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1 AITS-FT-VIII (Paper-1)-PCM (Sol.

)-JEE(Advanced)/18

FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS
FULL TEST – VIII
PAPER-1

Q. No. PHYSICS Q. No. CHEMISTRY Q. No. MATHEMATICS

1. AD 19. ABD 37. AC


ALL INDIA TEST SERIES

2. AD 20. BD 38. AB

3. AC 21. ABCD 39. ABCD

4. AD 22. CD 40. AC

5. ABCD 23. BC 41. AB

6. AB 24. ABC 42. AC

7. BCD 25. ABD 43. ABD

8. B 26. C 44. B

9. D 27. B 45. C

10. C 28. C 46. D

11. C 29. A 47. C

12. B 30. C 48. C

13. A 31. C 49. A

14. 3 32. 2 50. 0

15. 1 33. 3 51. 1

16. 4 34. 6 52. 4

17. 2 35. 4 53. 1

18. 2 36. 4 54. 0

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AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 2

Physics PART – I

SECTION – A
1. AD
2 2
 y   y 
Elastic potential energy    ,kinetic energy    . So for antinode elastic potential
 x   t 
y
energy is constant & minimum. always changes for all other points.
x
2. AD
Let’s assume, time taken by the queen to get into the hole is t
   V V cos 
t & also t  
2V sin  2V cos  eV cos 
Therefore
  
 
2V sin  2V cos  eV cos  V sin 
1 
 tan  
3
d 1
 
 r1  r2   d 2 3
2

d 2  9  d  3cm
3. AC
When parallel light falls from left side
3  3  2   2  1 
 
f R R
4 / 3  4 / 3  2   2  1
   f1  80cm
f1 R R
When parallel light falls from right side
1 1  2   2  4 / 3
   f 2  60cm
f2 R R

4. AD
For translatory equilibriumf+FB  mg  f  40 N f FB =10N

5
For rotational equilibrium 40  5  5   N  5 
3 m
 F
N'=125/3 newton as F+Fp  N '  F  110 / 3 Newton Fp =5N
10/3cm
But for F  110 / 3 Newton object will not be in translational
mg=50N
equilibrium so for translational equilibrium
9 355
 F  5  40  F  newton
10 9

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3 AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

5. ABCD

6. AB
Normal Reaction on any of the roller always has a horizontal compound directed towards right.
Therefore, friction acting on the rollers at every point at contact should have component towards
left.
Hence option (C) is incorrect.
Since friction on roller is in opposite direction of F, friction on the plank is in the direction of F.
Therefore, for the system to be in equilibrium, F should be less than mg sin  so option A and B
are correct.
If rollers are clamped so they cannot move, friction on rollers can be towards left as well as right.
Therefore friction on the plank at point A and B can be opposite to F, hence F can be greater
then mg sin  , so option D is incorrect.

7. BCD
13.6 Z 2 13.6Z 2
0.85= and 0.544 
n12 n22
As n2  n1  3  n1  12, n2  15
hc  1 1 
 RhcZ 2  2  2     4052nm
  12 15 
8. B

9. D

10. C

11. C

12. B

13. A
Sol. [Q. 11 – 13]
1 1 1 
Use     1   
f  R1 R2 

SECTION – C

14. 3
x coordinate of centre of mass of the rod

x  sin 
2
 
vx  cos  and ax   cos   sin  2 
2 2
2
When N1  0  cos   sin     1
Using COME:
 1 2 1 2
mg  cos   cos    m  2  m  2
2 2 4 2 12

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AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 4

  
 v  2  from IAOR  N1
P  Intantaneous axis 
3g2  of rotation 
   cos   cos       2   
 θ
3g
  sin       3
2 N2
2 Mg  '
Substituting the value of  and  in equation (1)
gives
2 1 1
 cos   cos   cos    sin  '  so N=3
3 3 3

15. 1
As the electric field is radial, by applying gauss law, we can write 
  Q E
 .ds   0
E

1  rˆ 
For r  , E  C 1  e  1/ 
 1/  
2
r=1/α
  2
 E.ds  C 1  e1   2  4 1 /  
Q
  4 C 1  e1   Q  1  e 1   N  1
0

