Professional Documents
Culture Documents
Reverse Osmosis On Open Intake Seawater: Pre-Treatment Strategy
Reverse Osmosis On Open Intake Seawater: Pre-Treatment Strategy
Reverse Osmosis On Open Intake Seawater: Pre-Treatment Strategy
Abstract
Pre-treatment of seawater feeding reverse osmosis (RO) membranes is a key step in designing desalination
plants. The pre-treatment process must be adapted to the seawater quality to be treated (wells, open intake, etc.),
especially when treating surface seawater with highly variable quality. After a general presentation of different pre-
treatment options in relation to the seawater quality, this paper is focussing on two case studies, two open intake
seawater pre-treatment upstream reverse osmosis desalination. The first site is located in the Gulf of Oman (Indian
Ocean), the second in the Persian Gulf. The pre-treatment uses different technology strategies, conventional pre-
treatment (coagulation and direct filtration on dual media filters) and innovative technologies (high rate dissolved
air flotation, ultrafiltration and microfiltration) according to the water quality. The parameters taken into account
for the water quality characterisation are the suspended solids, turbidity, fouling tendency, organic matters and
algae content. This paper presents the pre-treated water quality achieved by the two types of pre-treatment and
discusses potential impacts on RO hydraulic performances.
Presented at the EuroMed 2004 conference on Desalination Strategies in South Mediterranean Countries: Cooperation
between Mediterranean Countries of Europe and the Southern Rim of the Mediterranean. Sponsored by the European
Desalination Society and Office National de l'Eau Potable, Marrakech, Morocco, 30 May-2 June, 2004.
0011-9164/04/$- See front matter © 2004 Elsevier B.V. All rights reserved
doi;10.1016/j.desa1.2004.06.128
192 E Bonndlye et al. / Desalination 167 (2004) 191-200
such cases, it is possible to achieve SDI15(15 min. clarification step (direct clarification or ultra-
SDI) below 3 [1] using sand filtration without filtration/microfiltration membranes) can be
coagulant, or even simple 5 ~tm cartridge filters. protected by complementary pre-treatment, such
Due to increasing plant size and the limited as sand removal, settling and/or flotation. The
permeability of local soils implying a need for limits of each treatment must be evaluated in terms
numerous wells, onshore beach wells are used of design, water quality and adaptation to a
with less and less frequency and SWRO plants pollution event.
are operated with direct feed from open seawater This paper presents the results of two pilot
intakes [2]. studies performed on open seawater intakes. The
On open seawater intake, reverse osmosis objectives were to assess the limit of each
membranes are sensitive to different types of technology and to explore the potential of
pollution: particles, precipitated metals, organic technology associations to increase the reliability
matters, hydrocarbons, etc. An efficient pre- of the whole open intake seawater pre-treatment
treatment must control the flux of each pollutant. upstream reverse osmosis desalination.
The pre-treatment must be designed to face the
worst water quality, providing a constant and good
2. Material and method
RO feed water quality.
Direct filtration, using mono or dual media, is Both pilot tests were conducted on an open
the most common technology used for the filtra- seawater intake. Sand removal was evaluated as
tion of seawater upstream RO desalination plant. a pre-treatment step, mainly on the Persian Gulf.
This technique must be optimised and improved For high suspended solids content, a dissolved air
on variable quality surface seawater: the coagula- flotation unit was tested for turbidity, oil and
tion can be improved by a better understanding grease removal on the same site. The high rate
of the phenomenon, the use of different chemicals. flotation unit includes a pressurized water generator
Selected media and filters characteristics can also and a 1 m 2 separation cell.
improve the performances of this clarification The direct filtration was then studied in one or
treatment. Direct filtration treatment is evaluated two stages, depending on the feed water quality,
in terms of filtered water quality, cycle duration, using pilot units with 4 filtering columns operated
maturation and risk of breakthrough. This treat- in parallel or in series. Transparent plastic columns
ment technology can be improved using a double were used to optimise the backwash sequences.
step filtration. The filtering media tested were from several
On open intake surface water treatment, well- origins, anthracite, pumice, sand and garnet,
optimised direct filtration can be replaced by allowing an evaluation in term of effective size,
membrane clarification, such as ultrafiltration or shape and density.
