CBSE 2020 12 Chemistry

H$moS> Z§.
Code No. 56/1/1

amob Z§. narjmWu H$moS >H$mo CÎma-nwpñVH$m Ho$ _wI-n¥ð
Roll No. >na Adí` {bIo§ &
Candidates must write the Code on the
title page of the answer-book.
ZmoQ> NOTE
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n¥ð> 19 h¢ & paper contains 19 printed pages.
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{bI| & should be written on the title page of
the answer-book by the candidate.
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>37 àíZ h¢ & paper contains 37 questions.
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Adí` {bI| & answer-book before attempting it.
(V) Bg àíZ-nÌ H$mo n‹T>Zo Ho$ {bE 15 {_ZQ >H$m (V) 15 minute time has been allotted to
g_` {X`m J`m h¡ & àíZ-nÌ H$m {dVaU read this question paper. The
nydm©• _| 10.15 ~Oo {H$`m OmEJm & question paper will be distributed
10.15 ~Oo go 10.30 ~Oo VH$ N>mÌ Ho$db at 10.15 a.m. From 10.15 a.m. to
10.30 a.m., the students will
àíZ-nÌ H$mo n‹T>|Jo Am¡a Bg Ad{Y Ho$ Xm¡amZ read the question paper only and
do CÎma-nwpñVH$m na H$moB© CÎma Zht {bI|Jo & will not write any answer on the
answer-book during this period.
agm`Z {dkmZ (g¡ÕmpÝVH$)

CHEMISTRY (Theory)
{ZYm©[aV g_` : 3 KÊQ>o A{YH$V_ A§H$ : 70

Time allowed : 3 hours Maximum Marks : 70
.56/1/1 1 P.T.O.
gm_mÝ` {ZX}e :
{ZåZ{b{IV {ZX}em| H$mo ~hþV gmdYmZr go n{‹T>E Am¡a CZH$m g™Vr go nmbZ H$s{OE :
(i) `h àíZ-nÌ Mma IÊS>m| _| {d^m{OV {H$`m J`m h¡ – H$, I, J Ed§ K & Bg àíZ-nÌ _|
37 àíZ h¢ & g^r àíZ A{Zdm`© h¢ &
(ii) IÊS> H$ _| àíZ g§»`m 1 go 20 VH$ A{V bKw-CÎmar` àH$ma Ho$ àíZ h¢, àËòH$ àíZ 1 A§H$ H$m
h¡ & àËòH$ àíZ H$m CÎma EH$ eãX `m EH$ dmŠ` _| Xr{OE &
(iii) IÊS> I _| àíZ g§»`m 21 go 27 VH$ bKw-CÎmar` àH$ma Ho$ àíZ h¢, àËòH$ àíZ 2 A§H$m| H$m
h¡ &
(iv) IÊS> J _| àíZ g§»`m 28 go 34 VH$ XrK©-CÎmar` àH$ma-I Ho$ àíZ h¢, àËòH$ àíZ 3 A§H$m| H$m
h¡ &
(v) IÊS> K _| àíZ g§»`m 35 go 37 VH$ XrK©-CÎmar` àH$ma-II Ho$ àíZ h¢, àËòH$ àíZ 5 A§H$m| H$m
h¡ &
(vi) àíZ-nÌ _| H$moB© g_J« {dH$ën Zht h¡ & VWm{n, Xmo-Xmo A§H$m| Ho$ Xmo àíZm| _|, VrZ-VrZ A§H$m| Hoo$
Xmo àíZm| _| VWm nm±M-nm±M A§H$m| Ho$ VrZm| àíZm| _| AmÝV[aH$ {dH$ën {X`m J`m h¡ & Eogo àíZm| _|
go Ho$db EH$ hr {dH$ën H$m CÎma Xr{OE &
(vii) BgHo$ A{V[aº$, Amdí`H$VmZwgma, àËòH$ IÊS> Am¡a àíZ Ho$ gmW `Wmo{MV {ZX}e {XE JE h¢ &
(viii) Ho$ëHw$boQ>a AWdm bm°J Q>o~b Ho$ à`moJ H$s AZw_{V Zht h¡ &
IÊS> H$
{XE JE AZwÀN>oX H$mo n{‹T>E VWm àíZ g§»`m 1 go 5 Ho$ CÎma Xr{OE : 15=5
EopëH$b h¡bmBS>m| H$s à{VñWmnZ A{^{H«$`m _w»`V`m SN1 AWdm SN2 {H«$`m{d{Y Ûmam
hmoVr h¡ & à{VñWmnZ A{^{H«$`mE± hmoZo Ho$ {bE EopëH$b h¡bmBS> {H$gr ^r {H«$`m{d{Y H$mo
AnZmE±, CZHo$ {bE H$m~©Z h¡bmoOZ Am~ÝY H$s Y«wdUVm hr CÎmaXm`r hmoVr h¡ & SN1
A{^{H«$`mAm| H$m doJ H$m~m}H¡$Q>m`Z Ho$ ñWm{`Ëd na {Z^©a H$aVm h¡ O~{H$ SN2
A{^{H«$`mAm| H$m {Ì{d_{dÝ`mg H$maH$ na & `{X Amapå^H$ nXmW© {H$aob `m¡{JH$ hmo, Vmo
CËnmX `m Vmo à{Vbmo{_V hmoJm AWdm ao{g{_H$ {_lU, Omo EopëH$b h¡bmBS>m| Ûmam AnZmB© JB©
{H«$`m{d{Y Ho$ àH$ma na {Z^©a H$aVm h¡ & B©Wam| H$m HI go {dXbZ ^r {Ì{d_{dÝ`mg H$maH$
Am¡a H$m~m}H¡$Q>m`Z Ho$ ñWm{`Ëd go {Z`pÝÌV hmoVm h¡, Omo Bg ~mV H$m ÚmoVH$ h¡ {H$ H$m~©{ZH$
agm`Z _| `hr Xmo à_wI H$maH$ h¢ Omo h_| ghm`Vm H$aVo h¢ {H$ CËnmX {H$g àH$ma H$m
~ZoJm ?
.56/1/1 2
General Instructions :
Read the following instructions very carefully and strictly follow them :
(i) This question paper comprises four Sections – A, B, C and D. There are
37 questions in the question paper. All questions are compulsory.
(ii) Section A – Questions no. 1 to 20 are very short answer type questions,
carrying 1 mark each. Answer these questions in one word or one sentence.
(iii) Section B – Questions no. 21 to 27 are short answer type questions, carrying
2 marks each.
(iv) Section C – Questions no. 28 to 34 are long answer type-I questions, carrying
3 marks each.
(v) Section D – Questions no. 35 to 37 are long answer type-II questions, carrying
5 marks each.
(vi) There is no overall choice in the question paper. However, an internal choice
has been provided in 2 questions of two marks, 2 questions of three marks and
all the 3 questions of five marks. You have to attempt only one of the choices in
such questions.
(vii) In addition to this, separate instructions are given with each section and
question, wherever necessary.
(viii) Use of calculators and log tables is not permitted.
SECTION A
Read the given passage and answer the questions number 1 to 5 that follow : 15=5
The substitution reaction of alkyl halide mainly occurs by SN1 or SN2

mechanism. Whatever mechanism alkyl halides follow for the
substitution reaction to occur, the polarity of the carbon halogen bond is
responsible for these substitution reactions. The rate of SN1 reactions are
governed by the stability of carbocation whereas for SN2 reactions steric
factor is the deciding factor. If the starting material is a chiral compound,
we may end up with an inverted product or racemic mixture depending
upon the type of mechanism followed by alkyl halide. Cleavage of ethers
with HI is also governed by steric factor and stability of carbocation,
which indicates that in organic chemistry, these two major factors help
us in deciding the kind of product formed.
.56/1/1 3 P.T.O.
1. ~ZZo dmbo CËnmX H$s {Ì{d_agm`Z H$s àmJw{º$ H$s{OE `{X H$moB© Y«wdU KyU©H$ (àH$meV:
g{H«$`) EopëH$b h¡bmBS> SN1 {H«$`m{d{Y go à{VñWmnZ A{^{H«$`m gånÞ H$aVm h¡ &
2. Cg `§Ì H$m Zm_ ~VmBE Omo Cg H$moU Ho$ _mnZ Ho$ {bE à`wº$ hmoVm h¡ {Og na g_Vb
Y«w{dV àH$me Ky{U©V hmo OmVm h¡ &
3. _w»` CËnmX H$s àmJw{º$ H$s{OE O~ 2-~«mo_monoÝQ>oZ, EoëH$mohm°br KOH Ho$ gmW A{^{H«$`m
H$aVm h¡ &
4. CHI3 H$m EH$ Cn`moJ Xr{OE &
5. CZ CËnmXm| H$s g§aMZmE± {b{IE O~ Eo{Zgmob H$mo HI Ho$ gmW A{^{H«${`V {H$`m OmVm h¡ &
àíZ g§»`m 6 go 10 EH$ eãX CÎmar¶ h¢ : 15=5
6. `{X Ðd A Am¡a B Ho$ ŠdWZm§H$ H«$_e: 140C Am¡a 180C h¢, Vmo Cg Ðd H$s nhMmZ
H$s{OE {OgH$m 90C na dmîn Xm~ CƒVa hmoJm &
7. bmoho H$s dñVwAm| H$mo gwa{jV aIZo Ho$ {bE qµOH$ VWm {Q>Z _| go {H$gH$s H$moqQ>J ~ohVa h¡ ?
8. Š`m {H$gr A{^{H«$`m H$m doJ pñWam§H$ T na {Z^©a H$aoJm `{X A{^{H«$`m H$s Eact (g{H«$Ù
D$Om©) eyÝ` hmo ?
9. PVC Ho$ EH$bH$ H$s g§aMZm Xr{OE &
10. {H$gr An_mO©H$ _| CnpñWV H$m¡Z-gr g§aMZmË_H$ BH$mB© CgH$mo AO¡d{ZåZrH$aUr` ~Zm XoVr
h¡ ?
àíZ g§»`m 11 go 15 ~hþ{dH$ënr¶ àíZ h¢ : 15=5
11. Obr` {db`Z _| {ZåZ{b{IV _| go à~bV_ jma h¡

(A) _o{WbEo_rZ
(B) S>mB_o{WbEo_rZ
(C) Q´>mB_o{WbEo_rZ
(D) Eo{ZbrZ
.56/1/1 4
1. Predict the stereochemistry of the product formed if an optically active
alkyl halide undergoes substitution reaction by SN1 mechanism.
2. Name the instrument used for measuring the angle by which the plane
polarised light is rotated.
3. Predict the major product formed when 2-Bromopentane reacts with

alcoholic KOH.
4. Give one use of CHI3.
5. Write the structures of the products formed when anisole is treated with
HI.
Questions number 6 to 10 are one word answers : 15=5
6. Identify which liquid will have a higher vapour pressure at 90C if the
boiling points of two liquids A and B are 140C and 180C, respectively.
7. Out of zinc and tin, whose coating is better to protect iron objects ?
8. Will the rate constant of the reaction depend upon T if the Eact
(activation energy) of the reaction is zero ?
9. Give the structure of the monomer of PVC.
10. Which structural unit present in a detergent makes it non-biodegradable ?
Questions number 11 to 15 are multiple choice questions : 15=5
11. Out of the following, the strongest base in aqueous solution is
(A) Methylamine
(B) Dimethylamine
(C) Trimethylamine
(D) Aniline
.56/1/1 5 P.T.O.
12. {ZåZ{b{IV _| go {H$gHo$ Ûmam Am`moS>mo\$m°_© narjU Zht {X`m OmVm h¡ ?
(A) EWoZm°b
(B) EWoZ¡b
(C) noÝQ>oZ-2-AmoZ
(D) noÝQ>oZ-3-AmoZ
13. {ZåZ{b{IV g§H«$_U VÎdm| _| go {H$gHo$ Ûmam A{YH$V_ Am°ŠgrH$aU AdñWmE± àX{e©V H$s
OmVr h¢ ?
(A) Sc (Z = 21)
(B) Cr (Z = 24)
(C) Mn (Z = 25)
(D) Fe (Z = 26)
14. M_© g§ñH$aU CÚmoJ _| M_© H$m H$R>moa hmoZm {Z^©a H$aVm h¡
(A) d¡ÚwV H$U-g§MbZ na
(B) {dÚwV²-namgaU na
(C) nmañn[aH$ ñH§$XZ na
(D) {Q>ÝS>b à^md na
15. {XE JE `m¡{JH$ H$m ghr AmB©.`y.nr.E.gr. Zm_ Š`m h¡ ?
(A) 2,2-S>mB_o{Wbã`yQ>oZm°BH$ Aåb

(B) 2-H$m~m}pŠgb-2-_o{Wbã`yQ>Z
o
(C) 2-Eo{Wb-2-_o{WbàmonoZm°BH$ Aåb
(D) 3-_o{Wbã`yQ>oZ H$m~m}pŠg{bH$ Aåb
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12. Iodoform test is not given by
(A) Ethanol
(B) Ethanal
(C) Pentan-2-one
(D) Pentan-3-one
13. Out of the following transition elements, the maximum number of

oxidation states are shown by
(A) Sc (Z = 21)
(B) Cr (Z = 24)
(C) Mn (Z = 25)
(D) Fe (Z = 26)
14. Hardening of leather in tanning industry is based on

(A) Electrophoresis
(B) Electro-osmosis
(C) Mutual coagulation
(D) Tyndall effect
15. What is the correct IUPAC name of the given compound ?
(A) 2,2-Dimethylbutanoic acid

(B) 2-Carboxyl-2-methylbutane
(C) 2-Ethyl-2-methylpropanoic acid
(D) 3-Methylbutane carboxylic acid
.56/1/1 7 P.T.O.
àíZ g§»`m 16 go 20 Ho$ {bE, Xmo H$WZ {XE JE h¢ {OZ_| EH$ H$mo A{^H$WZ (A) VWm Xÿgao
H$mo H$maU (R) Ûmam A§{H$V {H$`m J`m h¡ & BZ àíZm| Ho$ ghr CÎma ZrMo {XE JE H$mo S>m| (i),
(ii), (iii) Am¡a (iv) _| go MwZH$a Xr{OE : 15=5
(i) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr H$WZ h¢ Am¡a H$maU (R), A{^H$WZ (A)
H$s ghr ì¶m»¶m h¡ &
(ii) A{^H$WZ (A) Am¡a H$maU (R) XmoZm| ghr H$WZ h¢, naÝVw H$maU (R),
A{^H$WZ (A) H$s ghr ì¶m»¶m Zht h¡ &
(iii) A{^H$WZ (A) ghr h¡, naÝVw H$maU (R) µJbV H$WZ h¡ &
(iv) A{^H$WZ (A) µJbV h¡, naÝVw H$maU (R) ghr H$WZ h¡ &
16. A{^H$WZ (A) : Au Am¡a Ag H$m {ZîH$f©U CZHo$ A`ñH$m| Ho$ NaCN Ho$ VZw {db`Z Ûmam
{ZjmbZ go {H$`m OmVm h¡ &
H$maU (R) : BZ A`ñH$m| go g§~Õ Aew{Õ`m± NaCN _| Kwb OmVr h¢ &
17. A{^H$WZ (A) : F2 AUw _| F – F Am~ÝY Xþ~©b hmoVm h¡ &
H$maU (R) : F na_mUw H$m AmH$ma N>moQ>m hmoVm h¡ &
18. A{^H$WZ (A) : Cnghg§`moOZ `m¡{JH$m| _| C^`X§Vr g§b½Zr Ho$ H$maU ~ÝYZr g_md`dVm
CËnÞ hmoVr h¡ &
H$maU (R) : C^`X§Vr g§b½Zr O¡go NO2 _| Xmo {^Þ XmVm na_mUw N Am¡a O hmoVo h¢ &
19. A{^H$WZ (A) : gyH«$mog EH$ AZnM`r eH©$am h¡ &
H$maU (R) : gyH«$mog _| ½bmBH$mo{g{S>H$ ~§Y hmoVm h¡ &
20. A{^H$WZ (A) : A{^{H«$`m H2 + Br2  2HBr _| AmpÊdH$Vm 2 àVrV hmoVr h¡ &
H$maU (R) : Xr hþB© àmW{_H$ A{^{H«$`m _| A{^H$maH$m| Ho$ Xmo AUw ^mJ boVo h¢ &
IÊS> I
21. {ZåZ{b{IV nXm| H$s n[a^mfm {b{IE : 12=2
(a) àem§VH$
(b) ny{VamoYr
AWdm
gm~wZm| H$s emoYZ {H«$`m g_PmBE & 2
.56/1/1 8
For questions number 16 to 20, two statements are given  one labelled
Assertion (A) and the other labelled Reason (R). Select the correct
answer to these questions from the codes (i), (ii), (iii) and (iv) as given
below : 15=5
(i) Both Assertion (A) and Reason (R) are correct statements, and
Reason (R) is the correct explanation of the Assertion (A).
(ii) Both Assertion (A) and Reason (R) are correct statements, but
Reason (R) is not the correct explanation of the Assertion (A).
(iii) Assertion (A) is correct, but Reason (R) is incorrect statement.
(iv) Assertion (A) is incorrect, but Reason (R) is correct statement.
16. Assertion (A) : Au and Ag are extracted by leaching their ores with a dil.
solution of NaCN.
Reason (R) : Impurities associated with these ores dissolve in NaCN.
17. Assertion (A) : F – F bond in F2 molecule is weak.

Reason (R) : F atom is small in size.
18. Assertion (A) : Linkage isomerism arises in coordination compounds

because of ambidentate ligand.
Reason (R) : Ambidentate ligand like NO2 has two different donor
atoms i.e., N and O.
19. Assertion (A) : Sucrose is a non-reducing sugar.

Reason (R) : Sucrose has glycosidic linkage.
20. Assertion (A) : The molecularity of the reaction H2 + Br2  2HBr

appears to be 2.
Reason (R) : Two molecules of the reactants are involved in the given
elementary reaction.
SECTION B
21. Define the following terms : 12=2
(a) Tranquilizers
(b) Antiseptic
OR
Explain the cleansing action of soaps. 2
.56/1/1 9 P.T.O.
22. 300 K na `y[a`m (‘moba Ðì¶‘mZ = 60 g/mol) Ho$ 5% {db`Z H$m namgaU Xm~
n[aH${bV H$s{OE & [R = 0·0821 L atm K–1 mol–1] 2
AWdm
{dem Zo Xmo Obr` {db`Z, EH$ _| 100 g Ob _| `y[a`m (‘moba Ðì¶‘mZ = 60 g/mol) Ho$
7·5 g Am¡a Xÿgao _| {H$gr nXmW© Z Ho$ 42·75 g, 100 g Ob _| {bE & `h ào{jV {H$`m
J`m {H$ XmoZm| {db`Z EH$g_mZ Vmn na {h_r^yV hþE & Z H$m _moba Ðì`_mZ n[aH${bV
H$s{OE & 2
23. A{^H$maH$ H$s gmÝÐVm Am¡a g_` Ho$ ~rM {XE JE J«m\$ H$m {díbofU H$s{OE & 12=2
(a) A{^{H«$`m H$s H$mo{Q> H$s àmJw{º$ H$s{OE &>

(b) g¡ÕmpÝVH$ Ñ{ï> go Š`m AZ§VH$mb Ho$ ~mX {H$gr A{^H$maH$ H$s gmÝÐVm KQ>H$a eyÝ`
hmo gH$Vr h¡ ? ì`m»`m H$s{OE &
24. {ZåZ{b{IV AUwAmo§ H$s AmH¥${V It{ME : 12=2

(a) XeOF4
(b) BrF3
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22. For a 5% solution of urea (Molar mass = 60 g/mol), calculate the osmotic
pressure at 300 K. [R = 0·0821 L atm K–1 mol–1] 2
OR
Visha took two aqueous solutions — one containing 7·5 g of urea (Molar
mass = 60 g/mol) and the other containing 42·75 g of substance Z in
100 g of water, respectively. It was observed that both the solutions froze
at the same temperature. Calculate the molar mass of Z. 2
23. Analyse the given graph, drawn between concentration of reactant vs.
time. 12=2
(a) Predict the order of reaction.
(b) Theoretically, can the concentration of the reactant reduce to zero

after infinite time ? Explain.
24. Draw the shape of the following molecules : 12=2
(a) XeOF4
(b) BrF3
.56/1/1 11 P.T.O.
25. {ZåZ{b{IV `m¡{JH$m| Ho$ gyÌ Xr{OE : 12=2
(a) nmoQ>¡{e`_ Q>oQ´>mhmBS´>mopŠgS>mo{µO§Ho$Q> (II)
(b) hoŠgmEoå_rZßb¡{Q>Z_ (IV) ŠbmoamBS>
26. Š`m hmoVm h¡ O~

(a) àmonoZmoZ H$mo _o{Wb_¡½Zr{e`_ Am`moS>mBS> Ho$ gmW A{^{H«${`V H$aHo$ Ob-AnK{Q>V
{H$`m OmVm h¡, Am¡a >
(b) ~oÝµOrZ H$mo {ZO©b AlCl3 H$s CnpñW{V _| CH3COCl Ho$ gmW A{^{H«${`V {H$`m
OmVm h¡ & 12=2
27. {ZåZ{b{IV ~hþbH$m| _| EH$bH$m| Ho$ Zm_ Am¡a g§aMZmE± {b{IE : 12=2
(a) ~¡Ho$bmBQ>
(b) {ZAmoàrZ
IÊS> J
1
28. {ZåZ{b{IV A{^{H«$`mAm| Ho$ AZwH«$_ _| A Am¡a B H$s g§aMZmE± Xr{OE : 6=3
2
NH3 NaOBr
(a) CH3COOH  
 A   B

Fe / HCl NaNO  HCl

(b) C6H5NO2  A  2  B
0 –5C
+ CuCN H O / H
(c) C6H5N2Cl  A 2 
    B

AWdm
(a) {ZåZ{b{IV `wJbm| Ho$ `m¡{JH$m| Ho$ ~rM Amn {dôX H¡$go H$a|Jo : 12=2
(i) Eo{ZbrZ Am¡a EWoZo_rZ

(ii) Eo{ZbrZ Am¡a N-_o{WbEo{ZbrZ
(b) {ZåZ{b{IV `m¡{JH$m| H$mo CZHo$ ŠdWZm§H$ Ho$ KQ>Vo hþE H«$_ _| ì`dpñWV H$s{OE : 1
ã`yQ>oZm°b, ã`yQ>oZo_rZ, ã`yQ>oZ
.56/1/1 12
25. Give the formulae of the following compounds : 12=2
(a) Potassium tetrahydroxidozincate (II)
(b) Hexaammineplatinum (IV) chloride
26. What happens when
(a) Propanone is treated with methylmagnesium iodide and then

hydrolysed, and
(b) Benzene is treated with CH3COCl in presence of anhydrous
AlCl3 ? 12=2
27. Write the names and structures of monomers in the following polymers :
12=2
(a) Bakelite
(b) Neoprene
SECTION C
1
28. Give the structures of A and B in the following sequence of reactions : 6=3
2
NH3 NaOBr
(a) CH3COOH   A  B

(b) C6H5NO2  A  2  B
0 –5C
+ CuCN H O / H
(c) C6H5N2Cl  A 2 
    B

OR
(a) How will you distinguish between the following pairs of
compounds : 12=2
(i) Aniline and Ethanamine
(ii) Aniline and N-methylaniline
(b) Arrange the following compounds in decreasing order of their

boiling points : 1
Butanol, Butanamine, Butane
.56/1/1 13 P.T.O.
29. {ZåZ{b{IV Ho$ {bE {dídgZr` ñnîQ>rH$aU Xr{OE : 13=3
(a) ½byH$mog 2,4-S>r.EZ.nr. narjU Zht XoVm &
(b) DNA Ho$ Xmo aÁOwH$ g_mZ Zht hmoVo, naÝVw EH$-Xÿgao Ho$ nyaH$ hmoVo h¢ &
(c) ñQ>mM© Am¡a gobwbmog XmoZm| _| EH$bH$m| Ho$ ê$n _| ½byH$mog BH$mB© hmoVr h¡ , {\$a ^r do
g§aMZmË_H$ Ñ{îQ> go {^Þ h¢ &
30. {ZåZ{b{IV Ho$ H$maU Xr{OE : 13=3
(a) gëâ`yag Aåb EH$ AnMm`H$ h¡ &
(b) âbwAmoarZ Ho$db EH$ Am°ŠgmoAåb ~ZmVr h¡ &
(c) CËH¥$îQ> J¡gm| Ho$ ŠdWZm§H$ He go Rn VH$ ~‹T>Vo h¢ &>
AWdm
{ZåZ{b{IV amgm`{ZH$ A{^{H«$`mAm| H$mo nyU© H$s{OE : 13=3
(a) MnO2 + 4 HCl 

(b) XeF6 + KF 
(c) I – (aq) + H+ (aq) + O2 (g) 
31. {ZåZ{b{IV H$s ^y{_H$m H$s ì`m»`m H$s{OE : 13=3
(a) ZnS Am¡a PbS H$mo n¥WH²$ H$aZo _| NaCN H$s &
(b) Aew{Õ Ho$ ê$n _| bm¡h`wº$ Cu Ho$ YmVwH$_© _| SiO2 H$s &
(c) Ti Ho$ n[aîH$aU _| Am`moS>rZ H$s &
32. ^m¡{VH$ A{YemofU Am¡a agmodemofU _| {dôX Ho$ VrZ {~ÝXþ Xr{OE & 3
33. A{^{H«$¶m H$m doJ {H$g àH$ma à^m{dV hmoJm O~

(a) A{^H$maH$ H$m n¥îR>r` joÌ\$b H$_ H$a {X`m OmE,
(b) CËH«$_Ur` A{^{H«$`m _| CËàoaH$ {_bm {X`m OmE, Am¡a
(c) A{^{H«$`m H$m Vmn ~‹T>m {X`m OmE ? 13=3
34. 75 g Eogr{Q>H$Aåb _| Kmobo OmZo dmbr EoñH$m°{~©H$ Aåb

(‘moba Ðì¶‘mZ = 176 g mol–1) H$s _mÌm (Ðì`_mZ) n[aH${bV H$s{OE {Oggo BgH$m
{h_m§H$ 1·5C H$_ hmo OmE & (Kf = 3·9 K kg mol–1) 3
.56/1/1 14
29. Give the plausible explanation for the following : 13=3
(a) Glucose doesn’t give 2,4-DNP test.
(b) The two strands in DNA are not identical but are complementary.
(c) Starch and cellulose both contain glucose unit as monomer, yet
they are structurally different.
30. Account for the following : 13=3

(a) Sulphurous acid is a reducing agent.
(b) Fluorine forms only one oxoacid.
(c) Boiling point of noble gases increases from He to Rn.
OR
Complete the following chemical reactions : 13=3
(a) MnO2 + 4 HCl 
(b) XeF6 + KF 
(c) I – (aq) + H+ (aq) + O2 (g) 
31. Explain the role of the following : 13=3
(a) NaCN in the separation of ZnS and PbS.

