FIITJEE Review Test -7 (JEE Advanced)

ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. A, B, C A, B, C, D A, D

2. A, B B, C, D B, C

3. A, B A, B, C, D A, D
REVIEW TEST -7

4. A, B, C, D B, C A, B, C

5. B, D A, C, D A, C

6. A, C A, D A, B, C

7. A, B, C A, B, D A, B

8. A, B, C A, B, C A, B

9. B, D A, D A, C, D

10. C, D B A, B, C, D

1. 4 7 2

2. 3 3 1

3. 2 8 8

4. 8 3 1

5. 5 5 4

6. 2 2 4

7. 4 8 6

8. 4 6 1

9. 3 4 7

10. 2 5 6

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 2 Review Test-7-Sol(Advanced)

Physics PART – I

SECTION – A

1. For massless pulley, F = 200N

2T = 200
 T = 100 N
For 4 kg block, T
a1
T  4g 60 2 T T
a1    15 m/s (upward) a2
4 4 T
For 8 kg block,
4g
T  8g 20 2
a2    2.5 m/s (upward)
8 8 8g

2. 2v0 = 5V  8 (conservation of momentum) v0

2 kg 5 kg
v + 4 = v0 (for elastic collision)
16
 v m/s and v 0 = (28/3) m/s
3 4 m/s 2 kg 5 kg v
Total momentum = 2v0 = (56/3) kg-m/s
Momentum of 5 kg block = 5v = (26/67) kg-m/s
1
Kcm =  7  v 2cm
2
2
1  2v 
  7   0   24.88 J
2  7 
1 1
Ktotal =  5  v 2   2  42  87.11J
2 2

3 In an adiabatic expansion, internal energy decreases and hence temperature decreases.

 from equation of state of ideal gas
PV = nRT, the product of P and V decreases
3kT
(b) vrms 
m
(c) The temperature in kelvin scale is not double

5 Charge stored on capacitor 3F = 36 C

Charge stored on capacitor 6F = 72 C
After connecting the plates
36  Q 72  Q

6 6
48  36
V3f   4V
3

6. An infinite wire can be taken as half of closed loop.


   0i
Hence  B  d  2


7 t = 2s, magnetic field is constant

 emf = 0
Around 2s, magnetic field increases and then decreases
 direction of emf will change
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Review Test-7-Sol(Advanced) 3

1 1 1
8.    v = 12 cm
v f u
v 12
m   2
u 6
 h2 = mh2 = –2  4.5 = - 9 cm
(v 1, h2) = (12cm, – 9cm)
The distance between the object and image is  6  122   4.5  9 2

T
9. Velocity of the pulse is given by v  . As the pulse move downward tension in the string
u
decreases and therefore velocity of the pulse decreases.
At the distance x from the ceiling.
m
T  L  x g
L
at the end B, T = mg
T T
v0  and v  
 
v T 1 x
 
v0 T L
1 x
v  v 0 .
L

10. In equilibrium Kx = (m1 + m2)g – m3g

Kx

m 4g T
When thread connecting m 4 is cut then
T=0
Kx

m4g
kx  m 4 g
 a
m4

SECTION – C

2 (  e)
1. vT  gR
9 
VT  R2
v  4R 2
 2
v R
 v = 4v
x=4

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 4 Review Test-7-Sol(Advanced)

1 1 v
2. m(8g)  mg2  mv 2
2 2
 v 2  4g

mv 2
 T  mg  3mg

k=3

(8g)

q1 q2
3.  , q1 +q2 = 2Q0
C1 C2
0 A  A
C 1 ; C 2 0
d0  vt d0  vt
q1 d0  vt

q2 d0  vt
2Q0
 q2  (d0  vt)
2d0
dq2 Q0 v
I  = 2 amp
dt d0

2
4. V  I R2   XL  XC 

10  I 32  (15  11)2
I = 2A
 The PD difference
VL  VC = I(XL  XC)
= 2(15  11) = 8V

1 2
5. e (0.71) =
2
m n  105 
 0.71  1.76  1011  2 = (n  105)2
n=5

6. An infinite wire can be taken as half of closed loop.


  0i
Hence  B  d 
2


7. Before connecting B with D and C with E, a balanced. Wheatstone bridge is formed between B
and E.
so RBE = R
and RAF  3R  3  2   6
 R = 10 – 6 = 4 
the new resistance decreases by 4.