microfiltration [6]. Furthermore, the impact of a Two fully automated ultrafiltration units were
lower cutoff pre-treatment could lead to an used. These pilot units included the filtration
increase of the RO reliability. The design permeate system and automatic backwashes controlled by
flux rate could be higher than the generally a PLC.
recommended design average flux rate in seawater The reagents tested were usually chemicals
RO systems operating on surface seawater, which used in water clarification: sulphuric acid for pH
is within the 7-8 gfd range (11.9-13.6 L/h.m2)[3], correction, Fe or A1 salt as coagulants (FeCI 3,
and recovery (40-45%)[2,3]. WAC HB, Kemira PIX 123), organic coagulants
Finally, facing high turbid water, risk of algae as filter aid (Kemazur 4527, Nalco 8103 and 8105,
bloom and/or hydrocarbon pollution, the main RO Floe) and floceulent aids (AQnionic polymer
V. Bonndlye et al. / Desalination 167 (2004) 191-200 193
ASP25, trach). Powdered activated carbon was One WGS267 portable particle counter and in-
also evaluated for organic matter removal im- line Met One PCT.
provement, and chlorine for disinfection shocks
or continuous preoxidation, and membrane back-
wash. 3. Results
Several on-line equipments were used for the
3.1. The G u l f o f Oman
process control: flowmeter (ABB) and flow con-
trollers (Burkert), pressure sensors for the head- The first site evaluated was good surface
loss follow-up (Jumo). seawater, using only one pre-treatment stage
The suspended solids were evaluated in terms before RO. An 18-month pilot study was per-
of turbidity and particles count. Turbidity was formed on the pre-treatment to study and optimise
analysed both on grab samples (Hach 2100P) and the direct coagulation in term of chemicals and
in-line, using both Seres turbilight and Hach filter media characteristics. Two periods were
1720C turbidimeters on raw and filtered water. studied in 2002 and 2003 to take into account the
UV absorbance (at 254 nm) and TOC were water seasonal variability. This paper presents the
analysed to characterise the organic matters. These pilot study and the fisrt results of an industrial
analyses were completed by pyrolysis - - GCMS plant constructed based on the pilot results.
analysis to evaluate the organic matters com- The water quality main characteristics are
position. presented in Table 1: water was taken 4 m below
Phytoplankton was followed during the whole the sea surface. During the test period, the
study. following parameters remained almost constant:
SDI was measured using manual apparatus and pH, turbidity, conductivity, Fe, mineralisation,
an automatic Chemetek FPA-3300 Filter plugging algae, UV, and hydrocarbons. The water quality
analyzer. For filtered water and permeates the was generally very good with turbidity around 0.2
SDI]5 was determined according to ASTM D NTU and 70% of the SDI 5 below 6 (Fig. 1): no
4189-95 (15 min filtration in the 75% fouling relation seems to exist between those two param-
range). For raw water, the SDI yielding 75% eters. 75% of the particles were in 1-2 pm range.
membrane fouling was recorded (SDI 5 or SDI3). The temperature was high, but normal for this part
Particle count analysis was performed with a Met of the world.
20 -'-'--"~
..........................................................................................................
............ ....... 1.0
18 ,, I, ,: I er,,, I 0.9
" [m
'11 I '. I o•, I
16 ,' ~ , , 0.8
l llll I i
• I I I
14 ~ ,, , , 0.7
,, ,,', . ) ,I .
r. ,, ;~, ;, ,:. ;" t p-
12 -- 0.6
] 10
,. ~ ~, , ,: Z
II ~1 rill i II
0.5
II I ,I I I .I I II ~ [
U) 8 I 0.4
6 ,," .; "' ' " he .','.;J/S. 0.3
4 0.2
- ' "'" ) w 1"- v 'lfl
2 0.1
Date (mrn/yyyy)
0 Fig. 1. Evolutionof the turbidityand
01/2002 02/2002 0312002 04/2002 05/2002 0612002 0712002 SDI values.
