CHEMISTRY

UN-OFFCIAL MOCK-6

Paper – 1

(One and a Half hours)

Answers to this Paper must be written on the paper provided separately.

Candidates are allowed additional 15 minutes for only reading the paper.

The time given at the head of this paper is the time allowed for writing the answers.

ALL QUESTIONS ARE COMPULSORY

The intended marks for questions or parts of questions are given in brackets [ ].

[1*30=30]

Question 1:

The phenomenon of osmosis was reported by:

(A) Traube (B) Graham (C) Abbe Nollet (D) Tyndall.

Question 2:

At higher altitudes, the boiling point of water lowers because:

(A) Atmospheric pressure is low (B) Temperature is low

(C) Atmospheric pressure is high (D) None of these.

Question 3:

The boiling point of a solvent containing a non-volatile solute

(A) is depressed (B) is elevated

(C) does not change (D) none of the above

Question 4:

The colligative properties of a dilute solution depend on

(A) the nature of the solute (B) the nature of the solute and the solvent

(C) the number of particles of solute (D) the number of particles of solvent

Question 5:

Which is true for solution with the same osmotic pressure at the same temperature?

(A) C₁ = C₂ (B) M₁ = M₂ (C) C₁ M₁ = C₂ M₂ (D) C₁/M₁ = C₂/M₂

Question 6:

Molal freezing point depression constant can be expressed in terms of freezing point of solvent (𝑇 ), heat of fusion (Δ𝐻 ) and molar mass (M)
as:

(A) 𝐾 = (B) 𝐾 = (C) 𝐾 = (D) 𝐾 =

Question 7:

The molal elevation constant is the ratio of elevation in boiling point to:

(A) Molarity (B) boiling point of pure liquid

(C) mole fraction of solute (D) molality of solution

1|P age Rajdeep Ghosh chemistry classes

Ph-9831293295
Question 8:

Sea water is converted into fresh water based upon the phenomenon of:

(A) Diffusion (B) Osmosis (C) Plasmolysis (D) Reverse osmosis

Question 9:

If Δ𝑇 is the depression in freezing point for the electrolyte and ΔT for the non-electrolyte of the same concentration, then Van't Hoff factor
(i) is:

(A) Δ𝑇 𝑋 Δ𝑇 (B) Δ𝑇 /Δ𝑇 (C) (D) Δ𝑇 / Δ𝑇

Question 10:

When 0.6 g of urea is dissolved in 100 g of water, the water will boil at (𝑘 for water = 0.52 Km-¹ and normal boiling point of water = 100 °C):

(A) 372.48 K (B) 373.52 K (C) 373.052 K (D) 273.52 K

Question 11:

If 𝐾 for water is 1.86°C mol-¹, a 0.1 m solution of urea in water will have the freezing point of:

(A) 0.186°C (B) 1.86°C. (C)-0.186°C (D) -0.372°C

Question 12:

Six grams of urea (molar mass= 60) are dissolved in 90 g of water. The relative lowering of vapour pressure is equal to:

(A) 0.0196 (B) 0.06 (C) 0.01 (D) 0.0202

Question 13:

The osmotic pressure of a solution at 273 K is 2.5 atm. The osmotic pressure of the same solution at 273°C is :

(A) 0.5 atm (B) 4 atm (C) 5 atm (D) 273 atm

Question 14:

A solution of solute 's' in benzene boils at 0.126° higher than benzene. The molality of the solution is (𝐾 for benzene = 2.52 Km-¹):

(A) 2m (B) 0.05m (C) 1m (D) 20m

Question 15:

The molal elevation constant for water is 0.52°. The elevation caused in the boiling point of water by dissolving 0.25 mole of a non-volatile
solute in 250 g of water will be:

(A) 0.52°C (B) 0.052°C (C) 5.2°C (D) 52°C

Question 16:

A 5% solution of glucose (molar mass = 180) is isotonic with a 2.5% solution of a substance X at the same temperature. The molar mass of X is:

(A) 90 (B) 45 (C) 180 (D) 360

Question 17:

An aqueous solution freezes at -0.186°C. The boiling point of the same solution (𝐾 = 1.86 Km-¹, 𝐾 = 0.512 K m-¹) is:

(A) 100.186°C (B) 100.512°C (C) 100.512/0.186 (D) 100.0512°C.