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Review Test-7-Sol(Advanced) 5

2IA
8. Force 
C
1 
Fx   kx 2   3
 2 
 2IA  3
  x  kx 2
 C  2
4 IA
 x .
3 KC

9. For K.E. to be maximum

F=0
2
or 1 – x = 0
x=1
W = K
t
 F dx  K  K
0
f i

1
or  1  x  dx  K
2
f 0
0
2
 Kf 
3
2 2
Given 
3 n

 1  1 
10. Shift = d  1    7  1  
   1.4 
Shift = 2 cm (downwards)

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 6 Review Test-7-Sol(Advanced)

Chemistry PART – II

SECTION – A

1. (A) KI  aq.  NH4 2 S  no reaction


H2 O
(B) Bi3   aq   dil. HCl  BiCl3   3
 Bi  3Cl


Bi3   aq   NaOH  excess   Bi  OH 3 

 White
3 dil. H2 SO 4 2
(C) Bi aq  Zn  Bi   Zn
Black 
;

(D) Cd2   aq.  NaOH  Cd  OH 2 

 White 

2. From B & C, CO2 releases. While from D SO3 gas releases, which actually dissolve in water.

3. (A)
OH OH OH
Cl
Fe 2 /H2 O2 Cl2 / AlCl3

  

Cl
NaOH /  NaOH / 

OH OH
OH

OH
CAS / CAN MeCN / H2 O 
O O
O

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Review Test-7-Sol(Advanced) 7

(D) CH3 CH3

HO CH3

4 OH2
Ce
   

 Ce3 
Ce 4 
O O HO CH3
CH3
CAN/MeCN

 H2 O
 Ce3 
 repeated
CH3
O

4. In Gossage process Ca(OH)2 is used with Na2CO3.

K2CO3 can not be prepared by Solvay-Ammonia process as KHCO3 formed in the process can
not be isolated in solid state from which K2CO3 would be recovered by heating.

5. Process Major Product

(A) OH
OH

(B)
OH

(C)

(D) OH

8. For D; pOH  pK b  log

Salt    Acid
Base    Acid
Hence on addition of acid (HCl)
pOH increases, hence pH decreases.

9. (C) there is deviation from Raoults’s law. If ideal : Ptotal would be 275
(D) KI  Hg22   Hg  HgI2 

10. (A) in presence of basic electrolyte, rate of corrosion decreases

(C) specific conductance decreases while equivalent conductance increases on dilution.
(D) In molten NaCl, electricity conduction occurs due to presence of free Na+ and Cl– ions.

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 8 Review Test-7-Sol(Advanced)

SECTION – C

1. Except 1, 2, 3
Cinnabar is an ore of Hg. It is HgS.
Due to roasting of CuFeS2 decompose into Cu2S and FeS.
White vitriol is ZnSO4.

O
||
2. Products are CH3 C  OCMe3 1 eq. and CH3COOH(1 eq.)

3. X = B2H6;

4. W  ngRT    3   2  500  3 K.cal

K 2K 33
5. By the given data Keq for the considered equilibrium process is by putting the valency K1, K2
K1
& K3 we get Keq = 5.

6.  is not negligible with respect to 1.

i.e.  = 0.095
[H+] = C = 0.0095
pH = 2.02

W it
8. n  ; n = n-factor
m 96500
= oxidation state of metal at ‘M’ reduces to Mo.
n=6

9. Number of stereogenic site = 2

And the molecule is asymmetric also.

10. NH2 NMe2 NMe

Me Me
NH3
, , , ,
N

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Review Test-7-Sol(Advanced) 9

Mathematics PART – III

SECTION – A

1. Since 1900 < f(1990) < 2000

1900 f 1990  2000
Therefore  
90 90 90
 1900   f  1990   2000 

 
90    90    90 
     
 f 1990    21.11  21 
 21     22  
 90   22.22  22
 f 1990  
Case-I: Suppose    21 then substituting x = 1990 in equation (1)
 90 
1990   f 1990  
1990  f 1990   19    90  
 19   90 
 f(1990) = 1904
 f 1990  
Case-II: Suppose    22 then substituting x = 1990 in equation (1)
 90 
f(1990) = 1994

2. f(x) is a downward parabola intersecting x-axis at 1 (for x  2) and another downward parabola
intersecting x-axis at 2.5 (for x > 2). Tangents at (1, 0) and (2.5, 0) will have the lowest and
highest y intercepts respectively, which are –4 and 20. Also, these tangents intersect at (2, 4)