194 V. Bonndlye et al. / Desalination 167 (2004) 191-200
Table 2
Filter medias tested (effective size ES in ram)
49 "r
4O
i
t-,
X 1 = Ill ~j ll _
¢3
15
~' VV \
40 pH pt
• ~r'tl .~ ~.~l.--~r , ,,
5
0 . SDI pt man. ,,
~o ~oo ~o 200 2~o 300 3~o 400 4~o
hours
Fig. 3. Full scale pre-treatment plant results in terms of SDI.
organic matters and suspended solids determined pre-treatment and ultrafiltration (UF) pre-
the choice o f pre-treatment before reverse treatment efficiencies prior to RO for desalting
osmosis, and the number of stage of the pre- seawater with high-fouling tendency. A four-stage
treatment. A four-month pilot study was conducted conventional pre-treatment process and two UF
on a variable seawater quality. The objective of processes were operated in parallel on open intake
this study was to assess and compare conventional seawater (Fig. 4).
The main characteristics of the raw seawater,
pumped 10 m below the sea surface (in a 15 m
Intake water deep area) are presented in Table 4. With
pump + pipe
an average turbidity around 0.7 NTU and algae
,, [
Sand/grit I
removaltank
~: ...... _ ......................................
Flotation I
AquaDAFTM ULTRAFILTRATION
~r
Dual*media I Ultraflltratlon 1 1
Filtration
Dual-media I I Ultraflltratlon2
Filtration
counts below 100 cell/mL, this surface seawater suspended solids, highly variable in this very
does not seem very difficult to treat, except shallow seawater intake (mainly during storm
regarding the SDI values, which are both events). UV absorbance removal was in 20-30%
permanently very high, and with wide fluctuations range (Fig. 6). Hydrocarbons were also well
(Fig. 5). removed when present in the suspension form,
The preliminary treatment, a dissolved air protecting the aim of the pre-treatment: the direct
flotation, allows a good removal of turbidity and filtration.
The direct filtration step included a double
Table 4 filtration with two coagulant injections: this
Raw water analysis treatment line was selected to take into account
the worst water quality expected in this surface
Parameters Average Min. Max. seawater. Media were chosen to improve both
Temperature, °C 32 32 35 filtration length and filtered water quality.
pH 8.18 8.08 8.26 The results obtained on the filtration pilot
Conductivity, mS/cm 62.7 62.2 63.4
Turbidity, NTU 0.74 0.48 1.13 during the 4-month period of operation yielding
SDI, %/min 21.7 10 45 rather good SDI (1.8-2.9 with incoming sea water
Total alkalinity, 123 122 125 SDI 10-45 %/min) (Table 5). Here also, the
mg/L CaCOa maturation was very short, and the risk of
Total hardness, 8027 8010 8040 breakthrough very low, due to the sticky nature
mg/LCaCO3 of the floe formed with the FeC13-floculant aid
TDS0 44.3 43 45.5
g/L (from conductivity) applied (Figs. 7 and 8). Filtering runs remained
UV absorbance,/m 1.3 0.9 2.2 longer than 24 h.
Algae, cell/ml 50 38 76 Ultrafiltration pre-treatment was evaluated in
* Temperature pH • SDI I
SO j • Turbidity - - ~-- UV absorbance i 5.0
45 • • 4.5
40 , -o •
i
4.0
35 *"w'r* '*r-*~"eT*: " -*** -'*'* * ] ~ N . '• *4*. ~m " ' ~ '** ,.at ~,..~LJli*t,.~ • • 3.5
E 10 ~-
~- 1.0
,- --'M,L- i L . W, __
0 0.0
Date (mm/dd)
Fig. 5. Raw water characteristics during the test period (temperature,pH, turbidity and UV absorbance).
198 V. Bonn~lye et aL / Desalination 167 (2004) 191-200
Flotation survey
30 3.0
I--
z
20
ti .°
15
ui
¢~
O1
E
~ ~o
t-
_ ~ v II I I Ill tr -.I 1.0
0
~ 5 0.5
, ~.~7 Q~,~
I
Fig. 7. Direct filtration optimisation - -
head losses and SDI follow up during a
filtering run using pumice and sand me-
ta 20 2 2 ~
dia, coagulation with ferric chlorine asso-
Backwash & Filter run time (hour)
Filtered to waste ciated with a coagulant aid.
V. Bonndlye et al. / Desalination 167 (2004) 191-200 199
40 . 2o
35
• --e-Sea ter •- 18
t] lst stage filtration i 16
3O I A 2nd stage filtration
~ 25
t" . . . . . ee -e - "eWe-e e~ 12~.
~ 2o ~ . ' .
"~' • O° •
.. o
•
- .