16. 4
xmin
mg
 0.5x dx  2  xmin  40cm
0

17. 2
2q 
mr 2    d vBr cos 
2 0

dw qvB sin  v
      1 dα
dt  mr rω
 q 
ma   2 d rwB cos  
0 2 x
dv qrwB sin 
a      2 dF
dt  m
w v
dw v
  2  r 2  wdw    v dv
dv r w 0 v0
x=r-rcosθ
v0
v dx=rsinθdθ
2
vdv qrwB sin 

dx m

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5 AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

v0 / 2 
vdv qrB
   sin 2  d
v0
2
v0  v 2 m 0
2mv0
q
Br
18. 2
m
For slight displacement  r x   g  ma  T  2
2

 r2g
 T  2sec

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AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 6

Chemistry PART – II

SECTION – A
19. ABD

Sol.
CH3 Me O O O
Me O O
S O S
S O S O
'A' 'B' 'C' 'D' NH2 'E'
Cl NH2 NH
O
-
O S O O O

Cl

20. BD

A.O. is a single e wave function
Area of the plot for r<52.9 pm is smaller than the area of the plot of r>52.9pm.
At higher atomic number every of 3d<4s
1 1  21 
E 2 5  RhcZ 2  2  2   RhcZ 2 
2 5  100 
1 1 3
E 2 4  RhcZ 2  2  2   RhcZ 2 
2 4  16
28
E25  E2 4
25
21. ABCD
For dissociative process (e.g.H2 to 2H), more pressure is required to get the same extent of
chemisorption as two species have to be chemisorbed.

In anionic surfactant negatively charged -COO group will repeal each other so at lower
concentration micelles will form.

22. CD

Ni 2+ O2  Ni 2+ O 2

O 2 Ni 2+ O 2 Li +

Ni 2+ O2 Ni3 O 2

Li + ion occupy Ni 2+ sites to form substitutional defects. In order to maintain the charge
+ 3+
neutrality, every Li ion is balanced by Ni ion and it becomes a p-type semiconductor.

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7 AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

23. BC
O O
O

'C' O 'D'
'B' O O
'A' C O NH2
CN
O NH2
1, 4 addition 
24. ABC
F-F < Cl-Cl < Br-Br < I-I (Bond length)
F H F
F F
O S S
F F
F H F

F F
F H F
O S 112 C S 97
F H F
F F
Oxygen being more EN, the electron density at S in OSF4 will decreases so it occupies less
space so bond angle Feq. - S - Feq. will increased.
H 2 S  92   O3 116.8   SO2 119.5   NO2 134 
S O+
-
O O O O
AsH 3 <NH 3 <SbH3 <H 2 O  BP 

25. ABD
2
k Cl 
 
Rate of reaction = k 2 Cl CHCl3  and 1 
k1  Cl2 
k1
Cl   Cl2 
k 1
k1 1/ 2
Rate of reaction = k2 . Cl2  CHCl3 
k 1
4.8 103
k  1.3 10 2   2.6  102
1.2 103

26. C
27. B
28. C
Sol. (Q. 26 – 28)
(I) Isothermal expansion
(II) Water & Ice will remain in equilibrium to 0°C & 1 atm pressure so ΔG=0

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AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 8

1 1 2/5 2/5


  P  10 
(III) For adiabatic reversible T2 P2 T P
1 1  T2  300  1   300    120 K
 P2  1
For adiabatic irreversible
 nRT2 nRT1 
C v (T2 -T1 )=-Pext (V2 -V1 )=-P2  - 
 P2 P1 
Cv T T 
(T2 -T1 ) = -P2  2 - 1 
nR  P2 P1 
(T2 -T1 ) TP
=-T2 + 1 2
γ-1 P1
 (γ-1) P2 1 
T2 =T1  + 
 γ P1 γ 
T2 =192K
(IV) Mixing of ideal gas at constant T & P in an isolated container
 q  0, w  0, U  0, S system  0, G  0
29. A
30. C
31. C
Sol. (Q. 29 to 31)
Increasing in polarity of the solvent will increase the rate if T.S. has more charge density in
comparison to reactant.

