
() Pentadentate 3. AllArrhenius acids are also Bronsted acid, but
d Hexadentate all Bronsted bases are not Arrhenius bases.
Discuss.
(ix) Co-ordination number of Co* in the
complex [Co(en),]Cl, is What is symbiosis ?
2
(a) 5. Explain crystal field splitting in tetrahedral field
5) 3 with suitable example.
)6
(d)1 6. CHF and CHF, reacts to form CH, and CF,
Explain it.
)The CFSE of [Cr{H,0)J" is
7. What do you mean by inner orbital (lowspin) and
(a) -0-8A outer orbital (high spin) complexes ? Give
example of each.
UDHB(Sem-IV)-Ch (CC-8)
(Continued) (Turn Over
UDHB(Sem-IV)-Ch (CC-8)
 (7)
6)
energy.
12. Discuss the crystal field stabilization
in liq.NH, is What are the factors affecting the crystal
field
8 Explain the solution of Na metal
conductor 5+ 10
blue and good electric splitting energy.
Justifythe hardness
9Using HSAB principle predict bind. 13. Explain how electronegativity
related to
forward or backward 15
way of the reaction will go, and softness of compounds.
Cul,+2CuF >2Cul+CuF,
GROUP-C
the following:
Answer any two questions of
15x 2
10. Discuss the effect of solvent and substituents
and base. 15
on relative strength of acid
1
and diadvantages of
11. Discuss the advantage reaction in.
liq.NH, as solventand following
LiR 3 x 5
liq.NH
(a) Acid-Base reaction Hb
(6) Ammonolysis
(c) Formation of ammoniates
(a) Redox reaction 13ti0 o nW
GK-800

(Continued) UDHB(Scm-IV)-Ch (CC-8)

UDHB(Sem-IV)-Ch (CC-8)