s Tiong Dei hoc Bach Khow TP Lica Krew TRA GIUA KY Khoa ky thust Héa hee Men: Ky thuat phin ing BG mon Qué trinh va thigt bj Thai gian lim bai: 45 phsit Hoc ky: 181 Ho & ten ete Mssv: Sinh vién duge sit dung tai Hew. ‘Tho gian lam bai khéng tinh th ian phit 2, thu bi, DE thi c602 tang, GTS we ; Hy cho bit mhuye dim cia ci lop hitb phn img bin phan ting dang Sng, binh phn ing Khusly | tnd inh, binh Khu tr host dng gién doan Ciu20 aim ‘Cho phan ung phin hy pha Kh fe nhursau: A-—>1,6R trong thiét bj bin phin ing gin doar. Nhpligu A nguyén chit va thé tich hn hop khi ting 50% sau 4 phat phan img. Ap suit hé khong d6i va bing 1,2 atm, nhigt | 9 phin emg 25°C. Xéc din pho tinh We d@ ca phn img tn. Ciu3 6 dig) et phn mg pha lng so ding: 24+ GE 2R v6iphuong win vin te (12,5 2 (mot min)C3c, ~(0.15 £1 mot min) C3 Phin img due thuc hin trong binh phan ing khudytrOn hoat dong Gn dinh thé tich 60 it. lai dng ahip ligu: mot dang chit 28 mol A/L, mét dng chir 1.6 mol B/L duge dua vio binh viru hong, thé tich bing nau 4 dat 46 chuyén héa cia tac chit gigi han Ia 75%. Gi si khdi lugng ring cia hdn hop phan tng khéng 46, xe dint lua luong cia mBi dng, whitescy Trdg Dai hoc Bach Kho * a tes a TP.HCM Kim TRA CUGT KY eee Mén: Kg thudt phan éng }8 man Qua trinh va thiét bi ‘Thoi gian Lam bai: 90 phi Hc kj: 181 Ho & tén SV: assy. Sinh vién durge si dung ta lig “Thai gian Iam bi Khong tn thai gian phit A, thu bi, BE thi cb 02 tang. 1 Cau 1 @.diém) ¢:Hlay phan tich sur anh hung cia nhigt d phan king dn qua tein thit ke thiet bi phan ig, o cau 2(2 diém) © ho phn ing ph ng dng hE A + 8 +5 duvet hin rng Bip rg Hh tn So din hoa ng én te Phuong inh 4 cba phi ing sau 012¢,¢} “aay m1 moll 'S'; Cy, Cy moll o Hai ding nhap ligu e6 cling luu long, 1.0 L/s véi ning d6 A va B Kin Iuot la 4 moll va 6 mol/L. Xe (diinh thé tich thiét bi phan ting néa d6 chuyén héa cia tée chat gidi han trong thict bi phan ting 1a 90%. "cau 36 diém * gt phn img déng thé pha kh khong thudn aghich eb phuong *F phan ch 56 cosy mg vin ein iene : rcv 10 at tinh phan tng nhur sau: 2A +B > R ie ACC: K-10" (mol/L) “_Crinh té tichthiét bj phn ding dang binh Khu 6n dinh host a ding ding nit, ing dp voi np ite pin v8 25% A, 25% va O% Ki tro theo thé ich ~ Dnhigt & 500°C, 10 atm) c6 luru luong 1a 6 L/s, than piva dé chuyéin héa ca tic chat gisi han dat 90%. a trCau 4G diém) Phin img khong thud nghich bie mét sau day dure thye hign @ A7éu kién Khoi Iuong sing khong 46i: ‘Trang 122Phan ding duge thye hign lign tuc bing hé hai binh phan ting khudly tron mae n6i tiép voi thé tich bin 118 30 it bin 2 18 60 it Tu Iu np lig vao binh 118180 L/phuitc6 nBng 46 ban du cua A [a 2 mol/L, khong chita R va S. a. Kéc dinh ridng 46 cde cht ti dara ‘cha hé 2 binh khudy. »._Néu sir dung mét binh khudy hoat déng lién tuc véi thé tich binh la 900 lit thay cho hé 2 binh Khuay nhur trén thi ning