(b) SiO2 in the metallurgy of Cu containing Fe as impurity.
(c) Iodine in the refining of Ti.
32. Give three points of difference between physisorption and chemisorption. 3
33. How will the rate of the reaction be affected when

(a) Surface area of the reactant is reduced,
(b) Catalyst is added in a reversible reaction, and
(c) Temperature of the reaction is increased ? 13=3
34. Calculate the mass of ascorbic acid (Molar mass = 176 g mol–1) to be
dissolved in 75 g of acetic acid, to lower its freezing point by 1·5C.
(Kf = 3·9 K kg mol–1) 3
.56/1/1 15 P.T.O.
IÊS> K
35. (a) A{^{H«$¶m
Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s)
Ho$ {bE G n[aH${bV H$s{OE & 3
{X`m J`m h¡ : Zn2+/Zn Ho$ {bE E = – 0·76 V
Cu2+/Cu Ho$ {bE E = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1.
(b) BªYZ gobm| Ho$ Xmo bm^ Xr{OE & 2
AWdm
(a) {ZåZ{b{IV `wJbm| _| go, H$maU g{hV Cg EH$ H$s àmJw{º$ H$s{OE Omo {dÚwV² Ymam
H$s A{YH$ _mÌm Ho$ MmbZ H$s AZw_{V XoVm h¡ : 13=3
(i) 30C na Mm±Xr H$m Vma AWdm 60C na Mm±Xr H$m Vma &
(ii) 0·1 M CH3COOH {db`Z AWdm 1 M CH3COOH {db`Z &
(iii) 20C na KCl {db`Z AWdm 50C na KCl {db`Z &
(b) {dÚwV²-amgm`{ZH$ gob Am¡a {dÚwV²-AnKQ>Zr gob Ho$ _Ü` A§Va Ho$ Xmo {~ÝXþ Xr{OE & 2
36. (a) {ZåZ{b{IV Ho$ H$maU {b{IE : 13=3

(i) H$m°na (I) `m¡{JH$ g\o$X hmoVo h¢ O~{H$ H$m°na (II) `m¡{JH$ a§JrZ hmoVo h¢ &
(ii) H«$mo_oQ> AnZm a§J Aåbr` {db`Z _| n[ad{V©V H$a XoVo h¢ &
(iii) Zn, Cd, Hg d-ãbm°H$ VÎd Vmo _mZo OmVo h¢ naÝVw g§H«$_U VÎd Zht &
(b) Co Am¡a Co2+ Ho$ BboŠQ´>m°{ZH$ {dÝ`mg {bIH$a Co2+ (Z = 27) Ho$ {bE
àMH«$U-_mÌ AmKyU© n[aH${bV H$s{OE & 2
AWdm
(a) b¡ÝWoZm°`S>m| Am¡a EopŠQ>Zm°`S>m| Ho$ _Ü` A§Va Ho$ VrZ {~ÝXþ Xr{OE & 3
(b) H$maU XoVo hþE EH$ na_mUw/Am`Z N>m±{Q>E Omo nyN>m J`m JwUY_© Xem©Vm hmo : 12=2
(i) Sc3+ AWdm Cr3+ (à{VMwå~H$s` ì`dhma Xem©Vm h¡)
(ii) Cr AWdm Cu (Cƒ JbZm§H$ Am¡a ŠdWZm§H$)
.56/1/1 16
SECTION D
35. (a) Calculate G for the reaction
Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s). 3

Given : E for Zn2+/Zn = – 0·76 V and
E for Cu2+/Cu = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1.
(b) Give two advantages of fuel cells. 2

OR
(a) Out of the following pairs, predict with reason which pair will
allow greater conduction of electricity : 13=3
(i) Silver wire at 30C or silver wire at 60C.
(ii) 0·1 M CH3COOH solution or 1 M CH3COOH solution.
(iii) KCl solution at 20C or KCl solution at 50C.
(b) Give two points of differences between electrochemical and

electrolytic cells. 2
36. (a) Account for the following : 13=3

(i) Copper (I) compounds are white whereas Copper (II)
compounds are coloured.
(ii) Chromates change their colour when kept in an acidic
solution.
(iii) Zn, Cd, Hg are considered as d-block elements but not as
transition elements.
(b) Calculate the spin-only moment of Co2+ (Z = 27) by writing the
electronic configuration of Co and Co2+. 2
OR
(a) Give three points of difference between lanthanoids and actinoids. 3
(b) Give reason and select one atom/ion which will exhibit asked
property : 12=2
(i) Sc3+ or Cr3+ (Exhibit diamagnetic behaviour)
(ii) Cr or Cu (High melting and boiling point)
.56/1/1 17 P.T.O.
37. (a) t-ã`y{Q>b EoëH$mohm°b Am¡a n-ã`yQ>oZm°b _| go H$m¡Z-gm Aåb CËào[aV {ZO©bZ Vrd«Vm go
XoJm Am¡a Š`m| ? 2
(b) {ZåZ{b{IV ê$nmÝVaU gånÞ H$s{OE : 13=3
(i) µ\$sZm°b go g¡{b{gbEopëS>hmBS>

(ii) t-ã`y{Q>bŠbmoamBS> go t-ã`y{Q>b E{Wb B©Wa
(iii) àmonrZ go àmonoZm°b
AWdm
(a) EWrZ go EWoZm°b ~ZZo H$s {H«$`m{d{Y Xr{OE & 2
(b) {ZåZ{b{IV ê$nm§VaU gånÞ H$aZo Ho$ {bE A{^H$_©H$ H$s àmJw{º$ H$s{OE : 13=3
(i) µ\$sZm°b go ~oÝµOmo{ŠdZmoZ

(ii) Eo{Zgmob go p-~«mo_moEo{Zgmob
(iii) µ\$sZm°b go 2,4,6-Q´>mB~«mo_moµ\$sZm°b
.56/1/1 18
37. (a) Out of t-butyl alcohol and n-butanol, which one will undergo acid
catalyzed dehydration faster and why ? 2
(b) Carry out the following conversions : 13=3

(i) Phenol to Salicylaldehyde
(ii) t-butylchloride to t-butyl ethyl ether
(iii) Propene to Propanol
OR
(a) Give the mechanism for the formation of ethanol from ethene. 2
(b) Predict the reagent for carrying out the following conversions : 13=3
(i) Phenol to benzoquinone
(ii) Anisole to p-bromoanisole
(iii) Phenol to 2,4,6-tribromophenol
.56/1/1 19 P.T.O.
H$moS> Z§.
Code No. 56/1/2
ZmoQ> NOTE

CHEMISTRY (Theory)

.56/1/2 1 P.T.O.
gm_mÝ` {ZX}e :
h¡ &
h¡ &
h¡ &
IÊS> H$
~ZoJm ?
.56/1/2 2
2 marks each.
3 marks each.
5 marks each.
such questions.
SECTION A

.56/1/2 3 P.T.O.
1. CËnmX H$s {Ì{d_agm`Z H$s àmJw{º$ H$s{OE `{X H$moB© Y«wdU KyU©H$ (àH$meV: g{H«$`)
EopëH$b h¡bmBS>> SN2 {H«$`m{d{Y go à{VñWmnZ A{^{H«$`m gånÞ H$aVm h¡ &
2. CZ CËnmXm| H$s g§aMZmE± {b{IE O~ Eo{Zgmob H$mo HI Ho$ gmW A{^{H«${`V {H$`m OmVm h¡ &
3. _w»` CËnmX H$s àmJw{º$ H$s{OE O~ 2-~«mo_moã`yQ>oZ, EoëH$mohm°br KOH Ho$ gmW A{^{H«$`m
H$aVm h¡ &
4. Cg `§Ì H$m Zm_ ~VmBE Omo Cg H$moU Ho$ _mnZ Ho$ {bE à`wº$ hmoVm h¡ {Og na g_Vb
Y«w{dV àH$me Ky{U©V hmo OmVm h¡ &

h¡ ?
7. nm°{bàmonrZ Ho$ EH$bH$ H$s g§aMZm Xr{OE &
8. `{X Ðd A Am¡a B Ho$ ŠdWZm§H$ H«$_e: 140C Am¡a 180C h¢, Vmo Cg Ðd H$s nhMmZ
H$s{OE {OgH$m 90C na dmîn Xm~ CƒVa hmoJm &
D$Om©) eyÝ` hmo ?
(A) 2,2-S>mB_o{Wbã`yQ>oZm°BH$ Aåb

(B) 2-H$m~m}pŠgb-2-_o{Wbã`yQ>Z
o
.56/1/2 4
2. Write the structures of the products formed when anisole is treated with
HI.
3. Predict the major product formed when 2-Bromobutane undergoes a
reaction with alcoholic KOH.
4. Name the instrument used for measuring the angle by which the plane
polarised light is rotated.

7. Give the structure of the monomer of polypropene.
8. Identify which liquid will have a higher vapour pressure at 90C if the
boiling points of two liquids A and B are 140C and 180C, respectively.

.56/1/2 5 P.T.O.
OmVr h¢ ?
(A) Sc (Z = 21)
(B) Cr (Z = 24)
(C) Mn (Z = 25)
(D) Fe (Z = 26)

(A) _o{WbEo_rZ
(B) S>mB_o{WbEo_rZ
(D) Eo{ZbrZ
15. Am`moS>mo\$m°_© narjU {H$gHo$ Ûmam Zht {X`m OmVm h¡ ?
(A) hoŠgoZ-2-AmoZ
(B) hoŠgoZ-3-AmoZ
(C) EWoZm°b
(D) EoWoZ¡b
.56/1/2 6
(A) Sc (Z = 21)
(B) Cr (Z = 24)
(C) Mn (Z = 25)
(D) Fe (Z = 26)

(A) Electrophoresis
(B) Electro-osmosis
(D) Tyndall effect
(A) Methylamine
(B) Dimethylamine
(C) Trimethylamine
(D) Aniline
15. Iodoform test is not given by
(A) Hexan-2-one
(B) Hexan-3-one
(C) Ethanol
(D) Ethanal
.56/1/2 7 P.T.O.
CËnÞ hmoVr h¡ &


H$maU (R) : gyH«$mog _| ½bmBH$mo{g{S>H$ ~§Y hmoVm h¡ &
.56/1/2 8
below : 15=5

appears to be 2.

solution of NaCN.

Reason (R) : Sucrose has glycosidic linkage.
.56/1/2 9 P.T.O.
IÊS> I

22. {ZåZ{b{IV AUwAm| H$s AmH¥${V It{ME : 12=2
(a) XeF4
(b) HClO4

(a) àem§VH$
(b) ny{VamoYr
AWdm
.56/1/2 10
SECTION B
time. 12=2

(a) XeF4
(b) HClO4

(a) Tranquilizers
(b) Antiseptic
OR
.56/1/2 11 P.T.O.
(a) nmoQ>¡{e`_ Q´>mBAm°Šg¡boQ>moEob{w _ZoQ> (III)

(b) Q>oQ´>mEoå_rZEŠdmŠbmo[aS>moH$mo~mëQ> (III) ŠbmoamBS>
AWdm
H$s{OE & 2
(a) ZmBbm°Z-6,6 >

(b) ã`yZm-S
(a) ã`yQ>oZmoZ H$mo _o{Wb_¡½Zr{e`_ ~«mo_mBS> Ho$ gmW A{^{H«${`V H$aHo$ Ob-AnK{Q>V
{H$`m OmVm h¡, Am¡a
(b) gmo{S>`_ ~oÝµOmoEQ> H$mo gmoS>m bmB_ Ho$ gmW Ja_ {H$`m OmVm h¡ ? 12=2
IÊS> J
28. 75 g Eogr{Q>H$Aåb _| Kmobo OmZo dmbr EoñH$m°{~©H$ Aåb

.56/1/2 12
(a) Potassium trioxalatoaluminate (III)
(b) Tetraammineaquachloridocobalt (III) chloride
OR
26. Write the names and structures of monomers in the following

polymers : 12=2
(a) Nylon-6,6
(b) Buna-S
(a) Butanone is treated with methylmagnesium bromide and then

hydrolysed, and
(b) Sodium benzoate is heated with soda lime ? 12=2
SECTION C
(Kf = 3·9 K kg mol–1) 3

.56/1/2 13 P.T.O.
AWdm
(a) MnO2 + 4 HCl 
(b) XeF6 + KF 
(c) I – (aq) + H+ (aq) + O2 (g) 
1
2
NH3 NaOBr
(a) CH3COOH   A  B


(b) C6H5NO2  A  2  B
0 –5C
+ CuCN H2O / H
(c) C6H5N2Cl    A    B

AWdm


.56/1/2 14
OR
(a) MnO2 + 4 HCl 
(b) XeF6 + KF 
(c) I – (aq) + H+ (aq) + O2 (g) 
1
2
NH3 NaOBr
(a) CH3COOH   A  B

(b) C6H5NO2  A  2  B
0 –5C
+ CuCN H O / H
(c) C6H5N2Cl    A 2   B

OR

compounds : 12=2

boiling points : 1

.56/1/2 15 P.T.O.
32. {H$gr A{^{H«$¶m H$m doJ H¡$go à^m{dV hmoJm, O~
(a) A{^H$maH$ H$m n¥îR>r` joÌ\$b ~‹T>m {X`m OmE,
(b) A{^{H«$`m H$m Vmn KQ>m {X`m OmE, Am¡a
(c) CËH«$_Ur` A{^{H«$`m _| CËàoaH$ {_bm {X`m OmE ? 13=3
33. (a) (i) {d{eîQ>Vm, Am¡a

(ii) A{YemofU H$s EÝW¡ënr
Ho$ AmYma na ^m¡{VH$ A{YemofU Am¡a agmodemofU H$s VwbZm H$s{OE & 2
(b) A{YemofU Ed§ AdemofU Ho$ ~rM AÝVa ñnï> H$s{OE & 1
34. {ZåZ{b{IV H$s ^y{_H$m ñnîQ> H$s{OE : 13=3

(a) Ni Ho$ emoYZ _| CO H$s &
(b) Fe Ho$ YmVwH$_© _| MyZm-nËWa H$s &
(c) \o$Z ßbdZ {d{Y _| AdZ_H$ H$s &
IÊS> K

AWdm

.56/1/2 16
(a) surface area of the reactant is increased,
(b) temperature of the reaction is decreased, and
(c) catalyst is added in a reversible reaction ? 13=3
33. (a) Compare physisorption and chemisorption on the basis of

(i) specificity, and
(ii) enthalpy of adsorption. 2
(b) Differentiate between adsorption and absorption. 1
(a) CO in the refining of Ni.
(b) Limestone in the metallurgy of Fe.

(c) Depressant in the froth floatation method.
SECTION D

OR
.56/1/2 17 P.T.O.
36. (a) A{^{H«$¶m
Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s)
Cu2+/Cu Ho$ {bE E = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1.
AWdm
H$s A{YH$ _mÌm Ho$ MmbZ H$s AZw_{V XoVm h¡ : 3

AWdm
.56/1/2 18
Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s). 3

E for Cu2+/Cu = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1.

OR
allow greater conduction of electricity : 3


solution.
OR
property : 12=2
.56/1/2 19 P.T.O.
H$moS> Z§.
Code No. 56/1/3
ZmoQ> NOTE

CHEMISTRY (Theory)

.56/1/3 1 P.T.O.
gm_mÝ` {ZX}e :
h¡ &
h¡ &
h¡ &
IÊS> H$
~ZoJm ?
.56/1/3 2
2 marks each.
3 marks each.
5 marks each.
such questions.
SECTION A

.56/1/3 3 P.T.O.
1. ~ZZo dmbo CËnmX H$s {Ì{d_agm`Z H$s àmJw{º$ H$s{OE `{X H$moB© Y«wdU KyU©H$ (àH$meV:
g{H«$`) EopëH$b h¡bmBS> SN1 {H«$`m{d{Y go à{VñWmnZ A{^{H«$`m gånÞ H$aVm h¡ &
2. g_Vb-Y«w{dV àH$me Š`m h¡ ?
3. ~ZZo dmbo CËnmXm| H$s g§aMZmE± {b{IE O~ EWm°Šgr~oÝµOrZ H$mo HI Ho$ gmW A{^{H«${`V
{H$`m OmVm h¡ &
4. _w»` CËnmX H$s àmJw{º$ H$s{OE O~ 2-~«mo_monoÝQ>oZ, EoëH$mohm°br KOH Ho$ gmW A{^{H«$`m
H$aVm h¡ &
6. `{X Ðd A Am¡a B Ho$ ŠdWZm§H$ $H«$_e: 140C Am¡a 180C h¢, Vmo Cg Ðd H$s nhMmZ
H$s{OE {OgH$m 90C na dmîn Xm~ {ZåZVa hmoJm &
h¡ ?
8. Q>oâbm°Z Ho$ EH$bH$ H$s g§aMZm Xr{OE &
D$Om©) eyÝ` hmo ?
(A) 2,2-S>mB_o{Wbã`yQ>oZm°BH$Aåb
(B) 2-H$m~m}pŠgb-2-_o{Wbã`yQ>Zo
.56/1/3 4
2. What is plane polarised light ?
3. Write the structures of the products formed when ethoxybenzene is

treated with HI.
4. Predict the major product formed when 2-Bromopentane reacts with

alcoholic KOH.
6. Identify which liquid will have lower vapour pressure at 90C if the
boiling points of two liquids A and B are 140C and 180C respectively.
8. Give the structure of the monomer of Teflon.

.56/1/3 5 P.T.O.

(A) _o{WbEo_rZ
(B) S>mB_o{WbEo_rZ
(D) Eo{ZbrZ
14. Am`moS>mo\$m°_© narjU {H$gHo$ Ûmam {X`m OmVm h¡ ?
(A) noÝQ>oZ-2-AmoZ
(B) EWoZm°BH$ Aåb
(C) noÝQ>oZ-3-AmoZ
(D) _oWm°Šgr_oWoZ
OmVr h¢ ?
(A) Sc (Z = 21)
(B) Cr (Z = 24)
(C) Mn (Z = 25)
(D) Fe (Z = 26)
.56/1/3 6
(A) Electrophoresis
(B) Electro-osmosis
(D) Tyndall effect
(A) Methylamine
(B) Dimethylamine
(C) Trimethylamine
(D) Aniline
14. Iodoform test is given by
(A) Pentan-2-one
(B) Ethanoic acid
(C) Pentan-3-one
(D) Methoxymethane

(A) Sc (Z = 21)
(B) Cr (Z = 24)
(C) Mn (Z = 25)
(D) Fe (Z = 26)
.56/1/3 7 P.T.O.
CËnÞ hmoVr h¡ &

H$maU (R) : ½byH$mog VWm \«$ŠQ>moµO Ho$ AnMm`H$ g_yh ½bmBH$mo{g{S>H$ Am~§Y {Z_m©U _|
à`wº$ hmoVo h¢ &
IÊS> I
AWdm
.56/1/3 8
below : 15=5

appears to be 2.

solution of NaCN.


Reason (R) : Reducing groups of glucose and fructose are involved in
glycosidic bond formation.
SECTION B
OR
.56/1/3 9 P.T.O.
H$s{OE & 2

(a) àem§VH$
(b) ny{VamoYr
AWdm
.56/1/3 10
time. 12=2

(a) Tranquilizers
(b) Antiseptic
OR
.56/1/3 11 P.T.O.
(a) ã`yZm-N
(b) ZmBbm°Z 6
25. {ZåZ{b{IV AUwAm| H$s AmH¥${V It{ME : 12=2
(a) H2S2O8>
(b) XeF2
(a) noÝQ>mEoå_rZH$m~m}ZoQ>moH$mo~mëQ> (III) ŠbmoamBS> >

(b) nmoQ>¡{e`_ Q>oQ´>mgm`{ZS>mo{ZH¡$boQ> (II)

(a) EogrQ>moZ H$mo Zn(Hg) / gmÝÐ HCl Ho$ gmW A{^{H«${`V {H$`m OmVm h¡, Am¡a
(b) EWoZ¡b H$mo _o{Wb_¡½Zr{e`_ ~«mo_mBS> Ho$ gmW A{^{H«${`V H$aHo$ Ob-AnK{Q>V
{H$`m OmVm h¡ ? 12=2
IÊS> J

AWdm
(a) MnO2 + 4 HCl 

(b) XeF6 + KF 
(c) I – (aq) + H+ (aq) + O2 (g) 
.56/1/3 12
12=2
(a) Buna-N
(b) Nylon 6

(a) H2S2O8
(b) XeF2

(a) Pentaamminecarbonatocobalt (III) chloride
(b) Potassium tetracyanidonickelate (II)

(a) Acetone is treated with Zn(Hg) / Conc. HCl, and
(b) Ethanal is treated with methylmagnesium bromide and then
hydrolysed ? 12=2
SECTION C

OR
(a) MnO2 + 4 HCl 
(b) XeF6 + KF 
(c) I – (aq) + H+ (aq) + O2 (g) 
.56/1/3 13 P.T.O.
29. 75 g Eogr{Q>H$ Aåb _| Kmobo OmZo dmbr EoñH$m°{~©H$ Aåb
30. A{^{H«$¶m H$m doJ {H$g àH$ma à^m{dV hmoJm O~

(a) A{^H$maH$ H$m n¥îR>r` joÌ\$b H$_ H$a {X`m OmE,
(b) CËH«$_Ur` A{^{H«$`m _| CËàoaH$ {_bm {X`m OmE, Am¡a
(c) A{^{H«$`m H$m Vmn ~‹T>m {X`m OmE ? 13=3
1
2
NH3 NaOBr
(a) CH3COOH   A  B


(b) C6H5NO2  A  2  B
0 –5C
+ CuCN H2O / H
(c) C6H5N2Cl    A    B

AWdm


.56/1/3 14
(Kf = 3·9 K kg mol–1) 3

(a) Surface area of the reactant is reduced,
(b) Catalyst is added in a reversible reaction, and
(c) Temperature of the reaction is increased ? 13=3
1
2
NH3 NaOBr
(a) CH3COOH   A  B

(b) C6H5NO2  A  2  B
0 –5C
CuCN H O / H
C6H5N2Cl    A 2 
+
(c)  B

OR

compounds : 12=2

boiling points : 1

.56/1/3 15 P.T.O.
33. {ZåZ{b{IV H$s ^y{_H$m ñnîQ> H$s{OE : 13=3
(a) \o$Z ßbdZ àH«$_ _| NaCN H$s &

(b) Zr Ho$ YmVwH$_© _| I2 H$s &
(c) Fe Ho$ YmVwH$_© _| MyZm-nËWa H$s &
34. {ZåZ{b{IV Ho$ AmYma na ^m¡{VH$ A{YemofU Am¡a agmodemofU _| {dôX H$s{OE :
(a) AmH$f©U ~b,

(b) Vmn, Am¡a
(c) A{YemofU H$s EÝW¡ënr & 13=3
IÊS> K
AWdm

.56/1/3 16
(a) NaCN in froth floatation process.
(b) I2 in the metallurgy of Zr.
(c) Limestone in the metallurgy of Fe.
34. Distinguish between physisorption and chemisorption on the basis of
(a) Force of attraction,
(b) Temperature, and

(c) Enthalpy of adsorption. 13=3
SECTION D

solution.

OR

property : 12=2

.56/1/3 17 P.T.O.
AWdm
37. (a) A{^{H«$¶m

Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s)
Cu2+/Cu Ho$ {bE E = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1.
AWdm
H$s A{YH$ _mÌm Ho$ MmbZ H$s AZw_{V XoVm h¡ : 3
.56/1/3 18
OR
Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s). 3

E for Cu2+/Cu = + 0·34 V
R = 8·314 JK–1 mol–1
F = 96500 C mol–1.

OR
allow greater conduction of electricity : 3

.56/1/3 19 P.T.O.
H$moS> Z§.
Code No. 56/2/1
ZmoQ> NOTE

CHEMISTRY (Theory)

.56/2/1 1 P.T.O.
gm_mÝ` {ZX}e :
h¡ &
h¡ &
h¡ &
IÊS> H$
à~b àH$ma Ho$ ¶m¡{JH$ O¡go Eo‘rZmo Aåb, hm°‘m}Z, V§{ÌH$m-g§MmaH$, S>r.EZ.E., EoëHo$bm°BS>,
a§OH$ Am{X ‘| Eo‘rZ A{^bjH$s` g‘yh dmbo H$m~©{ZH$ ¶m¡{JH$ CnpñWV hmoVo h¢ & Am¡fY
{OZH$m ‘mZdm| na eara{H«$¶mË‘H$ à^md hmoVm h¡ O¡go {ZH$moQ>rZ, ‘m°’$s©Z, H$moS>rZ Ed§ hramoBZ,
Am{X ‘| ^r Eo‘rZmo g‘yh {H$gr Z {H$gr ê$n ‘| hmoVm h¡ & ZmBQ´>moOZ na EH$mH$s Bbo³Q´>m°Z ¶w½‘
H$s CnpñW{V Ho$ H$maU Eo‘rZ jmaH$s¶ hmoVo h¢ & H$m~©{ZH$ T>m±Mo ‘| ZmBQ´>moOZ H$m ¶moJ Eo‘rZ Am¡a
Eo‘mBS> AUwAm| Ho$ Xmo dJm] H$m {Z‘m©U H$aVm h¡ & agm¶Z {dkmZ Ho$ N>mÌ hmoZo Ho$ ZmVo, h‘|
ZmBQ´>moOZ H$s gd©Vmo‘wIr àH¥${V H$s gamhZm H$aZr Mm{hE &
1. Eo_rZmo Aåb Š`m h¢ ?
2. Eo‘rZmo Aåb C^¶Y‘u ³¶m| hmoVo h¢ ?
3. Aåbr¶ Am¡a jmaH$s¶ Eo‘rZmo Aåb ‘| EH$ A§Va Xr{OE &
4. Amdí¶H$ Eo‘rZmo Aåb ³¶m h¢ ?
5. O~ EH$ Eo‘rZmo Aåb H$m H$m~m}p³gb {gam Xÿgao Eo‘rZmo Aåb Ho$ Eo‘rZmo {gao Ho$ gmW
g§K{ZV hmoVm h¡ Vmo ~ZZo dmbo Am~ÝY H$m Zm‘ {b{IE &
.56/2/1 2
2 marks each.
3 marks each.
5 marks each.
such questions.
SECTION A
Organic compounds containing amine as functional group are present in
a vivid variety of compounds, namely amino acids, hormones,
neurotransmitters, DNA, alkaloids, dyes, etc. Drugs including nicotine,
morphine, codeine and heroin, etc. which have physiological effects on
humans also contain amino group in one form or another. Amines are
basic because of the presence of lone pair of electrons on nitrogen.
Addition of nitrogen into an organic framework leads to the formation of
two families of molecules, namely amines and amides. As chemistry
students, we must appreciate the versatility of nitrogen.
1. What are amino acids ?
2. Why are amino acids amphoteric ?
3. Give one point of difference between acidic and basic amino acid.
4. What are essential amino acids ?
5. Name the linkage formed when carboxyl end of one amino acid condenses
with amino end of other amino acid.
.56/2/1 3 P.T.O.
6. ¶{X A¶ñH$ {H$gr Cn¶w³V {dbm¶H$ ‘| {dbo¶ hmo, Vmo CgHo$ gÁOrH$aU ‘| à¶w³V àH«$‘ H$m
Zm‘ {b{IE &
7. {H$gr EH$ YmVw H$m CXmhaU Xr{OE {OgH$m emoYZ AmgdZ {d{Y Ûmam {H$¶m Om gHo$ &
8. g§Hw$b [Co(NH3)5 NO2]Cl2 Ûmam {H$g àH$ma H$s g‘md¶dVm Xem©B© OmVr h¡ ?
9. H$moB© H$m~©{ZH$ ¶m¡{JH$ {g{bH$m Oob H$s gVh na A{Yemo{fV h¡ & H$m~©{ZH$ ¶m¡{JH$ H$mo
{g{bH$m Oob go hQ>mZo Ho$ àH«$‘ H$m Zm‘ {b{IE &
10. {H$gr A{^{H«$¶m H$s Hw$b H$mo{Q> H$m n[aH$bZ H$s{OE {OgHo$ doJ {Z¶‘ ì¶§OH$ H$s {ZåZ
àH$ma àmJw{³V H$s JB© :
3 /2 1/ 2
doJ = k[NO] [O 2 ]

11. ½byH$mog C6H12O6 (‘moba Ðì¶‘mZ : 180 g/‘mob) Ho$ 50 mL Obr¶ {db¶Z ‘|
6·02  1022 AUw CnpñWV h¢ & {db¶Z H$s gm§ÐVm hmoJr
(A) 0·1 M
(B) 0·2 M
(C) 1·0 M
(D) 2·0 M
12. ¶{X {H$gr Bbo³Q´>moS> H$m ‘mZH$ Bbo³Q´>moS> {d^d eyÝ¶ go A{YH$ hmo, Vmo h‘ {ZîH$f© {ZH$mb
gH$Vo h¢ {H$ BgH$m
(A) AnM{¶V ê$n hmBS´>moOZ J¡g H$s VwbZm ‘| A{YH$ ñWm¶r h¡ &
(B) Am°³grH¥$V ê$n hmBS´>moOZ J¡g H$s VwbZm ‘| A{YH$ ñWm¶r h¡ &
(C) AnM{¶V Am¡a Am°³grH¥$V ê$n g‘mZ ê$n go ñWm¶r h¢ &
(D) AnM{¶V ê$n hmBS´>moOZ J¡g go H$‘ ñWm¶r h¡ &
13. Co3+ (na‘mUw H«$‘m§H$ = 27) ‘| CnpñWV Hw$b A¶wp½‘V Bbo³Q´>m°Zm| H$s g§»¶m h¡
(A) 2
(B) 7
(C) 3
(D) 5
.56/2/1 4
6. Name the process used for the benefaction of ores if the ore is soluble in
some suitable solvent.
7. Give an example of a metal which can be purified by the process of

distillation.
8. What type of isomerism is shown by the complex [Co(NH3)5 NO2] Cl2 ?
9. An organic compound is adsorbed on the surface of silica gel. Name the

process of removing the organic compound from silica gel.
10. Calculate the overall order of the reaction whose rate law expression was
predicted as :
3 /2 1/ 2
Rate = k[NO] [O 2 ] .