SECTION – C

32. 2
12  2.9 100
% of carbon   79.09
44
1
R-OH+Na   R-ONa+ H 2  0.00275 mole 
2
Moles of oxygen  0.00275  2
Mass of oxygen  0.00275  2  16  0.088g
% of oxygen = 8.8
So % hydrogen  100  79.09  8.8  12.11
Empirical = C12 H 22 O
x+y 12+22
So = =2
17 17
33. 3
In equilibrium, vapour pressure of solution will remain same
p  nsugar   2 nNaCl 
   
p   nsugar  nH 2O Beaker B  2 nNaCl  nH 2O  BeakerA

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9 AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

0.1 2  0.1

0.1 
1  a  1000 2  0.1  1  a  1000
18 18
 a 1/ 3
0.1 0.3 3
So molarity of NaCl   
4 4 40
3
34. 6
I,II,III,IV,V,VI shows cis & trans isomerism
35. 4
Sol. Pressure of O 2 gas filled inside bulb   76  76  cm Hg  2 atm
O2 is a limiting reagent.
CH 4  2O2  CO2  2 H 2O (l)

4 mole 2 mole
PV  nRT
2  V   4  0.08 280 
V  44.8L  11.2  4 L
x4
36. 4
Fe 2+ ,Zn 2+ ,Ni 2+ ,Cu 2+
3 3
Forms precipitate as FeS,ZnS,NiS,CuS respectively Al ,Cr ions ppt as hydroxides
3+
Fe forms precipitate as FeS  not Fe2S3  .

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AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 10

Mathematics PART – III

SECTION – A
37. AC

n  k 1
2 sin  sin 2  x 
I n k   x
dx
n k
2
 2
k
Let x  t
2
n 1   k 
2
sin   sin 2    t  
  2 
I n k   dt
k
t
n
2  2 2

n 1

1 2 sin   sin 2  t 
I n k  k  t
dt
2 4 n
2
  2
In
I n k  k
24
38. AB

N
 9,3
V
θ
θ
M O X
A C

VC  3units, CO  9units
AN MN
As per property: AV  VN and 2
AV VC
 1 
 OM  6 tan  , AC  CM  3cot   9  3  2 tan   
 tan  
1
 m  1 or m 
2
n
 Eq of Axis can be
 y  3   1 x  9 
or
1
 y  3   x  9 
2

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11 AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

39. ABCD
Let the series be 21,21r,21r 2 ,........
21
Sum= is a positive integer
1-r
Also 21r is a positive integer

S=
 21 21 as 21r  N hence 21-21 r must be an integer
21-21r
Also 21r<21
Hence 21-21r may be equal to 1, 3, 7 or 9
i.e must be a divisor of (21) (21)
hence 21  21r  1 or 3or 7 or 9
21r=20, 18, 14 or 12
40. AC
f  x  is continuous on a closed interval so it attains a minimum value  .
1
Since  is in the range of f ,  f    1 . If   1, f  x   1x and  f  x  dx  1
0
Now, if  1 , by intermediate value theorem, since f is continuous it attains all values between
 and 1 . So for all x   , f  x   1 .
There fore
1 

 f  x  dx   f  x  dx  1   
0 0

2
Since f  x    ,  f  x  dx   and the equality is strict because f is continuous and thus
0

cannot be  for all x   and 1 at  . So


1 2
2  1 3 3
 f  x  dx    1          
0  2 4 4
1
3
   f  x  dx  1
4 0
41. AB
  
T= a b c cosα sinθ1
  
a b c cosα sinθ 2
  
a b c cosα sinθ3
     

Y  2 a  b  b c  c a 
     

 2 a b sin1  b c sin 2  c a sin3 
Y 2  1 1 1  1 1 1
  +  +    cos   1
       4
T cos  a b c  a b c 2
   

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AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 12

42. AC
1 1
lim f  x  f  2 x  is 1 or 0 depending upon x  n
or x  n but f  x   f  2 x  always tends
x0 2 2
 1 
towards zero f  2   f  1 
 1 but lim f  x  is 0, lim f  x   f  3  0
2  x2 x 3

43. ABD

z3
z2
θ
θ
O 1,0 
z1

z2  z3
1st option – chord  Z3  Z 2  is  to line joining and 1.
2
2nd option – angle by chord  Z3  Z 2  at 1, 0  is double of angle at  0, 0 
4th option – Ptolemy’s theorem
44. B
n
For option B total cost of all the n trips=  d PA  d PB 
2
i.e. we have to minimise d PA  d PB .
d PA  d PB  d AB where equality holds when p lies on line segment joining A & B
45. C
For option C total cost of all the n trips
n
  d PA  d PB  d PC 
3
d PA  d PB  d PC is minimum when P is interior point such that AB, BC, CA subtends 120 at P.

