Diagramas Txy y Pxy

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T 90 C

i Componente A B C Psati(kPa)
1 Benceno 13.7819 2726.81 217.572 136.496784
2 Etilbenceno 13.9726 3259.93 212.3 24.2603212

x1 x2 P(kPa) y1 y2
0 1 24.2603212 0 1
0.1 0.9 35.4839674 0.38467171 0.61532829
0.2 0.8 46.7076137 0.58447338 0.41552662
0.3 0.7 57.9312599 0.70685559 0.29314441
0.4 0.6 69.1549062 0.78951323 0.21048677
0.5 0.5 80.3785524 0.8490871 0.1509129
0.6 0.4 91.6021986 0.89406228 0.10593772
0.7 0.3 102.825845 0.92921919 0.07078081
0.8 0.2 114.049491 0.9574565 0.0425435
0.9 0.1 125.273137 0.98063406 0.01936594
1 0 136.496784 1 0

Diagrama P-xy
160
140
LIQUIDO
120 COMPRIMIDO
100
Presion (Kpa)

Px1 (LINEA DE
80 SATURACION BURBUJA)
py1 (LINEA DE
60 ROCIO)
40
VAPOR
20
SOBRECALENT
0 ADO
0 0.2 0.4 0.6 0.8 1 1.2
x1,y1
ECUACIÒN DE ANTOINE:
𝑳𝒏𝑷_𝒔𝒂𝒕=𝑨−𝑩/(𝑻+𝑪)

LEY DE RAOUTL:
P= ∑▒ 〖𝒙𝒊𝑷 _𝒔𝒂𝒕 〗

P=x1Psat1+x2Psat2

Px1 (LINEA DE
BURBUJA)
py1 (LINEA DE
ROCIO)
P 90 Kpa

i Componente A B C Tsati (C)


1 Benceno 13.7819 2726.81 217.572 76.1991122
2 Etilbenceno 13.9726 3259.93 212.3 131.836193

ΔT 5.56370806461 C

T (C) Psat1 (Kpa) Psat2 (Kpa) x1 x2 y1


76.1991122 90 14.4830815 1 0 1
81.7628203 106.947173569 17.9353115 0.8096077 0.1903923 0.96205839
87.3265284 126.287865884 22.0347802 0.65192526 0.34807474 0.91478055
92.8902364 148.240359684 26.8688421 0.52014805 0.47985195 0.85674371
98.4539445 173.02962964 32.5315449 0.40903373 0.59096627 0.78638838
104.017653 200.886559489 39.1235893 0.3145121 0.6854879 0.70201392
109.581361 232.04713841 46.7522448 0.23339961 0.76660039 0.60177456
115.145069 266.751645204 55.5312216 0.16318866 0.83681134 0.48367605
120.708777 305.243828215 65.5805025 0.10189084 0.89810916 0.34557278
126.272485 347.770088248 77.026137 0.04791931 0.95208069 0.18516558
131.836193 394.578671058 90 0 1 0
Temperatura (c)

140
DIAGRAMA T-xy
130

120

110

100

90

80

70
0 0.2 0.4 0.6 0.8 1
x1,y1
y2
0
0.03794161
0.08521945
0.14325629
0.21361162
0.29798608
0.39822544
0.51632395
0.65442722
0.81483442
1

xy

Tx1
Ty1

0.8 1 1.2

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