11. 50 mL of an aqueous solution of glucose C6H12O6 (Molar mass :
180 g/mol) contains 6·02  1022 molecules. The concentration of the
solution will be
(A) 0·1 M
(B) 0·2 M
(C) 1·0 M
(D) 2·0 M
12. If the standard electrode potential of an electrode is greater than zero,
then we can infer that its
(A) reduced form is more stable compared to hydrogen gas.
(B) oxidised form is more stable compared to hydrogen gas.
(C) reduced and oxidised forms are equally stable.
(D) reduced form is less stable than the hydrogen gas.
13. Total number of unpaired electrons present in Co3+ (Atomic number = 27)
is
(A) 2
(B) 7
(C) 3
(D) 5
.56/2/1 5 P.T.O.
14. A§VamH$mer ¶m¡{JH$m| Ho$ {df¶ ‘| µJbV H$WZ h¡
(A) do amgm¶{ZH$ Ñ{îQ> go A{^{H«$¶merb h¢ &
(B) do AË¶ÝV H$R>moa h¢ &
(C) do YmpËdH$ MmbH$Vm ~ZmE aIVo h¢ &
(D) CZHo$ JbZm§H$ CÀM hmoVo h¢ &
15.
(A) tert-ã¶y{Q>b EoëH$mohm°b

(B) 2,2-S>mB‘o{WbàmonoZm°b
(C) 2-‘o{Wbã¶yQ>oZ-2-Am°b
(D) 3-‘o{Wbã¶yQ>oZ-3-Am°b
16. A{^H$WZ (A) : EopëH$b h¡bmBS>m| Ho$ ³dWZm§H$ {ZåZ H«$‘ ‘| KQ>Vo h¢ :
R-I > R-Br > R-Cl > R-F
H$maU (R) : h¡bmoOZ na‘mUw Ho$ AmH$ma ‘| d¥{Õ Ho$ gmW dmÝS>a dmëg ~b KQ>Vo h¢ &
17. A{^H$WZ (A) : {ZåZ àMH«$U MVwî’$bH$s¶ g§Hw$b {dabo hr XoIo OmVo h¢ &
H$maU (R) : H$jH$m| H$s {dnmQ>Z D$Om©E± BVZr A{YH$ Zht hmoVr h¢ Omo ¶w½‘Z Ho$ {bE
~mÜ¶ H$a| &
18. A{^H$WZ (A) : Eoë~y{‘Z EH$ Jmo{bH$mH$ma àmoQ>rZ h¡ &
H$maU (R) : nm°{bnoßQ>mBS> H$s ûm¥§Ibm Hw§$S>br ~ZmH$a EH$ grYr ûm¥§Ibm ~Zm XoVr h¡ &
.56/2/1 6
14. The incorrect statement about interstitial compounds is
(A) They are chemically reactive.
(B) They are very hard.
(C) They retain metallic conductivity.
(D) They have high melting point.
15.
(A) tert-butyl alcohol

(B) 2,2-Dimethylpropanol
(C) 2-Methylbutan-2-ol
(D) 3-Methylbutan-3-ol
below : 15=5
(i) Both assertion (A) and reason (R) are correct statements, and
reason (R) is the correct explanation of the assertion (A).
(ii) Both assertion (A) and reason (R) are correct statements, but
reason (R) is not the correct explanation of the assertion (A).
(iii) Assertion (A) is correct, but reason (R) is incorrect statement.
(iv) Assertion (A) is incorrect, but reason (R) is correct statement.
16. Assertion (A) : Boiling points of alkyl halides decrease in the order
R-I > R-Br > R-Cl > R-F.
Reason (R) : Van der Waals forces decrease with increase in the size of
halogen atom.
17. Assertion (A) : Low spin tetrahedral complexes are rarely observed.
Reason (R) : The orbital splitting energies are not sufficiently large to
forcing pairing.
18. Assertion (A) : Albumin is a globular protein.

Reason (R) : Polypeptide chain coils around to give a straight chain.
.56/2/1 7 P.T.O.
19. A{^H$WZ (A) : ~¡Ho$bmBQ> VmnÑ‹T> ~hþbH$ h¡ &
H$maU (R) : Ja‘ H$aZo na, ~hþbH$s¶ ûm§¥Ibm bå~r Am¡a grYr ûm§¥Ibm ~Z OmVr h¡ &
20. A{^H$WZ (A) : p-ZmBQ´>moµ\$sZm°b H$s Anojm o-ZmBQ´>moµ\$sZm°b Xþ~©b Aåb h¡ &
H$maU (R) : Am§VaAmpÊdH$ (A§V:AUwH$) hmBS´>moOZ Am~ÝY Am°Wm} g‘md¶d H$mo n¡am
g‘md¶d H$s Anojm Xþ~©b H$a XoVm h¡ &
IÊS> I
21. {ZåZ{b{IV Ho$ ‘Ü¶ EH$-EH$ A§Va Xr{OE : 12=2
(a) àem§VH$ Am¡a nr‹S>mhmar
(b) ny{VamoYr Am¡a {dg§H«$m‘r (amoJmUwZmer)
AWdm
amgm¶{ZH$ g§KQ>Z Ho$ AmYma na YZm¶Zr Am¡a G Um¶Zr An‘mO©H$m| ‘| A§Va ñnîQ> H$s{OE &
àË¶oH$ dJ© H$m EH$-EH$ CXmhaU ^r Xr{OE & 2
22. {ZåZ{b{IV Ho$ {bE H$maU Xr{OE : 12=2
(a) EoëH$mohm°b ‘| Am~ÝY H$moU MVwî’$bH$s¶ H$moU go Oam-gm H$‘ hmoVm

h¡ &
(b) CH3OH ‘| C – OH Am~ÝY bå~mB© µ\$sZm°b ‘| C – OH Am~ÝY bå~mB© go
Oam-gr A{YH$ hmoVr h¡ &
23. {ZåZ{b{IV amgm¶{ZH$ g‘rH$aUm| H$mo nyU© Ed§ gÝVw{bV H$s{OE : 2
 
(a) MnO 4  H2O  I 
 
(b) MnO 4  H   I 
24. A{YemofU g‘Vmnr H$s n[a^mfm {b{IE & {H$gr R>mog A{YemofH$ Ho$ BH$mB© Ðì¶‘mZ Ûmam
EH$ {ZpíMV Vmn na A{Yemo{fV J¡g H$s ‘mÌm Ed§ Xm~ Ho$ ‘Ü¶ EH$ AmZw^{dH$ g§~§Y
Xr{OE & 2
AWdm
AmH$ma-daUmË‘H$ CËàoaU H$mo n[a^m{fV H$s{OE & Cg àH«$‘ H$m Zm‘ {b{IE {OgHo$ Ûmam
EoëH$mohm°bm| H$mo grYo hr J¡gmobrZ ‘| n[ad{V©V H$a {X¶m OmVm h¡ Am¡a {d{^Þ àH$ma Ho$
hmBS´>moH$m~©Z ~ZVo h¢ & 2
.56/2/1 8
19. Assertion (A) : Bakelite is a thermosetting polymer.
Reason (R) : On heating, polymeric chain becomes a long and straight
chain.
20. Assertion (A) : o-nitrophenol is a weaker acid than p-nitrophenol.

Reason (R) : Intramolecular hydrogen bonding makes ortho isomer
weaker than para isomer.
SECTION B
21. Give one point of difference between the following : 12=2
(a) Tranquilizers and Analgesics
(b) Antiseptics and Disinfectants
OR
Differentiate on the basis of chemical composition between cationic and
anionic detergents. Also give one example of each category. 2
22. Give reasons for the following : 12=2
(a) Bond angle in alcohol is slightly less than the tetrahedral

angle.
(b) C – OH bond length in CH3OH is slightly more than the C – OH
bond length in phenol.
23. Complete and balance the following chemical equations : 2

 
(a) MnO 4  H2O  I 
 
(b) MnO 4  H   I 
24. Define adsorption isotherm. Give the empirical relationship between the
quantity of gas adsorbed by unit mass of solid absorbent and pressure at
a particular temperature. 2
OR
Define shape-selective catalysis. Name the process by which alcohols
convert directly into gasoline and give a variety of hydrocarbons. 2
.56/2/1 9 P.T.O.
25. H$moB© A{^{H«$¶m A{^H$maH$ A Ho$ gmnoj àW‘ H$mo{Q> H$s h¡ Am¡a A{^H$maH$ B Ho$ gmnoj ^r
àW‘ H$mo{Q> H$s h¡ & doJ {Z¶‘ Xr{OE & Am¡gV doJ Am¡a VmËj{UH$ doJ Ho$ ~rM EH$ A§Va
^r Xr{OE & 2
26. {H$gr {dÚwV²-amgm¶{ZH$ gob

Mg (s) + Ag+ (aq)  Ag (s) + Mg2+ (aq)
Ho$ {bE gob {Zê$nU Xr{OE & 25C na Cn`w©³V gob Ho$ {bE ZoÝñQ>© g‘rH$aU ^r
{b{IE & 2
27. {ZåZ{b{IV pñW{V¶m| ‘| {db¶Z ‘| {dbo¶ H$s AdñWm H$s àmJw{³V H$s{OE : 2
(a) O~ ‘i’ EH$ go A{YH$ nm¶m J¶m &

(b) O~ ‘i’ EH$ go H$‘ nm¶m J¶m &
IÊS> J
28. {ZåZ{b{IV ~hþbH$m| Ho$ EH$bH$m| H$s g§aMZmE± Xr{OE : 13=3
(a) Q>oâbm°Z
(b) p½bßQ>b
(c) ZmBbm°Z-6
AWdm
{ZåZ{b{IV ~hþbH$m| Ho$ EH$bH$m| Ho$ Zm‘ {b{IE : 13=3
.56/2/1 10
25. A reaction is first order w.r.t. reactant A as well as w.r.t. reactant B. Give
the rate law. Also give one point of difference between average rate and
instantaneous rate. 2
26. For an electrochemical cell
Mg (s) + Ag+ (aq)  Ag (s) + Mg2+ (aq),
give the cell representation. Also write the Nernst equation for the above
cell at 25C. 2
27. Predict the state of the solute in the solution in the following situations : 2
(a) When ‘i’ is found to be more than one.
(b) When ‘i’ is found to be less than one.
SECTION C
28. Give the structures of the monomers of the following polymers : 13=3
(a) Teflon
(b) Glyptal
(c) Nylon-6
OR
Write the names of monomers of the following polymers : 13=3
.56/2/1 11 P.T.O.
(a) EWoZo‘rZ H$s VwbZm ‘| Eo{ZbrZ Xþ~©b jma h¡ &
(b) Eo{ZbrZ ’«$sS>ob-H«$mâQ²>g A{^{H«$¶m àX{e©V Zht H$aVr &
(c) J¡{~«Eb W¡{b‘mBS> g§íbofU Ûmam Ho$db Eo{b’¡${Q>H$ àmW{‘H$ Eo‘rZm| H$m {daMZ
{H$¶m Om gH$Vm h¡ &
30. {ZåZ{b{IV ¶m¡{JH$m| Ho$ àË¶oH$ g‘wÀM¶ H$mo nyN>o JE {dñWmnZ H$s A{^{H«$¶merbVm Ho$
1
Amamohr H«$‘ ‘| ì¶dpñWV H$s{OE Am¡a H$maU XoVo hþE CÎma H$s nw{ï> H$s{OE : 1 2=3
2
(a) 1-~«mo‘moã¶yQ>oZ, 2-~«mo‘moã¶yQ>oZ, 2-~«mo‘mo-2-‘o{WbàmonoZ (SN1 A{^{H«$¶m)
(b) 1-~«mo‘moã¶yQ>oZ, 2-~«mo‘moã¶yQ>oZ, 2-~«mo‘mo-2-‘o{WbàmonoZ (SN2 A{^{H«$¶m)
31. (a) K4[Mn(CN)6] H$m AmB©.¶y.nr.E.gr. Zm‘ VWm t2g Am¡a eg Ho$ nXm| ‘| Ho$ÝÐr¶ YmVw
na‘mUw H$m Bbo³Q´>m°{ZH$ {dÝ¶mg Xr{OE &
(b) ‘H$sboQ> à^md’ go ³¶m A{^àm¶ h¡ ? EH$ CXmhaU Xr{OE & 2+1=3
AWdm
{ZåZ{b{IV g§Hw$bm| Ho$ g§H$aU Ed§ Mwå~H$s¶ ì¶dhma {b{IE : 3
(i) [Fe(CN)6]4–
(ii) [CoF6]3–
(iii) [Ni(CO)4]
[ na_mUw H«$_m§H$ : Fe = 26, Co = 27, Ni = 28]
32. ~m°³gmBQ> go Eobw{‘Zm Ho$ {ZjmbZ go g§~§Õ amgm¶{ZH$ A{^{H«$¶mE± Xr{OE & 3
33. 2  10–3 M ‘oWoZm°BH$

Aåb H$s MmbH$Vm 8  10–5 S cm–1 h¡ & ¶{X ‘oWoZm°BH$ Aåb Ho$
{bE H$m ‘mZ 404 S cm2 mol–1 hmo, Vmo BgH$s ‘moba MmbH$Vm Am¡a {d¶moOZ ‘mÌm
n[aH${bV H$s{OE & 3
34. 600 gOb ‘| 31 g E{WbrZ ½bmBH$m°b (‘moba Ðì¶‘mZ = 62 g mol–1) KmobH$a à{V{h‘
{db¶Z ~Zm¶m J¶m & {db¶Z H$m {h‘m§H$ n[aH${bV H$s{OE & 3
(Ob Ho$ {bE Kf = 1·86 K kg mol–1)
.56/2/1 12
(a) Aniline is a weaker base compared to ethanamine.
(b) Aniline does not undergo Friedel-Crafts reaction.
(c) Only aliphatic primary amines can be prepared by Gabriel
Phthalimide synthesis.
30. Justify and arrange the following compounds of each set in increasing
1
order of reactivity towards the asked displacement : 1 2=3
2
(a) 1-Bromobutane, 2-Bromobutane, 2-Bromo-2-Methylpropane
(SN1 reaction)
(b) 1-Bromobutane, 2-Bromobutane, 2-Bromo-2-Methylpropane
(SN2 reaction)
31. (a) Give the IUPAC name and electronic configuration of central metal
atom in terms of t2g and eg of K4[Mn(CN)6].
(b) What is meant by ‘Chelate effect’ ? Give an example. 2+1=3

OR
Write the hybridisation and magnetic characters of the following
complexes : 3
4–
(i) [Fe(CN)6]
(ii) [CoF6]3–
(iii) [Ni(CO)4]
[Atomic number : Fe = 26, Co = 27, Ni = 28]
32. Give the chemical reactions involved in the leaching of alumina from
bauxite. 3
33. Conductivity of 2  10–3 M methanoic acid is 8  10–5 S cm–1. Calculate

its molar conductivity and degree of dissociation if for methanoic
–1
acid is 404 S cm2 mol . 3
34. An antifreeze solution is prepared by dissolving 31 g of ethylene glycol

(Molar mass = 62 g mol–1) in 600 g of water. Calculate the freezing point
of the solution. (Kf for water = 1·86 K kg mol–1) 3
.56/2/1 13 P.T.O.
IÊS> K
35. (a) {H$gr A{^{H«$¶m R  P Ho$ {bE {dem Zo R H$s gmÝÐVm Ed§ g‘¶ Ho$ ‘Ü¶ EH$
J«m’$ ItMm & Bg J«m’$ Ho$ AmYma na {ZåZ{b{IV àíZm| Ho$ CÎma Xr{OE :
(i) A{^{H«$¶m H$s H$mo{Q> H$s àmJw{³V H$s{OE &

(ii) dH«$ H$m T>mb ³¶m B§{JV H$aVm h¡ ?
(iii) doJ pñWam§H$ H$s BH$mB© ³¶m h¡ ? 13=3
(b) EH$ àW‘ H$mo{Q> H$s A{^{H«$¶m ‘| 25% {d¶moOZ hmoZo ‘| 25 {‘ZQ> bJVo h¢ &
t1/2 H$s JUZm H$s{OE & 2
[{X`m J`m h¡ : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021]
AWdm
(a) {H$gr àW‘ H$mo{Q> H$s A{^{H«$¶m Ho$ {bE doJ pñWam§H$ 60 s–1 h¡ & A{^H$maH$ H$mo
1
AnZr àmapå^H$ gmÝÐVm go KQ> H$a dm± ^mJ ah OmZo ‘| {H$VZm g‘¶ bJoJm ? 3
16
(b) {H$gr amgm`{ZH$ A{^{H«$¶m Ho$ doJ H$mo à^m{dV H$aZo dmbo Xmo H$maH$m| H$mo {b{IE & 1
(c) g§KÅ>m| Ho$ à^mdr g§KÅ>> hmoZo Ho$ {bE Xmo n[apñW{V¶m± {b{IE & 1
.56/2/1 14
SECTION D
35. (a) Visha plotted a graph between concentration of R and time for a
reaction R  P. On the basis of this graph, answer the following
questions :
(i) Predict the order of reaction.

(ii) What does the slope of the line indicate ?
(iii) What are the units of rate constant ? 13=3
(b) A first order reaction takes 25 minutes for 25% decomposition.

Calculate t1/2. 2
[Given : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021]
OR
(a) The rate constant for a first order reaction is 60 s–1. How much
time will it take to reduce the initial concentration of the reactant
1 th
to its value ? 3
16
(b) Write two factors that affect the rate of a chemical reaction. 1
(c) Write two conditions for the collisions to be effective collisions. 1

.56/2/1 15 P.T.O.
36. {H$arQ>mH$ma g§aMZm dmbm H$moB© A{H«$ñQ>br¶ R>mog ‘A’ dm¶w ‘| ObH$a J¡g ‘B’ ~ZmVm h¡ Omo
MyZo Ho$ nmZr H$mo Xÿ{Y¶m H$a XoVr h¡ & gë’$mBS> A¶ñH$m| Ho$ Ô©Z go ^r ‘B’ CËnm{XV hmoVr
h¡ & V2O5 H$s CnpñW{V ‘| ‘B’ Am°³grH¥$V hmoH$a ‘C’ XoVr h¡ VWm ‘C’ H$s CÀM bpãY Ho$
{bE H$‘ Vmn Am¡a CÀM Xm~ Cn¶w³V pñW{V¶m± h¢ & ‘C’, H2SO4 ‘| Ademo{fV hmoH$a ‘D’
XoVr h¡ & VËníMmV² ‘D’ H$m VZwH$aU H$aZo na AË¶{YH$ ‘hÎdnyU© ¶m¡{JH$ ‘E’ àmßV hmoVm h¡ &
CÚmoJ ‘| ‘E’ {d{^Þ ¶m¡{JH$m| Ho$ {Z‘m©U Ho$ {bE ì`mnH$ ê$n go CÎmaXm¶r h¡ & ‘E’ gmÝÐ
AdñWm ‘| Cu YmVw go A{^{H«$¶m H$aHo$ ¶m¡{JH$ ‘F’ XoVm h¡ & Bg dU©Z go
1
(a) ‘A’ go ‘F’ H$s g§aMZmE± ñnîQ> H$s{OE & 6=3
2
(b) ‘E’ Ho$ ‘F’ ‘|n[adV©Z Ho$ {bE g§Vw{bV amgm¶{ZH$ g‘rH$aU {b{IE & 1
(c) ‘E’ Ho$ CZ Xmo ‘hÎdnyU© H$m¶m] H$mo {b{IE {OZH$s amgm¶{ZH$ CÚmoJ ‘| ^y{‘H$m hmoVr
1
h¡ & 2=1
2
AWdm
(a) {ZåZ{b{IV àojUm| Ho$ {bE H$maU Xr{OE : 13=3
(i) h¡bmoOZ à~b Am°³grH$maH$ h¢ &

(ii) CËH¥$îQ> J¡gm| Ho$ ³dWZm§H$ AË¶{YH$ {ZåZ hmoVo h¢ &
(iii) OAm¡a Cl H$s {dÚwV²-G$UmË‘H$Vm bJ^J EH$ g‘mZ hmoVr h¡ {’$a ^r
Am°³grOZ H Am~ÝY ~ZmVm h¡ O~{H$ Cl Zht &
(b) {ZåZ{b{IV amgm¶{ZH$ g‘rH$aUm| H$mo nyU© Ed§ gÝVw{bV H$s{OE : 12=2
(i) NaOH + Cl2 
(R>§S>m VWm VZw)
–
(ii) I (aq) + H2O (l) + O3 (g) 
37. (a) EH$ H$m~©{ZH$ ¶m¡{JH$ ‘A’ {OgH$m AmpÊdH$ gyÌ C5H10O h¡, G$UmË‘H$
Q>m°boÝg narjU XoVm h¡, ³br‘oÝgZ AnM¶Z go n-noÝQ>oZ ~ZmVm h¡ naÝVw Am¶moS>mo’$m°‘©
narjU Zht XoVm & ‘A’ H$s nhMmZ H$s{OE VWm g^r gå~Õ A{^{H«$¶mE± Xr{OE & 1+1=2
(i) àmonoZm°BH$ Aåb go 2-~«mo‘moàmonoZm°BH$ Aåb
(ii) ~oÝµOm°¶b ³bmoamBS> go ~oÝµOp¡ ëS>hmBS>
.56/2/1 16
36. An amorphous solid ‘A’ which has a crown shaped structure, burns in air
to form a gas ‘B’ which turns lime water milky. ‘B’ is also produced by
roasting of sulphide ores. ‘B’ undergoes oxidation in the presence of V 2O5
to give ‘C’ and to carry out this oxidation low temperature and high
pressure is mandatory to get a good yield of ‘C’. ‘C’ is then absorbed in
H2SO4 to give ‘D’. ‘D’ is then diluted to give a very important compound
‘E’. ‘E’ is largely responsible for the manufacture of variety of compounds
in industry. ‘E’ in concentrated form, when combined with Cu metal,
gives compound ‘F’.
From this description
1
(a) Elucidate the structure of ‘A’ to ‘F’. 6=3
2
(b) Give a balanced chemical equation for the conversion of ‘E’ to ‘F’. 1
1
(c) Give two important functions of ‘E’ in the chemical industry. 2=1
2
OR
(a) Give reasons for the following observations : 13=3

(i) Halogens are strong oxidising agents.
(ii) Noble gases have very low boiling points.
(iii) O and Cl have nearly same electronegativity, yet oxygen
forms H bond while Cl doesn’t.
(b) Complete and balance the following chemical equations : 12=2

(i) NaOH + Cl2 
(cold + dil.)
–
(ii) I (aq) + H2O (l) + O3 (g) 
37. (a) An organic compound ‘A’ having molecular formula C5H10O gives
negative Tollens’ test, forms n-pentane on Clemmensen reduction
but doesn’t give iodoform test. Identify ‘A’ and give all the
reactions involved. 1+1=2

(i) Propanoic acid to 2-Bromopropanoic acid
(ii) Benzoyl chloride to benzaldehyde
.56/2/1 17 P.T.O.
(c) Amn ~oÝµO¡pëS>hmBS> Am¡a EogrQ>¡pëS>hmBS> Ho$ ~rM H¡$go {dôX H$a|Jo ? 1
AWdm
(a) {ZåZ{b{IV A{^{H«$¶mAm| Ho$ AZwH«$‘ H$mo nyU© H$s{OE :
1
(i) (A) go (D) H$s nhMmZ H$s{OE & 4=2
2
(ii) (A) H$m AmB©.¶y.nr.E.gr. Zm‘ {b{IE & 1
(b) Amn (i) EWoZm°b Am¡a àmonoZmoZ, VWm (ii) ~oÝµOm°BH$ Aåb Am¡a µ\$sZm°b Ho$ ~rM H¡$go
{dôX H$a|Jo ? 2
.56/2/1 18
(c) How will you distinguish between benzaldehyde and
acetaldehyde ? 1
OR
(a) Complete the following sequence of reactions :
1
(i) Identify (A) to (D). 4=2
2
(ii) Give the IUPAC name of (A). 1
(b) How can you distinguish between : 2

(i) Ethanol and Propanone, and
(ii) Benzoic acid and Phenol ?
.56/2/1 19 P.T.O.
H$moS> Z§.
Code No. 56/2/2
ZmoQ> NOTE

CHEMISTRY (Theory)

.56/2/2 1 P.T.O.
gm_mÝ` {ZX}e :
h¡ &
h¡ &
h¡ &
IÊS> H$
.56/2/2 2
2 marks each.
3 marks each.
5 marks each.
such questions.
SECTION A
.56/2/2 3 P.T.O.
6. Cg àH«$‘ H$m Zm‘ {b{IE {Og‘| YmVw H$mo dmînerb ¶m¡{JH$ ‘| n[ad{V©V {H$¶m OmVm h¡
VWm Xÿgar OJh EH$Ì H$a boVo h¢ &
10. A{^{H«$¶m H$s Hw$b H$mo{Q> H$m n[aH$bZ H$s{OE {OgH$m doJ {Z¶‘ h¡
doJ = k[NH3]5/2 [O2]1/2 .
11.

