Esprit RSLMRSL Manual Incl Wastewater

RSL & MRSL Guidelines
RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCTS_2018
Substance CAS NO. Limit Detection Limit Test Method
Acetophenone and 2-Phenyl-propan-2-ol
Acetophenone 98-86-2 <50 mg/kg 10 mg/kg Extraction in acetone, sonication for 30 min at
2-Phenyl-2-propanol 617-94-7 <50 mg/kg 10 mg/kg 60 degrees C, analysis with GC/MS
Alkylphenols (AP) and Alkylphenols Ethoxylates (APEOs), including all isomers*

Nonlyphenol (NPs), mixed isomers Various Extraction: 1g sample/20 ml THF sonication
10 mg/kg
Octylphenol (OPs), mixed isomers Various for 60 minutes at 70 degrees C.
Not Detected
Nonylphenol Ethoxylates (NPEOs) Various Textile: EN ISO 18254-1:2016
50 mg/kg
Octylphenol Ethoxylates (OPEOs) Leather: EN ISO 18218-1:2015
Various
*Recycle wool is exempt.
Chlorinated Paraffins
Short-Chain chlorinated Paraffins (SCCP) (C10-C13) 85535-84-8 <100 mg/kg 50 mg/kg Combined CADS/ISO 18219:2015
method V1:06/17
Extraction: ISO 18219 and analysis
Medium-Chain chlorinated Paraffins (MCCP) (C14-C17) 85535-85-9 <1000 mg/kg 100mg/kg by GC-NCI-MS.
Chloro Phenols
Pentachlorophenol (PCP) 87-86-5
2,3,4,5-Tetrachlorophenol 4901-51-3
1M KOH extraction,12-15 hours at
2,3,4-Trichlorophenol 15950-66-0
90 degrees C, derivatization and analysis
§ 64 LFGB B 82.02-08 or
2,3,6-Trichlorophenol 933-75-5 0.5 mg/kg each 0.05 mg/kg each
DIN EN ISO 17070:2015
Dichlorophenols various
Monochlorophenols various
RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCTS
Chloro Organic Carriers (COCs)
Chlorobenzene 108-90-7
1,2-Dichlorobenzene 95-50-1
1,2,3-Trichlorobenzene 87-61-6
1,2,3,4-Tetrachlorobenzene 634-66-2
Pentachlorobenzene 608-93-5
Hexachlorobenzene 118-74-1
2-Chlorotoluene 95-49-8
Sum<1,0 mg/kg 0,1 mg/kg DIN 54232:2010
2,3-Dichlorotoluene 32768-54-0
2,3,6-Trichlorotoluene 2077-46-5
2,4,5-Trichlorotoluene 6639-30-1
2,3,4,5-Tetrachlorotoluene 76057-12-0
Pentachlorotoluene 877-11-2
Dyes – Allergenic Disperse Dyes
Disperse Blue 1 2475-45-8

