Worksheet 1

//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [31]
1. The order of reactivity of following alcohols with halogen acids is .........
CH3
(A) CH3CH2 – CH2 – OH (B) CH3CH2 – CH – OH (C) CH3CH2 – C – OH

CH3 CH3
RK
(A) (A) > (B) > (C) (B) (C) > (B) > (A) (C) (B) > (A) > (C) (D) (A) > (C) > (B)
2. Which of the following alcohols will yield the corresponding alkyl chloride on reaction
with concentrated HCl at room temperature ?
A
(A) CH3CH2 – CH2 – OH (B) CH3CH2 – CH – OH
CH3
(C) CH3CH2 – CH – CH2OH

RM CH3
(D) CH3CH2 – C – OH
CH3 CH3
3. Identify the compound Y in the following reaction.
TE
+ –
NH3 N2Cl
Cu2Cl2
Y + N2
273–278K
Cl
WA
Cl
Cl
(A) (B) (C) (D)
Cl Cl
4. Toluene reacts with a halogen in the presence of iron (III) chloride giving ortho and para halo
compounds. The reaction is
T
(A) Electrophilic elimination reaction (B) Electrophilic substitution reaction

(C) Free radical addition reaction (D) Nucleophilic substitution reaction
SE
5. Which of the following is halogen exchange reaction ?

(A) RX + NaI ¾® RI + NaX
(B) C=C + HX ¾® C–C

H X
ZnCl 2
(C) R – OH + HX ¾¾¾ ® R – X + H2O
¾
(D)
6. Which reagent will you use for the following reaction ?

CH3CH2CH2CH3 ¾® CH3CH2CH2CH2Cl + CH3CH2CHClCH3
(A) Cl2 / UV light (B) NaCl + H2SO4
(C) Cl2 gas in dark Wish You - All The
(D) Best
Cl2 gas in the presence of iron in dark
Which reagent will you use for the following reaction ?
CH3CH2CH2CH3 ¾® CH3CH2CH2CH2Cl + CH3CH2CHClCH3
(A) Cl2 / UV light (B) NaCl + H2SO4
(C) Cl2 gas in dark (D) Cl2 gas in the presence of iron in dark
7. Arrange the following compounds in the increasing order of their densities.
Cl Cl Br
Cl Cl
(i) (ii) (iii) (iv)
(A) (i) < (ii) < (iii) < (iv) (B) (i) < (iii) < (iv) < (ii)
(C) (iv) < (iii) < (ii) < (i) (D) (ii) < (iv) < (iii) < (i)
8. Arrange the following compounds in increasing order of their boiling points.
RK
CH3
CH3
(i) CH – CH2Br (ii) CH3CH2CH2CH2Br (iii) H3C – C – CH3
CH3
Br
A
(A) (ii) < (i) < (iii) (B) (i) < (ii) < (iii) (C) (iii) < (i) < (ii) (D) (iii) < (ii) < (i)
9. In which of the following molecules carbon atom marked with asterisk (*) is asymmetric ?
I
H
C*
Br
Cl I
D
C*
Br
Cl OH
H
C*
CH3
C2H5
H
RM
H
C*
CH3
C2H5
(i) (ii) (iii) (iv)
TE
(A) (i), (ii), (iii), (iv) (B) (i), (ii), (iii) (C) (ii), (iii),(iv) (D) (i), (iii), (iv)
10. Which of the following structures is enantiomeric with the molecule (A) given below :
H
CH3
WA
C
H5C2
Br
(A)
H CH3 H Br
C2H5 H Br H
(A) H C C (B) Br C (C) H3C C (D) H C C
3 C2H5 5 2
Br C2H5 CH3
T
11. Which of the following is an example of vic-dihalide ?