12. ½byH$mog C6H12O6

(‘moba Ðì¶‘mZ : 180 g/‘mob) Ho$ 50 mL Obr¶ {db¶Z ‘|
(A) 0·1 M
(B) 0·2 M
(C) 1·0 M
(D) 2·0 M
.56/2/2 4
6. Name the process where the metal is converted into a volatile compound
and is collected elsewhere.


distillation.
10. Calculate the overall order of the reaction whose rate law is given by
Rate = k[NH3]5/2 [O2]1/2.
11.

solution will be
(A) 0·1 M
(B) 0·2 M
(C) 1·0 M
(D) 2·0 M
.56/2/2 5 P.T.O.
gH$Vo h¢ {H$ BgH$m
14. Mn2+ (na‘mUw H«$‘m§H$ = 25) ‘| CnpñWV Hw$b A¶wp½‘V Bbo³Q´>m°Zm| H$s g§»¶m h¡
(A) 2
(B) 7
(C) 3
(D) 5
H$mo H$maU (R) Ûmam A§{H$V {H$`m J`m h¡ & BZ àíZm| Ho$ ghr CÎma ZrMo {XE JE H$moS>m| (i),
.56/2/2 6
14. Total number of unpaired electrons present in Mn2+ (Atomic number = 25)
is
(A) 2
(B) 7
(C) 3
(D) 5

below : 15=5


.56/2/2 7 P.T.O.
~mÜ¶ H$a| &

IÊS> I

h¡ &
AWdm
 2
(a) MnO  S2O  H2O 
4 3
(b) MnO 4  C2O24   H  
^r Xr{OE & 2
.56/2/2 8
halogen atom.
forcing pairing.
chain.
SECTION B

angle.
OR
 2
(a) MnO  S2O  H2O 
4 3
(b) MnO 4  C2O24   H  
.56/2/2 9 P.T.O.
Xr{OE & 2
AWdm

Cu2+ (aq) + Ni (s)  Ni2+ (aq) + Cu (s)
{b{IE & 2
27. {ZåZ{b{IV pñW{V¶m| ‘| {db¶Z ‘| {dbo¶ H$s AdñWm H$s àmJw{³V H$s{OE : 2
(a) O~ ‘i’ H$m ‘mZ 0·3 nm¶m J¶m &
(b) O~ ‘i’ H$m ‘mZ 4 nm¶m J¶m &
IÊS> J
(a) {ZAmoàrZ
(b) ZmBbm°Z-6,6
(c) S>oH«$m°Z
AWdm
{ZåZ{b{IV ~hþbH$m| ‘| EH$bH$m| Ho$ Zm‘ {b{IE : 13=3
.56/2/2 10
OR

Cu2+ (aq) + Ni (s)  Ni2+ (aq) + Cu (s),
cell at 25C. 2
27. Predict the state of the solute in the solution in the following situations : 2
(a) When ‘i’ is found to be 0·3.
(b) When ‘i’ is found to be 4.
SECTION C
(a) Neoprene
(b) Nylon-6,6
(c) Dacron
OR
Write the names of monomers in the following polymers : 13=3
.56/2/2 11 P.T.O.
AWdm
(i) [Fe(CN)6]4–
(ii) [CoF6]3–
(iii) [Ni(CO)4]
[ na_mUw H«$_m§H$ : Fe = 26, Co = 27, Ni = 28]
30.
¶m¡{JH$m| H$mo {ZåZ{b{IV nyN>r JBª {dñWmnZ H$s A{^{H«$¶merbVm Ho$ Amamohr H«$‘ ‘|
1
ì¶dpñWV H$s{OE Am¡a H$maU XoH$a CÎma H$s nw{îQ> H$s{OE : 1 2=3
2
(a) SN1
(b) SN2

32. gmoZo Ho$ {ZjmbZ ‘| g§~Õ amgm¶{ZH$ A{^{H«$¶mE± Xr{OE & Bg àH«$‘ ‘| Zn H$s ^y{‘H$m ³¶m
h¡ ? 2+1=3
.56/2/2 12

OR
complexes : 3
(i) [Fe(CN)6]4–
(ii) [CoF6]3–
(iii) [Ni(CO)4]
30. Justify and arrange the following compounds namely
in increasing order of reactivity towards the asked displacement

1
namely : 1 2=3
2
(a) SN1
(b) SN2

32. Give the chemical reactions involved in the leaching of gold. What is the
role of Zn in this process ? 2+1=3
.56/2/2 13 P.T.O.
33. H$mobamD$e H$m {Z¶‘ {b{IE & Sr(NO3)2 H$s ‘moba MmbH$Vm n[aH${bV H$s{OE &

Sr2+ Am¡a NO Am¶Zm| H$s ‘moba Am¶{ZH$ MmbH$Vm H«$‘e… 119 S cm2 mol–1 Am¡a
3
72 S cm2 mol–1 h¡ & 3
IÊS> K
narjU Zht XoVm & ‘A’ H$s nhMmZ H$s{OE VWm g^r gå~Õ A{^{H«$¶mE± Xr{OE & 1+1=2
AWdm
1
2
{dôX H$a|Jo ? 2
.56/2/2 14
33. State Kohlrausch’s law. Calculate the molar conductance of Sr(NO3)2.
The molar ionic conductance of Sr2+ and NO3 ions are 119 S cm2 mol–1
and 72 S cm2 mol–1 respectively. 3

SECTION D

acetaldehyde ? 1
OR
1
2
.56/2/2 15 P.T.O.

[{X`m J`m h¡ : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021]
AWdm
1
16
.56/2/2 16
questions :


Calculate t1/2. 2
[Given : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021]
OR
1 th
to its value ? 3
16
.56/2/2 17 P.T.O.
1
2
1
h¡ & 2=1
2
AWdm

(iii) OAm¡a Cl H$s {dÚwV²-G$UmË‘H$Vm bJ^J EH$ g‘mZ hmoVr h¡ {’$a ^r
(i) NaOH + Cl2 
(R>§S>m VWm VZw)
–
(ii) I (aq) + H2O (l) + O3 (g) 
.56/2/2 18
1
2
1
2
OR


(i) NaOH + Cl2 
(cold + dil.)
–
(ii) I (aq) + H2O (l) + O3 (g) 
.56/2/2 19 P.T.O.
H$moS> Z§.
Code No. 56/2/3
ZmoQ> NOTE

CHEMISTRY (Theory)

.56/2/3 1 P.T.O.
gm_mÝ` {ZX}e :
h¡ &
h¡ &
h¡ &
IÊS> H$
.56/2/3 2
2 marks each.
3 marks each.
5 marks each.
such questions.
SECTION A
.56/2/3 3 P.T.O.
6. A¶ñH$m| Ho$ gÁOrH$aU Ho$ {bE à¶w³V Cg àH«$‘ H$m Zm‘ {b{IE Omo A¶ñH$ VWm J¢J
H$Um| Ho$ Amno{jH$ KZËd Ho$ A§Va na AmYm[aV h¡ &
10. Cg A{^{H«$¶m H$s Hw$b H$mo{Q> H$m n[aH$bZ H$s{OE {OgH$m doJ {Z¶‘ {ZåZ àH$ma {X¶m J`m
h¡ :
doJ = k[SO2]1/4 [O2]3/4 .

12.

13. ½byH$mog C6H12O6 (‘moba Ðì¶‘mZ : 180 g/‘mob) Ho$ 50 mL Obr¶ {db¶Z ‘|
(A) 0·1 M
(B) 0·2 M
(C) 1·0 M
(D) 2·0 M
.56/2/3 4
6. Name the process used for the benefaction of ores which is based on the
difference in the gravities of ore and the gangue particles.
distillation.
10. Calculate the overall order of the reaction whose rate law is given by
Rate = k[SO2]1/4 [O2]3/4.

12.

solution will be
(A) 0·1 M
(B) 0·2 M
(C) 1·0 M
(D) 2·0 M
.56/2/3 5 P.T.O.
14. Cr3+ (na‘mUw H«$‘m§H$ = 24) ‘| CnpñWV Hw$b A¶wp½‘V Bbo³Q´>m°Zm| H$s g§»¶m h¡
(A) 2
(B) 7
(C) 3
(D) 5
gH$Vo h¢ {H$ BgH$m

.56/2/3 6
14. Total number of unpaired electrons present in Cr3+ (Atomic number = 24)
is
(A) 2
(B) 7
(C) 3
(D) 5

below : 15=5



chain.
.56/2/3 7 P.T.O.
~mÜ¶ H$a| &
IÊS> I
21. {ZåZ{b{IV pñW{V¶m| ‘| {dbo¶ H$s AdñWm H$s àmJw{³V H$s{OE : 12=2
(a) àm¶mo{JH$ Vm¡a na kmV {H$¶m J¶m ‘moba Ðì¶‘mZ dmñV{dH$ ‘mZ go A{YH$ hmoVm h¡ &
(b) ‘i’ H$m ‘mZ 0·4 hmo &

–
F2 (g) + 2I (aq)  2F – (aq) + I2 (s)
{b{IE & 2


(a) MnO  Fe 2   H  
4

(b) MnO  Mn 2   H2O 
4

AWdm
.56/2/3 8
forcing pairing.
halogen atom.
SECTION B
21. Predict the state of the solute in the following situations : 12=2
(a) Experimentally determined molar mass is more than the true value.
(b) ‘i’ value is 0·4.

–
F2 (g) + 2I (aq)  2F – (aq) + I2 (s),
cell at 25C. 2


(a) MnO  Fe 2   H  
4

(b) MnO  Mn 2   H2O 
4

OR
.56/2/3 9 P.T.O.

h¡ &
Xr{OE & 2
AWdm
^r Xr{OE & 2
IÊS> J
(a) àmH¥${VH$ a~a
(b) ã¶yZm-S
(c) ZmodmoboH$
AWdm
{ZåZ{b{IV ~hþbH$m| ‘| EH$bH$m| Ho$ Zm‘ {b{IE : 13=3
.56/2/3 10

angle.
OR
SECTION C
(a) Natural rubber
(b) Buna-S
(c) Novolac
OR
Write the names of monomers in the following polymers : 13=3
.56/2/3 11 P.T.O.
29. Mm±Xr Ho$ {ZjmbZ ‘| g§~Õ amgm¶{ZH$ A{^{H«$¶mE± Xr{OE & Bg àH«$‘ ‘| Zn H$s ³¶m
^y{‘H$m h¡ ? 3
30. H$mobamD$e H$m {Z¶‘ {b{IE & Ba(OH)2 H$s ‘moba MmbH$Vm n[aH${bV H$s{OE & Ba2+
Am¡a OH– Am¶Zm| H$s ‘moba Am¶{ZH$ MmbH$Vm H«$‘e… 127 Am¡a 199 S cm2 mol–1 h¡ & 3

AWdm
(i) [Fe(CN)6]4–
(ii) [CoF6]3–
(iii) [Ni(CO)4]
[ na_mUw H«$_m§H$ : Fe = 26, Co = 27, Ni = 28]
34. Eo{Wb ³bmoamBS>, AmBgmoàmo{nb ³bmoamBS>, V¥Vr¶H$ ã¶y{Q>b ³bmoamBS> ¶m¡{JH$m| H$mo
{ZåZ{b{IV nyN>r JB© {dñWmnZ H$s A{^{H«$¶merbVm Ho$ Amamohr H«$‘ ‘| ì¶dpñWV H$s{OE
Am¡a H$maU XoH$a AnZo CÎma H$s nw{îQ> H$s{OE : 3
(a) SN1
(b) SN2
.56/2/3 12
29. Give the chemical reactions involved in the leaching of silver. What is the
role of Zn in this process ? 3
30. State Kohlrausch’s law. Calculate the molar conductance of Ba(OH)2.

–
The molar ionic conductance of Ba2+ and OH ions are 127 and
2 –1
199 S cm mol respectively. 3



OR
complexes : 3
(i) [Fe(CN)6]4–
(ii) [CoF6]3–
(iii) [Ni(CO)4]
34. Justify and arrange the following compounds namely, ethyl chloride,
isopropyl chloride, tertiary butyl chloride in increasing order of reactivity
towards the asked displacement namely : 3
(a) SN1
(b) SN2
.56/2/3 13 P.T.O.
IÊS> K
1
2
1
h¡ & 2=1
2
AWdm
(iii) O Am¡a Cl H$s {dÚwV²-G$UmË‘H$Vm bJ^J EH$ g‘mZ hmoVr h¡ {’$a ^r
(i) NaOH + Cl2 
(R>§S>m VWm VZw)
(ii) I– (aq) + H2O (l) + O3 (g) 
narjU Zht XoVm & ‘A’ H$s nhMmZ H$s{OE VWm g^r gå~Õ A{^{H«$¶mE±
Xr{OE & 1+1=2
.56/2/3 14
SECTION D
1
2
1
2
OR


(i) NaOH + Cl2 
(cold + dil.)
–
(ii) I (aq) + H2O (l) + O3 (g) 
.56/2/3 15 P.T.O.
AWdm
1
2
{dôX H$a|Jo ? 2

.56/2/3 16
acetaldehyde ? 1
OR
1
2

questions :

.56/2/3 17 P.T.O.
[{X`m J`m h¡ : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021]
AWdm
1
16
.56/2/3 18
Calculate t1/2. 2
[Given : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021]
OR
1 th
to its value ? 3
16
.56/2/3 19 P.T.O.
H$moS> Z§.
Code No. 56/3/1
ZmoQ> NOTE

CHEMISTRY (Theory)

.56/3/1 1 P.T.O.
gm_mÝ` {ZX}e :
h¡ &
h¡ &
h¡ &
IÊS> H$
AmdV© gmaUr Ho$ d-ãbm°H$ ‘| dJ© 3 go 12 Ho$ VÎd AmVo h¢ Omo g§H«$‘U VÎdm| Ho$ ê$n ‘| OmZo
OmVo h¢ & gm‘mÝ¶ ê$n go BZ VÎdm| H$m Bbo³Q´>m°{ZH$ {dÝ¶mg (n – 1) d1–10 ns1–2 h¡ & BZ
na‘mUwAm| Ho$ Cnm§{V‘ D$Om© ñVa Ho$ d-H$jH$m| ‘| Bbo³Q´>m°Z âo OmVo h¢ VWm Bg àH$ma
g§H«$‘U YmVwAm| H$s VrZ n§{³V¶m± AWm©V² 3d, 4d d 5d loUr àmßV hmoVr h¢ & VWm{n Zn, Cd
Am¡a Hg H$mo g§H«$‘U VÎd Zht ‘mZm OmVm h¡ & g§H«$‘U VÎd Hw$N> A{^bmj{UH$ JwU Xem©Vo
h¢ O¡go n[adV©Zr` Am°³grH$aU AdñWmE±, g§Hw$b {Z‘m©U, a§JrZ Am¶Zm| Am¡a {‘lmVwAm| H$m
~ZZm, CËàoaH$s¶ g{H«$¶Vm Am{X & g§H«$‘U YmVwE± (Zn, Cd Am¡a Hg Ho$ AndmXm| Ho$ gmW)
H$R>moa hmoVr h¢ Am¡a BZHo$ JbZm§H$ CÀM hmoVo h¢ &
.56/3/1 2
2 marks each.
3 marks each.
5 marks each.
such questions.
SECTION A
The d-block of the periodic table contains the elements of the groups
3 – 12 and are known as transition elements. In general, the electronic
configuration of these elements is (n – 1) d1–10 ns1–2. The d-orbitals of the
penultimate energy level in their atoms receive electrons giving rise to
the three rows of the transition metals i.e., 3d, 4d and 5d series.
However, Zn, Cd and Hg are not regarded as transition elements.
Transition elements exhibit certain characteristic properties like variable
oxidation states, complex formation, formation of coloured ions and
alloys, catalytic activity, etc. Transition metals are hard (except Zn, Cd
and Hg) and have a high melting point.
.56/3/1 3 P.T.O.
1. Zn, Cd Am¡a Hg g§H«$‘U VÎd ³¶m| Zht ‘mZo OmVo h¢ ?
2. 3d loUr H$m H$m¡Z-gm g§H«$_U YmVw n[adV©Zr¶ Am°³grH$aU AdñWmE± Zht Xem©Vm h¡ ?
3. g§H«$‘U YmVwE± Am¡a CZHo$ ¶m¡{JH$ CËàoaH$s¶ g{H«$¶Vm ³¶m| Xem©Vo h¢ ?
4. g§H«$‘U YmVwAm| Ho$ JbZm§H$ CÀM ³¶m| hmoVo h¢ ?
5. Obr¶ {db¶Z ‘| Cu2+ Am¶Z a§JrZ ³¶m| hmoVm h¡ O~{H$ Zn2+ Am¶Z a§JhrZ hmoVm h¡ &
6. Anmobmo A§V[aj H$m¶©H«$‘ ‘| à¶moJ ‘| bmE JE gob H$m Zm‘ {b{IE &
7. 1 ‘mob H2O H$mo O2 ‘| Am°³grH¥$V H$aZo Ho$ {bE {H$VZo Hy$bm°‘ H$s Amdí¶H$Vm hmoVr h¡ ?
8. {H$gr àW‘ H$mo{Q> H$s A{^{H«$¶m Ho$ {bE g‘¶ Ho$ gmW ln[R] Ho$ {dMaU H$mo Xem©Zo dmbo
J«m’$ Ho$ T>mb H$m _mZ {b{IE &
9. Cg S>mBg¡Ho$amBS> H$m Zm‘ {b{IE Omo Ob-AnKQ>Z na ½byH$mog Ho$ Xmo AUw XoVm h¡ &
10. X§V‘§OZ ‘| BñVo‘mb {H$E OmZo dmbo g§píbîQ> An‘mO©H$ Ho$ dJ© H$m Zm‘ {b{IE &
11. {ZåZ{b{IV ‘| go {H$gH$m emoYZ ‘§S>b n[aîH$aU {d{Y Ûmam hmoVm h¡ ?

(A) Cu
(B) Zn
(C) Ge
(D) Sn
12. ao{g_rH$aU hmoVm h¡

(A) SN2 A{^{H«$¶m ‘|
(B) SN1 A{^{H«$¶m ‘|
(C) Z Vmo SN2 A{^{H«$`m ‘| Am¡a Z hr SN1 A{^{H«$¶m ‘|
(D) SN2 A{^{H«$¶m Am¡a SN1 A{^{H«$¶m XmoZm| ‘|
.56/3/1 4
1. Why are Zn, Cd and Hg non-transition elements ?
2. Which transition metal of 3d series does not show variable oxidation

states ?
3. Why do transition metals and their compounds show catalytic activity ?
4. Why are melting points of transition metals high ?
5. Why is Cu2+ ion coloured while Zn2+ ion is colourless in aqueous

solution ?
6. Name the cell which was used in the Apollo Space Programme.
7. How many coulombs are required for the oxidation of 1 mol of H2O to O2 ?
8. Write the slope value obtained in the plot of ln[R] vs. time for a first
order reaction.
9. Name the disaccharide which on hydrolysis gives two molecules of

glucose.
10. Name the class of the synthetic detergent which is used in toothpaste.
11. Which of the following is refined by the zone refining process ?

(A) Cu
(B) Zn
(C) Ge
(D) Sn
12. Racemisation occurs in

(A) SN2 reaction
(B) SN1 reaction
(C) Neither SN2 nor SN1 reactions
(D) SN2 reaction as well as SN1 reaction
.56/3/1 5 P.T.O.
13. CHCl3 Am¡a EoëH$mohm°br KOH Ho$ gmW CH2 – NH2 H$mo J‘© H$aZo na ~Zm XþJ©ÝY
XoZo dmbm nXmW© h¡
14. ¶m¡{JH$ CrCl3 . 6H2O H$m EH$ ‘mob AgNO3 {db¶Z Ho$ Am{Y³¶ Ho$ gmW A{^{H«$¶m
H$aHo$ AgCl (s) Ho$ Xmo ‘mob ~ZmVm h¡ & ¶m¡{JH$ H$m g§aMZmË‘H$ gyÌ h¡
(A) [Cr(H2O)5 Cl] Cl2 . H2O
(B) [Cr(H2O)3 Cl3] . 3H2O
(C) [Cr(H2O)4 Cl2] Cl . 2H2O
(D) [Cr(H2O)6] Cl3
15. noßQ>mBS> ~§Y CnpñWV hmoVm h¡

(A) H$m~m}hmBS´>oQ>m| ‘|
(B) {dQ>m{‘Zm| ‘|
(C) àmoQ>rZm| ‘|
(D) a~a ‘|
.56/3/1 6
13. CH2 – NH2 on heating with CHCl3 and alcoholic KOH gives foul
smell of
14. One mole of CrCl3 . 6H2O compound reacts with excess AgNO3 solution
to yield two moles of AgCl (s). The structural formula of the compound is
(A) [Cr(H2O)5 Cl] Cl2 . H2O
(B) [Cr(H2O)3 Cl3] . 3H2O
(C) [Cr(H2O)4 Cl2] Cl . 2H2O
(D) [Cr(H2O)6] Cl3
15. Peptide linkage is present in

(A) Carbohydrates
(B) Vitamins
(C) Proteins
(D) Rubber
below : 15=5

.56/3/1 7 P.T.O.
16. A{^H$WZ (A) : gmÝÐVm KQ>Zo Ho$ gmW {dÚwV²-AnKQ>ç H$s MmbH$Vm KQ>Vr h¡ &
H$maU (R) : VZwH$aU H$aZo na à{V BH$mB© Am¶VZ ‘| Am¶Zm| H$s g§»¶m ~‹T>Vr h¡ &
17. A{^H$WZ (A) : EoëH$mohm°bm| ‘| C–O–H Am~ÝY H$moU MVwî’$bH$s¶ H$moU go Oam gm
H$‘ hmoVm h¡ &
H$maU (R) : Am°³grOZ na Xmo EH$mH$s Bbo³Q´>m°Z ¶w½‘ Ho$ ~rM à{VH$fu AÝV:{H«$¶m Ho$
H$maU hmoVm h¡ &
18. A{^H$WZ (A) : g§Hw$b [Pt(NH3)4 Cl2]2+ H$s Anojm g§Hw$b [Pt(en)2 Cl2]2+ H$‘
ñWm¶r hmoVm h¡ &
H$maU (R) : g§Hw$b [Pt(en)2 Cl2]2+ H$sboQ> à^md Xem©Vm h¡ &
19. A{^H$WZ (A) : namgaU Xm~ EH$ AUwg§»¶ JwUY‘© h¡ &
H$maU (R) : namgaU Xm~ ‘mobaVm Ho$ AZwH«$‘mZwnmVr hmoVm h¡ &
20. A{^H$WZ (A) : EopëS>hmBS>m| H$s Anojm H$sQ>moZm| H$s A{^{H«$¶merbVm A{YH$ hmoVr h¡ &
H$maU (R) : EopëS>hmBS>m| H$s VwbZm ‘| H$sQ>moZm| ‘| H$m~m}{Zb H$m~©Z H$‘ Bbo³Q´>m°ZamJr
hmoVm h¡ &
IÊS> I
21. Xr JB© A{^{H«$¶m
A + 3B  2C
‘|, C Ho$ ~ZZo H$m doJ 2·5  10–4 mol L–1 s–1 h¡ &
n[aH${bV H$s{OE :
(i) A{^{H«$¶m H$m doJ, Am¡a
(ii) B Ho$ bwßV hmoZo H$m doJ & 2
22. {ZåZ{b{IV H$s ^y{‘H$m {b{IE :

(i) Eobw{‘{Z¶‘ Ho$ {ZîH$f©U ‘| NaAlF4 H$s 1
(ii) Ni Ho$ emoYZ ‘| CO H$s 1
AWdm
~m°³gmBQ> A¶ñH$ Ho$ {ZjmbZ Ûmam ewÕ Eobw{‘Zm àmßV H$aZo go gå~Õ amgm¶{ZH$ g‘rH$aU|
{b{IE & 2
.56/3/1 8
16. Assertion (A) : Conductivity of an electrolyte decreases with decrease in
concentration.
Reason (R) : Number of ions per unit volume increases on dilution.
17. Assertion (A) : The C – O – H bond angle in alcohols is slightly less than
the tetrahedral angle.
Reason (R) : This is due to the repulsive interaction between the two
lone electron pairs on oxygen.
18. Assertion (A) : [Pt(en)2 Cl2]2+ complex is less stable than

[Pt(NH3)4 Cl2]2+ complex.
Reason (R) : [Pt(en)2 Cl2]2+ complex shows chelate effect.
19. Assertion (A) : Osmotic pressure is a colligative property.

Reason (R) : Osmotic pressure is directly proportional to molarity.
20. Assertion (A) : Reactivity of ketones is more than aldehydes.

