1.

Which one of the following is a sec-allylic carbocation

⊕ ⊕

1) C H 2 −CH =CH 2 2) CH 3 −CH =CH −C H 2

⊕ ⊕

3) C6 H 5−CH =C H 4) CH 3 −C H−CH =CH 2

2. Which of the following pairs is / are correctly matched?
I. Carbocation : electrophile II. Free radical : paramagnetic
III. Carbene : Incomplete octer IV. Carbanion : Incomplete octer
1) Only I 2) I and II 3) I, II, III and IV 4) I, II and III
3. Most stable carbonium ion is +
+ + + CH2
a) CH2 b) CH2c) CH2 d)

Cl OCH 3
NO 2
4. Write correct order of stability of carbocation
+
+ CH2
CH

+
C H
(1) (3) (4)
(2)
a) 2 >4 >3 >1 b) 4> 2> 3> 1 c) 2> 3> 1> 4 d)1>2>3>4

5. The covalent compound, which does not give positive test in Lassaigne’s test is
1) 1,3 – Dinitrobenzene 2) Glycine 3) Urea 4) Hydrazine
6. Glucose and fructose are
1) chain isomers 2) functional isomers
3) position isomers 4) metamers
7. Two substances when separated on the basis of partition coefficient between two liquid
phase, the technique is known as
1) Column chromatography 2) Paper chromatography
3) GLC 4) TLC
8. In which of the following compounds percentage of nitrogen cannot be estimated
accurately by Kjeldlhl’s method
1) Urea 2) Phenyl hydrazine 3) Nitrobenzene 4) Gaunidine
9. Which of the following has the most acidic hydrogen
a)3-hexanone b)2,4-hexanedione c)2,5-hexanedione d)2,3-hexanedione

10. Which one of the following is strongest acid

(A) 2-chloropentanoic acid
(B) 3-chloropentanoic acid
(C) 5-chloropentanoic acid
(D) 4-chloropentanoic acid

Sol. [A]
 2-chloropentanoic acid, due to more effective – I effect.

11. Benzoic acid is less acidic than salicylic acid because of -

(A) Hydrogen bond (B) Inductive effect

(C) Resonance (D) none of these

Sol. [D]

It is due to ortho effect.(sterric inhibition of resonance)

12. In a reaction of C6H5Y, the major product (>60%) is m-isomer, so the group Y is -
(A) –COOH (B) –Cl

(C) –OH (D) –NH2

Sol. [A]

–COOH have (–M effect)

13. Which one of the following compounds will be most easily attacked by an electrophile ?

Cl

(A) (B)

CH3 OH

(C) (D)

Sol. [D]

–OH group show (+M) effect and also +M effect is greater from (–CH3) group.

14. The compound that is most reactive towards electrophilic nitration is -

(A) Toluene (B) Benzene

(C) Benzoic acid (D) Nitrobenzene

Sol. [A]

CH3 COOH NO2

 – COOH, & –NO2 group are deactivating thus they are less reactive towards electrophile nitration then
benzene.

 – CH3 group is activating thus it is most reactive towards electrophilic nitration then benzene.
 15. Which one of the following chlorides gives white precipitate with AgNO 3 most readily -

(A) CH2=CH–CH2Cl

(B) CH2=CH–Cl

(C) CH3–CH2Cl

(D) (C6H5)2CH–Cl

Sol. [D]

16. In the anion HCOO–, the two carbon-oxygen bonds are found to be equal length. What is the reason for it -

(A) the C=O bond is weaker than the C—O bond

(B) the anion HCOO– has two resonating structures

(C) the electronic orbitals of carbon atom are hybridized

(D) the anion of obtained by removal of proton from the acid molecule

17. If benzene ring has one OH, one NO2 and one CHO, IUPAC name can never be
[1] 2-hydroxy-3-nitrobenzene carbaldehyde [2] 2-hydroxy-4-nitrobenzene carbaldehyde
[3] 2-hydroxy-6-nitrobenzene carbaldehyde [4] 4-formyl-2-nitrophenol

Key: 4 [priority order: CHO > OH > NO2]

18. MF: C5H10O represents all the following except
[1] pentanone-2 [2] pentanal [3] pentanol-1 [4] cyclic Ether
[40] Key: 3 [CnH2nO = aldehyde, ketone, cyclic ether if n > 2]