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ZHD en Extern
ZHD en Extern
1907/2006
TRAC111
1.2 Relevant identified uses of the substance or mixture and uses advised against:
For the full text of the H-Statements mentioned in this Section, see Section 16.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
3.2 Mixtures
Hazardous components
Chemical Name CAS-No. Classification Concentration:
EC-No. (REGULATION (EC) No 1272/2008) [%]
REACH No.
Triethanolamine 102-71-6 Not Classified 20 - < 25
203-049-8
01-2119486482-31
Acetic acid, 2-hydroxy-2- 129836-12-0 Acute toxicity Category 4; H302 2.5 - < 5
phosphono-, potassium salt Skin sensitization Category 1; H317
Sodium Hydroxide 1310-73-2 Skin corrosion Category 1A; H314 0.1 - < 0.25
215-185-5 Corrosive to metals Category 1; H290
01-2119457892-27
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
For the full text of the H-Statements mentioned in this Section, see Section 16.
In case of skin contact : Wash off immediately with plenty of water for at least 15
minutes.
Use a mild soap if available.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.
Get medical attention.
In case of eye contact : Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
Get medical attention.
Protection of first-aiders : In event of emergency assess the danger before taking action.
Do not put yourself at risk of injury. If in doubt, contact
emergency responders.Use personal protective equipment as
required.
4.2 Most important symptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
Unsuitable extinguishing : Do not use water unless flooding amounts are available.
media
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
Further information : Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations. In the
event of fire and/or explosion do not breathe fumes.
Advice for emergency : If specialised clothing is required to deal with the spillage, take
responders note of any information in Section 8 on suitable and unsuitable
materials.
Hygiene measures : Handle in accordance with good industrial hygiene and safety
practice. Remove and wash contaminated clothing before re-
use. Wash face, hands and any exposed skin thoroughly after
handling.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
MONITORING MEASURES
A small volume of air is drawn through an absorbant or barrier to trap the substance(s) which can
then be desorbed or removed and analyzed as referenced below:
Substance(s) Method Analysis Absorbant
Sodium Hydroxide US NIOSH: 7401 Titration PTFE filter
DNEL
Triethanolamine : End Use: Workers
Exposure routes: Inhalation
Potential health effects: Long-term systemic effects
Value: 5 mg/m3
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
PNEC
Triethanolamine : Fresh water
Value: 0.32 mg/l
Marine water
Value: 0.032 mg/l
Intermittent use/release
Value: 5.12 mg/l
Marine sediment
Value: 1.7 mg/kg
Soil
Value: 0.151 mg/kg
Marine water
Value: 0.00041 mg/l
Intermittent release
Value: 0.005 mg/l
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
STP
Value: 0.3 mg/l
Marine sediment
Value: 0.0147 mg/kg
Soil
Value: 0.027 mg/kg
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
Viscosity
Viscosity, dynamic : no data available
Viscosity, kinematic : 2.153 mm2/s (20 °C)
10.1 Reactivity
No dangerous reaction known under conditions of normal use.
10.2 Chemical stability
At temperatures greater than 30°C a component of this product may degrade leading to the production of
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
Toxicity
Product
Acute oral toxicity : Acute toxicity estimate : > 2,000 mg/kg
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
Components
Acute oral toxicity : Triethanolamine
LD50 rat: 6,400 mg/kg
Sodium Tolyltriazole
LD50 rat: 1,310 mg/kg
Mercaptobenzothiazole
LD50 rat: 3,800 mg/kg
1,2-Benzisothiazolin-3-one
LD50 rat: 1,020 mg/kg
Components
Acute inhalation toxicity : Sodium Molybdate Dihydrate
LC50 rat: > 1.93 mg/l
Exposure time: 4 h
Components
Acute dermal toxicity : Mercaptobenzothiazole
LD50 rabbit: > 7,940 mg/kg
Chronic Exposure : Health injuries are not known or expected under normal
use.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
12.1 Ecotoxicity
Product
Environmental Effects : Harmful to aquatic life with long lasting effects.
Components
Toxicity to fish : Triethanolamine
96 h LC50: 11,800 mg/l
Mercaptobenzothiazole
96 h LC50 Rainbow Trout: 0.73 mg/l
Method: OECD 203
Components
Toxicity to daphnia and other : Triethanolamine
aquatic invertebrates 48 h EC50: 609.88 mg/l
Mercaptobenzothiazole
48 h EC50 Daphnia magna: 0.71 mg/l
Method: OECD 202
Sodium Hydroxide
48 h EC50: 40 mg/l
Components
Toxicity to algae : Triethanolamine
72 h EC50: > 100 mg/l
Mercaptobenzothiazole
72 h EC50 Green Algae (Pseudokirchneriella
subcapitata, previously Selenastrum capricornutum):
0.5 mg/l
Method: OECD 201
1,2-Benzisothiazolin-3-one
72 h EC50: 0.15 mg/l
Components
Toxicity to bacteria : Triethanolamine
> 1,000 mg/l
Mercaptobenzothiazole
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
Components
Toxicity to fish (Chronic : Mercaptobenzothiazole
toxicity) 89 d NOEC Rainbow Trout: 0.041 mg/l
Method: OECD 210
Components
Toxicity to daphnia and other : Triethanolamine
aquatic invertebrates (Chronic 21 d NOEC: 125 mg/l
toxicity)
Mercaptobenzothiazole
21 d NOEC Daphnia magna: 0.08 mg/l
Method: OECD 211
Product
no data available
Components
Biodegradability : Triethanolamine
Result: Readily biodegradable.