(A) Dichloromethane (B) 1, 2-dichloroethane (C) Ethylidene chloride (D) Allyl chloride
SE
12. The position of –Br in the compound in CH3CH = CHC(Br)(CH3)2 can be classified as ..... .
(A) Allyl (B) Aryl (C) Vinyl (D) Secondary
13. Chlorobenzene is formed by reaction of chlorine with benzene in the presence of AlCl3. Which of
the following species attacks the benzene ring in this reaction ?
(A) Cl– (B) Cl+ (C) AlCl3 (D) [AlCl4]–
14. Ethylidene chloride is a/an .......... .
(A) vic-dihalide (B) gem-dihalide (C) allylic halide (D) vinylic halide
15. What is ‘A’ in the following reaction ?
CH2 – CH = CH2
+ HCl ¾® A
Wish You - All The Best

CH2 – CH = CH2 CH2 – CH2 – CH2 – Cl
Cl
What is ‘A’ in the following reaction ?
CH2 – CH = CH2
+ HCl ¾® A
CH2 – CH = CH2 CH2 – CH2 – CH2 – Cl

Cl
(A) (B)
CH2 – CH – CH3 Cl
CH – CH2 – CH3
Cl
RK
(C) (D)
16. A primary alkyl halide would prefer to undergo .......... .

(A) SN1 reaction (B) SN2 reaction (C) a–Elimination (D) Racemisation
A
17. Which of the following alkyl halides will undergo SN1 reaction most readily ?
(A) (CH3)3C – F (B) (CH3)3C – Cl (C) (CH3)3C – Br (D) (CH3)3C – I
18.
(A) 1-Bromo-2-ethylpropane
RM
Which is the correct IUPAC name for CH3 – CH – CH2 – Brr ?
C2H5
(B) 1-Bromo-2-ethyl-2-methylethane
(C) 1-Bromo-2-methylbutane (D) 2-Methyl-1-bromobutane
19. What should be the correct IUPAC name for diethylbromomethane ?
TE
(A) 1-Bromo-1,1-diethylmethane (B) 3-Bromopentane
(C) 1-Bromo-1-ethylpropane (D) 1-Bromopentane
20. The reaction of toluene with chlorine in the presence of iron and in the absence of light yields
.......... .
WA
CH2Cl CH3
Cl
(A) (B)
(C) H 3C Cl (D) Mixture of (B) and (C)

T
Cl Cl Cl
CH 3
SE
21. (i) (ii) (iii)
CH3 CH3
(A) (i) < (ii) < (iii) (B) (ii) < (i) < (iii) (C) (iii) < (ii) < (ii) (D) (i) < (iii) < (ii)
Cl Cl Cl
O2N NO2
22. (i) (ii) (iii)
NO2 NO2
(A) (iii) < (ii) < (i) (B) (ii) < (iii) < (i) (C) (i) < (iii) < (i) (D) (i) < (ii) < (iii)

Cl Cl Cl
CH 3
23. (i) (ii) (iii)
CH3
(A) (i) < (ii) < (iii) (B) (i) < (iii) < (ii) (C) (iii) < (ii) < (i) (D) (ii) < (iii) < (i)
Cl Cl Cl
NO2
24. (i) (ii) (iii)
NO2
(A) (i) < (ii) < (iii) (B) (iii) < (ii) < (i) (C) (i) < (iii) < (ii) (D) (iii) < (i) < (ii)
25. Which of the following compounds will give racemic mixture on nucleophilic substitution by OH–
ion ?
RK
Br
|
(i) CH2 – CH – Br (ii) CH3 – C – CH3 (iii) CH2 – CH – CH2Br
C 2H 5 | C 2H 5
C2H 5
(A) (i) (B) (i), (ii) and (iii) (C) (ii) and (iii) (D) (i) and (ii)
A
26. Which of the carbon atoms present in the molecule given below are asymmetric ?
HO
O
HO H
1 2 3
C –– C –– C –– C
H OH
4
O
H
RM
(A) 1, 2, 3, 4 (B) 2, 3 (C) 1, 4 (D) 1, 2, 3
Reaction of C6H5CH2Br with aqueous sodium hydroxide follows ..........
TE
27.
(A) SN1 mechanism
(B) SN2 mechanism
(C) Any of the above two depending upon the temperature of reaction.
WA
(D) Saytzeff rule

28. Molecules whose mirror image is non-superimposable over them are known as chiral. Which of
the following molecules is chiral in nature ?
(A) 2-Bromobutane (B) 1-Bromobutane
(C) 2-Bromopropane (D) 2-Bromopropan-2-ol
29. Chloromethane on treatment with excess of ammonia yields mainly
T
CH3
(A) N, N-Dimethylmethanamine CH3 – N
CH3
SE
(B) N-methylmethanamine (CH3 – NH – CH3)