Disperse Orange 1 2581-69-3
12223-33-5
Disperse Orange 37/76/59 13301-61-6
51811-42-8
<50 mg/kg each 15 mg/kg DIN 54231:2005
Disperse Brown 1 23355-64-8
Disperse Red 1 2872-52-8
Disperse Yellow 1 119-15-3
Dyes - Navy Blue Colorants
Component 1: C39H23ClCrN7O12S·2Na 118685-33-9
Not Detected 15 mg/kg DIN 54231:2005
Component 2: C46H30CrN10O20S2·3Na Not allocated
Dyes - Carcinogenic Dyes
Acid Red 26 3761-53-3
Basic Red 9 569-61-9
Basic Violet 14 632-99-5
Basic Blue 26 2580-56-5
Basic Violet 3 548-62-9
Basic Green 4 (oxalate, chloride or free) 2437-29-8/569-64-2/
10309-95-2
Direct Black 38 1937-37-7 <50 mg/kg each 15 mg/kg DIN 54231:2005
Direct Blue 6 2602-46-2
Direct Red 28 573-58-0
Direct Brown 95 16071-86-6
4-Dimethylaminoazobenzene (Solvent Yellow 2) 60-11-7
Solvent Blue 4 6786-83-0
4,4'-bis(dimethylamino)-4''-(methylamino)trityl alcohol 561-41-1
Carcinogenic Arylamines (Free available or cleavage from dyestuff)
o-Toluidine 95-53-4
2,4-Xylidine 95-68-1
2,6-Xylidine 87-62-7
o-Anisidine (2-Methoxyaniline) 90-04-0
p-Chloroaniline 106-47-8
p-Cresidine 120-71-8
2,4,5-Trimethylaniline 137-17-7
4-Chloro-o-toluidine 95-69-2 Textile: DIN EN 14362-1:2017 (with and
2,4-Toluylendiamine 95-80-7 without extraction)
2,4-Diaminoanisole 615-05-4 Leather: DIN EN ISO 17234-1:2015
2-Naphthylamine 91-59-8
2-Amino-4-nitrotoluene 99-55-8
<15 mg/kg each 5 mg/kg
4-Aminobiphenyl 92-67-1 4-Aminoazobenzene:
4-Aminoazobenzene 60-09-3 Textile: DIN EN 14362-3:2017
4,4'-Oxydianiline 101-80-4
Leather: DIN EN ISO 17234-2:2015
Benzidine 92-87-5
4,4'-Diaminobiphenylmethane 101-77-9
o-Aminoazotoluene 97-56-3
3,3'-Dimethyl-4,4'-diaminobiphenylmethane 838-88-0
3,3'-Dimethylbenzidine 119-93-7
4,4'-Thiodianiline 139-65-1
3,3'-Dichlorobenzidine 91-94-1
4,4'-Methylene-bis-(2-chloroaniline) 101-14-4
3,3'-Dimethoxybenzidine 119-90-4
Substance CAS No. Limit Detection Limit Test Method
Flame Retardants
Hexabromocyclododecane (HBCDD) 25637-99-4
3194-55-6
Tetrabromodiphenylether (tetraBDE) 40088-47-9
Pentabromodiphenylether (pentaBDE) 32534-81-9
Hexabromodiphenylether (hexaBDE) 36483-60-0
Heptabromodiphenylether (heptaBDE) 68928-80-3
Hexabromobiphenyl 36355-01-8
Octabromodiphenylether (octaBDE) 32536-52-0
Nonabromodiphenylether (nonaBDE) 63936-56-1
Decabromodiphenylether (decaBDE) 1163-19-5
2,2-Bis(bromomethyl)propan-1,3-diol (BBMP) 3296-90-0
Bis(2,3-dibromopropyl)phosphate (BIS) 5412-25-9
Pentabromobenzene 608-90-2
Not Detected 5 mg/kg
Polybrominated Biphenyles (PBB) 59536-65-1
EN ISO 17881-1 & 2:2016
Tris(2,3-dibromopropyl)phosphate (TRIS) 126-72-7
Tris(aziridinyl)phosphine oxide (TEPA) 545-55-1
Tetrabromobisphenol A (TBBP A) 79-94-7
Tetrabromobisphenol-A-bis (2,3-dibromopropylether) 21850-44-2
(BDBPT)
1,2-Bis(pentabromophenyl)ethane (EBP) 84852-53-9
Triphenylphosphate (TPhP) 115-86-6
Tricresylphosphate (TCP) 1330-78-5
Tris(2-chloroethyl)phosphate (TCEP) 115-96-8
Tris(1,3-dichloroisopropyl)phosphate (TDCPP) 13674-87-8
Tris(2-chloro-1-methylethyl) phosphate (TCPP) 13674-84-5
Trixylyl phosphate (TXP) 25155-23-1
Formaldehyde
Leather: EN ISO 17226-2:2008 with UV-Vis
Formaldehyde 50-00-0 <75 mg/kg 16 mg/kg
Textile: DIN EN ISO 14184-1:2011 with UV-Vis
Heavy Metals - Extractable
Textile Leather
Antimony (Sb) 7440-36-0 <30 mg/kg <30 mg/kg 1.0 mg/kg
Arsenic (As) 7440-38-2 <0,2 mg/kg <0,2 mg/kg 0,1 mg/kg
Barium (Ba) 7440-39-3 <1000 mg/kg <1000 mg/kg 50 mg/kg
Cadmium (Cd) 7440-43-9 <0,1 mg/kg <0,1 mg/kg 0,05 mg/kg
Textile: 0,5 mg/kg

Chromium (Cr) 7440-47-3 <1,0mg/kg <200 mg/kg
Leather: 1.0 mg/kg
Textile: DIN EN ISO 16711-2:2016
Cobalt (Co) 7440-48-4 <1,0 mg/kg <1,0 mg/kg 0,5 mg/kg
Leather: DIN EN ISO 17072-1:2017
Copper (Cu) 7440-50-8 <25,0 mg/kg <25,0mg/kg 5,0 mg/kg
Lead (Pb) 7439-92-1 <0,2mg/kg <0,2 mg/kg 0,1 mg/kg
Mercury (Hg) 7439-97-6 <0,02 mg/kg <0,02 mg/kg 0,02 mg/kg

Nickel (Ni) 7440-02-0 <1,0 mg/kg <1,0 mg/kg 0,5 mg/kg
Selenium (Se) 7782-49-2 <500 mg/kg <500 mg/kg 50 mg/kg
Textile: 0,5 mg/kg Textile: GB/T 17593-3:2006

Chromium VI (Cr VI) 18540-29-9 <0,5 mg/kg <3,0 mg/kg
Leather: 3.0 mg/kg Leather: DIN EN ISO 17075:2015
Heavy Metals - Total
Cadmium (Cd) 7440-43-9 <40 mg/kg
Lead (Pb) 7439-92-1 <90 mg/kg

10 mg/kg DIN EN 16711-1:2016
Arsenic (As) 7440-38-2 ≤100 mg/kg
Mercury (Hg) 7439-97-6 <10 mg/kg

Isocyanate
Methylenediphenyl diisocyanate (MDI) 101-68-8 Not Detected 5 mg/kg DIN EN ISO 10283:2007
Nickel release
<0,5 µg/cm²/week EN 12472:2005 + A1:2009 and

