BATCH XII & DROPPER’S 2021 (ADV)

TOPIC ALDEHYDE AND KETONE DPP 16E

Marking Scheme : Single Correct (+3,-1) M M: 96 Time : 1 hr

Single Choice Questions :

1.

The products G & H are respectively.

(a) (b)

(c) (d)

2. ; product X is :

(a) (b) (c) (d)

3. ; product is :

(a) (b) (c) (d)

4. ; product is :

(a) (b) (c) (d)

5. ; product is :

(a) (b) (c) (d)

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6. ; product is :

(a) (b) (c) (d)

7. BrCH2COOEt + Me2CHCH2CHO  E CrO

  F HOCH
 2CH
2  4  H H
 G LiAlH  I.

Zn 3 / Py OH 3O

(a) Me2CHCH2CH(OH)CH2COOEt (b) Me2CHCH2COCH2COOEt

(c) (d)

8.

W is sweet smelling compound and liberates H2 with Na metal. Identify the correct option.

(a) (b)

(c) (d)

9. Which one of the following is not correct to get cinnammic acid :

(a) C6 H5  CH  O   (b) C6 H 5  CH  O  

(CH3CO)2 O / CH3COONa CH 2 (COOC 2 H 5 ) 2
Pyridine

(c) C 6 H 5  CH  O  (d) C6 H 5  CH  O 

(i) BrCH2  COOC2H5 / Zn / 


CH 3COOC2 H5 / OH
(ii) H O / H  / 
2

10. PhCOCHBr2   B 

 A   C . The compound ‘C’ is :
OH  OH  OH +

(a) PhCH(OH)CHO (b) PhCH(OH)COOH (c) PhCOCBr2 (d) None of these

H

11. From the above reaction what should be the structure of A ?

(a) (b) (c) (d)

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12. What will be the product of the following reaction Ph(Me)CHCOMe ?
RCO H
Ph(Me)CHCOMe 
3 

(a) RhC(Me)HOCOMe (b) (c) PhCH(Me)OCOOMe (d) None of these

13. Which step is not feasible in the following loop ?

(a) step - a (b) step - b (c) step - c (d) step - d

14. Cyanohydrin formation constant will be highest for ?

(a) (b) (c) (d)

15. ; What shall be the question?

(a) (b) (c) HCOOH (d) HCHO

16. ; . The product R is :

(a) (b)

(c) CH 3 CH3=CH-COOH (d)

17.   A    B  Conc.HCl

 
Zn  Hg
 C. The product ‘C’ is :

OH CH 3 MgBr
heat H 3O 

O
O

(a) (b) (c) (d)

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18. PhCHO + (CH3CO)2O A B. The product B is :
CH3COONa HBr

(a) PhCH = CHCH2Br (b) PhCH  CH 2  COOH (c) PhCH2CH(Br)COOH (d) PhCH = CH–COBr
|
Br
19. Among the following which one will show significant hydration ?

(I) CCl3CHO (II) (CH3)3CCO(CH3)3 (III) O (IV) CH3COCH3

(a) I and III (b) II and III (c) III and IV (d) I and II
20. The number of stereoisomeric products formed in the following reaction is

(a) 1 (b) 8 (c) 4 (d) 2

21. Predict the product of the following reaction ?

(a) (b) (c) (d)

Cl
22. The structure of major product (pseudoionone) is,

(a) (b) (c) (d)

CHO

HCHO (excess)
23. The end products of following reaction would be, NaOH (excess)

C
O CH3

CHO CH2OH CHO COONa

(a) + HCOONa (b) + HCOONa (c) (d) + CH3OH

C C C C
O CH3 O C(CH3OH) 3 O C(CH3OH) 3 O C(CH3OH) 3

24. Ethanal reacts most readily with :

(a) (b) NH2.NH–C6H5 (c) NH2–OH (d) NH2–NH2

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25. In which of the following compounds O18 exchange can be observed on keeping it in H2O18

(a) (b) (c) (d)

26. What will be the product of the following reaction

Ph H3C CH3 CH3

(a) (b) (c) (d)
N CH3 N CH3 N H3C N
CH3 CH3
Ph Ph Ph

27. The possible number of stereoisomers of the product of following reaction would be:
NH2OH
CH3–CH = CH – CH – CHO

CH3
(a) 2 (b) 4 (c) 6 (d) 8
28. Which of the following ketone racemises in aqueous solution containing some acidic or basic impurities.

(a) (b) (c) (d) All

29. The final product (C) of the following reactions would be

 
NH 2OH.HCl
(1)
(A) 
PCl5
(2)
(B) 
Br2 / Fe
(3)
(C)

(a) (b)

(c) (d)

30. In which case two moles of HCN can be added.

(I) (II) (III) (IV)

(a) I, IV (b) II, III (c) I only (d) All

31. The product/s of the following reaction is

(a) (b) (c) (d)

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 Pd – CaCO , H
CH3COCH 3  A  B   C 
H C  C  C  Na + H O Al O
32. 3 2 3 2 2 3
D
CH3
|
(a) CH2=CH—CH=CH2 (b) CH=CH—CH=CH2 (c) CH==C—C==CH2 (d) None of these
| |
CH3 CH3
33. Given the set of reactions. Identify the end product

(a) (b) (c) (d)

34. Which one can easily hydrate ?

(a) (b) (c) (d)

35.

