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(19)

*EP003838850A1*
(11) EP 3 838 850 A1
(12) EUROPEAN PATENT APPLICATION
published in accordance with Art. 153(4) EPC

(43) Date of publication: (51) Int Cl.:


23.06.2021 Bulletin 2021/25 C02F 11/10 (2006.01) C10G 1/00 (2006.01)

(21) Application number: 19850710.5 (86) International application number:


PCT/CN2019/075309
(22) Date of filing: 18.02.2019
(87) International publication number:
WO 2020/034611 (20.02.2020 Gazette 2020/08)

(84) Designated Contracting States: • ZHANG, Haimin


AL AT BE BG CH CY CZ DE DK EE ES FI FR GB Jinan, Shandong 250000 (CN)
GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO • LI, Zongcai
PL PT RO RS SE SI SK SM TR Jinan, Shandong 250000 (CN)
Designated Extension States: • NIU, Jie
BA ME Jinan, Shandong 250000 (CN)
KH MA MD TN • TONG, Lanying
Jinan, Shandong 250000 (CN)
(30) Priority: 13.08.2018 CN 201810916528 • SHI, Shengyu
Jinan, Shandong 250000 (CN)
(71) Applicant: Niutech Environment Technology • LU, Feng
Corporation Jinan, Shandong 250000 (CN)
Jinan, Shandong 250000 (CN) • NIU, Bin
Jinan, Shandong 250000 (CN)
(72) Inventors:
• NIU, Xiaolu (74) Representative: Grünecker Patent- und
Jinan, Shandong 250000 (CN) Rechtsanwälte
• HAN, Guoqian PartG mbB
Jinan, Shandong 250000 (CN) Leopoldstraße 4
80802 München (DE)

(54) OIL SLUDGE PYROLYSIS DEVICE

(57) An oil sludge pyrolysis device, comprising an


outer cylinder body (1) and an inner cylinder body (2), a
spiral conveyor belt (3) being provided on an inner wall
of the inner cylinder body (2), and thermally conductive
pipes (4) being provided on the spiral conveyor belt (3).
Said device enlarges the heat exchange area during oil
sludge pyrolysis, improves the heat exchange efficiency
and the heat utilization rate, and increases the pyrolysis
speed of oil sludge at a low temperature.
EP 3 838 850 A1

Printed by Jouve, 75001 PARIS (FR)