Reason (R) : The carbonyl carbon of ketones is less electrophilic as
compared to aldehydes.
SECTION B
21. In the given reaction

A + 3B  2C,
the rate of formation of C is 2·5  10–4 mol L–1 s–1.
Calculate the
(i) rate of reaction, and
(ii) rate of disappearance of B. 2
22. Write the role of the following :

(i) NaAlF4 in the extraction of Aluminium 1
(ii) CO in the refining of Ni 1

OR
Write the chemical equations involved in the leaching of bauxite ore to
prepare pure alumina. 2
.56/3/1 9 P.T.O.
23. ^m¡{VH$ A{YemofU Am¡a agmoemofU Ho$ ~rM Xmo AÝVa {b{IE & 2
AWdm
àË¶oH$ Ho$ {bE Cn¶w³V CXmhaU g{hV {ZåZ{b{IV nXm| H$mo n[a^m{fV H$s{OE : 2
(i) ghMmar H$mobm°BS>

(ii) O/W B‘ëeZ (nm¶g)
24. (a) g§Hw$b [CoF6]3 – H$m AmB ¶y nr E gr Zm‘ Am¡a g§H$aU {b{IE &
({X¶m J`m h¡ : Co H$m na‘mUw H«$‘m§H$ = 27)
(b) g§Hw$b [Co(en)2 Cl2]2+ Ûmam {H$g àH$ma H$s g‘md¶dVm Xem©B© OmVr h¡ ? Bg
g§Hw$b Ho$ Cg g‘md¶d H$s g§aMZm H$m Zm‘ {b{IE Omo Y«wdU KyU©H$ hmo & 2
25. H$maU Xr{OE : 2
(i) Xm‹T>r ~ZmZo Ho$ gm~wZ ‘| p½bgam°b hmoVm h¡ &

(ii) à{VAåbm| H$m Cn¶moJ A{YH$ g‘¶ VH$ Zht H$aZm Mm{hE &
26. {ZåZ{b{IV nXm| H$s n[a^mfm {b{IE : 2
(i) Amo{bJmog¡Ho$amBS>
(ii) And¥V eH©$am
27. {ZåZ{b{IV A{^{H«$¶m Ho$ CËnmXm| H$mo {b{IE :
6 XeF4 + 12 H2O 
³¶m ¶h A{^{H«$¶m Ag‘mZwnmVZ A{^{H«$¶m h¡ ? AnZo CÎma Ho$ g‘W©Z ‘| H$maU Xr{OE & 2
.56/3/1 10
23. Write two differences between physisorption and chemisorption. 2
OR
Define the following terms with a suitable example of each : 2
(i) Associated colloids
(ii) O/W emulsion
24. (a) Write the IUPAC name and hybridisation of the complex [CoF6]3–.
(Given : Atomic number of Co = 27)
(b) What type of isomerism is shown by the complex [Co(en)2 Cl2]2+ ?
Name the structure of an isomer of this complex which is optically

active. 2
25. Give reasons : 2
(i) Shaving soaps contain glycerol.
(ii) Antacids should not be used for longer time.
26. Define the following terms : 2
(i) Oligosaccharides
(ii) Invert sugar
27. Write the products of the following reaction :
6 XeF4 + 12 H2O 
Is this reaction a disproportionation reaction ? Give reasons in support of

your answer. 2
.56/3/1 11 P.T.O.
IÊS> J
28. 298 K na Xr JB© A{^{H«$¶m Ho$ {bE A{YH$V‘ H$m¶© Am¡a log Kc n[aH${bV H$s{OE : 3
Ni (s) + 2 Ag+ (aq)  Ni2+ (aq) + 2 Ag (s)

{X¶m J`m h¡ :
Eo 2  = – 0·25 V, Eo  = + 0·80 V
Ni / Ni Ag / Ag
1 F = 96500 C mol–1
29. {H$gr àW‘ H$mo{Q> H$s A{^{H«$¶m H$mo 40% nyU© hmoZo ‘| 80 {‘ZQ> bJVo h¢ & doJ pñWam§H$ (k)
H$m ‘mZ n[aH${bV H$s{OE & {H$VZo g‘¶ ‘| A{^{H«$¶m 90% nyU© hmoJr ? 3
[ {X`m J`m h¡ : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021, log 5 = 0·6771,
log 6 = 0·7782]
30. {ZåZ{b{IV ~hþbH$m| ‘| EH$bH$m| Ho$ Zm‘ Am¡a g§aMZmE± {b{IE : 3

(i) ã¶yZm-S
(ii) ZmBbm°Z-6,6
(iii) ~¡Ho$bmBQ>
31. {ZåZ{b{IV A{^{H«$¶mAm| Ho$ ‘w»¶ CËnmX/CËnmXm| H$mo {b{IE : 3
.56/3/1 12
SECTION C
28. Calculate the maximum work and log Kc for the given reaction at 298 K : 3
Ni (s) + 2 Ag+ (aq)  Ni2+ (aq) + 2 Ag (s)

Given :
Eo 2  = – 0·25 V, Eo  = + 0·80 V
Ni / Ni Ag / Ag
1 F = 96500 C mol–1
29. A first order reaction is 40% complete in 80 minutes. Calculate the value
of rate constant (k). In what time will the reaction be 90% completed ? 3
[Given : log 2 = 0·3010, log 3 = 0·4771, log 4 = 0·6021, log 5 = 0·6771,

log 6 = 0·7782]
30. Write the names and structures of the monomers in the following
polymers : 3
(i) Buna-S
(ii) Nylon-6,6
(iii) Bakelite
31. Write the major product(s) of the following reactions : 3
.56/3/1 13 P.T.O.
32. (a) {ZåZ{b{IV A{^{H«$¶m H$s {H«$¶m{d{Y {b{IE :
H
2 CH3CH2OH  CH3CH2OCH2CH3 + H2O
413 K
(b) ³¶y‘rZ go µ\$sZm°b H$m {daMZ {b{IE & 2+1=3

AWdm
Amn {ZåZ{b{IV n[adV©Z H¡$go gånÞ H$a|Jo : 3
(i) gmo{S>¶‘ ’$sZm°³gmBS> go o-hmBS´>mo³gr~oÝµOmoBH$ Aåb
(ii) EogrQ>moZ go àmonrZ
(iii) µ\$sZm°b go ³bmoamo~oÝµOrZ
33. {Z{‘©V CËnmXm| H$mo {b{IE O~ (CH3)3 C – CHO {ZåZ{b{IV A{^H$‘©H$m| Ho$ gmW
A{^{H«$¶m H$aVm h¡ : 3
(i) VZw NaOH H$s CnpñW{V ‘| CH3COCH3

(ii) HCN
(iii) gmÝÐ NaOH
34. àË¶oH$ Ho$ {bE Cn¶w³V CXmhaU XoH$a Ðd{damJr Am¡a ÐdamJr gm°b H$mo n[a^m{fV H$s{OE &
Ðd{damJr gm°b H$s VwbZm ‘| ÐdamJr gm°b H$m ñH§$XZ H${R>Z ³¶m| hmoVm h¡ ? 3
AWdm
{ZåZ{b{IV nXm| H$mo n[a^m{fV H$s{OE : 3
(i) AmH$ma-daUmË‘H$ CËàoaU
(ii) H«$mâQ> Vmn
(iii) noßQ>Z (noßQ>mBµOoeZ)
IÊS> K
35. (a) H$maU Xr{OE : 3
(i) µOrZm°Z H$s ^m±{V hr{b¶‘ ¶m¡{JH$ Zht ~ZmVr &
(ii) HOCl H$s Anojm HClO4 à~bVa Aåb h¡ &
(iii) J§YH$ EH$ ~hþna‘mUwH$ R>mog h¡ O~{H$ Am°³grOZ {Ûna‘mUwH$ J¡g h¡ &
.56/3/1 14
32. (a) Write the mechanism of the following reaction :
H
413 K
(b) Write the preparation of phenol from cumene. 2+1=3

OR
How can you convert the following : 3
(i) Sodium phenoxide to o-hydroxybenzoic acid
(ii) Acetone to propene
(iii) Phenol to chlorobenzene
33. Write the products formed when (CH3)3 C – CHO reacts with the
following reagents : 3
(i) CH3COCH3 in the presence of dilute NaOH
(ii) HCN
(iii) Conc. NaOH
34. Define Lyophobic and Lyophilic sol with a suitable example of each. Why
is coagulation of Lyophilic sol difficult as compared to Lyophobic sol ? 3
OR
Define the following terms : 3
(i) Shape-selective catalysis
(ii) Kraft temperature
(iii) Peptization
SECTION D
35. (a) Give reasons : 3
(i) Helium does not form compounds like Xenon.

(ii) HClO4 is a stronger acid than HOCl.
(iii) Sulphur is a polyatomic solid whereas Oxygen is a diatomic

gas.
.56/3/1 15 P.T.O.
(b) ¶h Xem©Zo Ho$ {bE {H$ gmÝÐ H2SO4
(i) Am°³grH$maH$, Ed§
(ii) {ZO©bZ H$_©H$ H$s ^m±{V H$m¶© H$aVm h¡,
àË¶oH$ Ho$ {bE CXmhaU Ho$ ê$n _| EH$-EH$ A{^{H«$¶m {b{IE & 2
AWdm
(a) {ZåZ{b{IV Ho$ {bE H$maU Xr{OE :
(i) Cl– Am¶Z H$s Anojm F – Am¶Z H$s Ob¶moOZ EÝW¡ënr A{YH$ hmoVr h¡ & 1
(ii) dJ©-16 Ho$ Am°³gmBS>m| ‘| SO2 EH$ AnMm¶H$ h¡, O~{H$ TeO2 EH$
Am°³grH$maH$ h¡ & 1
(b) F2 H$s Ob Ho$ gmW A{^{H«$¶m {b{IE & Am¶moS>rZ (I2) Ob Ho$ gmW A{^{H«$¶m
³¶m| Zht H$aVr ? 1+1
(c) XeF2 H$s g§aMZm ~ZmBE & 1
36. (a) H$maU Xr{OE : 3
(i) ¶Ú{n  NH2 g‘yh Bbo³Q´>m°ZamJr à{VñWmnZ A{^{H«$¶mAm| ‘| Am°Wm} Ed§
n¡am {ZX}eH$ hmoVm h¡ {’$a ^r Eo{ZbrZ ZmBQ´>moH$aU Ûmam ¶WoîQ> _mÌm ‘|
‘oQ>m-ZmBQ´>moEo{ZbrZ XoVr h¡ &
(ii) Obr¶ {db¶Z ‘| (CH3)3 N H$s Anojm (CH3)2 NH A{YH$ jmaH$s¶
hmoVm h¡ &
(iii) ewÕ àmW{‘H$ Eo‘rZm| Ho$ {daMZ Ho$ {bE EopëH$b h¡bmBS>m| H$m
Eo‘moZr-AnKQ>Z EH$ AÀN>r {d{Y Zht h¡ &
(b) {ZåZ{b{IV Ho$ ‘Ü¶ {dôX H$s{OE : 2
(i) CH3CH2NH2 Am¡a (CH3CH2)2 NH
(ii) Eo{ZbrZ Am¡a CH3NH2
AWdm
(a) {ZåZ{b{IV A{^{H«$¶mAm| ‘| A Am¡a B H$s g§aMZmE± {b{IE :
CuCN H 2O / H 
(i) C6H5 N 2 Cl–  A   B 1
NH3 NaOBr
(ii) CH3COOH   A  B 1

(b) ‘o{Wb Eo_rZ H$s ~oÝµOm°¶b ³bmoamBS> Ho$ gmW amgm¶{ZH$ A{^{H«$¶m {b{IE Am¡a
àmßV CËnmX H$m AmB ¶y nr E gr Zm‘ {b{IE & 1+1
(c) {ZåZ{b{IV H$mo CZHo$ pKb ‘mZm| Ho$ ~‹T>Vo hþE H«$‘ ‘| ì¶dpñWV H$s{OE : 1
C6H5NH2, NH3, C2H5NH2, (C2H5)2 NH
.56/3/1 16
(b) Write one reaction as an example of each, to show that
conc. H2SO4 acts as
(i) an oxidising agent, and
(ii) a dehydrating agent. 2
OR
(a) Account for the following :
(i) Hydration enthalpy of F – ion is more than Cl – ion. 1
(ii) SO2 is a reducing agent, whereas TeO2 is an oxidising agent
in group-16 oxides. 1
(b) Write the reaction of F2 with water. Why does I2 not react with
water ? 1+1
(c) Draw the structure of XeF2. 1

(i) Although – NH2 group is o/p directing in electrophilic
substitution reactions, yet aniline, on nitration gives good
yield of m-nitroaniline.
(ii) (CH3)2 NH is more basic than (CH3)3 N in an aqueous
solution.
(iii) Ammonolysis of alkyl halides is not a good method to
prepare pure primary amines.
(b) Distinguish between the following : 2
(i) CH3CH2NH2 and (CH3CH2)2 NH
(ii) Aniline and CH3NH2
OR
(a) Write the structures of A and B in the following reactions :
 CuCN H O /H
(i) C6H5 N 2 Cl–  A 2  B 1
NH3 NaOBr
(ii) CH3COOH   A  B 1

(b) Write the chemical reaction of methyl amine with benzoyl chloride
and write the IUPAC name of the product obtained. 1+1
(c) Arrange the following in the increasing order of their pKb values : 1
.56/3/1 17 P.T.O.
37. (a) {H$gr {db¶Z ‘| 5·85 g NaCl (‘moba Ðì¶‘mZ = 58·5 g mol–1) à{V brQ>a
{db¶Z {dÚ‘mZ h¡ & BgH$m 27C na namgaU Xm~ 4·75 dm¶w‘§S>b (atm) h¡ & Bg
{db¶Z ‘| NaCl H$s {d¶moOZ ‘mÌm n[aH${bV H$s{OE & 3
({X¶m J`m h¡ : R = 0·082 L atm K–1 mol–1)
(b) hoZar {Z¶‘ {b{IE & JmoVmImoam| Ûmam à¶w³V dm¶w H$mo hr{b¶‘ go VZwH$aU H$aHo$
Q>¡ÝH$m| ‘| ³¶m| âm OmVm h¡ ? 1+1
AWdm
(a) F – CH2 – COOH (‘moba Ðì¶‘mZ = 78 g mol–1) Ho$ 19·5 g H$mo 500 g Ob
‘| KmobZo na {h‘m§H$ ‘| 1C H$m AdZ‘Z XoIm J¶m & F – CH2 – COOH H$s
{d¶moOZ ‘mÌm n[aH${bV H$s{OE & 3
[ {X¶m J`m h¡ : Ob Ho$ {bE Kf = 1·86 K kg mol–1]
(b) H$maU Xr{OE :

(i) 0·1 M KCl H$m ³dWZm§H$ 0·1 M ½byH$mog H$s VwbZm ‘| CÀMVa hmoVm h¡ & 1
(ii) bdU {‘bmZo na ‘m§g A{YH$ g‘¶ VH$ n[aa{jV ahVm h¡ & 1
.56/3/1 18
37. (a) A solution contains 5·85 g NaCl (Molar mass = 58·5 g mol–1) per
litre of solution. It has an osmotic pressure of 4·75 atm at 27C.
Calculate the degree of dissociation of NaCl in this solution. 3
(Given : R = 0·082 L atm K–1 mol–1)
(b) State Henry’s law. Why is air diluted with helium in the tanks
used by scuba divers ? 1+1
OR
(a) When 19·5 g of F – CH2 – COOH (Molar mass = 78 g mol–1) is

dissolved in 500 g of water, the depression in freezing
point is observed to be 1C. Calculate the degree of dissociation of
F – CH2 – COOH. 3
[Given : Kf for water = 1·86 K kg mol–1]
(b) Give reasons :

(i) 0·1 M KCl has higher boiling point than 0·1 M Glucose. 1
(ii) Meat is preserved for a longer time by salting. 1
.56/3/1 19 P.T.O.
H$moS> Z§.
Code No. 56/3/2
ZmoQ> NOTE

CHEMISTRY (Theory)

.56/3/2 1 P.T.O.
gm_mÝ` {ZX}e :
h¡ &
h¡ &
h¡ &
IÊS> H$
.56/3/2 2
2 marks each.
3 marks each.
5 marks each.
such questions.
SECTION A
.56/3/2 3 P.T.O.
6. o-S>mB³bmoamo~oÝµOrZ Am¡a p-S>mB³bmoamo~oÝµOrZ ‘| go {H$gH$m JbZm§H$ CÀMVa h¡ ?
7. O~ ~oÝµOrZ S>mBEoµOmo{Z¶‘ ŠbmoamBS>, EWoZm°b Ho$ gmW A{^{H«$¶m H$aVm h¡ Vmo àmßV CËnmX
{b{IE &
8. NaCl Ho$ Obr¶ {db¶Z H$m {dÚwV²-AnKQ>Z H$aZo na H¡$WmoS> na àmßV CËnmX {b{IE &
9. Cg S>mBg¡Ho$amBS> H$m Zm‘ {b{IE Omo Ob-AnK{Q>V hmoH$a ½byH$mog Am¡a J¡b¡³Q>mog XoVm h¡ &
10. ZtX bmZo dmbr Jmo{b¶m| ‘| {H$g àH$ma Ho$ amgm¶{ZH$ nXmW© à¶w³V hmoVo h¢ ?
11. {ZåZ{b{IV KCl Ho$ {db¶Zm| ‘| go {H$gH$m {d{eîQ> MmbH$Ëd ‘mZ CÀMV‘ hmoJm ?
(A) 0·5 M
(B) 0·01 M
(C) 0·1 M
(D) 1·0 M
12. A{^{H«$¶m H$s {H$g H$mo{Q> Ho$ {bE A{^{H«$¶m doJ Ed§ doJ pñWam§H$ H$s BH$mB© g‘mZ hmoVr
h¡ ?
(A) àW‘
(B) eyÝ¶
(C) {ÛVr¶
(D) AY©
.56/3/2 4

states ?

solution ?
6. Out of o-dichlorobenzene and p-dichlorobenzene, which has higher

melting point ?
7. Write the product when benzene diazonium chloride reacts with ethanol.
8. Write the product obtained at cathode on electrolysis of aqueous solution

of NaCl.
9. Name the disaccharide which on hydrolysis gives glucose and galactose.
10. What type of chemical substances are used in sleeping pills ?
11. Which of the following solutions of KCl will have the highest value of
specific conductance ?
(A) 0·5 M
(B) 0·01 M
(C) 0·1 M
(D) 1·0 M
12. The unit of the rate of reaction is the same as that of the rate constant
for a
(A) first order reaction
(B) zero order reaction
(C) second order reaction
(D) half-order reaction
.56/3/2 5 P.T.O.
13. {ZåZ{b{IV A{^{H«$¶mAm| ‘| go {H$gHo$ Ûmam ’$’$moboXma Vm±~m àmßV hmoVm h¡ ?
(A) Cu2+ + Zn  Zn2+ + Cu
(B) Cu2S + FeS  2 Cu + FeS2
(C) Cu2S + 2 Cu2O  6 Cu + SO2
(D) Cu2O + C  2 Cu + CO
14. EDTA h¡
(A) EH$X§Vwa {bJÝS>
(B) {ÛX§Vwa {bJÝS>
(C) C^X§Vr {bJÝS>
(D) fQ>X§Vwa {bJÝS>
15. àmoQ>rZm| H$s {ÛVr¶H$ g§aMZm ‘| Eo‘rZmo Aåbm| Ho$ AUwAm| Ho$ H$m¡Z -go ^mJ Amng ‘| hmBS´>moOZ
Am~§Y go Ow‹S>o hmoVo h¢ ?
(A) NH2 g‘yh
(B) COOH g‘yh
(C) Am¡a – NH  g‘yh
(D) Cn`w©³V ‘| go H$moB© Zht

16. A{^H$WZ (A) : µ’$m°{‘©H$ Aåb H$s Anojm Eogr{Q>H$ Aåb A{YH$ à~b hmoVm h¡ &
H$maU (R) : Eogr{Q>H$ Aåb ‘| Bbo³Q´>m°Z XmVm ‘o{Wb g‘yh O – H Am~§Y H$m {dXbZ
H${R>Z H$a XoVm h¡ &
.56/3/2 6
13. By which of the following reactions is blister copper obtained ?
(A) Cu2+ + Zn  Zn2+ + Cu
(B) Cu2S + FeS  2 Cu + FeS2
(C) Cu2S + 2 Cu2O  6 Cu + SO2
(D) Cu2O + C  2 Cu + CO
14. EDTA is a
(A) monodentate ligand
(B) bidentate ligand
(C) ambidentate ligand
(D) hexadentate ligand
15. Which parts of amino acids molecules are linked through hydrogen bonds
in the secondary structure of proteins ?
(A) NH2 group
(B) COOH group
(C) and – NH  groups
(D) None of the above

below : 15=5

16. Assertion (A) : Acetic acid is stronger than formic acid.
Reason (R) : In acetic acid, the electron releasing methyl group makes
it difficult to break the O – H bond.
.56/3/2 7 P.T.O.
18. A{^H$WZ (A) : g§Hw$b [Pt(NH3)4 Cl2]2+ H$s Anojm g§Hw$b [Pt(en)2 Cl2]2+ H$‘
ñWm¶r hmoVm h¡ &
H$maU (R) : g§Hw$b [Pt(en)2 Cl2]2+ H$sboQ> à^md Xem©Vm h¡ &
19. A{^H$WZ (A) : p-‘o{Wbµ’$sZm°b H$s VwbZm ‘| µ’$sZm°b A{YH$ Aåbr¶ h¡ &
H$maU (R) : p-‘o{Wbµ’$sZm°b ‘| Bbo³Q´>m°Z XmVm g‘yh H$s CnpñW{V BgH$mo H$‘ Aåbr¶
H$a XoVr h¡ &
20. A{^H$WZ (A) : namgaU Xm~ EH$ AUwg§»¶ JwUY‘© h¡ &
H$maU (R) : namgaU Xm~ ‘mobaVm Ho$ AZwH«$‘mZwnmVr hmoVm h¡ &
IÊS> I

AWdm
{b{IE & 2
22. Xr JB© A{^{H«$¶m

A + 3B  2C
n[aH${bV H$s{OE :
23. (a) g§Hw$b [CoF6]3 – H$m AmB ¶y nr E gr Zm‘ Am¡a g§H$aU {b{IE &
({X¶m J`m h¡ : Co H$m na‘mUw H«$‘m§H$ = 27)
(b) g§Hw$b [Co(en)2 Cl2]2+ Ûmam {H$g àH$ma H$s g‘md¶dVm Xem©B© OmVr h¡ ? Bg
g§Hw$b Ho$ Cg g‘md¶d H$s g§aMZm H$m Zm‘ {b{IE Omo Y«wdU KyU©H$ hmo & 2
.56/3/2 8
concentration.
18. Assertion (A) : [Pt(en)2 Cl2]2+ complex is less stable than
[Pt(NH3)4 Cl2]2+ complex.
Reason (R) : [Pt(en)2 Cl2]2+ complex shows chelate effect.
19. Assertion (A) : Phenol is more acidic than p-methylphenol.
Reason (R) : The presence of an electron releasing group in
p-methylphenol makes it less acidic.
20. Assertion (A) : Osmotic pressure is a colligative property.
Reason (R) : Osmotic pressure is directly proportional to molarity.
SECTION B


OR

A + 3B  2C,
Calculate the
23. (a) Write the IUPAC name and hybridisation of the complex [CoF6]3–.
(Given : Atomic number of Co = 27)
(b) What type of isomerism is shown by the complex [Co(en)2 Cl2]2+ ?

Name the structure of an isomer of this complex which is optically
active. 2
.56/3/2 9 P.T.O.
AWdm

25. {ZåZ{b{IV A{^{H«$¶m Ho$ CËnmX {b{IE : 1

XeF6 + 2 H2O 
1
³¶m ¶h A{^{H«$¶m aoS>m°³g A{^{H«$¶m h¡ ? XeF6 H$s g§aMZm ~ZmBE & + 1 =1
2 2
26. {ZåZ{b{IV nXm| H$s n[a^mfm {b{IE : 2

(i) ½bmBH$mo{g{S>H$ ~§Y
(ii) àmH¥$V àmoQ>rZ
27. H$maU Xr{OE : 1+1=2
(i) em{IV ûm¥§Ibm dmbo An‘mO©H$m| H$s Anojm Aem{IV ûm¥§Ibm dmbo An‘mO©H$m| H$mo
dar¶Vm Xr OmVr h¡ &
(ii) EñnmQ>}‘ Ja‘ ImZm ~ZmZo Ho$ {bE à¶w³V Zht {H$¶m OmVm h¡ &
IÊS> J
log 6 = 0·7782]
.56/3/2 10
OR
(ii) O/W emulsion
25. Write the products of the following reaction : 1

XeF6 + 2 H2O 
1 1
Is this reaction a redox reaction ? Draw the structure of XeF6. + =1
2 2
26. Define the following terms : 2
(i) Glycosidic linkage
(ii) Native protein
27. Give reasons : 1+1=2

(i) Unbranched chain detergents are preferred over branched chain
detergents.
(ii) Aspartame is not used in cooking hot dishes.
SECTION C

log 6 = 0·7782]
.56/3/2 11 P.T.O.
Ni (s) + 2 Ag+ (aq)  Ni2+ (aq) + 2 Ag (s)

{X¶m J`m h¡ :
Eo 2  = – 0·25 V, Eo  = + 0·80 V
Ni / Ni Ag / Ag
1 F = 96500 C mol–1
31. {ZåZ{b{IV ~hþbH$m| ‘| EH$bH$m| Ho$ Zm‘ Am¡a g§aMZmE± {b{IE : 1+1+1=3
(i) ã¶yZm-N
(ii) àmH¥${VH$ a~a
(iii) ZmBbm°Z-6
AWdm
(ii) H«$mâQ> Vmn
.56/3/2 12
Ni (s) + 2 Ag+ (aq)  Ni2+ (aq) + 2 Ag (s)

Given :
Eo 2  = – 0·25 V, Eo  = + 0·80 V
Ni / Ni Ag / Ag
1 F = 96500 C mol–1
polymers : 1+1+1=3
(i) Buna-N
(ii) Natural rubber
(iii) Nylon-6
OR
(iii) Peptization
.56/3/2 13 P.T.O.
H
413 K

AWdm
A{^{H«$¶m H$aVm h¡ : 3

(ii) HCN
(iii) gmÝÐ NaOH
IÊS> K
({X¶m J`m h¡ : R = 0·082 L atm K–1 mol–1)
Q>¡ÝH$m| ‘| ³¶m| âm OmVm h¡ ? 1+1
AWdm
.56/3/2 14
H
413 K

OR
(ii) HCN
(iii) Conc. NaOH
SECTION D
OR

.56/3/2 15 P.T.O.
(b) H$maU Xr{OE :
36. (a) H$maU Xr{OE : 3

AWdm
37. (a) H$maU Xr{OE : 3

hmoVm h¡ &
.56/3/2 16
(b) Give reasons :


gas.

conc. H2SO4 acts as

OR

water ? 1+1

solution.
.56/3/2 17 P.T.O.

AWdm
CuCN H O /H
(i) C6H5 N 2 Cl–  A 2  B 1
NH3 NaOBr
(ii) CH3COOH   A  B 1

(c) pKb ‘mZm| Ho$ ~‹T>Vo hþE H«$‘ ‘| ì¶dpñWV

{ZåZ{b{IV H$mo CZHo$ H$s{OE : 1
.56/3/2 18
OR
CuCN H 2O / H 
(i) C6H5 N 2 Cl–  A   B 1
NH3 NaOBr
(ii) CH3COOH   A  B 1

.56/3/2 19 P.T.O.
H$moS> Z§.
Code No. 56/3/3
ZmoQ> NOTE

CHEMISTRY (Theory)

.56/3/3 1 P.T.O.
gm_mÝ` {ZX}e :
h¡ &
h¡ &
h¡ &
IÊS> H$
.56/3/3 2
2 marks each.
3 marks each.
5 marks each.
such questions.
SECTION A
.56/3/3 3 P.T.O.

6. O~ ~oÝµOrZ S>mBEµOmo{Z¶‘ ³bmoamBS> H$mo KI Ho$ gmW A{^H¥$V {H$¶m OmVm h¡ Vmo {Z{‘©V
CËnmX H$m Zm‘ {b{IE &
7.
8. g§Hw$b [Ag(CN)2]– go Ag àmßV H$aZo Ho$ {bE à¶w³V AnMm¶H$ H$m Zm‘ {b{IE &
9. Cg {dQ>m{‘Z H$m Zm‘ {b{IE {OgH$s hrZVm go ‘amo‹S> (convulsions) n‹S>Vo h¢ &
10. {ZåZ{b{IV ¶m¡{JH$m| ‘| go CZHo$ {M{H$Ëgr¶ JwUm| Ho$ AmYma na {df‘ ¶m¡{JH$ H$m M¶Z
H$s{OE :
B³d¡{Zb, ë¶y{‘Zb, ~mBWm¶moZb, goH$moZb
11. BªYZ gob ‘|

(A) amgm¶{ZH$ D$Om©, d¡ÚwV D$Om© ‘| n[ad{V©V hmoVr h¡ &
(B) BªYZ H$s XhZ D$Om© H$mo amgm¶{ZH$ D$Om© ‘| n[ad{V©V {H$¶m OmVm h¡ &
(C) BªYZ H$s XhZ D$Om© H$mo d¡ÚwV D$Om© ‘| n[ad{V©V {H$¶m OmVm h¡ &
(D) d¡ÚwV D$Om© H$mo amgm¶{ZH$ D$Om© ‘| n[ad{V©V {H$¶m OmVm h¡ &
12. ewîH$ b¡³bm§eo gob ‘| H¡$WmoS> hmoVm h¡

(A) qOH$ nmÌ
(B) MnO2
(C) J«¡’$mBQ> N>‹S>
(D) NH4Cl
.56/3/3 4

states ?

solution ?

6. Write the name of the product when benzene diazonium chloride is
treated with KI.
7.
8. Name the reducing agent used to obtain Ag from [Ag(CN)2]– complex.
9. Name the vitamin whose deficiency causes convulsions.

10. Pick out the odd one from among the following compounds on the basis of
their medicinal properties :
Equanil, Luminal, Bithional, Seconal

11. In fuel cell
(A) chemical energy is converted to electrical energy.
(B) energy of combustion of fuel is converted to chemical energy.
(C) energy of combustion of fuel is converted to electrical energy.
(D) electrical energy is converted to chemical energy.
12. In a Leclanche dry cell, the cathode is
(A) Zn container
(B) MnO2
(C) Graphite rod
(D) NH4Cl
.56/3/3 5 P.T.O.
13. {H$gr àW‘ H$mo{Q> A{^{H«$¶m Ho$ {bE doJ pñWam§H$ CgHo$ àmapå^H$ A{^{H«$¶m doJ Ho$ ~am~a
hmoJm O~ A{^H$maH$ H$s àmapå^H$ gmÝÐVm h¡
(A) 1  10–2 M
(B) 1M
(C) 10 M
(D) 0·1 M
14. O~ {H$gr d4 g§Hw$b Ho$ {bE o > P hmo Vmo {H«$ñQ>b joÌ {gÕmÝV Ho$ AmYma na BgH$m
Bbo³Q´>m°{ZH$ {dÝ¶mg h¡
(A) t2g3 eg1
(B) t2g2 eg2
(C) t2g1 eg3
(D) t2g4 eg0
15. {ZåZ{b{IV ‘| go H$m¡Z-gm AZnM`r eH©$am h¡ ?