(C) Methanamine (CH3NH2)
(D) Mixture containing all these in equal proportion
30. Which is the correct increasing order of boiling points of the following compounds ?
1-Bromoethane, 1-Bromopropane, 1-Bromobutane, Bromobenzene
(A) Bromobenzene < 1-Bromobutane< 1-Bromopropane < 1-Bromoethane
(B) Bromobenzene < 1-Bromoethane< 1-Bromopropane < 1-Bromobutane
(C) 1-Bromopropane < 1-Bromobutane< 1-Bromoethane < Bromobenzene
(D) 1-Bromoethane < 1-Bromopropane< 1-Bromobutane < Bromobenzene
31. Which is the correct increasing order of boiling points of the following compounds ?
1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
(A) Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane
(B) 1-Iodobutane < 1-Bromobutane< 1-Chlorobutane < Butane
(C) Butane < 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane
Which is the correct increasing order of boiling points of the following compounds ?
1-Iodobutane, 1-Bromobutane, 1-Chlorobutane, Butane
(A) Butane < 1-Chlorobutane < 1-Bromobutane < 1-Iodobutane
(B) 1-Iodobutane < 1-Bromobutane< 1-Chlorobutane < Butane
(C) Butane < 1-Iodobutane < 1-Bromobutane < 1-Chlorobutane
(D) Butane < 1-Chlorobutane < 1-Iodobutane < 1-Bromobutane
A RK
RM
TE
T WA
SE

Section [ A ] : 1 Mark MCQ
No Ans Chap Sec Que Universal_QueId

1. B Chap 10 (Part2) D-A 1 QP21P11B1212_P2C10S4Q1
2. D Chap 10 (Part2) D-A 2 QP21P11B1212_P2C10S4Q2
3. A Chap 10 (Part2) D-A 3 QP21P11B1212_P2C10S4Q3
8. C Chap 10 (Part2) D-A 8 QP21P11B1212_P2C10S4Q8
Welcome To Future - Quantum Paper

Student Name : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
Roll Number : 0 1 2 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9
A B C D A B C D A B C D A B C D
1. 11. 21. 31.
2. 12. 22.
3. 13. 23.
4. 14. 24.
5. 15. 25.
6. 16. 26.
7. 17. 27.
8. 18. 28.
9. 19. 29.
10. 20. 30.
Student Name : _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
Roll Number : 0 1 2 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9
1. 11. 21. 31.
2. 12. 22.
3. 13. 23.
4. 14. 24.
5. 15. 25.
6. 16. 26.
7. 17. 27.
8. 18. 28.
9. 19. 29.
10. 20. 30.
OMR ANSWER SHEET
Marks Identifier :
1. 11. 21. 31.
2. 12. 22.
3. 13. 23.
4. 14. 24.
5. 15. 25.
6. 16. 26.
7. 17. 27.
8. 18. 28.
9. 19. 29.
10. 20. 30.
OMR ANSWER SHEET
Marks Identifier :
1. 11. 21. 31.
2. 12. 22.
3. 13. 23.
4. 14. 24.
5. 15. 25.
6. 16. 26.
7. 17. 27.
8. 18. 28.
9. 19. 29.
10. 20. 30.
//X Section A
• Choose correct answer from the given options. [Each carries 1 Mark] [31]
1.
2.
3.
4.

5.
6.
7.
8.
9.

10.
11.
12.
13.
14.
15.

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19.

20.
21.
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24.

25.
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27.
28.
29.

30.
31.

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//X Section A

(A) CH3CH2 – CH2 – OH (B) CH3CH2 – CH – OH (C) CH3CH2 – C – OH

(C) CH3CH2 – CH – CH2OH

(A) Electrophilic elimination reaction (B) Electrophilic substitution reaction

5. Which of the following is halogen exchange reaction ?

(B) C=C + HX ¾® C–C

6. Which reagent will you use for the following reaction ?

11. Which of the following is an example of vic-dihalide ?

Wish You - All The Best

CH2 – CH = CH2 CH2 – CH2 – CH2 – Cl

16. A primary alkyl halide would prefer to undergo .......... .

(C) H 3C Cl (D) Mixture of (B) and (C)

21. (i) (ii) (iii)

Wish You - All The Best

(D) Saytzeff rule

(B) N-methylmethanamine (CH3 – NH – CH3)

Wish You - All The Best

No Ans Chap Sec Que Universal_QueId

Welcome To Future - Quantum Paper

OMR ANSWER SHEET

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper

Welcome To Future - Quantum Paper

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