a6 céc chat tai di ra s8 thay di bao nhiéu Fin so véi h@ ban dau? KB me HET E F, ee Wate ye Bon ny Trang 222Kiem TRA CUO! KY ‘Trdng Dai hoe Bach Khoa TP.HCM i i “kos "7 thuat Héa hoc Mon: Ky thuat ph: “ 7 'B9 mon Qué tinh va thigt Bi “Thai gia lim bai: 90 ——— Hoe ky: 17207) vy: Ho &etén SV: ssi ‘sinh vidn duge sit dung ta leu. 1 “Tho pian Lam bai kh6ng tinh thoi gian phit 4, thu bal, De th 0602 rank ‘ Ciu1(1 diém) “Tinh bay cdc phuomg phép theo dai mite d6 phn ing, cau ¢ 2) (1itin) Trinh biy phurong hung chon hit db 5b) (ain) Khong abit do ti wu la gl? Truong hap ndo cin pha 6p dung ‘va thit bj thuc hién phan ting, ? Ap dung cho cde lai thiét bi phan ting durge chon ? Cin 3.@ diém ‘in hap 20% (thé tich) ozone, 80% Khong Khi 6 1.5 atm va 93°C phan ting trong binh Ong véi Iuu |ugng 1 Ls. Phan king phan hiy ozone nhu sau: 20, ->30, Phuog trinh te d6 phin ting! ~fge = KCoyey Voi k= 0,05 Lol. Xée dink thé tich thiét bi phan img trén néiu d@ chuyén héa cia ozone 1d 60%, Cau 4 (4 digm) Cho phan ving nhu sau: A+B > R+S+T Day la phan ting so ding tai diéu kign ti Ié nbng dé ban dau cia téc chit C, Gi hing 36 t6e 46 phan img k = 5,2 Limo. 6 82°C. Trén co sd s6 ligu nay ta xay dung mét thiét bi san xudt thir dé xée tinh tinh kha thi ca vige sin xudt R tir? dong nbp ligu cé sin nhur sau: dung dich 30% khdi luong A rong nuréc va dung dich 20% kh6i ugng B 4. Tinh thé tich bink pin srg dang dng. Biét rng d6 chuyén héa cha tac chat A 1a 90% va nang suat 100 kg Rh,b. Lap bang can bang vat chat cho thiét bi phan ung voi day du théng s6 mol va kROi lwong, KhOi lugng riéng ciia hén hgp phan ting khang déi va bing 1020 kg/m’. Khéi lrgng phan tir (kg/kmol) |Aitoc cho nhwr sau: ; A B R s T 805 84 ae 585 44 HETKIEM TRA CUOI KY Mén: ky thuat phan ng “Thai gian lam bai: 90 Pit Hoe kj 171 "trong Bai noe Bach Khoa TP.HCM ‘hoa Kj that Ha hoe mon Qu enh vi hi bi lo & tan SV: Masv: ‘sinh vidn duge sir dung tai Tigo. sn phit 4, thu Dai, D8 thi e602 trang “Thi gian Lim bai khong tinh thoi cau 14 diém) “ho phan ing pha lng Kg sn nighid ding nh sae A+ BFC. TRIN MS tren dutge the mick Gi ue ot dons ing mbit, La hang mide @ théing 3 binh khudy 06: ang th teh 2 mol/L. hién trong hé ku vao binh thi nit 18 10 Kith wang €6 cha A va B trong ign trén Ih 3,5L/molh, jong nhap ligula Cy, Hing 36 t6e dé phin sing 6 du Ii a Hay cho bit tinh chat cia mob wh Néu d@ chuyéh ha ca A ta au ra ce Ne sat Binh Khim 3 théng 14 75% thi thé tich. mai binh phan tng 1a bao shigu ? cin 2G dim) Cho phan ting pha khi dng thé: A *) p> #20 due thy hign trong thiét Bi phan ting Khuy tom, dn din hoat dong itm tue 6 dtu kign dang ap. Proms trinh te dé cia phan ting nh sau KCCy voi k= 0.42 Limols vi Ke= 1.0 mol AKC) én hop 20 mls 6 nit dO 200°C, dp suat 5 at. Xée dink png ahép igu ding mol A vAB cs loons trong thi bj phi ing 18 90% the uch ide phin ting vi dd chy oa cA ciu 3G