H+
36.
H2O
N

(a) (b) (c) (d)

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 O

O C OC2H5 +
(1)HCl (i)LiAlH4/Et2O
37. X Y Z; Identify X, Y and Z
H3 O

(2) CH2OH (ii) H2O

CH2OH

38. Arrange the following compounds in decreasing orders of Keq for hydrate formation.

(X) (Y) (Z) (W)

(a) Z > Y > X > W (b) Z > X > Y > W (c) Z > W > X > Y (d) Z > X > W > Y
39. Give the correct sequence of reagents for the following conversion :

(a)

(b)

(c)

(d)

C O
40. What product is formed in the following reaction HO Ag2O
H

(a) (b) (c) (d)

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41. Which ketone is most reactive in carbonyl addition reaction
O O

(a) (b) (c) (d)

42. Identify the compound ‘E’

(a) (b)

(c) (d)
43. Given a set of reactions. Identify the compound W

1-heptyne S T U V W
LiNH 2 1–Chloro–3–bromopropane (1) Mg H2, Lindlar’s catalyst CrO3
(2) n–C10 H21CHO / H


(n)-C5H11 (CH2)2–C–C10H21(n–) (n)-C 5H 11

H O
(a) C=C (b) C=C
O (CH2) 3–C–C10H21–(n)
H H H
C5H 11-(n) H C5H 11-(n)
H O OH
(c) C=C (d) C=C
H (CH2)3–C–C10H21–(n) H (CH2)3–C–C10H21–(n)
H
H3O
44. (CH 3 ) 2 C=CH-CH 2 -CH 2 -C(CH 3 )=CH-CHO


(a) (b) (c) (d)

45. Identify the correct set of compounds L, M, N, C, P

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46. The product of the following reaction are (Hint: Cannizzaro type reaction),
PhMgBr + 2PhCHO 


(a) (b)

(c) (d)

C4H9Li R'X C4H9Li R''X HgCl 2, CdCO 3

47. P Q S T U ; the final product U is
S S H 2O

O
S  S
(a) S S
(b) S S
(c)  (d) C
Li R' R''
H R' R' R'' H
48. Glyceraldehyde is commonly made from the oxidaton of
(a) Acrolin (b) Acetal of acrolin (c) Glycerol (d) Hemiacetal of acrolin
Multiple Choice Questions
Ph CH
1.PCl5 / Ether H2 O
49. C N A B+C A, B, C are
pCH3C6H4 2.H2O

(a) PhCONH-p-CH3C5H4 (b) PhCOOH (c) pCH3C6H4NH2 (d) PhCHO

COOH
X Y Z ; X, Y, Z are :
(1) PCl 5 NH 2OH.HCl H2SO 4
50. H Ar (2) (CH3)2Cd
Et
H3C OH
COCH3 C N NHCOCH3 NHCOCH3
(a) H Ar (b) H Ar (c) H Ar (d) H Et
Et Et Et Ar

51. . Product A and C are :

(a) (b) (c) (d)

52. Which one can be the product of the following reaction ?

(a) A diacid (b) A monoacid (c) A diol (d) An alcohol

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53. Which of these carbonyl compounds oh reduction with Zn - Hg / HCI will give the same compound as
product

(a) (b)

(c) (d)

54. Given the statements for a compound C10H16O which on vigrous oxidation yields acetone, oxalic acid
and CH3COCH2CH2COOH, are true
(a) It reacts with hydroxylamine to give C10H17ON
(b) It reduces with Tollen’s reagent to give a compound C10H16O2
(c) It has 2 stereoisomers (d) It is optically active
55. NH2NHCONH2 (1 mole) when added to a mixture of cyclohexanone (1 mole) and benzaldehyde (1
mole) then the product are
(a) Semicarbazone of cyclohexane (kinetically controlled)
(b) Semicarbazone of benzaldehyde (Thermodynamically controlled)
(c) Semicarbazone of benzaldehyde (kinetically controlled)
(d) Semicarbazone of cyclohexane (Thermodynamically controlled)
56. Anhydrous acids bring about formation of acetals where as aqueous acids bring about hydrolysis of
acetals because
(a) High alcohol, low water concentration shift the hemiacetal-acetal and aldehyde-hemiacetal equilibria
in the direction of the acetal.
(b) Low alcohol, high water concentrations shift the equilibria in the direction of aldehyde.
(c) Reverse statements of A and B are true (d) None of these

57. mixture of products may have :

18 18
O O

(a) (b) H3C C H (c) H3C C D (d)

58. Aldehyde and ketones can not distinguished by
(a) Conc. H2SO4 (b) Na / ether (c) Ag2O moist (d) Cold KMnO4
59. Which Compound will be oxidised by HIO4
OH

(a) CH3CHOH–CHO (b) (c) (d) CH2OHCHOHCH2OCH3

OH

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60. The suitable reagents of the following reaction are :

(b)     

I2 /NaOH H NH3 /Δ Br2 +KOH
(a)
+

(1) (2) (3) (4)

(c)        (d)   

NH 2OH PCl
5 dil.NaOH/Δ 3 N H/Δ NH 2OH Δ
(1) (2) (3) (4) (1) (2)

61. The suitable reagent of the following reaction is

(a) K2Cr2O7 / H  (b) N 2 H 4 /OH  (c) PCl5/NaBH4 (d) CrO3 / H  , N2H4 / H  ,

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All students are advised to solve DPPs within allowed time only.
All discussions are scheduled in every 4th doubt discussion class
–MKA Sir (Guruji)

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