Nickel release 7440-02-0 <0,1 µg/cm²/week
articles in skin contact DIN EN 1811:2015
N-Nitrosamines
N-nitrosodimethylamine 62-75-9
N-nitrosodiethylamine 55-18-5
N-nitrosodiproylamine 621-64-7
N-nitrosodibutylamine 924-16-3
GB/T 24153, determination using GC/MS
N-nitrosopiperidine 100-75-4 <0,5 mg/kg each 0.5 mg/kg each
and further confirmation with LC/MS/MS
N-nitrosopyrrolidine 930-55-2
N-nitrosomorpholine 59-89-2
N-nitroso-N-methylaniline 614-00-6
N-nitroso-N-ethylaniline 612-64-6
Organotin Compounds
Monobutyltin (MBT) various
Dibutyltin (DBT) various
Tributyltin (TBT) various
Tricyclohexyltin (TCyHT) various
Trioctyltin (TOT) various
Triphenyltin (TPhT) various
Tripropyltin (TPT) various
Trimethyltin (TMT) various <0,5 mg/kg each 0.2 mg/kg each CEN ISO/TS 16179:2012
Dioctyltin (DOT) various
Dimethyltin (DMT) various
Diphenyltin (DPT) various
Monooctyltin (MOT) various
Methyltin (MT) various
Tetrabutyltin (TEBT) various
Trimethyltin (TMT) various
Other Banned Amine
p-Phenylenediamine 106-50-3 <50 mg/kg 15 mg/kg DIN EN ISO 14362-1:2017
Perfluorinated Compounds (PFCs)
1763-23-1,
2795-39-3,
29457-72-5,
PFOS and its derivates 29081-56-9
70225-14-8,
56773-42-3
251099-16-8
335-67-1,
3825-26-1,
335-95-5,
2395-00-8,
PFOA and its derivates
335-93-3,
335-66-0,
376-27-2,
3108-24-5
Perfluorobutanoic acid (PFBA) 375-22-4
Perfluoropentanoic acid (PFPeA) 2706-90-3
Perfluorohexanoic acid (PFHxA) 307-24-4
Perfluoroheptanoic acid (PFHpA) 375-85-9
Not Detected 1 ug/m² DIN CEN/TS 15968
Perfluorooctane sulphonamide (PFOSA) 754-91-6
N-Methyl-heptadecafluorooctane sulfonamide (N-Me-FOSA) 31506-32-8
N-Ethyl-heptadecafluorooctane sulfonamide (N-Et-FOSA) 4151-50-2
N-Methyl-heptadecafluorooctane sulfonamidoethanol (N-ME-FOSE) 24448-09-7
N-Ethyl-heptadecafluorooctane sulfonamidoethanol (N-ET-FOSE) 1691-99-2
Perfluorononanoic acids (PFNA) various

Perfluorododecanoic acids (PFDA) various
Henicosafluoroundecanoic acid (PFUdA) 2058-94-8
Tricosafluorododecanoic acid (PFDoA) 307-55-1
Pentacosafluorotridenoic acid (PFTrDA) 72629-94-8
Heptacosafluorotetradecanoic acid (PFTeDA) 376-06-7

Pesticides, Agriculture
Extraction with organic solvent,
See Appendix A for a complete list Various <0,5 mg/kg each <0,5 mg/kg each analysis with GC/MS according to DIN
38407-37.
PVC - Cause of Carcinogenic Vinyl Chloride
If Beilstein Test positive, should be

PVC 75-01-4 Usage ban N.A.
further analysed by FT-IR.
Phthalates
Bis-(2-ethylhexyl) phthalate (DEHP) 117-81-7