diém) Cho phn ding isomer héa pha Long thu nghich bac 1 in A cPR Hing s6 cin bing iia phan ting 12 ig rhit (ci hai hféu phn tng) nur sa Trang 12ante sir dung eho phan ty THEO Phan img dang KhudytxGn hot déng én din c& thé tich 1000 it uve sit dung cho pt a va nhap ligu khéng, < f Sut rong nha ligu 18 1500 Lh, Nong, dé cia A trong nhap lig ld 2,5 mol/L va nhap Hew ena » Xéc dinh nibng 46 thap nhat o6 thé od cita A trong dong ra Nong 40 ciia A trong dng ra 18,5 moVL. Hay xéc dinh hing s6 te d6 thudn cita phan ting, Mot thigt bi phan dng khuy tron Gn dinh thir 2 c6 thé ch 1000 lit duge méc néi tiép vao binh the nhit, Hay xéc dinh Iu Iwong cia A vio binh thir nit néu néng a6 cua A tai du ra cia binh this 2 vin i 1,5 moVL. va thanh pin ding nhdp ligu khang di HET «/ Truong Dai hoc Bach Khoa TP.HCM ktm TRA CUO! KY Khoa Kj thuat Héa hoe ‘Man: Ky thuat phan ns ‘Bo mén Qué trinh va thiét bi ‘Thai gian lam bai 90, phat —- Hoc kj: 161 Ho & tén SV: MSsV: Sinh vign duge sit dung tai Hig. “Thai gin Lam bai King tinh thai gin ph, tu Ba, DE hi c602 Wane (Cau 1 @ diém) Phan img hydrodealkylation durgc sir dung d& chuyén héa toluene thanh bezene theo phuong tink | phan ing sau: CH, + Hy > CH, + CH. immnerman vi York 4 nghien cf phn ing Khong mht 700-950 kong me v8 thay dng Ay la phi ig Khéng thud ng, 6 phzong tinh te 9 phn ing hr sa pw hy x[HHg}s by =3.510° xon() (1 mol)? #; E=$9900 cal’mol Dong nhép gu gm hydrogen va toluene theo lf mol2; 1, su lung hap lsu 1.0 kent seluenefh, phan ding 6 du Kin épsudt Khi quyén va nit phan ing la 850°C, Xéc din thé ich sinh kus hoat dng lin tac dn hit A 49 chuyeénhéa ca toluene dat doe 60% ciu2G diém) shining pa ing bic 1, khong thud nghicks A 9 RAGS voi h-=hy=0.5 min" dure the sign rong 1 bi phin img ding ghép vs 1 bin Khu hoat ing Gn inh vi the ich {Ra sin phim mong mudn. Nhép liga vio Binh inh 1a 200 phan ting dng 6 sudt lxgng mol 1a 200 mol/min, “chong cha R v8 Swi wing do th cht A la 2 molfL. Xe dinh ning 48 va sult wong cic cht tai Bu 1 -acia fe Binh phin tng, cau 3 6 dim) [opin ingpha ing dng thé hub hii seit ai AY Ring ~ 150°C, hing s6 te 46 phn ing thudn la 1,280h" va hing s6 cin bing 12,3, a 61125°C, hing s6 te d6 phan tng thusin 10,280" va hing s6 cn bling 1a 3,51 rang 12 6 eoang hus tr oat dng in inh, Binh dig oth eh 75 it mgt phan sng LASS ran ung duge thge hi trong hé phn Ging gm 1 inh phan mg Ging mac 6 Jép vei 1 binh phan ding ahi, Fp ing Ky tc thé ch 8150 nit phn eg 125°C ding. Dn OMP vi a Tuomg 855 KU ng Ad A 1 6.5 mol A/L va khéng chia R doe din vio bin Sng b ac inh sudt rong va ning d cic chit ri khdi Binh kus hig 2 pin dng ca binh Khu thap hon bit ng. Sur kr bigt ny c6 mela Khong? HY si hich dtu nay. ‘Néa lou hong ahép ligu thay 86 d& 6 chuyéin héa cia A ta iu ra Binh Khudy dat 50%, cic thong skh Khong thay di, hay xée din sua ugng sin phim R thu eee aw Hits Trang 212