MUMBAI / AKOLA / DELHI / KOLKATA / GHAZIABAD / NASHIK / GOA / BOKARO / PUNE

IIT – JEE: 2021 Assignment DATE: / /21

TIME: 1 Hr. TOPIC: Acid & Amines MARKS:

MULTIPLE CORRECT ANSWER(S) TYPE

This section contains 15 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D) for its answer, out which ONE OR MORE is/are correct. (+4, –2)
Partial Marks: +1 For darkening a bubble corresponding to each correct option. Provided NO
incorrect option is darkened. In all other cases, minus (–2) mark will be awarded in these parts.
For Example: If (A), (C)and (D)are all the correct options for a question, darkening all these
three will result in +4 marks; darkening only (A)and (D)will result in +2marks; and
darkening (A)and (B)will result in –2 marks, as a wrong option is also darkened.

1. The correct statement are:

(A) If  x  is PhCH  O , then (z) is also PhCH  O

(B) If  x  is PhCH  O , then (y) is Ph  CH  CH  CH  CH  COOH

(C) If (z) is

(D) x can be CH3  CH  O .

C4 H 6 O 4  X  

H 3O ,CaO,  CaOl, 
 LiAlH 4         Y   hexanedioic acid, X and Y are
LAH HBr NaCN
2.

(A) (B)

(C) (D)
 O
||
Ph  CH 2 3  C Cl    X     Y    Z

AlCl3 Na 2 Cr2 O7 .H heat heat
3.

(A) (B)

(C) (D)

4. trans-2-methylcyclohexanol+ acetyl chloride 

X
X  NaOH  aq  

 Y  sodium aceate

(A) (B)

(C) (D)

5. In which of the following reactions correct major product is mentioned?

(A)

(B)

(C)

(D)
  O
 
6. In which of the following reactions, the intremediate species acyl nitrene  R  C N :  and
 
 
intermediate compoundalkyl isocyanate  R  N  C  O  are involved?
O
||
Br2  KOH
(A) R  C  NH 2   
H 2O
 R  NH 2
O O
||  ||
(B) R  C  NH  OH 
  E  NH  C OMe
OH
H2O
MeOH


(C) R  C  N 3 
H2O
 R  NH 2
O O
|| ||
HN 3  H 
(D) R  C  OH 
 
 
H2O
 R  NH  C OPh
H 2O PhOH

7. Among the following reactions, which form salicylic acid(after acidification)?

(A) (B)

(C) (D)

8. Identify coupling reactions.

(A)

(B)

(C)

(D)

9. Identify correctly matched reactions with their products

 (A)

(B)

(C)

(D)

10. Which of the following reactions will give phenyl cyanide as a product?
(A) Reaction of benzene diazonium chloride with cuprous cyanide and KCN
(B) Heating bromobenzene with alcoholic potassium cyanide
(C) Dehydration of benzaldoxime by heating with acetic anhydride
(D) Fusing sodium benzene sulphonate with NaCN

11. Which of the following compounds will give liberation of nitrogen gas when treated with
NaNO2 and HCl at low temperature?
(A) Benzylamine (B) N, N  Dimethylaniline
(C) Diethylamine (D) Alanine

12. The reactions that can be used to prepare benzylamine are

(A) Reduction of benzamide with H 2 / Pd .
(B) Reduction of benzenecarbonitrile with SnCl 2 / HCl
(C) Reaction of potassium phthalimide with benzylbromide followed by hydrolysis.
(D) reaction of benzoyl chloride with ammonia

13. Which of the following reactionts yield an amine?

(A) R  X _ NH 3 
(B) R  CH  NOH   H  
Na,C2 H5OH


(C) R  CN  H 2 O 
H

(D) R  CONH 2  4  H  
LiAlH 4

14. Reaction of RCONH 2 with a mixture of Br2 and KOH gives RNH 2 as the main product. The
intermediate involved in the reaction are
(A) RCONHBr (B) E  NHBr (C) R  N  C  O (D) RCONBr2

15. Which of the following arylamines can from a diazonium salt on reaction with sodium nitrite in
hydrochloric acid?
(A) 4  Chloro  2  nitroaniline
(B) N  Ethyl  2  methylaniline
(C) m  Ethylaniline
(D) p  Aminoacetophenone

NUMERICAL VALUE TYPE

This section contains 10 questions. Each question is numerical value type. For each question,
enter the correct numerical value (in decimal notation, truncated/rounded-off to second
decimal place. (e.g. 6.25, 7.00, –0.33, –.30, 30.27, –127.30).
Marking scheme: +4 for correct answer, 0 if not attempted and 0 in all other cases.

16.
Is mixed and reacted with Br2 / KOH then how many products are obtained.

17. Total number of   Keto monocarboxylic acids (including stereoisomers) which on heating give

18. Two stereoisomers(cis and trans) of 3,4- Dibromocyclopentane-1,1- dicarboxylic acid undergo
decarboxylation, find out the number of product formed.

19. Two stereoisomers(cis and trans) of 3,4-Dibromocyclopentane-1,1- dicarboxylic acid undergo

decarboxylation, find out the total number of product formed.

20.
The total number of products obtained in above reaction is.

21.
 Assign the number 1,2,3,4 for the formation of products A,B,C,D in appropriate box as per the given
instruction.
If aliphatic nucleophilic substitution reaction the assign  3
If aromatic nucleophilic substitution reaction the assign  4
If esterfication reaction the assign =1
If dehydration reaction then assign  2

22. If formic acid,a ceting acid, propanoic acid and benzoic acid is mixed with phosphorus and Bromine
then how many are formed.

23.
is mixed and reacted with Br2 / KOH then how many products are obtained

24.
Double bond equivalent of D is:

25. How many isomers ‘x’ of C8 H10 when reacts with hot alkaline KMnO 4 gives only aromatic
dicarboxylic acid? How many isomers ‘y’ of C4 H 8 when reacts with hot alkaline KMnO 4 gives
carbonodioxide?
Sum of x  y  ?