(A) gyH«$mog
(B) ‘mëQ>mog
(C) ½byH$mog
(D) b¡³Q>mog
16. A{^H$WZ (A) : AZmXe© {db¶Z pñWa³dmWr {‘lU ~ZmVo h¢ &
H$maU (R) : A{YH$V‘ ³dWZm§H$s pñWa³dmWr, G UmË‘H$ {dMbZ Xem©Zo dmbo {db¶Z
go ~ZVo h¢ &
.56/3/3 6
13. The rate constant for a first order reaction is equal to the initial rate of
reaction when the initial concentration of the reactant is
(A) 1  10–2 M
(B) 1M
(C) 10 M
(D) 0·1 M
14. On the basis of crystal field theory, electronic configuration of d4 complex

when o > P is
(A) t2g3 eg1
(B) t2g2 eg2
(C) t2g1 eg3
(D) t2g4 eg0
15. Which of the following is a non-reducing sugar ?

(A) Sucrose
(B) Maltose
(C) Glucose
(D) Lactose
below : 15=5
16. Assertion (A) : Non-ideal solutions form azeotropic mixture.

Reason (R) : Maximum boiling azeotropes are formed by a solution
showing negative deviation.
.56/3/3 7 P.T.O.
17. A{^H$WZ (A) : AgNO3 {db¶Z Ho$ gmW g§Hw$b [Cr(H2O)3 Cl3] Adjon Zht XoVm h¡ &
H$maU (R) : g§Hw$b [Cr(H2O)3 Cl3] H$m Am¶ZZ Zht hmoVm &
19. A{^H$WZ (A) : EopëS>hmBS>m| H$s Anojm H$sQ>moZm| H$s A{^{H«$¶merbVm A{YH$ hmoVr h¡ &
H$maU (R) : EopëS>hmBS>m| H$s VwbZm ‘| H$sQ>moZm| ‘| H$m~m}{Zb H$m~©Z H$‘ Bbo³Q´>m°ZamJr
hmoVm h¡ &
20. A{^H$WZ (A) : EoëH$mohm°bm| ‘| C–O–H Am~ÝY H$moU MVwî’$bH$s¶ H$moU go Oam gm
H$‘ hmoVm h¡ &
H$maU (R) : Am°³grOZ na Xmo EH$mH$s Bbo³Q´>m°Z ¶w½‘ Ho$ ~rM à{VH$fu AÝV:{H«$¶m Ho$
H$maU hmoVm h¡ &
IÊS> I

AWdm
{b{IE & 2
AWdm

.56/3/3 8
17. Assertion (A) : The complex [Cr(H2O)3 Cl3] does not give precipitate
with AgNO3 solution.
Reason (R) : The complex [Cr(H2O)3 Cl3] is non-ionizable.

concentration.
19. Assertion (A) : Reactivity of ketones is more than aldehydes.

Reason (R) : The carbonyl carbon of ketones is less electrophilic as
compared to aldehydes.
20. Assertion (A) : The C – O – H bond angle in alcohols is slightly less than
the tetrahedral angle.
Reason (R) : This is due to the repulsive interaction between the two
lone electron pairs on oxygen.
SECTION B


OR
OR
(ii) O/W emulsion
.56/3/3 9 P.T.O.
23. Xr JB© A{^{H«$¶m
A + 3B  2C
n[aH${bV H$s{OE :

24. àË¶oH$ Ho$ {bE Cn¶w³V CXmhaU XoH$a {ZåZ{b{IV nXm| H$s n[a^mfm {b{IE : 2
(i) nr‹S>mhmar
(ii) YZm¶Zr An‘mO©H$
25. (a) Amn H¡$go àX{e©V H$a gH$Vo h¢ {H$ g§Hw$b [Co(NH3)5 Cl] SO4 Ed§
[Co(NH3)5 SO4] Cl Am¶ZZ g‘md¶d h¢ ?
(b) AmB ¶y nr E gr ‘mZXÊS> H$m à¶moJ H$aVo hþE {ZåZ{b{IV g§Hw$b H$m gyÌ {b{IE : 2
nmoQ>¡{e¶‘ Q´>mBAm°³g¡boQ>moH«$mo‘oQ> (III)
26. (a) Amn D-½byH$mog Ho$ noÝQ>mEogrQ>oQ> ‘| EopëS>hmBS> g‘yh H$s AZwnpñW{V H$s ì¶m»¶m
H¡$go H$a gH$Vo h¢ ?
(b) RNA ‘| CnpñWV jmaH$m| Ho$ Zm‘ {b{IE & BZ‘| go H$m¡Z-gm DNA ‘| Zht hmoVm
h¡ ? 2
27. {ZåZ{b{IV A{^{H«$¶m Ho$ CËnmXm| H$mo {b{IE :
6 XeF4 + 12 H2O 
³¶m ¶h A{^{H«$¶m Ag‘mZwnmVZ A{^{H«$¶m h¡ ? AnZo CÎma Ho$ g‘W©Z ‘| H$maU Xr{OE & 2
.56/3/3 10
A + 3B  2C,
Calculate the
24. Define the following terms with a suitable example of each : 2
(i) Analgesics
(ii) Cationic detergent
25. (a) How can you show that complexes [Co(NH3)5 Cl] SO4 and
[Co(NH3)5 SO4] Cl are ionization isomers ?
(b) Write the formula of the following complex using IUPAC norms : 2
Potassium trioxalatochromate (III)
26. (a) How can you explain the absence of an aldehyde group in the
pentaacetate of D-glucose ?
(b) Name the bases present in RNA. Which one of these is not present
in DNA ? 2
27. Write the products of the following reaction :
6 XeF4 + 12 H2O 
Is this reaction a disproportionation reaction ? Give reasons in support of

your answer. 2
.56/3/3 11 P.T.O.
IÊS> J
H
413 K

AWdm

Ni (s) + 2 Ag+ (aq)  Ni2+ (aq) + 2 Ag (s)

{X¶m J`m h¡ :
Eo 2  = – 0·25 V, Eo  = + 0·80 V
Ni / Ni Ag / Ag
1 F = 96500 C mol–1
.56/3/3 12
SECTION C

H
413 K

OR
Ni (s) + 2 Ag+ (aq)  Ni2+ (aq) + 2 Ag (s)

Given :
Eo 2  = – 0·25 V, Eo  = + 0·80 V
Ni / Ni Ag / Ag
1 F = 96500 C mol–1
.56/3/3 13 P.T.O.
log 6 = 0·7782]
32. {ZåZ{b{IV ~hþbH$m| ‘| EH$bH$m| Ho$ Zm‘ Am¡a g§aMZmE± {b{IE : 3

(i) {ZAmoàrZ
(ii) ‘ob¡‘rZ-’$m°‘}pëS>hmBS> ~hþbH$
(iii) Q>oâbm°Z
AWdm
(ii) H«$mâQ> Vmn
A{^{H«$¶m H$aVm h¡ : 3
(ii) HCN
(iii) gmÝÐ NaOH
IÊS> K
35. (a) H$maU Xr{OE : 3
hmoVm h¡ &
.56/3/3 14

log 6 = 0·7782]
polymers : 3
(i) Neoprene
(ii) Melamine-formaldehyde polymer
(iii) Teflon
OR
(iii) Peptization
(ii) HCN
(iii) Conc. NaOH
SECTION D
solution.
.56/3/3 15 P.T.O.
AWdm
CuCN H O /H
(i) C6H5 N 2 Cl–  A 2  B 1
NH3 NaOBr
(ii) CH3COOH   A  B 1

(c) pKb ‘mZm| Ho$ ~‹T>Vo hþE H«$‘ ‘| ì¶dpñWV

{ZåZ{b{IV H$mo CZHo$ H$s{OE : 1
({X¶m J`m h¡ : R = 0·082 L atm K–1 mol–1)
Q>¡ÝH$m| ‘| ³¶m| âm OmVm h¡ ? 1+1
AWdm
(b) H$maU Xr{OE :
.56/3/3 16
OR
CuCN H O /H
(i) C6H5 N 2 Cl–  A 2  B 1
NH3 NaOBr
(ii) CH3COOH   A  B 1

OR

(b) Give reasons :

.56/3/3 17 P.T.O.
37. (a) H$maU Xr{OE : 3
AWdm
.56/3/3 18


gas.

conc. H2SO4 acts as

OR

water ? 1+1
.56/3/3 19 P.T.O.
Series : HMJ/4 SET – 1
OSS/1GRLH/1  .
Code No. 56/4/1
 .    -  - 
Roll No.   
Candidates must write the Code on
the title page of the answer-book.
 NOTE
(I)       -   (I) Please check that this question
 15   paper contains 15 printed pages.
(II) -         (II) Code number given on the right
   -  -  hand side of the question paper
should be written on the title page
 
of the answer-book by the candidate.
(III)      -  37  (III) Please check that this question
  paper contains 37 questions.
(IV)         (IV) Please write down the Serial
,       Number of the question in the
answer-book before attempting
it.
(V)  -     15   (V) 15 minute time has been allotted
     -    to read this question paper. The
question paper will be distributed
 10.15     10.15  
at 10.15 a.m. From 10.15 a.m. to
10.30     -   10.30 a.m., the students will read
      -  the question paper only and will
     not write any answer on the
  ()

CHEMISTRY (Theory)
{ZYm©[aV g‘¶ : 3 KÊQ>o A{YH$V‘ A§H$
: 70
.56/4/1. 321A 1 P.T.O.

  
           
(i) -      – , ,         
(ii) - – - 1  20   -    ,   1 
              
(iii) - – - 21  27  -    ,   2  
 
(iv) - – - 28  34  - -1   ,   3 
  
(v) - – - 35  37  - -2   ,   5 
  
(vi)       , -     , -     
 -                 
    
(vii)  , ,            
(viii)           
 – 
         1  5    
               
     AgNO3   KI       -
                
      ,  ,    ,      
   ,            
1.         ?
2.                ?
3. AgNO3   KI     -      ?
4.             
5. KI  K2SO4   - -          ?

.56/4/1. 2
(i) Question paper comprises four sections – A, B, C and D.
(ii) There are 37 questions in the question paper. All questions are
compulsory.
(iii) Section – A : Q. No. 1 to 20 are very short answer type questions
carrying one mark each. Answer these questions in one word or one
sentence.
(iv) Section – B : Q. No. 21 to 27 are short answer type questions carrying
two marks each.
(v) Section – C : Q. No. 28 to 34 are long answer type-I questions carrying
three marks each.
(vi) Section – D : Q. No. 35 to 37 are long answer type-II questions
carrying five marks each.
(vii) There is NO overall choice in the question paper. However, an internal
choice has been provided in 2 questions of two marks, 2 questions of
three marks and all the 3 questions of five marks. You have to
attempt only one of the choices in such questions.
(viii) However, separate instructions are given with each section and
(ix) Use of calculators and log tables is NOT permitted.
SECTION – A
Read the given passage and answer the questions 1 to 5 that follow :
Colloidal particles always carry an electric charge which may be
either positive or negative. For example, when AgNO3 solution is added to
KI solution, a negatively charged colloidal sol is obtained. The presence of
equal and similar charges on colloidal particles provide stability to the
colloidal sol and if, somehow, charge is removed, coagulation of sol occurs.
Lyophobic sols are readily coagulated as compare to lyophilic sols.
1. What is the reason for the charge on sol particles ?
2. Why the presence of equal and similar charges on colloidal particles provide
stability ?
3. Why a negatively charged sol is obtained on adding AgNO3 solution to KI
solution ?
4. Name one method by which coagulation of lyophobic sol can be carried out.
5. Out of KI or K2SO4, which electrolyte is better in the coagulation of
positive sol ?
.56/4/1. 3 P.T.O.
 6  10     :
6.                
7.     SN1       ?
8. C3H9N         NaOH     
      
9.     -   ?

, , 
10.          
 11  15    :

11. 
 [Co(NH3)5Cl] Cl2         ?
(a) 4 (b) 2 (c) 3 (d) 5
12.    

(a)   PbO2, PbSO4     
(b)   Pb  PbSO4     
(c)   H2SO4          
(d)     
13. ln[R]          

k –k
(a) + k (b) (c) –k (d)
2.303 2.303
( [R]      )
14. [Co(NH3)4 Cl2] Br2  [Co(NH3)4 Br2] Cl2   
(a)   (b)  
(c)   (d)  
15. -   
(a)   (b)  
(c)   (d)  
.56/4/1. 4
Questions 6 to 10 are one word answers :
6. Name the method applied for the concentration of Bauxite ore in the
extraction of Aluminium.
7. Out of and , which one is more reactive towards

SN1 reaction ?
8. Write an isomer of C3H9N which gives foul smell of isocyanide when

treated with chloroform and ethanolic NaOH.
9. Which one of the following is an antidepressant drug ?

Chloramphenicol, Luminal, Bithional
10. Write the name of component of starch which is water soluble.
Questions 11 to 15 are Multiple Choice Questions :

11. How many ions are produced from the complex [Co(NH 3)5Cl] Cl2 in
solution ?
(a) 4 (b) 2 (c) 3 (d) 5
12. In a lead storage battery

(a) PbO2 is reduced to PbSO4 at the cathode.
(b) Pb is oxidised to PbSO4 at the anode.
(c) Both electrodes are immersed in the same aqueous solution of
H2SO4.
(d) All the above are true.
13. The slope in the plot of ln [R] Vs. time gives

k –k
(a) + k (b) (c) – k (d)
2.303 2.303
(where [R] is the final concentration of reactant.)
14. The pair [Co(NH3)4 Cl2] Br2 and [Co(NH3)4 Br2] Cl2 will show
(a) Linkage isomerism (b) Hydrate isomerism
(c) Ionization isomerism (d) Coordinate isomerism
15. An -helix is a structural feature of

(a) Sucrose (b) Polypeptides
(c) Nucleotides (d) Starch
.56/4/1. 5 P.T.O.
 16  20 :
(A)  (A)   (R)       (R),  (A)  
  
(B)  (A)   (R)    ,   (R),  (A)  
   
(C)  (A)  ,   (R)    
(D)  (A)  ,   (R)    
16.  (A) : F2     

 (R) :         
17.  (A) : (CH3)3 C–O–CH3  HI      (CH3)3 C–I 
CH3OH    
 (R) :  SN1     
18.  (A) :        
 (R) :     (n – 1)d  ns    
   
19.  (A) :           
 (R) :           
20.  (A) :   -      
 (R) :         
    20  1 = 20
 – 
21.     
(i)               
   ?
(ii)        ? 1+1=2
22.       

(a)   
(b)  ( ) 1+1=2

(i) Cu2S  Cu (ii)   [Ag (CN)2]–  Ag
          1+1=2
.56/4/1. 6
Questions 16 to 20 :
(A) Both Assertion (A) and Reason (R) are correct statements, and
(B) Both Assertion (A) and Reason (R) are correct statements, but
(C) Assertion (A) is correct, but Reason (R) is wrong statement.
(D) Assertion (A) is wrong, but Reason (R) is correct statement.
16. Assertion (A) : F2 is a strong oxidising agent.

Reason (R) : Electron gain enthalpy of fluorine is less negative.
17. Assertion (A) : (CH3)3 C–O–CH3 gives (CH3)3 C–I and CH3OH on
treatment with HI.
Reason (R) : The reaction occurs by SN1 mechanism.
18. Assertion (A) : Transition metals have low melting points.

Reason (R) : The involvement of greater number of (n – 1)d and ns
electrons in the interatomic metallic bonding.
19. Assertion (A) : Hydrolysis of an ester follows first order kinetics.

Reason (R) : Concentration of water remains nearly constant during
the course of the reaction.
20. Assertion (A) : Benzoic acid does not undergo Friedal-Crafts reaction.
Reason (R) : The carboxyl group is activating and undergo electrophilic
substitution reaction. 20  1 = 20
SECTION – B
(i) a pressure greater than osmotic pressure is applied on the solution
side separated from solvent by a semipermeable membrane ?
(ii) acetone is added to pure ethanol ? 1+1=2
22. Write the principle of the following refining methods :

(a) vapour phase refining
(b) chromatography 1+1=2
OR
Write chemical equations involved to obtain :
(i) Cu from Cu2S
(ii) Ag from [Ag (CN)2]– complex 1+1=2
.56/4/1. 7 P.T.O.
23.   (MnO2)  KMnO4        
  2

2–
(i)  (II)   (ii)  (II)     (Cr2O 7 )  
          1+1=2
24.  

        
(i) [Ni(CN)4]2– (ii) [Fe(H2O)6]2+
(  :   Ni = 28, Fe = 26) 1+1=2
25.            
(i)  () (ii)  1+1=2
26.              
(i)   (ii)       1+1=2
27.     298 K  760 mm Hg   CO2     
  (298 K    CO2   KH = 1.25  106 mm Hg ) 2
 – 
28. 5g   (M = 122 g mol–1) 35g       2.94 K  
              
     ?
(   Kf = 4.9 K kg mol–1) 3
29. N2O5               
k = (2.5  1014 s–1) e(–25000K)/T
    Ea          300    3
30.          

(i) -6 (ii)    (PVC) (iii)  1+1+1=3
.56/4/1. 8
23. Write the balanced chemical equations involved in the preparation of
KMnO4 from pyrolusite ore (MnO2). 2
OR
Write the balanced ionic equations showing the oxidising action of
2–
acidified dichromate (Cr2O 7 ) solution with (i) Iron (II) Ion and (ii) tin (II)
ion. 1+1=2
24. Write the IUPAC names and hybridisation of the following complexes :
(i) [Ni(CN)4]2– (ii) [Fe(H2O)6]2+
(Given : Atomic number Ni = 28, Fe = 26) 1+1=2
25. Define the following terms with a suitable example in each :

(i) Antibiotics (ii) Antiseptics 1+1=2
26. Write the reactions showing the presence of following in the open
structure of glucose :
(i) a carbonyl group
(ii) Straight chain with six carbon atoms 1+1=2
27. State Henry’s law. Calculate the solubility of CO2 in water at 298 K under
760 mm Hg.
(KH for CO2 in water at 298 K is 1.25  106 mm Hg) 2
SECTION – C
28. The freezing point of a solution containing 5g of benzoic acid (M = 122 g
mol–1) in 35g of benzene is depressed by 2.94 K. What is the percentage
association of benzoic acid if it forms a dimer in solution ?
(Kf for benzene = 4.9 K kg mol–1) 3
29. The rate constant for the first order decomposition of N 2O5 is given by the
following equation :
k = (2.5  1014 s–1) e(–25000K)/T
Calculate Ea for this reaction and rate constant if its half-life period be
300 minutes. 3
30. Write the name and structures of monomer(s) in the following polymers :
(i) Nylon-6 (ii) PVC (iii) Neoprene 1 + 1 + 1 = 3
.56/4/1. 9 P.T.O.
31.       
Cr2+, Cu2+, Cu+, Fe2+, Fe3+, Mn3+
      
(i)    
(ii)     
(iii)     
       1+1+1=3
32. (i)       2, 2, 3--3-  - 
      
(ii)    -     ?
(iii)   (A)  (B)   
Na/  Mg/ 

(A)   (B) 1+1+1=3

      ?
(i) -1-  1-
(ii)   
(iii)     1+1+1=3
33.           
(i)        :
(CH3)2NH, CH3NH2, C6H5NH2
(ii)          :
(CH3)3N, (CH3)2NH, CH3NH2
(iii)      :
(C2H5)2NH, (C2H5)3N, C2H5NH2 1+1+1=3
34.    /   :
PCC (CH3CO)2O
(i)  (ii) 
CH3COOH
H3O+
(iii) + CH3MgBr  1+1+1=3

.56/4/1. 10
31. Following ions are given :
Cr2+, Cu2+, Cu+, Fe2+, Fe3+, Mn3+
Identify the ion which is
(i) a strong reducing agent.
(ii) unstable in aqueous solution.
(iii) a strong oxiding agent.
Give suitable reason in each. 1+1+1=3
32. (i) Write the structure of major alkene formed by -elimination of

2, 2, 3–trimethyl–3–bromopentane with sodium ethoxide in ethanol.
(ii) Which one of the compounds in the following pairs is chiral ?
(iii) Identify (A) and (B) in the following :
Na/dry ether Mg/dry ether

(A)   (B) 1+1+1=3
OR
How can you convert the following ?
(i) But-1-ene to 1-iodobutane
(ii) Benzene to acetophenone
(iii) Ethanol to propanenitrile 1+1+1=3
33. Arrange the following compounds as directed :

(i) In increasing order of solubility in water :
(ii) In decreasing order of basic strength in aqueous solution :
(iii) In increasing order of boiling point :
(C2H5)2NH, (C2H5)3N, C2H5NH2 1+1+1=3
34. Write the product(s) of the following reactions :
PCC (CH3CO)2O
(i)  (ii) 
CH3COOH
H3O+
(iii) + CH3MgBr  1+1+1=3
OR
.56/4/1. 11 P.T.O.
(a)  SN1     
 NaOH
(CH ) C–Br  (CH ) C–OH + NaBr
3 3 3 3
(b)    2--2-        2 + 1 = 3

 – 
35. (a) 0.05 M KOH       5  103 ohm    -
  0.625 cm2   50 cm    ,   
    
(b)     CuCl2         
  
o o
(  : E 2 = + 0.34 V, E 1
Cu /Cu  Cl /Cl –  = + 1.36 V
2 2
o o
E  = 0.00 V, E  1 = + 1.23 V ) 3+2=5
H /H 2 (g), Pt 2 O 2 /H 2O 

(a)     e.m.f.   :
Zn(s)/Zn2+ (0.1 M) || (0.01 M) Ag+/Ag(s)
  : E oZn 2 /Zn = –0.76 V, E oAg  /Ag = + 0.80 V
[  : log 10 = 1]
(b) ‘X’  ‘Y’       ‘X’    2.5    
 ‘Y’  25                ?3 + 2 = 5
36. (a)    (A)    C4H8O , 2, 4-...  
 -       –      
NaOH  I2             
(A) NaBH4       (B)     H2SO4    
     (C)     (C)      
    
(A), (B)  (C)          (A)  (i)
NaOH/I2  (ii) NaBH4     
(b)   :
(i)          
(ii)     -       3+2=5

.56/4/1. 12
(a) Write the mechanism of the following S N1 reaction :
Aq. NaOH
(CH3) C–Br  (CH3) C–OH + NaBr
3 3
(b) Write the equation for the preparation of 2-methyl-2-
methoxypropane by Williamson synthesis. 2+1=3
SECTION – D
35. (a) The electrical resistance of a column of 0.05 M KOH solution of
length 50 cm and area of cross-section 0.625 cm2 is 5  103 ohm.
Calculate its resistivity, conductivity and molar conductivity.
(b) Predict the products of electrolysis of an aqueous solution of CuCl2
with platinum electrodes.
o o
(Given : E = + 0.34 V, E
Cu 2 /Cu 12 Cl2/Cl –  = + 1.36 V
o o
E = 0.00 V, E  1 = + 1.23 V ) 3+2=5
H  /H 2 (g), Pt 2 O 2 /H 2O 
OR
(a) Calculate e.m.f. of the following cell :
Zn(s)/Zn2+ (0.1 M) || (0.01 M) Ag+/Ag(s)
o o
Given : E = –0.76 V, E = + 0.80 V
Zn 2  /Zn Ag  /Ag
[Given : log 10 = 1]
(b) X and Y are two electrolytes. On dilution molar conductivity of ‘X’
increases 2.5 times while that Y increases 25 times. Which of the two
is a weak electrolyte and why ? 3+2=5
36. (a) An organic compound (A) having molecular formula C4H8O gives
orange red precipitate with 2, 4-DNP reagent. It does not reduce
Tollens’ reagent but gives yellow precipitate of iodoform on heating
with NaOH and I2. Compound (A) on reduction with NaBH4 gives
compound (B) which undergoes dehydration reaction on heating with
conc. H2SO4 to form compound (C). Compound (C) on Ozonolysis
gives two molecules of ethanal.
Identify (A), (B) and (C) and write their structures. Write the
reactions of compound (A) with (i) NaOH/I2 and (ii) NaBH4.
(b) Give reasons :
(i) Oxidation of propanal is easier than propanone.
(ii) -hydrogen of aldehydes and ketones is acidic in nature. 3+2=5
OR
.56/4/1. 13 P.T.O.
(a)      :
(i)   
(ii)    
(b)    /   
(i) DIBAL–H
(i) CH3–CH=CH–CH2–CN 
(ii) H3O+
CrO3
(ii) CH3–CH2–OH 
(c)          ? 2+2+1=5
37. (a)      :

(i)     –2        
(ii) HF  HI      
(iii)  SO2        
(b) S–O–S         
(c)      :
XeF2 + H2O  3+1+1=5

(a)  16         
(i)     
(ii)      
(iii)       
      
(b)     :
S + H2SO4 
()
Cl2 + NaOH 
(  ) 3+1+1=5
___________
.56/4/1. 14
(a) Draw structures of the following derivatives :
(i) Cyanohydrin of cyclobutanone
(ii) Hemiacetal of ethanal
(b) Write the major product(s) in the following :
(i) DIBAL–H
(i) CH3–CH=CH–CH2–CN 
(ii) H3O+
CrO3
(c) How can you distinguish between propanal and propanone ? 2 + 2 + 1 = 5
37. (a) Account for the following :

(i) Tendency to show –2 oxidation state decreases from oxygen to
tellurium.
(ii) Acidic character increases from HF to HI.
(iii) Moist SO2 gas acts as a reducing agent.
(b) Draw the structure of an oxoacid of sulphur containing S–O–S
linkage.
(c) Complete the following equation :
XeF2 + H2O  3+1+1=5
OR
(a) Among the hydrides of group 16, write the hydride
(i) Which is a strong reducing agent.
(ii) Which has maximum bond angle.
(iii) Which is most thermally stable.
Give suitable reason in each.
(b) Complete the following equations :
S + H2SO4 
(Conc.)
Cl2 + NaOH 
(Cold and dilute) 3+1+1=5
___________
.56/4/1. 15 P.T.O.
.56/4/1. 16
OSS/1GRLH/1  .
Code No. 56/4/2
 .    -  - 
Roll No.   
 NOTE
 
it.
 10.15     10.15  
at 10.15 a.m. From 10.15 a.m. to
  ()

CHEMISTRY (Theory)
: 70
.56/4/2. 321B 1 P.T.O.

  
           
(i) -      – , ,         
(ii) - – - 1  20   -    ,   1 
              
(iii) - – - 21  27  -    ,   2  
 
(iv) - – - 28  34  - -1   ,   3 
  
(v) - – - 35  37  - -2   ,   5 
  
(vi)       , -     , -     
 -                 
    
(vii)  , ,            
(viii)           
 – 
         1  5    
               
     AgNO3   KI       -
                
      ,  ,    ,      
   ,            
1.         ?
2.                ?
3. AgNO3   KI     -      ?
4.             