--
•
|
g) is -" .': -- : - - • • --@ "-. : : = -- -T
• • n Q 04
• • " • °° • "• . . • e• [] a •'°%[] 16
lO
5
2
o I I I I-0
o
o 8 o
Date (mmmldd)
Fig. 8. SDI value in the raw water in each of the dual media filtered water.
High filtration flux was obtained on the thracite as top layer media). The coagulation strategy
pressurized in-out Aquasource membranes, what- optimised during the pilot test includes a double
ever the feed water quality (120-140 L/h/m: in coagulant injection during the worst period (SDI
dead-end filtration). higher than 8) and adapted coagulation pH to the
fouling tendency of the ferric hydroxide formed.
In the case of more degraded water, with a high
4. Discussion
water quality variability expected, and to face
The two seawaters tested can be characterised pollution events (in terms of turbidity, algae bloom
by a low turbidity and low organic content: the or hydrocarbons), the association of dissolved air
main differences observed during the pilot studies flotation with double direct filtration gives a very
are the SDI value range and variability (Fig. 9). efficient and reliable pre-treatment upstream
The Persian Gulf surface water has a high and reverse osmosis: the treatment line is more robust
unstable SDI. Some very high turbidity peaks, and and able to handle very bad water quality. In this
some hydrocarbon pollutions are also reported. case again, filter's media and coagulation chemicals
The pre-treatment must be adapted to the surface and conditions must be optimised to reach low
seawater characteristics, and must be able to face and steady SDI in the filtered water. Alternative
the degraded periods. clarification treatment using membranes (ultra-
A single stage direct filtration using dual media filtration or microfiltration) gives similar treated
is well adapted to the good surface seawater en- water quality. The remaining question being the
countered in the Gulf of • m a n . In this case, the SDI adaptation to characterise the fouling potential
filtration media must be selected to optimise both of a permeated water.
filtered water quality (using a low effective size sand These very good values on both conventional
or garnet) and filtration duration (pumice or an- and membrane treatments should result in both
200 E Bonndlye et al. / Desalination 167 (2004) 191-200
50
45 k
40 a
35
~. 30
•-~ : • ~ •
low cartridge consumption and long time between demonstrate the reliability and robustness of such
cleanings, then long expected life of the reverse treatment facing variable surface seawater.
osmosis membranes.
References
5. Conclusion
[ 1] M.A. Galloway and J.G Minnery, Ultrafiltration as pre-
The pilot testing during 9 months on the Gulf treatment to seawater reverse osmosis, Proc. 2001
of Oman, which was paramount to optimise the AWWA Membrane Conference, San Antonio, TX,
pre-treatment stage and the chemical regime in 2001, 10 p.
relation to the seawater quality improves the [2] N. Wade and K. Callister, Desalination: the state of
art, J. CIWEM, 11 April (1997) 87-97.
optimisation of the process. The results were used [3] M. Wilfand M.K. Schierach, Improved performance
for the commissioning of the full industrial plant, and cost reduction of RO sweater systems using UF
a 37.5 MGD open seawater intake desalination pretreatment, Desalination, 135 (2001) 61--68.
plant located in Fujairah. Preliminary full-scale [4] S.C.J.M. van Hoof, A. Hashim and A.J. Kordes, The
plant results demonstrate that the foreseen per- effect of ultrafiltration as pretreatment to reverse
osmosis in wastewater reuse and seawater desalination
formance and water quality are being achieved.
applications, Desalination, 124 (1999) 231-242.
In the Persian Gulf, on a rather bad surface [5] A. Teuler, K. Glucina and J.M. Laln6, Assessment of
seawater intake, the pre-treatment including UF pretreatment prior RO membranes for seawater
dissolved air flotation, direct filtration or ultra- desalination, Desalination, 125 (1999) 89-96.
filtration, gives good results in terms of turbidity, [6] V. Borm61ye, A. Brehant, M.A. Sanz and M. Perez,
algae and hydrocarbon removal, leading to a Surface seawater pre-treatment upstream reverse
osmosis: long term test using ultrafiltmtion membranes,
reliable SDI far bellow 3 value. Proc. IDA World Congress, Nassau, Bahamas, Sept.
These pilot tests improve the knowledge of 2003, 15 p.
surface seawater treatment upstream RO and