46. D
For option D total cost of all the n trips
n
  d PA  d PB  2d PC 
3
As d PA  d PC  d AC & d PB  d PC  d BC
 d PA  d PB  2d PC  d AC  d BC
Equality holds when P is vertex C
47. C
A3  B 3 & A2 B  B 2 A subtracting both we get
A2  A  B   B 2  B  A
  A2  B 2   A  B   0
 det .  A2  B 2   0 (otherwise A  B which is not true)
48. C
49. A
Sol. (Q. 48 to 49) By given information

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13 AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

2 when i=j
a ij = 
0 when i  j
A=  a ij 
2 0 0 0
0 2 0 0 
A= 
0 0 2 0
 
0 0 0 2
A =24
n-1
adjA = A  (16)3  212
3 12
 adj  adjA  = adjA  236   23   (1  7)12
=12 C 0 +12C1 71 +....+12 C12 712
 236  1
 
 7  7
-1
Given A=  I+B  I-B 
T -1 -1
Now, AA =  I+B  I-B   I+B   I-B 
-1 -1
=  I+B  I+B   I-B   I-B  =I×I=I
2
 AA T = I  A =1  A =±1
Given A  0  A  1
 det(2 A)  det  adjA 
2
=23det A-  detA 
=8×1-12 =7
I6+i,3 -Ii+3,3 , i=j
a ij  
0, i j
1 1
 x i 6 xi  3  1
I 6 i ,3  I 3i ,3    3  3 dx   x i 3dx 
0
x 1 x 1  0
i4
1 
5 0 0 
 
1 1 1
 A=  0 0  A = 
 6  5×6×7 210
 
0 1
0
 7 

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AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 14

 J 6,5 72 J11,5 
 
For B=  J 7,5 63 J12,5 
J J13,5 
 8,5 56
Applying C1  C1 +C3
J 6,5 +J11,5 72 J11,5
B = J 7,5 +J12,5 63 J12,5
J 8,5 + J13,5 56 J13,5
x6
1 1 x
11
1 x  1 x  1
J 6,5 +J11,5 =  5
dx+  5
dx =   x- 5 dx+   x 6 -x+ 5 dx =
0 x +1 0 x +1 0
 x +1  0
 x +1  7
1
72 J11,5
7 72 72 J11,5
1 1
63 J12,5  63 63 J12,5  0
8 7 8 9
1 56 56 J13,5
56 J13,5
9

SECTION – C

50. 0
The required line shall be represented by
 y  x   1  z  1  0 &  y  x   2  z  1  0............. 1
Where  x, y , z  is any general point on the line.

At z  0, x 2  y 2  1
 y  x   1.....................  2 
 y  x   2 ...................  3
 2  3
 y 2  x 2  12
 1  12  12  1
Substituting 1 & 2 from (1)
 y  x   y  x  1  y 2  x2  z 2  1
 z  1 z  1
x2  y 2  z 2  1  0
       0

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15 AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18

51. 1
C
L2

I
L3 L1
r

A D B
Intersection point of x  2 y  6  0 and x  y  2  0 is the Incentre of the ABC
I  2, 4 
r  in radius = Perpendicular distance of I from the line AB
2  12  4

10
r  10
 A  A B C
  r cot 2  a   r cot 2  a  r cot 2  b  r cot 2  c
 sa a sbb scc
 3s
 
    rs   10 
    1
  r cot A  a    3s   3 
   2 


52. 4
P T
 5,3  3   /2

2

 C  2,3
A

 

2 2

B
CT  CB  r  4
2
PT  52  3  3   
 45 6 3  3  3 
PT  6
Let ACB  
1
Ar  CAB    r  r  sin   8sin 
2
1
Ar  CAT    r  r  sin      8sin 
2
In  PBT

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AITS-FT-VIII (Paper-1)-PCM (Sol.)-JEE(Advanced)/18 16

 BT 8
tan  
2 PT 6
 4
2 tan2
 sin   2  3  24
 16 25
1  tan 2 1
2 9
24 384
Ar  CAB   Ar  CAT   16sin   16  
25 25
   384 hence  384   15  19  15  4
53. 1
Satisfying then given solution in differential equation
get  a
1
2
 
 2a  1  2  b 2  2b  1 x  2  b  1 e ax  0 which must be true for
2
every 1 & 2  R so a  2a  1  0, b 2  2b  1  0  a  b  1
54. 0
(1, 2) and (3, 6) are foci of ellipse
2 5
2ae  2 5  2a   2  5  45
e
2
 sin   1   cos   2 
2

2
 sin   3   cos  6 
2
  
 1  45  1  5 
1  5  and 1  
45 are maximum distance of (1,2) are (3,6) from circle
x 2  y 2  1  (1, 2), (3, 6), ( ,  ) are collinear
2    0

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