5. KI  K2SO4   - -          ?
.56/4/2. 2
compulsory.
sentence.
two marks each.
three marks each.
SECTION – A
stability ?
solution ?
positive sol ?
.56/4/2. 3 P.T.O.
 6  10     :
6.         PbS  ZnS        
  
7. CH2Cl  ,    OH–   SN1   

    ?
8. CH3NH2  CH3OH        ?
9.      ()   ?

, , 
10.           
 11  15    :

11. 
 [Co(en)3]3+  ‘Co’    
(a) 3 (b) 6 (c) 4 (d) 5
12.   , -        

(a) E = E (b) E = 0
(c) E > E (d) E < E
13.            ?
0.693 2k 2.303 [R]0
(a) (b) (c) (d)
k [R]0 k 2k
( [R]0      k    )
14.  (0)   (t) 

         
   ?
2 5 4
(a) t =  (b) t =  (c) t =  (d) t = 2 0
9 0 9 0 9 0
15. –D(+)   –D(+)  

(a)   (b)  (c)  (d)  
.56/4/2. 4
6. Name the depressant which is used to separate PbS and ZnS containing
ore in froth floatation process.
7. Out of CH2Cl and , which will react faster in SN1

reaction with OH– ?
8. Out of CH3NH2 and CH3OH, which has higher boiling point ?
9. Which one of the following is a narcotic analgesic ?

Penicillin, Codeine, Ranitidine
10. Write the name of linkage joining two monosaccharides.

11. The coordination number of ‘Co’ in the complex [Co(en) 3]3+ is
(a) 3 (b) 6
(c) 4 (d) 5
12. An electrochemical cell behaves like an electrolytic cell when

(a) Ecell = Eexternal (b) Ecell = 0
(c) Eexternal > Ecell (d) Eexternal < Ecell
13. The half-life period for a zero order reaction is equal to

0.693 2k 2.303 [R]0
(a) (b) (c) (d)
k [R]0 k 2k
(where [R]0 is initial concentration of reactant and k is rate constant.)
14. The crystal field splitting energy for octahedral (0) and tetrahedral (t)
complexes is related as
2 5 4
(a) t =  (b) t =  (c) t =  (d) t = 2 0
9 0 9 0 9 0
15. –D(+) glucose and –D(+) glucose are

(a) Geometrical isomers (b) Enantiomers
(c) Anomers (d) Optical isomers
.56/4/2. 5 P.T.O.
 16  20 :
(A)  (A)   (R)       (R),  (A)  
  
(B)  (A)   (R)    ,   (R),  (A)  
   
(C)  (A)  ,   (R)    
(D)  (A)  ,   (R)    
16.  (A) : Cl2   F2        

 (R) :      -   
17.  (A) :           
 (R) :           
18.  (A) :        

 (R) :    d      
19.  (A) : (CH3)3 C–O–CH3  HI      (CH3)3 C–I 
CH3OH    
 (R) :  SN1     
20.  (A) :   -      
 (R) :         
    20  1 = 20
 : 
21.   (MnO2)  KMnO4        
  2

2–
(i)  (II)   (ii)  (II)     (Cr2O 7 )  
          1+1=2
22.     

(i)               
   ?
(ii)        ? 1+1=2
.56/4/2. 6
16. Assertion (A) : F2 has lower bond dissociation enthalpy than Cl2.
Reason (R) : Fluorine is more electronegative than chlorine.
17. Assertion (A) : Hydrolysis of an ester follows first order kinetics.

Reason (R) : Concentration of water remains nearly constant during
the course of the reaction.
18. Assertion (A) : Transition metals have high melting point.

Reason (R) : Transition metals have completely filled d-orbitals.
treatment with HI.
Reason (R) : The carboxyl group is activating and undergo
electrophilic substitution reaction. 20  1 = 20
SECTION–B
OR
Write the balanced ionic equations showing the oxidising action of acidified
2–
dichromate (Cr2O 7 ) solution with (i) Iron (II) Ion and (ii) tin (II) ion. 1+1=2

.56/4/2. 7 P.T.O.
23.  
            
(i) [Ni(CO)4] (ii) [CoF6]3–
(  Ni = 28, Co = 27) 1+1=2
24.     298 K  760 mm Hg   CO2     
  (298 K    CO2   KH = 1.25  106 mm Hg ) 2
25.             
(i)  (ii)   1+1=2
26.              
(i)   (ii)   1+1=2
27.       

(a)    (b)  ( ) 1+1=2

(i) Cu2S  Cu (ii)  [Ag (CN)2]–  Ag
          1+1=2
 : 
28. N2O5               
k = (2.5  1014 s–1) e(–25000K)/T
    Ea          300    3
29.       

Cr2+, Cu2+, Cu+, Fe2+, Fe3+, Mn3+
      
(i)    
(ii)     
(iii)     
       1+1+1=3
30. 5g   (M = 122 g mol–1) 35g       2.94 K  
              
     ?
(   Kf = 4.9 K kg mol–1) 3
.56/4/2. 8
23. Write IUPAC name and hybridization of the following complexes :
(i) [Ni(CO)4] (ii) [CoF6]3–
(Atomic number Ni = 28, Co = 27) 1+1=2
760 mm Hg.
(i) Tranquilizers (ii) Anionic detergent 1+1=2
(i) an aldehyde group
(ii) a primary alcohol 1+1=2
OR
(i) Cu from Cu2S
SECTION : C
k = (2.5  1014 s–1) e(–25000K)/T
300 minutes. 3
Cr2+, Cu2+, Cu+, Fe2+, Fe3+, Mn3+
.56/4/2. 9 P.T.O.
31.          
(i)  6, 6 (ii)  (iii) PHBV 1+1+1=3
32.           

(i)        :
(ii)          :

(iii)      :

(C2H5)2NH, (C2H5)3N, C2H5NH2 1+1+1=3
33.    /   :
PCC
(i) 
(CH3CO)2O
(ii) 
CH3COOH
H3O+
(iii) + CH3MgBr  1+1+1=3

(a)  SN1     
 NaOH
3 3
(b)    2--2-        2 + 1 = 3
.56/4/2. 10
31. Write the name and structures of monomers in the following polymers :
(i) Nylon 6, 6 (ii) Terylene (iii) PHBV 1+1+1=3
(C2H5)2NH, (C2H5)3N, C2H5NH2 1+1+1=3
PCC (CH3CO)2O
(i)  (ii) 
CH3COOH
H3O+
(iii) + CH3MgBr  1+1+1=3
OR
(a) Write the mechanism of the following S N1 reaction
Aq. NaOH
3 3

.56/4/2. 11 P.T.O.
34. (i)       2, 2, 3--3-  - 
      
(ii)    -     ?
(iii)   (A)  (B)   
Na/  Mg/ 

(A)   (B) 1+1+1=3

      ?
(i) -1-  1-
(ii)   
(iii)     1+1+1=3
 : 
35. (a)      :
(i)     –2        
(ii) HF  HI      
(iii)  SO2        
(b) S–O–S         
(c)      :
XeF2 + H2O  3+1+1=5

(a)  16         
(i)     
(ii)      
(iii)       
      
(b)     :
S + H2SO4 
()
Cl2 + NaOH 
(  ) 3+1+1=5
.56/4/2. 12

(A)   (B) 1+1+1=3
OR
SECTION : D
tellurium.
linkage.
(c) Complete the following equation : 3+1+1=5
XeF2 + H2O 
OR
S + H2SO4 
(Conc.)
Cl2 + NaOH 
.56/4/2. 13 P.T.O.
36. (a) 0.05 M KOH       5  103 ohm    -
  0.625 cm2   50 cm    ,   
    
(b)     CuCl2         
  
o o
(  : E 2 = + 0.34 V, E 1
Cu /Cu  Cl /Cl –  = + 1.36 V
2 2
o o
E  = 0.00 V, E  1 = + 1.23 V ) 3+2=5
H /H 2 (g), Pt 2 O 2 /H 2O 

(a)     e.m.f.   :
Zn(s)/Zn2+ (0.1 M) || (0.01 M) Ag+/Ag(s)
  : E oZn 2 /Zn = –0.76 V, E o  = + 0.80 V
Ag /Ag
[  : log 10 = 1]
(b) ‘X’  ‘Y’       ‘X’    2.5    
 ‘Y’  25                ? 3 + 2 = 5
37. (a)    (A)    C4H8O , 2, 4-...  
 -       –      
NaOH  I2             
(A) NaBH4       (B)     H2SO4    
     (C)     (C)      
    
(A), (B)  (C)          (A)  (i)
NaOH/I2  (ii) NaBH4     
(b)   :
(i)          
(ii)     -       3+2=5

(a)      :
(i)    (ii)    
(b)    /   
(i) DIBAL–H
(i) CH3–CH=CH–CH2–CN 
(ii) H3O+
CrO3
(c)          ? 2+2+1=5
___________
.56/4/2. 14
o o
(Given : E 2 = + 0.34 V, E 1 – = + 1.36 V
Cu /Cu  2 Cl2/Cl 
o o
E = 0.00 V, E  1 = + 1.23 V ) 3+2=5
H  /H 2 (g), Pt 2 O 2 /H 2O 
OR
Zn(s)/Zn2+ (0.1 M) || (0.01 M) Ag+/Ag(s)
o o
Given : E 2  = –0.76 V, E  = + 0.80 V
Zn /Zn Ag /Ag
[Given : log 10 = 1] 3+2=5
is a weak electrolyte and why ?
(b) Give reasons :
OR
(i) DIBAL–H
(i) CH3–CH=CH–CH2–CN 
(ii) H3O+
CrO3
___________
.56/4/2. 15 P.T.O.
.56/4/2. 16
OSS/1GRLH/1  .
Code No. 56/4/3
 .    -  - 
Roll No.   
 NOTE
 
it.
 10.15     10.15  
at 10.15 a.m. From 10.15 a.m. to
  ()

CHEMISTRY (Theory)
: 70
.56/4/3. 321C 1 P.T.O.

  
           
(i) -      – , ,         
(ii) - – - 1  20   -    ,   1 
              
(iii) - – - 21  27  -    ,   2  
 
(iv) - – - 28  34  - -1   ,   3 
  
(v) - – - 35  37  - -2   ,   5 
  
(vi)       , -     , -     
 -                 
    
(vii)  , ,            
(viii)           
SECTION – A
         1  5    
               
     AgNO3   KI       -
                
      ,  ,    ,      
   ,            
1.         ?
2.                ?
3. AgNO3   KI     -      ?
4.             
5. KI  K2SO4   - -          ?
.56/4/3. 2
compulsory.
sentence.
two marks each.
three marks each.
SECTION – A
stability ?
solution ?
positive sol ?
.56/4/3. 3 P.T.O.
 6  10     :
6.          
7. CH3CH2CH2Cl  CH2=CH–CH2–Cl    SN1    

  ?
8. C3H9N               ?
9.         ?
10.                
 11  15    :

11.         
  ?
(a) [Fe(CO)5] (b) [Fe(H2O)6]3+ (c) [Fe(C2O4)3]3–(d) [Fe(CN)6]3–
12.              ?

(a) G = –ve Eo = +ve (b) G = +ve Eo = 0
(c) G = –ve Eo = 0 (d) G = +ve Eo = –ve
13.       ,    [R]        
 
k k
(a) (b) – k (c) (d) +k
2.303 2.303
( [R]     )
14. [Cr(H2O)6]Cl3  [Cr(H2O)5Cl] Cl2·H2O       
  ?
(a)   (b)  
(c)   (d)  
15. DNA            

(a)  (b)  (c)  (d) 
.56/4/3. 4
6. Name the method used for the refining of Zinc.
7. Out of CH3CH2CH2Cl and CH2=CH–CH2–Cl, which one is more reactive

towards SN1 reaction ?
8. Write an isomer of C3H9N which does not react with Hinsberg reagent.
9. What type of protein is present in keratin ?
10. Name the compound which is added to soap to provide antiseptic

properties.

11. Which of the following is the most stable complex ?
(a) [Fe(CO)5] (b) [Fe(H2O)6]3+ (c) [Fe(C2O4)3]3–(d) [Fe(CN)6]3–
12. Which of the following is correct for spontaneity of a cell ?

(a) G = –ve Eo = +ve (b) G = +ve Eo = 0
(c) G = –ve Eo = 0 (d) G = +ve Eo = –ve
13. For a zero order reaction, the slope in the plot of [R] Vs. time is
k k
(a) (b) – k (c) (d) + k
2.303 2.303
(where [R] is the final concentration of reactant)
14. What type of isomerism is shown by the pair [Cr(H2O)6]Cl3 and [Cr(H2O)5Cl]
Cl2 · H2O ?
(a) Ionization isomerism (b) Coordination isomerism
(c) Solvate isomerism (d) Linkage isomerism
15. Which one is the complementary base of cytosine in one strand to that in
other strand of DNA ?
(a) Adenine (b) Guanine
(c) Thymine (d) Uracil
.56/4/3. 5 P.T.O.
 16  20 :
(A)  (A)   (R)       (R),  (A)  
  
(B)  (A)   (R)    ,   (R),  (A)  
   
(C)  (A)  ,   (R)    
(D)  (A)  ,   (R)    
16.  (A) : F2      

 (R) : F-F     (bond Ho)   
17.  (A) :   -      
 (R) :         
   
18.  (A) :        

 (R) :     (n – 1)d  ns    
   
19.  (A) : (CH3)3 C–O–CH3  HI      (CH3)3 C–I 
CH3OH    
 (R) :  SN1     
20.  (A) :             
 (R) :         20  1 = 20
 : 
21.       
(a)    (b)  ( ) 1+1=2

(i) Cu2S  Cu (ii)   [Ag (CN)2]–  Ag
          1+1=2
.56/4/3. 6
16. Assertion (A) : F2 has low reactivity.

Reason (R) : F-F bond has low bond Ho.
Reason (R) : The carboxyl group is activating and undergo
electrophilic substitution reaction.
18. Assertion (A) : Transition metals have low melting points.

Reason (R) : The involvement of greater number of (n – 1)d and ns
electrons in the interatomic metallic bonding.
treatment with HI.
20. Assertion (A) : For complex reactions molecularity and order are not
same
Reason (R) : Order of reaction may be zero. 20  1 = 20
SECTION–B
OR
(i) Cu from Cu2S
.56/4/3. 7 P.T.O.
22.     
(i)               
   ?
(ii)        ? 1+1=2
23.  

        
(i) [Co(NH3)6]3+ (ii) [NiCl4]2–
(     : Ni = 28, Co = 27) 1+1=2
24.   (MnO2)  KMnO4        
  2

2–
(i)  (II)   (ii)  (II)     (Cr2O 7 )  
          1+1=2
25.              
(i) –OH  (ii)    1+1=2
26.     298 K  760 mm Hg   CO2     
  (298 K    CO2   KH = 1.25  106 mm Hg ) 2
27.            
(i)  (ii)   1+1=2
 : 
28.       
Cr2+, Cu2+, Cu+, Fe2+, Fe3+, Mn3+
      
(i)    
(ii)     
(iii)     
       1+1+1=3
29. 5g   (M = 122 g mol–1) 35g       2.94 K  
              
     ?
(   Kf = 4.9 K kg mol ) –1 3
.56/4/3. 8
23. Write the IUPAC name and hybridisation of the following complexes :
(i) [Co(NH3)6]3+ (ii) [NiCl4]2–
(Given : Atomic number : Ni = 28, Co = 27) 1+1=2
OR
Write the balanced ionic equations showing the oxidising action of acidified
2–
dichromate (Cr2O 7 ) solution with (i) Iron (II) Ion and (ii) tin (II) ion. 1+1=2
(i) five –OH groups (ii) a carbonyl group 1+1=2
760 mm Hg.

(i) Antacids (ii) Artificial Sweetener 1+1=2
SECTION : C
Cr2+, Cu2+, Cu+, Fe2+, Fe3+, Mn3+

.56/4/3. 9 P.T.O.
30. N2O5               
k = (2.5  1014 s–1) e(–25000K)/T
    Ea          300    3
31.          

(a) -S (b)  (c) 
  1+1+1=3
32.    /   :
PCC (CH3CO)2O
(i)  (ii) 
CH3COOH
H3O+
(iii) + CH3MgBr  1+1+1=3

(a)      
SN1
 NaOH
(CH3) C–Br  (CH3) C–OH + NaBr
3 3
(b)    2--2-        2 + 1 = 3
33. (i)       2, 2, 3--3-  - 
      
(ii)    -     ?
(iii)   (A)  (B)   
Na/  Mg/ 

(A)   (B) 1+1+1=3

      ?
(i) -1-  1-
(ii)   
(iii)     1+1+1=3
.56/4/3. 10
k = (2.5  1014 s–1) e(–25000K)/T
300 minutes. 3
(a) Buna-S (b) Glyptal (c) Bakelite 1 + 1 + 1 = 3
PCC (CH3CO)2O
(i)  (ii) 
CH3COOH
H3O+
(iii) + CH3MgBr  1+1+1=3
OR
(a) Write the mechanism of the following S N1 reaction
Aq. NaOH
3 3


(A)   (B) 1+1+1=3
OR
.56/4/3. 11 P.T.O.
34.           
(i)        :
(ii)          :
(iii)      :
(C2H5)2NH, (C2H5)3N, C2H5NH2 1+1+1=3
 : 
35. (a)    (A)    C4H8O , 2, 4-...   
-       –       NaOH 
I2              (A) NaBH4  
    (B)     H2SO4        
 (C)     (C)    
      
(A), (B)  (C)          (A)  (i)
NaOH/I2  (ii) NaBH4     
(b)   :
(i)          
(ii)     -       3+2=5

(a)      :
(i)   
(ii)    
(b)    /   
(i) DIBAL–H
(i) CH3–CH=CH–CH2–CN 
(ii) H3O+
CrO3
(c)          ? 2+2+1=5
.56/4/3. 12
(C2H5)2NH, (C2H5)3N, C2H5NH2 1+1+1=3
SECTION : D
(b) Give reasons :
OR
(i) DIBAL–H
(i) CH3–CH=CH–CH2–CN 
(ii) H3O+
CrO3
.56/4/3. 13 P.T.O.
36. (a)      :
(i)     –2        
(ii) HF  HI      
(iii)  SO2        
(b) S–O–S         
(c)      : 3+1+1=5
XeF2 + H2O 

(a)  16         
(i)     
(ii)      
(iii)       
      
(b)     :
S + H2SO4 
()
Cl2 + NaOH 
(  ) 3+1+1=5
37. (a) 0.05 M KOH       5  103 ohm    -
  0.625 cm2   50 cm    ,   
    
(b)     CuCl2         
  
o o
(  : E 2 = + 0.34 V, E 1
Cu /Cu  Cl /Cl –  = + 1.36 V
2 2
o o
E  = 0.00 V, E  1 = + 1.23 V ) 3+2=5
H /H 2 (g), Pt 2 O 2 /H 2O 

(a)     e.m.f.   :
Zn(s)/Zn2+ (0.1 M) || (0.01 M) Ag+/Ag(s)
  : E oZn 2 /Zn = –0.76 V, E o  = + 0.80 V
Ag /Ag
[  : log 10 = 1]
(b) ‘X’  ‘Y’       ‘X’    2.5    
 ‘Y’  25                ?3 + 2 = 5
.56/4/3. 14
tellurium.
linkage.
(c) Complete the following equation :
XeF2 + H2O  3+1+1=5
OR
S + H2SO4 
(Conc.)
Cl2 + NaOH 
o o
(Given : E = + 0.34 V, E
Cu 2 /Cu 12 Cl2/Cl –  = + 1.36 V
o o
E = 0.00 V, E  1 = + 1.23 V ) 3+2=5
H  /H 2 (g), Pt 2 O 2 /H 2O 
OR
Zn(s)/Zn2+ (0.1 M) || (0.01 M) Ag+/Ag(s)
o o
Given : E = –0.76 V, E = + 0.80 V
Zn 2  /Zn Ag  /Ag
[Given : log 10 = 1]
is a weak electrolyte and why ? 3+2=5
___________
.56/4/3. 15 P.T.O.
.56/4/3. 16
OSS/1GRLH/1  .
Code No. 56/5/1
 .    -  - 
Roll No.   
 NOTE
 
it.
 10.15     10.15  
at 10.15 a.m. From 10.15 a.m. to
  ()

CHEMISTRY (Theory)
{ZYm©[aV g‘¶ : 3 KÊQ>o A{YH$V‘ A§H$ : 70

.56/5/1. 322A 1 P.T.O.

  
           
(i) -      – , ,    
(ii)  -  37        
(iii) - – - 1  20   -    ,   1 
              
(iv) - – - 21  27  -    ,   2  
 
(v) - – - 28  34  - -1   ,   3 
  
(vi) - – - 35  37  - -2   ,   5 
  
(vii)       , -     , -     
 -                 
    
(viii)  , ,            
(ix)           
.56/5/1. 2
(ii) There are 37 questions in the questions paper. All questions are
compulsory.

sentence.

two marks each.

three marks each.
(vi) Section – D : Q. No. 35 to 37 are long answer type-II questions carrying

five marks each.

.56/5/1. 3 P.T.O.
 : 
         1  5    
  -           
        – 1       
              ,
              
              ,
,              ,
       (HX)         
  XX', XX'3, XX'5  XX7        
  
1.           ?
2.            ?
3.   (HF  HI)           
4.         ?
5.    X  X     ?
  6  10     

6.           
7. 1  MnO4–  Mn2+              ?
8.           log [Ro] / [R]     
      
9.               
10.              
.56/5/1. 4
SECTION : A
The halogens have the smallest atomic radii in their respective periods.
The atomic radius of fluorine is extremely small. All halogens exhibit – 1
oxidation state. They are strong oxidising agents and have maximum
negative electron gain enthalpy. Among halogens, fluorine shows
anomalous behaviour in many properties. For example electro negativity
and ionisation enthalpy are higher for fluorine than expected whereas
bond dissociation enthalpy, m.p. and b.p. and electron gain enthalpy are
quite lower than expected. Halogens react with hydrogen to give hydrogen
halides (HX) and combine amongst themselves to form a number of
compounds of the type XX, XX3, XX5 and XX7 called inter-halogens.
1. Why halogens have maximum negative electron gain enthalpy ?
2. Why fluorine shows anomalous behaviour as compared to other halogens ?
3. Arrange the hydrogen halides (HF to HI) in the decreasing order of their
reducing character.
4. Why fluorine is a stronger oxidizing agent than chlorine ?
5. What are the sizes of X and X in the interhalogen compounds ?
Question 6 to 10 are one word answers.
6. Name the cell used in hearing aids and watches.
7. How much charge in terms of Faraday is required to reduce one mol of

MnO4– to Mn2+ ?
8. Write the slope value obtained in the plot of log [Ro] / [R] Vs. time for a
first order reaction.
9. Name the sweetening agent used in the cooking of sweets for a diabetic
patient.
10. Name the polymer which is used for making electrical switches and
combs.
.56/5/1. 5 P.T.O.
 . 11  15    
11.           
(a) H2 (b) CO2
(c) CO (d) N2
12.      NaOH         
(a)   (b)  
(c)   (d)  
13. CH3CONH2    NaOH  Br2      
(a) CH3CH2NH2 (b) CH3CH2Br
(c) CH3NH2 (d) CH3COONa
14. [Ni(CO)4]  Ni    

(a) 0 (b) 2
(c) 3 (d) 4
15.    
(a)  (b) 
(c)  (d) 
 16  20 
(A)  (A)   (R)       (R),  (A)  
  
(B)  (A)   (R)       (R),  (A)  
   
(C)  (A)  ,   (R)    
(D)  (A)  ,   (R)    
16.  (A) :          

 (R) :             
17.  (A) :   C-O-C      -   
 (R) :            
18.  (A) :           
 (R) :         ,    
  
.56/5/1. 6
Questions 11 to 15 are multiple choice questions.
11. In the Mond’s process the gas used for the refining of a metal is
(a) H2 (b) CO2
(c) CO (d) N2
12. The conversion of an alkyl halide into an alcohol by aqueous NaOH is

classified as
(a) a dehydrohalogenation reaction
(b) a substitution reaction
(c) an addition reaction
(d) a dehydration reaction
13. CH3CONH2 on reaction with NaOH and Br2 in alcoholic medium gives
(a) CH3CH2NH2 (b) CH3CH2Br
(c) CH3NH2 (d) CH3COONa
14. The oxidation state of Ni in [Ni(CO)4] is

(a) 0 (b) 2
(c) 3 (d) 4
15. Amino acids are
(a) acidic (b) basic
(c) amphoteric (d) neutral
Questions 16 to 20.
16. Assertion (A) : Conductivity of an electrolyte increases with decrease in
concentration.
Reason (R) : Number of ions per unit volume decreases on dilution.
17. Assertion (A) : The C-O-C bond angle in ethers is slightly less than
tetrahedral angle.
Reason (R) : Due to the repulsive interaction between the two alkyl
groups in ethers.
Reason (R) : Crystal field splitting energy is less than pairing energy
for tetrahedral complexes.
.56/5/1. 7 P.T.O.
19.  (A) :        
 (R) :         
20.  (A) :            
 (R) :   C – H       C – C  
   20  1 = 20
 – 
21.                  
    ? 2
22.     

(a)      NaCN 
(b)     CO   1+1=2

            ?      
     2
23.               
 ? 2

               ?  
        ? 2
24. (a)  [Fe(CN)6]3–       


(  : Fe    = 26)
(b)           ? 1+1=2
25. ,        ?         
         2
26.        
(i)
(ii) 1+1=2
.56/5/1. 8
19. Assertion (A) : Elevation in boiling point is a colligative property.
Reason (R) : Elevation in boiling point is directly proportional to
molarity.
20. Assertion (A) : Oxidation of ketones is easier than aldehydes.

Reason (R) : C-C bond of ketones is stronger than C-H bond of
aldehydes. 20  1 = 20
SECTION – B
21. State Raoult’s law for a solution containing volatile components. What is
the similarity between Raoult’s law and Henry’s law ? 2
22. Write the role of

(a) Dilute NaCN in the extraction of Gold.
(b) CO in the extraction of Iron. 1+1=2
OR
How is leaching carried out in the case of low grade copper ores ? Name
the method used for refining of copper metal. 2
23. Define adsorption with an example. What is the role of adsorption in

heterogeneous catalysis ? 2
OR
Define Brownian movement. What is the cause of Brownian movement in
colloidal particles ? How is it responsible for the stability of Colloidal Sol ? 2
24. (a) Write the IUPAC name and hybridisation of the complex [Fe(CN) 6]3–.
(Given : Atomic number of Fe = 26)
(b) What is the difference between an ambidentate ligand and a
chelating ligand ? 1+1=2
25. How do antiseptics differ from disinfectants ? Name a substance which

can be used as a disinfectant as well as an antiseptic. 2
26. Identify the monomers in the following polymers :
(i)
(ii) 1+1=2
.56/5/1. 9 P.T.O.
27.     
(i) H2S2O8 (ii) XeF6 1+1=2
 : 
28. AlCl3  0.01 m   – 0.068 C       
   [      Kf = 1.86 K kg mol–1] 3
29.       A  B  ZnSO4  CuSO4 
 ,  2A        B    2g Cu   
       ?  A    Zn      ?
[   Cu = 63.5 g mol–1, Zn = 65 g mol–1; 1F = 96500 C mol–1] 3
30.      

(i)   
(ii)      
(iii)    1+1+1=3
31.   A, B, C, D, E  F   
6½=3
32.          