Dibutyl phthalate (DBP) 84-74-2
Benzylbutyl phthalate (BBP) 85-68-7
Diisononyl phthalate (DINP) 28553-12-0
Diisodecyl phthalate (DIDP) 26761-40-0
Dioctyl phthalate (DNOP) 117-84-0
Diisobutyl phthalate (DIBP) 84-69-5
Di-C6-8 branched alkyl phthalate (DIHP) 71888-89-6 <50 mg/kg each
Di-C7-11 branched alkyl phthalate (DHNUP) 68515-42-4
EN ISO 14389:2014
Di-n-Hexyl phthalate (DnHP) 84-75-3 50 mg/kg
CPSC-CH-C1001-09.3
Bis(2-methoxyethyl) phthalate (DMEP) 117-82-8
131-18-0, 605-50-5,
Dipentyl phthalate (n-, iso, or mixed) (DPP)
776297-69-9
Dicyclohexyl phthalate (DCHP) 84-61-7
Dihexyl phthalate branched and linear (DHxP) 68515-50-4
Diisohexyl phthalate (DIHxP) 71850-09-4
Dimethyl phthalate (DMP) 131-11-3
Sum <1000mg/kg
Diethyl phthalate (DEP) 84-66-2
1,2-Benzenedicarboxylic acid, dipentylester, branched and linear (DPP) 84777-06-0 < 500 mg/kg
RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCT
Polycyclic Aromatic Hydrocarbons (PAHs)
Benzo[a]pyrene 50-32-8
Benzo[e]pyrene 192-97-2
Benz[a]anthracene 56-55-3
Benzo(b)fluoranthene 205-99-2
Benzo[j]fluoranthene 205-82-3
<0,5 mg/kg each
Benzo[k]fluoranthene 207-08-9
Chrysene 218-01-9
Dibenz[a,h]anthracene 53-70-3
Benzo[ghi]perylene 191-24-2
Indeno[1,2,3-cd]pyrene 193-39-5
Acenaphthylene 208-96-8
Acenaphthene 83-32-9
Anthracene 120-12-7 0,2 mg/kg AfPS GS 2014:01 PAK
Fluorene 86-73-7 Sum <10,0 mg/kg
Fluoranthene 206-44-0
Phenanthrene 85-01-8
Pyrene 129-00-0
Naphthalene 91-20-3 < 2,0 mg/kg
Sum of above 18 PAH’s <10,0 mg/kg
Cyclopenta[c,d]pyrene 27208-37-3
Dibenz[a,e]pyrene 192-65-4
Dibenz[a,h]pyrene 189-64-0
<1,0 mg/kg each
Dibenz[a,i]pyrene 189-55-9
Dibenz[a,l]pyrene 191-30-0
1-Methylpyrene 2381-21-7
Acidic and Alkaline Substances
Textile: with skin contact: 4,0 - 7,5
Textile: EN ISO 3071:2005
pH-Value without skin contact: 4,0 - 9,0
Leather: 3,0 - 8,5 Leather: EN ISO 4045: 2018
Substance CAS-No. Limit Detection Limit Test Method
Preservative Agents
Triclosan 3380-34-5 <10 mg/kg 5 mg/kg Extraction with organic solvent, analyzed by
GC/MS or LC-MS
Dimethylfumarate 624-49-7 <0,1 mg/kg 0.1 mg/kg DIN CEN ISO/TS 16186:2012
2-Thiocyanomethylthiobenzothiazol (TCMTB) 21564-17-0 <500 mg/kg 100 mg/kg ISO 13365:2011
o-Phenylphenol (OPP) 90-43-7 <500 mg/kg 10 mg/kg ISO 13365:2011
PCB and PCT
Halogenated terphenyls including polychlorinated

various
terphenyls (PCT)
Not Detected 1 mg/kg DIN ISO EN 15318
Halogenated biphenyls including polychlorinated
various
biphenyls (PCB)
Solvents
N,N-Dimethylformamide (DMFa) 68-12-2 <300 mg/kg 10 mg/kg DIN CEN ISO/TS 16189:2013
Formamide 75-12-7 <200 mg/kg 15 mg/kg Extraction with organic solvent, analyzed by
GC/MS.
Volatile Organic Compounds (VOCs)
Benzene 71-43-2 <5 mg/kg
Carbon tetrachloride 56-23-5
Chloroform 67-66-3
1,2-Dichloroethane 107-06-2
1,1-Dichlorethylene 75-35-4
Dimethylacetamide (DMAC) 127-19-5
Pentachloroethane 76-01-7 General VOC Screening:
1,1,1,2- Tetrachloroethane 630-20-6 Total: 1000 mg/kg 1 mg/kg GC-MS Headspace 45 mins at 120°C
1,1,2,2- Tetrachloroethane 79-34-5
Tetrachloroethylene (PER) 127-18-4
Toluene 108-88-3
1,1,1- Trichloroethane 71-55-6
1,1,2- Trichloroethane 79-00-5
Trichloroethylene 79-01-6
Xylenes (meta-, ortho-, para-) 1330-20-7
Chemical Supplier Wastewater Testing
Commercial Formulation
Limit General (Raw Wastewater)
Techniques for Detection Limit Status of
Substance CAS No.
Textile & Analyzing for Formulations Reporting Elimination
Synthetic. Leather Chemicals Limit
Standard Test Method
Leather Processing
Processing (in µg/L)
Alkylphenols (AP) and Alkylphenols Ethoxylates (APEOs) including all isomers
Nonylphenol (NP), 104-40-5

mixed isomers 11066-49-2 ISO 18857-2 (modified
25154-52-3 dichloromethane
84852-15-3 50 ppm extraction) or ASTM
250 ppm D7065 (GC/MS or
Octylphenol (OP), 140-66-9
LC/MS(-MS)
1806-26-4
mixed isomers 27193-28-8 No intentional use.
Nonylphenol ethoxylates (NPEO) 9016-45-9 GC-MS/LC-MS 5 Banned since July
26027-38-3 2013.
37205-87-1 (n>2): ISO 18254-1;
68412-54-4
127087-87-0 100 ppm (n=1,2): ISO 18857-2 or
500 ppm ASTM D7056
Octylphenol ethoxylates (OPEO) 9002-93-1
9036-19-5
68987-90-6
Substance CAS No.
Leather Processing
Dyes – Disperse (Sensitizing)

56524-77-7
Disperse Orange 37/59/76 13301-61-6 Not Phase-out by 1

250 ppm LC 50 ppm Liquid extraction, LC/MS 50 ppm
applicable January, 2020.
Disperse Brown 1 23355-64-8

Substance CAS No.
Leather Processing
Dyes - Navy Blue Colorants
Component 1: 118685-33-9 No intentional use.