Question 18:

The osmotic pressure of a 0.2 m solution of non-electrolyte at 27°C (R = 0.082 L atm K-¹mol-¹) is:

(A) 4.92 atm (B) 1 atm (C) 0.2 atm (D) 27 atm

2|P age Rajdeep Ghosh chemistry classes

Ph-9831293295
Question 19:

If depression in freezing point of a solution of 1 g of solute having molar mass 100 in 10 g of water is Δ𝑇, then the molal depression constant

of water is :

(A) 10 Δ𝑇 (B) 100 Δ𝑇 (C) 1000 Δ𝑇 (D) Δ𝑇

Question 20:

The freezing point of water is lowered to -17.8°C by adding methanol. The volume of methanol (density 0.787 g/ml) added to 10 L of water is
(𝐾 = 1.86 Km-¹):

(A) 38.9 L (B) 3.89 L (C) 306.23 L (D) 3062.3 L.

Question 21:

Osmotic pressure of a sugar solution at 24°C is 2.5 atm. The concentration of the solution in gm mole per litre is :

(A) 10.25 (B) 1.025 (C) 102.5 (D) 0.1025

Question 22:

The osmotic pressure of a 3.5% solution of cane sugar at 150°C is :

(A) 4 atm (B) 3.4 atm (C) 3.55 atm (D) 2.45 atm.

Question 23:

When 0.1 mole of glucose is dissolved in 10 mole of water, the vapour pressure of water is:

(A) Increased by 1% (B) Increased by 10% (C) Decreased by 1% (D) Decreased by 10%.

Question 24:

What mass of ethanol (𝐶 𝐻 𝑂𝐻) , a non on electrolyte must be added to 10 L of water to give a solution that freezes at-10.0°C? Assume the
density of water = 1.0 g/ml and 𝐾 (H₂O) = 1.86 K kg mol-¹:

(A) 85.7 kg (B) 24.8 kg (C) 5.38 kg (D) 2.47 kg.

Question 25:

A 0.5 molal solution of ethylene glycol in water is used as coolant in a car. If the freezing point constant of water be 1.86°C per mol, the
mixture will freeze at:

(A) 0.93°C (B) - 0.93°C (C) 1.86°C (D) - 1.86°C

Question 26:
A solution containing 4.2 g of urea in 500 ml was found to be isotonic with a 5% (wt./vol.) solution of an organic non-volatile solute. The molar
mass of the solute is
(A) 35.71 (B) 325.8 (C) 357.1 (D) 418.6

Question 27:
The osmotic pressure of 5% of glucose (Π ) is related to that of 5% aqueous solution of urea (Π ) as:
(A) Π = Π (B) Π < Π (C) Π > Π (D) Π = Π /2

Question 28:
An element (atomic mass = 100 g/mol) having bcc structure has unit cell edge 400 pm. The density of the element is:
(A) 10.376 𝑔 𝑐𝑚 (B) 5.1888 𝑔 𝑐𝑚 (C) 7.289 𝑔 𝑐𝑚 (D) 2.144 𝑔 𝑐𝑚

Question 29:
A metal crystallizes in cubic close packed (ccp). The atomic radius of metal is 144 pm and its atomic mass is 197 a.m.u. Its density is
(A) 19.4 𝑔 𝑐𝑚 (B) 1.94 𝑔 𝑐𝑚 (C) 29.4 𝑔 𝑐𝑚 (D) 2.94 𝑔 𝑐𝑚

Question 30:

A compound AB crystallizes in bcc lattice with unit cell edge length of 480 pm. If the radius of 𝐵 is 225 pm, then the radius of 𝐴 is:

(A) 225 pm (B) 190.7 pm (C) 129.6 pm (D) 132.8 pm

3|P age Rajdeep Ghosh chemistry classes

Ph-9831293295