Problem 8

a) CH2=CHCO2H will absorb more radiation and be visible on UV as it has a double

bond.
b) CH3C ≡ C—C ≡ CCH will appear at a higher intensity as it has two triple bonds instead
of two double bonds.

c) will more readily absorb radiation due to the oxygen, which is

more excitable than a CH3

Problem 29
2500 A ̊ * 10-4 μm/A ̊ = 0.25 μm
0.25 μm * nm/ `10-3 μm = 250 nm

Problem 32
300 nm * 10-9 m/ nm = 3.00 * 10-7 m
(c )(h) (3.0∗10 8 m/s )(6.63∗1 0−34)
= =6.63∗10−19 Joules
λ −7
( 3.00∗1 0 m)
(6.63 * 10-19)(6.02 * 1023) = (3.99 * 105 joules)* 1 calorie/4.184 joules
9.54 * 104 calories/einstein

Problem 38
A=ϵ bc ϵ = a * molecular weight
(134L/cm*g)(93.13 g/mol) = 12479.42 L/cm*mol
(12479.42)(1.00)(1.00 * 10-4) = 1.25 absorbance

Problem 42
0.0702g ferrous ammonium sulfate 2.5mL sulfuric acid 0.463 sample absorbance
 0.463 + 0.0022 = 8.6092x
(0.463 + 0.0022)/8.6092 = x
X = 0.054 mg Fe

Problem 45
A = aA(1.00cm)cA + aB(1.00cm)cB
0.726 = (157)(1.00)cA + (0)(1.00)cB
0.726 = 157cA
CA = 0.0462 g/L = 4.62 mg/L

0.544 = (12.6)(1.00)(0.0462) + (186)(1.00)cB

0.544 = 0.582 + 186cB
-0.0381 = 186cB
CB = -0.000205 g/L = -0.205 mg/L

Problem 14
3 M HCl ratio between HCl & tri-n-butylphosphate for PdCl2 2.3 25mL of
7.0*10-4 M solution into 10mL tri-n-butylphosphate
100(2.3)/(2.3+(25/10)) = 230/(2.3+2.5) = 230/4.8 = 48%

Problem 17
Distribution ratio 25 10mL aqueous with 10mL of organic 10mL aqueous with 2
5.0mL organic
100(25)/(25+1) = 2500/26 = 96.2% extracted with 10mL organic

[(10)/((25*5)+10)]2 = [10/(125+10)]2 = [10/135] = [0.074]2 = 0.00549 = 0.55% remains

99.45% extracted by 2x5mL organic