3. For such skew symmetric determinants, roots of 2 = 0 lie between the roots of 3 = 0 and, in
general, roots of n = 0 lie between roots of n + 1 = 0

4. If r consecutive powers of x are missing from a polynomial, then (1) it has atleast r imaginary
roots if r is even and (2) either (r + 1) or (r – 1) imaginary roots if r is odd depending on the sign of
coefficients just next to the gap.
De Gua’s Rule

9
C1 tan   9 C3 tan3   9C5 tan5   9 C7 tan7   9C9 tan9 
5. tan  9   9
0
C2 tan2   9C4 tan4   9 C6 tan6   9 C8 tan8 
tan    9 C1  9C3 tan2   9C5 tan4   9C7 tan6   9 C9 tan8    0
 k 
So, roots of tan    0 can be taken as k = –4, –3, –2, –1, 0, 1, 2, 3, 4
 9 
 k 
tan  = 0 corresponds to k = 0 and tan2   where k = 1, 2, 3, 4 are roots of the equation
 9
9 9 9 2 9 3 9 4
C1  C3   C5   C7   C9   0
9
C7
Sum of roots = 9
 36
C9
9
C1
Product of roots = 9
9
C9

6. Just adjust the domain to make the function one-one onto

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 10 Review Test-7-Sol(Advanced)

7. Equation of tangent (Y – y) = m(X – x)

Put X = 0, Y = y – mx
Now, (OT)2 = PT2
 (y – mx)2 = x2 + m2x2
 y2 + m2x2 – 2mxy = x2 + m2x2
dy y 2  x 2

dx 2xy
On solving y2 + x2 = cx
If it passes through (2, 2)  c = 4
(x – 2)2 + y2 = 4
Its director circle will be (x – 2)2 + y2 = 8
Put x = 0, y2 = 4  y = 2, –2
Intercept on y-axis is 4

 0 2
8. (A) skew-symmetric matrices of even order can be invertible e.g.  
 2 0 
(B) if AB = 0 one of the matrices is zero
n  n  1
(C) minimum number of ciphers in upper triangular matrix of order ‘n’ is  5050
2
 n = 101
(D) we have |10AB| = 103|A||B| = (103)(5)(2) = 104

9. (A) f(x) f(c)  x  (c – h, c + h) where h  0– is equivalent to lim f  x  f  c  which equals f(c)2

x 0
 f(x) is continuous
 f(x) f(c) > 0  x  (c – h, c + h) where h  0–
1  1  2  n 
(B) we have I  lim ln  1    1   .....  1   
n n n n n 
   
1 n  k 1 n  k x 2
= lim ln   1   = lim  ln  1     ln xdx = x ln x  x x 1 = –1 + 2 ln 2
n  n k 1  n  n  n
k 1  n
b
(C) given f(x)  0   f  x  dx  0
a
b
but given  f  x  dx  0 so this can be true only when f(x) = 0
a
b
(D)  f  x  dx  0  y = f(x) cuts x-axis atleast once
a

10. (A) May be false since if 0 < f(x) < 1

b b
2 2
f (x) < f(x) and  f  x  dx   f  x  dx
a a
(B) May be false since if f(x) < 0
d 2 2
f  x   2f  x  f '  x   0 when f(x) > 0 and so f (x) is decreasing while f(x) is increasing
dx
(C) May be false since a function can be negative and increasing
(D) May be false since a function may not be differentiable at x = c for which it attains minimum

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Review Test-7-Sol(Advanced) 11

SECTION – C
2 2
1. f() = sin  + 3 sin  cos  + 5 cos 
3
= 1  4 cos2   sin2
2
3
= 3  2cos 2  sin 2
2
 
Minimum of f() and f     will be same because of type of function a sin  + b cos  and is =
2 
5 1
3 =
2 2
1
g  
2
1
 2
g 

2. p   x, q   xy, r  xyz
p2 – 2q = 45
pq – r = –18
p3 – 3pq = –67
Solve the cubic in p to get the rational root p = –1 for equation
p3 – 135p – 134 = 0
|p| = 1

3. x  z  y x  y z  y x  y z 
 x z  y x  y z 1 
 x z x 
z 1
Now, apply AM–GM
48/3 xz  1