C39H23ClCrN7O12S·2Na 250 ppm LC 50 ppm Banned already
Component 2: Not before 2012.
C46H30CrN10O20S2·3Na allocated
Dyes - Carcinogenic or Equivalent Concern
Direct Black 38 1937-37-7
Direct Blue 6 2602-46-2
Acid Red 26 3761-53-3
Basic Red 9 569-61-9
Direct Red 28 573-58-0 200 ppm
Basic Violet 14 632-99-5 Phase out by 1

250 ppm LC
2437-29-8 January 2020.
Basic Green 4
569-64-2 Liquid extraction, LC/MS 500
(oxalate, chloride or free)
10309-95-2
Basic Blue 26 2580-56-
Disperse Blue 1 52475-45-8 50 ppm

Substance CAS No.
Leather Processing
Dyes – Azo (Forming Restricted Amines)
4,4'-methylene-bis- 101-14-4
(2-chloroaniline)
4,4’methylenedianiline 101-77-9
4,4'oxydianiline 101-80-4
4-chloroaniline 106-47-8
3,3'dimethoxylbenzidine 119-90-4
3,3'-dimethylbenzidine 119-93-7
6-methoxy-m-toluidine 120-71-8
2,4,5-trimethylaniline 137-17-7
4,4'-thiodianiline 139-65-1
4-aminoazobenzene 60-09-3 EN 14362-1
4-methoxy-m-phenylenediamine 615-05-4 EN 14362-3
4,4'-methylenedi-o-toluidine 838-88-0 No intentional use.
150 ppm LC, GC, GC/MS 50 ppm 0.1 Banned since March
2,6-xylidine 87-62-7
Reduction step with 2016.
o-anisidine (2-Methoxyaniline) 90-04-0 sodiumdithionite, solvent
extraction, GC/MS or
2-naphthylamine 91-59-8 LC/MS.
3,3'-dichlorobenzidine 91-94-1
4-aminodiphenyl 92-67-1
Benzidine 92-87-5
o-toluidine 95-53-4
2,4-xylidine 95-68-1
4-chloro-o-toluidine 95-69-2
4-methyl-m-phenylenediamine 95-80-7
o-aminoazotoluene 97-56-3
(Solvent Yellow 3)
5-nitro-o-toluidine 99-55-8
Substance CAS No.
Leather Processing
Chlorobenzenes and Chlorotoluenes (“Chloro Organic Carriers”, COCs)
1,2-dichlorobenzene 95-50-1 1000 ppm

Monochlorobenzene 108-90-7
1,3-dichlorobenzene 541-73-1
1,4-dichlorobenzene 106-46-7
1,2,3-trichlorobenzene 87-61-6
1,2,3,4-tetrachlorobenzene 634-66-2
1,2,3,5-tetrachlorobenzene 634-90-2
1,2,4,5-tetrachlorobenzene 95-94-3 USEPA 82608, 8270D.
2-chlorotoluene 95-49-8
Not intentional use.
3-chlorotoluene 108-41-8 Dichloromethane 0.2 Phase out by 1
4-chlorotoluene 106-43-4 extraction followed by
January 2020.
2,3-dichlorotoluene 32768-54-0 GC/MS.
2,4-dichlorotoluene 95-73-8
2,5-dichlorotoluene 19398-61-9 Sum = 200 ppm GC-MS 100 ppm
2,3,4-trichlorotoluene 7359-72-0
2,3,4,5-tetrachlorotoluene 76057-12-0
Pentachlorotoluene 877-11-2
Any other isomers of mono-, di-, tri-, tetra-, penta-
and hexa-chlorobenzene and mono-, di-, tri-,
tetra- and penta-chlorotoluene
Commercial Formulation General
Limit (Raw Wastewater)
Techniques Detection Limit Status of
Substance CAS No.
Textile & for Analyzing for Formulations Reporting Elimination
Synthetic. Leather Limit
Chemicals Standard Test Method
Leather Processing
Chlorophenols
Tetrachlorophenol (TeCP) 25167-83-3