(i)        H2O2   
(ii) 358 K  20% H3PO4       (CH3)3C–OH   
(iii) HI        31=3


      ?
(i)   o- 
(ii)    
(iii)     1+1+1=3
.56/5/1. 10
27. Draw the structures of the following :
(i) H2S2O8 (ii) XeF6 1+1=2
SECTION : C
28. A 0.01 m aqueous solution of AlCl3 freezes at – 0.068 C. Calculate the
percentage of dissociation. [Given : Kf for Water = 1.86 K kg mol–1] 3
29. When a steady current of 2A was passed through two electrolytic cells A
and B containing electrolytes ZnSO4 and CuSO4 connected in series, 2 g of
Cu were deposited at the cathode of cell B. How long did the current flow ?
What mass of Zn was deposited at cathode of cell A ?
[Atomic mass : Cu = 63.5 g mol–1, Zn = 65 g mol–1; 1F = 96500 C mol–1] 3
30. Differentiate between following :

(i) Amylose and Amylopectin
(ii) Globular protein and Fibrous protein
(iii) Nucleotide and Nucleoside 1+1+1=3
31. Identify A, B, C, D, E and F in the following :
6½=3
32. Give the structures of final products expected from the following reactions :
(i) Hydroboration of propene followed by oxidation with H2O2 in
alkaline medium.
(ii) Dehydration of (CH3)3C–OH by heating it with 20% H3PO4 at 358 K.
(iii) Heating of with HI. 31=3

OR
(i) Phenol to o-hydroxybenzaldehyde.
(ii) Methanal to ethanol
(iii) Phenol to phenyl ethanoate. 1+1+1=3
.56/5/1. 11 P.T.O.
33.   
(i)  -    
(ii)                
(iii)            31=3
34.           3

     
(i)   (ii)   (iii)  1 + 1 + 1 = 3
 : 
35. (a)   
(i)          
(ii)          
(iii) Zn, Cd  Hg        
(b)     
(i) Na2CrO4  Na2Cr2O7
(ii) MnO2  K2MnO4 3+2=5

(a)      
(i)    Ti3+    Sc3+   
(ii) Cr2+     
(b)           
(c)      
2
3 MnO4 + 4H+  2+2+1=5
36. (a)             
 
(i)  NaOH    CH3CHO
(ii) H2N – NH
 NaOH
(iii)
(b)      
(i) CH3 – CH = CH – CO – CH3  CH3 – CH2 – CO – CH = CH2
(ii)     3 + (1 + 1) = 5

.56/5/1. 12
33. Give reasons :
(i) Aniline does not undergo Friedal-Crafts reaction.
(ii) Aromatic primary amines cannot be prepared by Gabriel’s
phthalimide synthesis.
(iii) Aliphatic amines are stronger bases than ammonia. 31=3
34. Write three differences between lyophobic sol and lyophilic sol. 3
OR
Define the following terms :
(i) Protective colloid
(ii) Zeta potential
(iii) Emulsifying agent 1+1+1=3
SECTION : D
35. (a) Give reasons :
(i) Transition metals and their compounds show catalytic activities.
(ii) Separation of a mixture of Lanthanoid elements is difficult.
(iii) Zn, Cd and Hg are soft and have low melting point.
(b) Write the preparation of the following :
(i) Na2Cr2O7 from Na2CrO4
(ii) K2MnO4 from MnO2 3+2=5
OR
(i) Ti3+ is coloured whereas Sc3+ is colourless in aqueous solution.
(ii) Cr2+ is a strong reducing agent.
(b) Write two similarities between chemistry of lanthanoids and actinoids.
(c) Complete the following ionic equation :
2
3 MnO4 + 4H+  2+2+1=5
36. (a) Write the products formed when benzaldehyde reacts with the
following reagents :
(i) CH3CHO in presence of dilute NaOH
(ii) H2N – NH
(iii) Conc. NaOH
(b) Distinguish between following :
(i) CH3 – CH = CH – CO – CH3 and CH3 – CH2 – CO – CH = CH2
(ii) Benzaldehyde and Benzoic acid. 3 + (1 + 1) = 5
OR
.56/5/1. 13 P.T.O.
(a)       
CH3
Zn/Hg
(i) C = O 
 HCl
CH3
NaOH/CaO
(ii) 

(a) DIBAL-H
(iii) CH2 = CH – CH2 – CN 
(b) H3O+
(b)            
   
CH3COCH3, HCHO, CH3CHO,
(c)   2, 4 – ...      3+1+1=5
37. (a)       25%    40        
       80%   ?
(b)             
         3+2=5

(a)       50%    300 K  30     320
K  10        (Ea)   
(R = 8.314 J K–1 mol–1)
(b)           
(c)                ?
[   log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021, log 5 = 0.6991]
3+1+1=5
___________
.56/5/1. 14
(a) Write the final products in the following :
CH3
Zn/Hg
(i) C = O 
Conc HCl
CH3
NaOH/CaO
(ii) 

(a) DIBAL-H
(iii) CH2 = CH – CH2 – CN 
(b) H3O+
(b) Arrange the following in the increasing order of their reactivity
towards nucleophilic addition reaction :
(c) Draw the structure of 2, 4 DNP derivative of acetaldehyde. 3+1+1=5
37. (a) A first order reaction is 25% complete in 40 minutes. Calculate the
value of rate constant. In what time will the reaction be 80%
completed ?
(b) Define order of reaction. Write the condition under which a
bimolecular reaction follows first order kinetics. 3+2=5
OR
(a) A first order reaction is 50% complete in 30 minutes at 300 K and in 10
minutes at 320 K. Calculate activation energy (Ea) for the reaction.
(R = 8.314 J K–1 mol–1)
(b) Write the two conditions for collisions to be effective collisions.
(c) How order of reaction and molecularity differ towards a complex
reaction ?
[Given : log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021, log 5 = 0.6991]
3+1+1=5
___________
.56/5/1. 15 P.T.O.
.56/5/1. 16
OSS/1GRLH/1  .
Code No. 56/5/2
 .    -  - 
Roll No.   
 NOTE
 
it.
 10.15     10.15  
at 10.15 a.m. From 10.15 a.m. to
  ()

CHEMISTRY (Theory)

.56/5/2. 322B 1 P.T.O.

  
           
(i) -      – , ,    
(ii)  -  37        
(iii) - – - 1  20   -    ,   1 
              
(iv) - – - 21  27  -    ,   2  
 
(v) - – - 28  34  - -1   ,   3 
  
(vi) - – - 35  37  - -2   ,   5 
  
(vii)       , -     , -     
 -                 
    
(viii)  , ,            
(ix)           
.56/5/2. 2
compulsory.

sentence.

two marks each.

three marks each.

five marks each.

.56/5/2. 3 P.T.O.
 : 
         1  5    
  -           
        – 1       
              ,
              
              ,
,              ,
       (HX)         
  XX', XX'3, XX'5  XX7        
  
1.           ?
2.            ?
3.   (HF  HI)           
4.         ?
5.    X  X     ?
  6  10     :
6.     OH–   SN1     ?
7.     
8.           ?
9.               
10.            (-)    
     
.56/5/2. 4
SECTION : A
bond dissociation enthalpy, m.p and b.p and electron gain enthalpy are
reducing character.
6. Out of and , which will undergo SN1 reaction faster with

OH– ?
7. Write the IUPAC name of .
8. What type of linkage is present in polysaccharides ?
9. Name an artificial sweetener whose use is limited to cold drinks.
10. Name the polymer which is used for making non-stick utensils.
.56/5/2. 5 P.T.O.
 . 11  15    
11.          
 = 0 – A C
        ?
(a)  = 0  C  A (b)  = 0  C  
(c)  = 0  C  0 (d)  = 0  C  1
12.         

(a)     
(b)     
(c)             
(d)    
13.    X  Y ,      ‘X’       
        ‘X’      
(a) 1 (b) 0
(c) 2 (d) 1/2
14.     AgNO3        ?
(a) K2 [Pt(en)2Cl2] (b) [Co (NH3)3Cl3]
(c) [Cr (H2O)6]Cl3 (d) [Fe (H2O)3Cl3]
15.     

(a) Cu2S, Cu2O   (b) Cu2S, CuO  
(c) Cu2S, FeO   (d) Cu2S, FeS  
 16  20 
(A)  (A)   (R)       (R),  (A)  
  
(B)  (A)   (R)       (R),  (A)  
   
(C)  (A)  ,   (R)    
(D)  (A)  ,   (R)    
16.  (A) :    0.1 M KCl     0.1 M  
    
 (R) :  , KCl          
.56/5/2. 6
Question 11 to 15 are multiple choice questions.
11. Kohlrausch given the following relation for strong electrolytes :
 = 0 – A C
Which of the following equality holds ?
(a)  = 0 as C  A (b)  = 0 as C  
(c)  = 0 as C  0 (d)  = 0 as C  1
12. In an electrochemical process, a salt bridge is used

(a) as a reducing agent.
(b) as an oxidizing agent.
(c) to complete the circuit so that current can flow.
(d) None of these
13. In a chemical reaction X  Y, it is found that the rate of reaction doubles

when the concentration of X is increased four times. The order of the
reaction with respect to X is
(a) 1 (b) 0
(c) 2 (d) 1/2
14. Which of the following will give a white precipitate upon reacting with AgNO3 ?
(a) K2 [Pt(en)2Cl2] (b) [Co (NH3)3Cl3]
(c) [Cr (H2O)6]Cl3 (d) [Fe (H2O)3Cl3]
15. Copper matte contains

(a) Cu2S, Cu2O and silica (b) Cu2S, CuO and silica
(c) Cu2S, FeO and silica (d) Cu2S, FeS and silica
Questions 16 to 20.
16. Assertion (A) : 0.1 M solution of KCl has greater osmotic pressure than
0.1 M solution of glucose at same temperature.
Reason (R) : In solution, KCl dissociates to produce more number of
particles.
.56/5/2. 7 P.T.O.
17.  (A) :          
 (R) :             
18.  (A) :              
 (R) :           
        
19.  (A) :            
 (R) :   C – H       C – C  
  
20.  (A) :           
 (R) :         ,    
   20  1 = 20
 : 
21.     
(a)      NaCN 
(b)     CO   2

            ?      
     2
22.                  
    ? 2
23.     

(i) H2 S2 O 7
(ii) BrF5 2
24.               
 ? 2

               ?  
        ? 2
.56/5/2. 8
concentration.
18. Assertion (A) : Ortho and para-nitrophenols can be separated by steam

distillation.
Reason (R) : Ortho isomer associates through intermolecular
hydrogen bonding while Para isomer associates through
intramolecular hydrogen bonding.
19. Assertion (A) : Oxidation of ketones is easier than aldehydes.

Reason (R) : C-C bond of ketones is stronger than C-H bond of
aldehydes.
for tetrahedral complexes. 20  1 = 20
SECTION : B
(b) CO in the extraction of Iron. 2
OR

(i) H2S2O7
(ii) BrF5 2

OR
.56/5/2. 9 P.T.O.
25.       
(i)
(ii) 2
26.           2
27. ,        ?         
         2
 : 
28.   A, B, C, D, E  F   
6½=3
29. AlCl3  0.01 m   – 0.068 C       
   [      Kf = 1.86 K kg mol–1] 3
30.            
(a)  
(b)   
(c)    1+1+1=3
31.       A  B  ZnSO4  CuSO4 
 ,  2A        B    2g Cu   
       ?  A    Zn      ?
32.           3


     
(i)   (ii)   (iii)  1 + 1 + 1 = 3
.56/5/2. 10
(i)
(ii) 2
26. Discuss the nature of bonding in metal carbonyls. 2
27. How do antiseptics differ from disinfectants ? Name a substance which

can be used as a disinfectant as well as an antiseptic. 2
SECTION : C
6½=3

(a) Polysaccharides (b) Denatured protein (c) Fibrous protein
1+1+1=3
OR
(i) Protective colloid (ii) Zeta potential (iii) Emulsifying agent
1+1+1=3
.56/5/2. 11 P.T.O.
33.          
(i)        H2O2   
(ii) 358 K  20% H3PO4       (CH3)3C–OH   
(iii) HI        31=3


      ?
(i)   o- 
(ii)    
(iii)     31=3
34.   

(i)  -    
(ii)                
(iii)            31=3
 : 
35. (a)       25%    40        
       80%   ?
(b)             
         3+2=5

(a)       50%    300 K  30     320
K  10        (Ea)   
(R = 8.314 J K–1 mol–1)
(b)           
(c)                ?
[   log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021, log 5 = 0.6991]
3+1+1=5
36. (a)   
(i)          
(ii)          
(iii) Zn, Cd  Hg        
(b)     
(ii) MnO2  K2MnO4 3+2=5

.56/5/2. 12
alkaline medium.
OR
(i) Phenol to o-hydroxy benzaldehyde.
(iii) Phenol to phenyl ethanoate. 31=3
34. Give reasons :
(ii) Aromatic primary amines cannot be prepared by Gabriel’s
phthalimide synthesis.
SECTION : D
35. (a) A first order reaction is 25% complete in 40 minutes. Calculate the value
of rate constant. In what time will the reaction be 80% completed ?
bimolecular reaction follows first order kinetics. 32=5
OR
(R = 8.314 J K–1 mol–1)
reaction ?
3+1+1=5
(i) Transition metals and their compounds show catalytic activities.
OR
.56/5/2. 13 P.T.O.
(a)      
(i)    Ti3+    Sc3+   
(ii) Cr2+     
(b)           
(c)      
2
3 MnO4 + 4H+  2+2+1=5
37. (a)             
 
(i)  NaOH    CH3CHO
(ii) H2N – NH
 NaOH
(iii)
(b)      
(ii)    3 + (1 + 1) = 5

(a)       
CH3
Zn/Hg
(i) C = O 
 HCl
CH3
NaOH/CaO
(ii) 

(a) DIBAL-H
(iii) CH2 = CH – CH2 – CN 
(b) H3O+
(b)            
   
(c)   2, 4 – ...      3+1+1=5

___________
.56/5/2. 14
(b) Write two similarities between chemistry of lanthanoids and
actinoids.
2
3 MnO4 + 4H+  2+2+1=5
(ii) H2N – NH
(iii) Conc. NaOH

OR
CH3
Zn/Hg
(i) C = O 
Conc HCl
CH3
NaOH/CaO
(ii) 

(a) DIBAL-H
(iii) CH2 = CH – CH2 – CN 
(b) H3O+

___________
.56/5/2. 15 P.T.O.
.56/5/2. 16
OSS/1GRLH/1  .
Code No. 56/5/3
 .    -  - 
Roll No.   
 NOTE
 
it.
 10.15     10.15  
at 10.15 a.m. From 10.15 a.m. to
  ()

CHEMISTRY (Theory)

.56/5/3. 322C 1 P.T.O.

  
           
(i) -      – , ,    
(ii)  -  37        
(iii) - – - 1  20   -    ,   1 
              
(iv) - – - 21  27  -    ,   2  
 
(v) - – - 28  34  - -1   ,   3 
  
(vi) - – - 35  37  - -2   ,   5 
  
(vii)       , -     , -     
 -                 
    
(viii)  , ,            
(ix)           
.56/5/3. 2
compulsory.

sentence.

two marks each.

three marks each.

five marks each.

.56/5/3. 3 P.T.O.
 : 
         1  5    
  -           
        – 1       
              ,
              
              ,
,              ,
       (HX)         
  XX', XX'3, XX'5  XX7        
  
1.           ?
2.            ?
3.   (HF  HI)           
4.         ?
5.    X  X     ?
  6  10     :

6.  C5H12  -         
  
7.    (CH3)3N  (CH3)2NH       ?
8.  – [Pt(en)2Cl2]2+   – [Pt(en)2Cl2]2+        ?
9.                 
10.       ?
.56/5/3. 4
SECTION : A
bond dissociation enthalpy, m.p and b.p and electron gain enthalpy are
reducing character.

6. A hydrocarbon C5H12 gives only one monochloride on photochemical
chlorination. Identify the compound.
7. Out of (CH3)3N and (CH3)2NH, which one is more basic in aqueous

solution ?
8. Out of Cis – [Pt(en)2Cl2]2+ and Trans – [Pt(en2)Cl2]2+, which one is

optically active ?
9. Name the method of refining used to obtain semiconductor of very high

purity.
10. Is a homopolymer or copolymer ?
.56/5/3. 5 P.T.O.
 . 11-15    
11. ZnSO4   1  Zn         
(a) 3F (b) 2F
(c) 1F (d) 4F
12.            Zn     , 
(a) EZn2+/Zn = EFe2+/Fe (b) EZn2+/Zn < EFe2+/Fe
(c) EZn2+/Zn > EFe2+/Fe (d)     
13.       

(a)     (b)     
(c)     (d)    
14. 
 (-O) (III)   
(a) [Co(ONO)3 (NH3)3] (b) [Co(NO2)3 (NH3)3]
(c) [Co(ONO2)3 (NH3)3] (d) [Co(NO2) (NH3)3]
15.        ?

(a)  (b) 
(c)  (d) 
 16  20 
(A)  (A)   (R)       (R),  (A)  
  
(B)  (A)   (R)       (R),  (A)  
   
(C)  (A)  ,   (R)    
(D)  (A)  ,   (R)    
16.  (A) :          

 (R) :     -  - ,
-      
17.  (A) :          
 (R) :             
.56/5/3. 6
Question No. 11-15 are multiple choice questions :
11. The amount of electricity required to produce one mole of Zn from ZnSO 4
solution will be :
(a) 3F (b) 2F
(c) 1F (d) 4F
12. Zinc is coated over iron to prevent rusting of iron because

(a) EZn2+/Zn = EFe2+/Fe (b) EZn2+/Zn < EFe2+/Fe
(c) EZn2+/Zn > EFe2+/Fe (d) None of these
13. The unit of rate constant depends upon the

(a) molecularity of the reaction.
(b) activation energy of the reaction.
(c) order of the reaction.
(d) temperature of the reaction.
14. The formula of the complex triamminetri(nitrito-O)Cobalt (III) is

(a) [Co(ONO)3 (NH3)3] (b) [Co(NO2)3 (NH3)3]
(c) [Co(ONO2)3 (NH3)3] (d) [Co(NO2) (NH3)3]
15. Which of the following is a disaccharide ?

(a) Glucose (b) Starch
(c) Cellulose (d) Lactose
Questions 16 to 20.
16. Assertion (A) : An ideal solution obeys Henry’s law.
Reason (R) : In an ideal solution, solute-solute as well as solvent-
solvent interactions are similar to solute-solvent
interaction.

concentration.
.56/5/3. 7 P.T.O.
18.  (A) :      ,   
  
 (R) :           
19.  (A) :           
 (R) :         ,    
  
20.  (A) :   C-O-C      -   
 (R) :             20  1 = 20
 : 
 [Fe(CN)6]3–       
21. (a) 
(  : Fe    = 26)
(b)           ? 1+1=2
22.     

(i) HClO4
(ii) XeOF4 1+1=2
23.     

(a)      NaCN 
(b)     CO   1+1=2

            ?      
     2
24.       

(i)
(ii)
1+1=2
.56/5/3. 8
18. Assertion (A) : Benzaldehyde is less reactive than ethanal towards
nucleophilic addition reactions.
Reason (R) : Ethanal is more sterically hindered.
for tetrahedral complexes.
20. Assertion (A) : The C-O-C bond angle in ethers is slightly less than
tetrahedral angle.
Reason (R) : Due to the repulsive interaction between the two alkyl
groups in ethers. 20  1 = 20
SECTION : B
21. (a) Write the IUPAC name and hybridisation of the complex [Fe(CN)6]3– .
(Given : Atomic number of Fe = 26)
(b) What is the difference between an ambidentate ligand and a
chelating ligand ? 1+1=2

(i) HClO4
(ii) XeOF4 1+1=2

(b) CO in the extraction of Iron. 1+1=2
OR

(i)
(ii)
1+1=2
.56/5/3. 9 P.T.O.
25.                 ? 2

               ?  
        ? 2
26.                  
    ? 2
27.             
(i)  
(ii)   1+1=2
 : 
28.          
(i)        H2O2   
(ii) 358 K  20% H3PO4       (CH3)3C–OH   
(iii) HI        31=3

      ?
(i)   o- 
(ii)    
(iii)     1+1+1=3
29.   A, B, C, D, E  F   
6½=3
30. AlCl3  0.01 m   – 0.068 C       
   [      Kf = 1.86 K kg mol–1] 3
31. (i) DNA  -    ?

(ii)     D-        ?
(iii)          ? 1+1+1=3
.56/5/3. 10
OR

(i) Bacteriocidal antibiotics
(ii) Food preservatives. 1+1=2
SECTION : C
alkaline medium.
OR
(i) Phenol to o-hydroxy benzaldehyde.
(iii) Phenol to phenyl ethanoate. 1+1+1=3
6½=3
31. (i) What are the hydrolysis products of DNA ?

(ii) What happens when D-glucose is treated with Bromine water ?
(iii) What is the effect of denaturation on the structure of proteins ? 1 + 1 + 1 = 3
.56/5/3. 11 P.T.O.
32.       A  B  ZnSO4  CuSO4 
 ,  2A        B    2g Cu   
       ?  A    Zn      ?
33.           3

     
(i)   (ii)   (iii)  1 + 1 + 1 = 3
34.   
(i)  -    
(ii)                
(iii)            31=3
 : 
35. (a)             
 
(i)  NaOH    CH3CHO
(ii) H2N – NH
 NaOH
(iii)
(b)      
(ii)    3 + (1 + 1) = 5

(a)       
CH3
Zn/Hg
(i) C = O 
 HCl
CH3
NaOH/CaO
(ii) 

(a) DIBAL-H
(iii) CH2 = CH – CH2 – CN 
(b) H3O+
(b)            
   
(c)   2, 4 – ...      3+1+1=5
.56/5/3. 12
OR
(i) Protective colloid (ii) Zeta potential (iii) Emulsifying agent
1+1+1=3
34. Give reasons :
(ii) Aromatic primary amines cannot be prepared by Gabriel’s phthalimide
synthesis.
SECTION : D
(ii) H2N – NH
(iii) Conc. NaOH
OR
CH3
Zn/Hg
(i) C = O 
Conc HCl
CH3
NaOH/CaO
(ii) 

(a) DIBAL-H
(iii) CH2 = CH – CH2 – CN 
(b) H3O+
.56/5/3. 13 P.T.O.
36. (a)       25%    40        
       80%   ?
(b)             
         3+2=5

(a)       50%    300 K  30     320
K  10        (Ea)   
(R = 8.314 J K–1 mol–1)
(b)           
(c)                ?
[   log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021, log 5 = 0.6991]
3+1+1=5
37. (a)   

(i)          
(ii)          
(iii) Zn, Cd  Hg        
(b)     
(ii) MnO2  K2MnO4 3+2=5

(a)      
(i)    Ti3+    Sc3+   
(ii) Cr2+     
(b)           
(c)      
2
3 MnO4 + 4H+  2+2+1=5
___________
.56/5/3. 14
36. (a) A first order reaction is 25% complete in 40 minutes. Calculate the
value of rate constant. In what time will the reaction be 80%
completed ?
bimolecular reaction follows first order kinetics. 3+2=5
OR
(R = 8.314 J K–1 mol–1)
reaction ?
3+1+1=5

(i) Transition metals and their compounds show catalytic
activities.
OR
(b) Write two similarities between chemistry of lanthanoids and
actinoids.
2
3 MnO4 + 4H+  2+2+1=5
___________
.56/5/3. 15 P.T.O.
.56/5/3. 16

CBSE 2020 12 Chemistry

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H$moS> Z§.

Code No. 56/1/1

agm`Z {dkmZ (g¡ÕmpÝVH$)

{ZYm©[aV g_` : 3 KÊQ>o A{YH$V_ A§H$ : 70

The substitution reaction of alkyl halide mainly occurs by SN1 or SN2

àíZ g§»`m 6 go 10 EH$ eãX CÎmar¶ h¢ : 15=5

11. Obr` {db`Z _| {ZåZ{b{IV _| go à~bV_ jma h¡

3. Predict the major product formed when 2-Bromopentane reacts with

4. Give one use of CHI3.

Questions number 6 to 10 are one word answers : 15=5

9. Give the structure of the monomer of PVC.

10. Which structural unit present in a detergent makes it non-biodegradable ?

Questions number 11 to 15 are multiple choice questions : 15=5

11. Out of the following, the strongest base in aqueous solution is

15. {XE JE `m¡{JH$ H$m ghr AmB©.`y.nr.E.gr. Zm_ Š`m h¡ ?

(A) 2,2-S>mB_o{Wbã`yQ>oZm°BH$ Aåb

13. Out of the following transition elements, the maximum number of

14. Hardening of leather in tanning industry is based on

15. What is the correct IUPAC name of the given compound ?

(A) 2,2-Dimethylbutanoic acid

17. Assertion (A) : F – F bond in F2 molecule is weak.

18. Assertion (A) : Linkage isomerism arises in coordination compounds

19. Assertion (A) : Sucrose is a non-reducing sugar.

20. Assertion (A) : The molecularity of the reaction H2 + Br2  2HBr

(a) A{^{H«$`m H$s H$mo{Q> H$s àmJw{º$ H$s{OE &>

24. {ZåZ{b{IV AUwAmo§ H$s AmH¥${V It{ME : 12=2

(a) Predict the order of reaction.

(b) Theoretically, can the concentration of the reactant reduce to zero

24. Draw the shape of the following molecules : 12=2

(a) nmoQ>¡{e`_ Q>oQ´>mhmBS´>mopŠgS>mo{µO§Ho$Q> (II)

(b) hoŠgmEoå_rZßb¡{Q>Z_ (IV) ŠbmoamBS>

26. Š`m hmoVm h¡ O~

Fe / HCl NaNO  HCl

(i) Eo{ZbrZ Am¡a EWoZo_rZ

26. What happens when

(a) Propanone is treated with methylmagnesium iodide and then

(b) Arrange the following compounds in decreasing order of their

(a) MnO2 + 4 HCl 

31. {ZåZ{b{IV H$s ^y{_H$m H$s ì`m»`m H$s{OE : 13=3

33. A{^{H«$¶m H$m doJ {H$g àH$ma à^m{dV hmoJm O~

34. 75 g Eogr{Q>H$Aåb _| Kmobo OmZo dmbr EoñH$m°{~©H$ Aåb

30. Account for the following : 13=3

(a) MnO2 + 4 HCl 

(b) XeF6 + KF 

(c) I – (aq) + H+ (aq) + O2 (g) 

31. Explain the role of the following : 13=3

(a) NaCN in the separation of ZnS and PbS.

32. Give three points of difference between physisorption and chemisorption. 3

33. How will the rate of the reaction be affected when

36. (a) {ZåZ{b{IV Ho$ H$maU {b{IE : 13=3

Zn (s) + Cu2+ (aq)  Zn2+ (aq) + Cu (s). 3

(b) Give two advantages of fuel cells. 2

(b) Give two points of differences between electrochemical and

36. (a) Account for the following : 13=3

(b) {ZåZ{b{IV ê$nmÝVaU gånÞ H$s{OE : 13=3

(i) µ\$sZm°b go g¡{b{gbEopëS>hmBS>

(i) µ\$sZm°b go ~oÝµOmo{ŠdZmoZ

(b) Carry out the following conversions : 13=3

agm`Z {dkmZ (g¡ÕmpÝVH$)

{ZYm©[aV g_` : 3 KÊQ>o A{YH$V_ A§H$ : 70

The substitution reaction of alkyl halide mainly occurs by SN1 or SN2

àíZ g§»`m 6 go 10 EH$ eãX CÎmar¶ h¢ : 15=5

(A) 2,2-S>mB_o{Wbã`yQ>oZm°BH$ Aåb

Questions number 6 to 10 are one word answers : 15=5