4. If x  [3, ), then y = x(x – 3) is increasing function

 x  [3, ), then f(x) = x(x – 3) is also an increasing function
y=x x(x – 3)
 one-one function y=
Equation f(x) = f–1(x) has the same solution as f(x) = x
x(x – 3)
Now curve y = x and y =  intersect at one point for x  3
Number of solution = 1 x=3

2
5. We have  +  = –t and  = –2t
2

So
 2  2       2 t2 1
and
1

1 1
 2 
1
2
 2
  2
      4 t     4t 2t
2 2
 1  1 1   2  t2 1  1 1  3t 2 3
I    x  2   x  2     dx = x     x   
   4 t   4t 2 2t  
   dx =  2 3
1   1   8 4t
Differentiating w.r.t ‘t’
dI 3t 3
  3 0
dt 4 2t
 t  4 2
 t has to be positive

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 12 Review Test-7-Sol(Advanced)

Then Imin = I  2   3 42  3 
4 9
8
3 
a
b
c

 a + b + c]least = 20

1 3V
6. Volume  V   A 1h1  h1 
3 A1
Same for h2, h3, h4
So, (A1 + A2 + A3 + A4)(h1 + h2 + h3 + h4)
 3V 3V 3V 3V 
=  A1  A 2  A 3  A 4      
 A1 A 2 A 3 A 4 
 1 1 1 1 
= 3V  A1  A 2  A 3  A 4      
 A1 A 2 A 3 A 4 
A.M.  H.M.
A1  A 2  A 3  A 4 4

4  1 1 1 1 
    
A
 1 A 2 A 3 A 4 

 1 1 1 1 
  A1  A 2  A 3  A 4        16
 A1 A 2 A 3 A 4 
 1 1 1 1 
Minimum value of  A1  A 2  A 3  A 4      
 A1 A 2 A 3 A 4 
240
= 3V(16) = 48V = 48  5 = 240 = 4
60

7. Centre of the given circle is O(4, –3)

A
The circumcircle of PAB will circumscribe the
quadrilateral PBOA also, hence one of the
diameters must be OP O(4, –3)
 Equation of circumcircle of PAB will be P(2, 3)
(x – 2)(x – 4) + (y – 3)(y + 3) = 0 B
2 2
 x + y – 6x – 1 = 0 ….. (1)
Director circle of given ellipse will be
(x + 5)2 + (y – 3)2 = 9 + b2
 x2 + y2 + 10x – 6y + 25 – b2 = 0 ….. (2)
 From (1) and (2) by applying condition of orthogonality, we get
2[–3(5) + 0(–3)] = –1 + 25 – b2
 –30 = 24 – b2
2
b = 54
 b2 
  is 6
 9 

8. Let xi be the root where x  0 and x  R

x4 – a1x3i – a2x2 + a3xi + a4 = 0
 x4 – a2x2 + a4 = 0 ….. (1)
and a1x3 – a3x = 0 ….. (2)
From equation (2), we get a1x2 – a3 = 0
a
 x 2  3 (as x  0)
a1

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Review Test-7-Sol(Advanced) 13

a32 a2a3
Putting this in equation (1), we get   a4  0
a12 a1
 a23  a4 a12  a1a2 a3
a3 aa
  1 4 1
a1a2 a2a3

3
9. |sec  sec  sec | =
2
sec  sec  sec    tan   i  tan   i  tan   i 
3
 tan  tan  tan    tan   tan   tan    i  tan  tan   tan  tan   tan  tan   1
2
For imaginary part to be maximum real part must be 0
3
 max  tan  tan   tan  tan   tan  tan   1 
2
3 5
 max  tan  tan   tan  tan   tan  tan     1 =
2 2
p+q=7

10. p(x) = (x – I)(ax4 + bx3 + cx2 + dx + e)

Where a, b, c, d, e must be integer
[Note: When we are going to follow Dlrisbion method we will get integral are of quotient also]
Let q(x) = ax4 + bx3 + cx + dx + e
p(2) = (2 – I) q(2) = 13
 13 = 1  13 or 13  1 or – 1  –13 or –13  –1
 2 – I = 13, –13, 1 or –1
 I = –11, 15, –1, 3
p(10) = 5
 (10 – I) = 5, –5, 1 or –1
 I = 5, 15, 9, 11
 I = 15 (is the only possibility)
1+5=6

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