Sum = 20 ppm
Pentachlorophenol (PCP) 87-86-5
2-chlorophenol 95-57-8
2,3-dichlorophenol 576-24-9
2,5-dichlorophenol 583-78-8 USEPA 8270 D.
Solvent extraction,
3,4-dichlorophenol 95-77-2 derivatisation with KOH, Phase out by 1
3,5-dichlorophenol 591-35-5 GC-MS acetic anhydride 0.5 January 2020.
Sum = 50 ppm 10 ppm followed by GC/MS.
2,3,4-trichlorophenol 15950-66-0
EN ISO 17070
2,3,5-trichlorophenol 933-78-8 ISO 14154:2005
2,3,4,5-tetrachlorophenol 4901-51-3
Substance CAS No.
Leather Processing
Flame Retardants
Tris(2-chloroethyl)phosphate 115-96-8
(TCEP)
Decabromodiphenylether 1163-19-5
(DecaBDE)
Tris(2,3-dibromopropyl)phosphate
126-72-7
(TRIS)
Pentabromodiphenylether 32534-1-9
(PentaBDE)
Octabromodiphenylether 32536-52-0 US EPA 8270,
(OctaBDE)
ISO 22032,
Bis(2,3-dibromopropyl)phosphate
5412-25-9
(BIS) USEPA 527 and USEPA
8321B.
Tris(aziridinyl)phosphine oxide GC-MS No intentional use.
545-55-1 5
(TEPA) 250 ppm 250 ppm Banned already
50 ppm
Polybromobiphenyles (PBB) 59536-65-1 Dichloromethane before 2012.
extraction GC/MS or
Tetrabromobisphenol A (TBBP A) 79-94-7
LC/MS(-MS)
Hexabromocyclodecane (HBCDD) 3194-55-6
2,2-bis(bromomethyl)-1,3- 3296-90-0
propanediol (BBMP)
Tris(1,3-dichloro- 13674-87-8
isopropyl)phosphate (TDCP) 50 ppm (textile &
synth. Leather)
Short-chain chlorinated Paraffins
85535-84-8 50 ppm 250 ppm (leather)
(SCCP) (C10-C13)
Chemical Supplier
Wastewater Testing
Commercial Formulation General (Raw Wastewater)
Limit Techniques Detection Limit Status of
Substance CAS No.
Leather Processing
Glycols
Bis(2-methoxyethyl)-ether 111-96-6
2-ethoxyethanol 110-80-5
US EPA 8270
2-ethoxyethyl acetate 111-15-9

Phase out by 1
50 ppm HPLC, LC-MS 50 ppm Liquid extraction, LC/MS 50
January 2020.
Ethylene glycol dimethyl ether 110-71-4 50 ppm
2-methoxyethanol 109-86-4 GC-MS
2-methoxyethylacetate 110-49-6
Triethylene glycol dimethyl ether 112-49-2
2-methoxypropylacetate 70657-70-4 1000 ppm
Halogenated Solvents
1,2-dichloroethane 107-06-2
US EPA 8260B
Methylene chloride 75-09-2 5 ppm 5 ppm Phase out by 1
GC-MS 1
January 2020.
Tetrachloroethylene 127-18-4 Headspace GC/MS or
Purge-and-Trap-GC/MS
Trichloroethylene 79-01-6 40 ppm 40 ppm
Chemical Supplier
Wastewater Testing
General (Raw Wastewater)
Limit
Substance CAS No.
Leather Processing
Organotin Compounds
20 ppm
(exception:
100 ppm for
poly-
urethane
Dibutyltin (DBT) 20 ppm
based
thickeners
used at
< 20 % ISO 17353.
loading) Phase out by 1
GC-MS, LRMS 5 ppm Derivatisation with 0,01
January 2020.
NaB(C2H5)
Mono-, di-, and tri-methyltin
various GC/MS
derivatives
Mono-, di-, and tri-butyltin

various 5 ppm
derivatives
Mono-, di-, and tri-phenyltin various
derivatives
Mono-, di-, and tri-octyltin
various
derivatives
Substance CAS No.
Leather Processing
Polycyclic Aromatic Hydrocarbons (PAHs)
Benzo[a]pyrene (BaP) 50-32-8 20 ppm 5 ppm
Benzo[e]pyrene 192-97-2
Benz[a]anthracene 56-55-3
Benzo[b]fluoranthene 205-99-2
Benzo[j]fluoranthene 205-82-3
Benzo[k]fluoranthene 207-08-9 US EPA 8270
Chrysene 218-01-9 DIN 38407-39
GC-MS Phase out by 1
Dibenz[a,h]anthracene 53-70-3 1
January 2020.
Benzo[ghi]perylene 191-24-2 Sum = 200 Solvent extraction
Sum = 200 ppm
Indeno[1,2,3-cd]pyrene 193-39-5 20 ppm GC/MS
ppm
Acenaphthylene 208-96-8
Acenaphthene 83-32-9
Anthracene 120-12-7
Fluorene 86-73-7
Fluoranthene 206-44-0
Phenanthrene 85-01-8
Pyrene 129-00-0
Naphthalene 91-20-3 300 ppm GC-MS, LC
Substance CAS No.
Leather Processing
Perfluorinated Compounds (PFCs)
PFOS and related substances Various Sum = 2 ppm

LC-MS 1 ppm
PFOA and related substances Various Sum = 2 ppm
355-46-4 Sum = 2 ppm 0.01
PFOS
432-50-7
DIN 38407-42 (modified)
PFOA 335-67-1 Sum = 2 ppm
29420-49-3
PFBS No intentional use.
29420-43-3 Ionic PFC:
Eliminated from
PFHxA 307-24-4 Concentration or direct
production since
injection, LC/MS(-MS)
8:2 FTOH 678-39-7 December 2014.
Non-ionic PFC (FTOH):

Derivatisation with acetic 1
6:2 FTOH 647-42-7 anhydride followed by
GC/MS
Substance CAS No.
Leather Processing
Phthalates – including all esters of ortho-phthalic acid
Bis-(2-ethylhexyl) phthalate (also:

117-81-7
Di(ethylhexylphthalate) (DEHP)
Bis(2-methoxyethyl) phthalate 117-82-8
(DMEP)
Di-n-octyl phthalate (DNOP) 117-84-0
Di-iso-decyl phthalate (DIDP) 26761-40-0
Di-isononyl phthalate (DINP) 28553-12-0
Di-n-hexyl phthalate (DnHP) 84-75-3
Dibutyl phthalate (DBP) 84-74-2
Butyl benzyl phthalate (BBP) 85-68-7
US EPA 8270D,
Dinonyl phthalate (DNP) 84-76-4
Sum of all phthalates ISO 18856
Diethyl phthalate (DEP) 84-66-2 Phase out by 1
GC-MS 100 ppm 10
= 250 ppm January 2020.
Di-n-propyl phthalate (DPRP) 131-16-8 Dichloro-methane
Di-isobutyl phthalate (DIBP) 84-69-5 extraction GC/MS
Di-cyclohexyl phthalate (DCHP) 84-61-7
Di-iso-octyl phthalate (DIOP) 27554-26-3
Di-C7-11 branched alkyl phthalate
(also: 1,2-benzenedicarboxylic
68515-42-4
acid, di-C7-11-branched and
linear alkyl esters) (DHNUP)
Di-C6-8 branched alkyl phthalate
(also: 1,2-benzenedicarboxylic
71888-89-6
acid, di-C6-8-branched alkyl
esters, C7-rich) (DIHP)
Substance CAS No.
Leather Processing
Heavy Metals
0.05
Arsenic (As) 7440-38-2 50 ppm EN ISO 11885

USEPA 200.7, USEPA
ICP-OES, AAS 200.8, USEPA 6010c,
Cadmium (Cd) 7440-43-9 20 ppm (50 ppm for pigments) USEPA 6020a 0.1
10 ppm
For leather:
Lead (Pb) 7439-92-1 100 ppm 0.1
Cr (III) tanning
agents can be 0.05 Phase-out by 1
monitored for Cr EN ISO 18412 January 2020.
Chromium (VI) 18540-29-9 10 ppm (VI); EN ISO USEPA 218.6
17075 (current
use), ISO/DIS
19071 (draft) ENISO 18412 or ISO 0.01
17852
Mercury (Hg) 7439-97-6 4 ppm (25 ppm for pigment) 2 ppm
USEPA 200.7, USEPA
200.8, USEPA 6010c,
USEPA 6020a
Volatile Organic Compounds (VOCs)
Benzene 71-43-2 50 ppm

ISO 11423-1
20 ppm Phase out by 1
GC-MS Headspace- or Purge- 1
January 2020.
o-cresol 95-48-7 and-Trap-GC/MS
p-cresol 106-44-5 500 ppm US EPA 8260
m-cresol 108-39-4
Xylenes (meta-, ortho-, para-) 1330-20-7 100 ppm
Designation or Abbreviation Explanation
CAS No. (= CAS Registry Number®) A unique number by which only one chemical substance can be identified on an international level.
Detection Limit The minimum concentration of a substance that can be measured and reported with 99 %
confidence that the analyte concentration is greater than zero.
Esprit products Apparel, footwear and accessories
mg/kg Unit for defining mass fraction (mass portion) of a chemical substance.
N.D. Not detectable.
µg/L Unit for defining the mass concentration of a chemical substance.
ppm Unit for defining the concentration of a chemical substance = 1 part per 1 million parts = 10 −6 = 1
Teil pro Million = 0,0001 %
(It is only approximately the same as mg/l.)
Reporting Limit Lowest concentration that can be reliably achieved within specified limits of precision and accuracy
during routine laboratory operating conditions. Good laboratory practice dictates that a reporting
limit is 10 times the Detection Limit, taking into consideration variability associated with analyzing
samples from a wide variety of sources with many potential complicating factors, e.g. matrix
effects.
ZDHC Zero Discharge of Hazardous Chemicals Program (http://www.roadmaptozero.com/)
Pesticide Name CAS NO. Pesticide Name CAS NO. Pesticide Name CAS NO.
DDT 1,1,1-Trichlor-
2,2-bis-(4- Dicofol 115-32-2 Mirex 2385-85-5
50-29-3
chlorophenyl)-ethane
and isomers
53-19-0, Dicrotophos 141-66-2 Monocrotophos 6923-22-4
DDD
72-54-8
3424-82-6, 120738-89-8,
DDE Dimethoate 60-51-5 Nitenpryam
72-55-9 150824-47-8
135410-20-7, Endrin 72-20-8 Parathion 56-38-2
Acetamiprid
160430-64-8
Endosulfan and its 115-29-7, 959-98-8,
Aldicarb 116-06-4 Parathionmethyl 298-00-0
isomers 33213-65-9
Aldrin 309-00-2 Esfenvalerate 66230-04-4 Pentachloroanisole 1825-21-4
Azinophosmethyl 86-50-0 Ethylendibromid 106-93-4 Profenophos 41198-08-7
Azinophosethyl 2642-71-9 Fenvalerate 51630-58-1 Quinalphos 13593-03-8
Bromophosethyl 4824-78-6 Heptachlor 76-44-8 Quintozene 82-68-8