Sodium Tolyltriazole
Result: Readily biodegradable.
Mercaptobenzothiazole
2.5 %, Result: Poorly biodegradable, Exposure time: 14 d,
OECD 301 C (MITI)
1,2-Benzisothiazolin-3-one
Result: Not applicable - inorganic
Sodium Hydroxide
Result: Not applicable - inorganic
no data available
no data available
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
Product
Assessment : This substance/mixture contains no components considered
to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.
no data available
Dispose of in accordance with the European Directives on waste and hazardous waste.Waste codes should
be assigned by the user, preferably in discussion with the waste disposal authorities.
The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in
compliance with the selected mode of transport.
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
:
(Q)SAR - (Quantitative) Structure Activity Relationship; ADN - European Agreement concerning the
International Carriage of Dangerous Goods by Inland Waterways; ADR - European Agreement concerning
the International Carriage of Dangerous Goods by Road; ASTM - American Society for the Testing of
Materials; bw - Body weight; CLP - Classification Labelling Packaging Regulation; Regulation (EC) No
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SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006
TRAC111
1272/2008; DIN - Standard of the German Institute for Standardisation; ECHA - European Chemicals
Agency; EC-Number - European Community number; ECx - Concentration associated with x% response;
ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ErCx - Concentration
associated with x% growth rate response; GHS - Globally Harmonized System; IARC - International Agency
for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the
Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal inhibitory
concentration; ICAO - International Civil Aviation Organization; IMDG - International Maritime Dangerous
Goods; IMO - International Maritime Organization; ISO - International Organisation for Standardization;
LC50 - Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test population
(Median Lethal Dose); MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s.
- Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration; NO(A)EL - No
Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; OECD - Organization for
Economic Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention;
PBT - Persistent, Bioaccumulative and Toxic substance; REACH - Regulation (EC) No 1907/2006 of the
European Parliament and of the Council concerning the Registration, Evaluation, Authorisation and
Restriction of Chemicals; RID - Regulations concerning the International Carriage of Dangerous Goods by
Rail; SADT - Self-Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TRGS - Technical
Rule for Hazardous Substances; UN - United Nations; vPvB - Very Persistent and Very Bioaccumulative;
DSL - Domestic Substances List (Canada); KECI - Korea Existing Chemicals Inventory; TSCA - Toxic
Substances Control Act (United States); AICS - Australian Inventory of Chemical Substances; IECSC -
Inventory of Existing Chemical Substances in China; ENCS - Existing and New Chemical Substances
(Japan); ISHL - Industrial Safety and Health Law (Japan); PICCS - Philippines Inventory of Chemicals and
Chemical Substances; NZIoC - New Zealand Inventory of Chemicals; TCSI - Taiwan Chemical Substance
Inventory; CMR - Carcinogen, Mutagen or Reproductive Toxicant; GLP - Good Laboratory Practice
Sources of key data used to : IARC Monographs on the Evaluation of the Carcinogenic Risk
compile the Safety Data of Chemicals to Man, Geneva: World Health Organization,
Sheet International Agency for Research on Cancer.
Numbers quoted in the MSDS are given in the format: 1,000,000 = 1 million and 1,000 = 1 thousand. 0.1 = 1
tenth and 0.001 = 1 thousandth
REVISED INFORMATION: Significant changes to regulatory or health information for this revision is
indicated by a bar in the left-hand margin of the SDS.
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a guidance for safe
handling, use, processing, storage, transportation, disposal and release and is not to be considered a
warranty or quality specification. The information relates only to the specific material designated and
may not be valid for such material used in combination with any other materials or in any process, unless
specified in the text.
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Nalco® TRAC111
Closed System Treatment
Product Bulletin
NALCO TRAC111 is a multifunctional product designed for the complete protection of multi-metal closed
loop cooling systems. NALCO TRAC111 is particularly suited for the effective protection of modern
systems which are characterized by low water volume and small bore pipework.
NALCO TRAC111 contains corrosion inhibitors, dispersants, scale inhibitors and buffers for the effective
protection of all metal surfaces including carbon steel, yellow metals and aluminium.
ACTIVE CONSTITUENTS
Component Function
Molybdate Mild steel corrosion inhibitor
Polycarboylates Mild steel corrosion inhibitor
Azoles Yellow metal corrosion inhibitor
Phosphonate Mild steel corrosion inhibitor
Polymers Dispersant
Buffers pH regulation
REGULATORY APPROVALS
NALCO TRAC111 is intended for industrial use only. It should not be fed to potable water systems. Refer
to the Material Safety Data Sheet (MSDS), SECTION 15 for the most recent information on approvals.
MATERIALS OF COMPATIBILITY
The dosage of NALCO TRAC111 will vary depending on the operating characteristics of your system.
Your NALCO Water sales engineer will recommend the optimum dosage for cost-effective control and
results.
Read SECTION 8 of the Material Safety Data Sheet for specific personal protective equipment (PPE) and
SECTION 3 for health effects information.
STORAGE
REMARKS
If you need assistance or more information on this product, please call your nearest Nalco
representative.
For more news about Nalco, an Ecolab company, visit our website www.nalco.ecolab.com
For Medical and Transportation Emergencies involving Nalco products, please see the Safety Data Sheet
for the phone number.
ADDITIONAL INFORMATION