Captafol 2425-06-1 Heptachlor epoxide 1024-57-3 Strobane 8001-50-1
Hexachlorocyclohexan 2,4,5-T (Acetic acid, (2,4,5-
Carbaryl 63-25-2 608-73-1 93-76-5
e (-HCH) trichlorophenoxy)-)
2,4,5-TP (Propanoic acid, 2-(2,4,5-
Chlorbenzilat 510-15-6 Hexachlorobenzene 118-74-1 93-72-1
trichlorophenoxy)-)
138261-41-3, 105827-78-
Dinoseb and salts 88-85-7 Imidacloprid Thiacloprid 111988-49-9
9
Dinotefuran 16525-70-0 Isobenzan (Telodrin) 297-78-9 Thiamethoxam 153719-23-4
DTTB 63405-99-2 Isodrin 465-73-6 Tolylfluanide 731-27-1
2,4-D 94-75-7 Kelevan 4234-79-1 Trifluralin 1582-09-8
Lead hydrogen
DEF (Tribufos) 78-48-8 7784-40-9 Halogenated naphthalenes (PCNs) various
arsenate
Monomethyl-tetrachlorodiphenyl
Deltamethrin 52918-63-5 Malathion 121-75-5 76253-60-6
methane
Diazinon 333-41-5 MCPA 94-74-6 Monomethyl-dichlorodiphenyl methane 81161-70-8
Dibromchlorpropan
96-12-8 MCPB 94-81-5 Monomethyl-dibromo-diphenyl methane 99688-47-8
(DBCP)
Dieldrin 60-57-1 Mecoprop 93-65-2 Toxaphene 8001-35-2
Diclofluanide 1085-98-9 Metamidophos 10265-92-6
Dichlorprop 120-36-5 Methoxychlor 72-43-5

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RSL & MRSL Guidelines

RESTRICTED SUBSTANCES LIST (RSL) FOR RAW MATERIALS/FINISHED PRODUCTS_2018

Substance CAS NO. Limit Detection Limit Test Method

Acetophenone and 2-Phenyl-propan-2-ol

Alkylphenols (AP) and Alkylphenols Ethoxylates (APEOs), including all isomers*

Pentachlorophenol (PCP) 87-86-5

Substance CAS NO. Limit Detection Limit Test Method

Chloro Organic Carriers (COCs)

Dyes – Allergenic Disperse Dyes

Disperse Blue 1 2475-45-8

Substance CAS No. Limit Detection Limit Test Method

Heavy Metals - Extractable

Textile: 0,5 mg/kg

Lead (Pb) 7439-92-1 <0,2mg/kg <0,2 mg/kg 0,1 mg/kg

Mercury (Hg) 7439-97-6 <0,02 mg/kg <0,02 mg/kg 0,02 mg/kg

Textile: 0,5 mg/kg Textile: GB/T 17593-3:2006

Heavy Metals - Total

Cadmium (Cd) 7440-43-9 <40 mg/kg

Lead (Pb) 7439-92-1 <90 mg/kg

Substance CAS No. Limit Detection Limit Test Method

<0,5 µg/cm²/week EN 12472:2005 + A1:2009 and

Substance CAS No. Limit Detection Limit Test Method

Perfluorinated Compounds (PFCs)

N-Ethyl-heptadecafluorooctane sulfonamide (N-Et-FOSA) 4151-50-2

N-Methyl-heptadecafluorooctane sulfonamidoethanol (N-ME-FOSE) 24448-09-7

N-Ethyl-heptadecafluorooctane sulfonamidoethanol (N-ET-FOSE) 1691-99-2

Perfluorononanoic acids (PFNA) various

Substance CAS No. Limit Detection Limit Test Method

If Beilstein Test positive, should be

Bis-(2-ethylhexyl) phthalate (DEHP) 117-81-7

Substance CAS No. Limit Detection Limit Test Method

Polycyclic Aromatic Hydrocarbons (PAHs)

Halogenated terphenyls including polychlorinated

Alkylphenols (AP) and Alkylphenols Ethoxylates (APEOs) including all isomers

Nonylphenol (NP), 104-40-5

Dyes – Disperse (Sensitizing)

Disperse Blue 7 3179-90-6

Disperse Blue 26 3860-63-7

Disperse Blue 35 12222-75-2

Disperse Blue 106 12223-01-7

Disperse Blue 124 61951-51-7

Disperse Orange 1 2581-69-3

Disperse Orange 3 730-40-5

Disperse Orange 37/59/76 13301-61-6 Not Phase-out by 1

Disperse Red 1 2872-52-8

Disperse Red 11 2872-48-2

Disperse Red 17 3179-89-3

Disperse Yellow 1 119-15-3

Disperse Yellow 3 2832-40-8

Disperse Yellow 9 6373-73-5

Disperse Yellow 39 12236-29-2

Disperse Yellow 49 54824-37-2

Dyes - Navy Blue Colorants

Component 1: 118685-33-9 No intentional use.

Dyes - Carcinogenic or Equivalent Concern

Direct Black 38 1937-37-7

Direct Blue 6 2602-46-2

Acid Red 26 3761-53-3

Basic Red 9 569-61-9