1 EP 3 838 850 A1 2

Description ing the operation process of the spiral belt pushing the
material, when the material contacts with the thermally
Technical field conductive pipes, the thermally conductive pipes provide
contact heat for material pyrolysis; when the material and
[0001] The present invention belongs to the technical 5 the thermally conductive pipes do not contact, the ther-
field of environmental protection, and specifically relates mally conductive pipes provide radiant heat for material
to an oil sludge pyrolysis device. pyrolysis.
[0006] Further, a plurality of thermally conductive pipes
Background technology are evenly arranged on each screw pitch of the spiral
10 conveyor belt. It is preferable to have three thermally con-
[0002] Oil sludge is the abbreviation of sludge contain- ductive pipes evenly arranged on each screw pitch. The
ing oil, which is the solid waste containing oil produced thermally conductive pipes are arranged along the rota-
in oil exploitation, transportation, refining and the process tion direction of the spiral conveyor belt to provide more
of oily wastewater treatment. In general, the oil content heat for the materials to be pyrolysed and increase the
in oil sludge is 10-50% or even higher, while the water 15 heating area of the materials to be pyrolysed. In addition,
content is above 30%. In China’s petrochemical industry, the heating area of the material is increased and the uti-
more than 800,000 tons of oily sludge is produced annu- lization rate of heat is greatly improved due to the full use
ally on average, and the treatment of this part of sludge of heat, further the pyrolysis temperature of oil sludge is
is a long-term problem in China’s petrochemical field. At reduced to a certain extent. The decrease of pyrolysis
present, domestic and overseas sewage oil sludge treat- 20 temperature helps avoid coke formation and extend the
ment technologies include more than ten kinds of service life of the equipment.
processing methods including landfill, profile control in- [0007] As the oil sludge to be pyrolysed has high mois-
jection into the formation, solidification treatment, ther- ture content and is viscous, the solid heat carrier is dis-
mal desorption, solvent extraction, incineration coking persed in the inner cylinder body of the invention. The
pyrolysis, biological treatment, and comprehensive utili- 25 solid heat carrier is a metal sphere or a non-metal sphere.
zation, etc. However, many of the above methods face The oil sludge to be pyrolysed can be evenly wrapped
the problems such as high processing cost, complex on the surface of the solid heat carrier after being mixed
processing equipment, low efficiency and secondary pol- with a solid heat carrier, which makes the oil sludge rel-
lution in practical large-scale industrial applications, all atively dispersed and increases the heating area of the
of which greatly limit their further use. It is a good choice 30 oil sludge, making it easier for pyrolysis. In addition, be-
to treat oil sludge by high-temperature pyrolysis. Howev- cause there is a solid heat carrier in the inner cylinder
er, due to oil sludge has the features of high oil content, body, in the pyrolysis process, there is a relative move-
high viscosity, fine particles and difficulty in dehydration, ment between the solid heat carrier and the inner cylinder
prior art is in lack of corresponding effective oil sludge body, which plays a certain role in clearing coke formation
pyrolysis equipment. 35 and avoiding the occurrence of coke formation, and fur-
ther improves the service life of the equipment. The di-
Content of invention ameter of the aforesaid sphere is 5-50mm.
[0008] The thermally conductive pipes are hollow
[0003] In view of the above problem, the invention pro- pipes, and the heat source comes from the hot air in the
vides an oil sludge pyrolysis device, by using this inven- 40 hot air chamber between the outer cylinder body and the
tion, the heat exchange area in the oil sludge pyrolysis inner cylinder body. The thermally conductive pipes are
process can be enlarged, the heat exchange efficiency connected with the hot air chamber. With the movement
can be improved, further the oil sludge pyrolysis speed of the spiral conveyor belt, the thermally conductive pipes
can be improved, thus realizing the full pyrolysis of oil also move. When the thermally conductive pipes are ro-
sludge. 45 tated to a suitable angle, the hot air enters the thermally
[0004] The specific technical scheme of the invention conductive pipes. When the thermally conductive pipes
is: an oil sludge pyrolysis device, comprising an outer are rotated to other angles, the hot air comes out of the
cylinder body and an inner cylinder body, a spiral con- thermally conductive pipes, thus realizing continuous
veyor belt being provided on an inner wall of the inner heat exchange.
cylinder body, and thermally conductive pipes being pro- 50 [0009] After the above pyrolysis, the oil sludge is py-
vided on the spiral conveyor belt. rolysed into high temperature oil gas, water vapor and
[0005] During the working process, the oil sludge to be solid products. Liquid products and a small amount of
pyrolysed enters the inner cylinder body of the pyrolysis combustible gas are obtained after cooling high temper-
device and runs to the discharge port under the action ature oil gas and water vapor. The liquid products are
of the spiral conveyor belt, and pyrolysis is carried out at 55 transported to the tank area by an oil pump. The purified
the same time. The inner wall of the inner cylinder body combustible gas is used as fuel for pyrolysis heating. The
is provided with a spiral conveyor belt, the spiral conveyor flue gas produced by the production line is discharged
belt is provided with the thermally conductive pipes, dur- after being purified up to the standard by a flue gas pu-

2
3 EP 3 838 850 A1 4

rification system. The solid products obtained from py- Embodiment 3


rolysis is cooled to a safe temperature and then trans-
ported to the solid product silo for temporary storage. [0022] An oil sludge pyrolysis device, comprising an
[0010] In summary, by using of the oil sludge pyrolysis outer cylinder body and an inner cylinder body, a spiral
device described in this invention, the heat exchange ar- 5 conveyor belt being provided on an inner wall of the inner
ea in the oil sludge pyrolysis process is expanded and cylinder body, and thermally conductive pipes being pro-
the heat exchange efficiency is improved, which greatly vided on the spiral conveyor belt.
improves heat utilization rate, speeds up the pyrolysis [0023] Thermally conductive pipes are evenly ar-
speed of the oil sludge at a lower temperature, realizes ranged on each screw pitch of the spiral conveyor belt.
the full recovery of the fossil oil in the oil sludge, and 10 Two thermally conductive pipes are arranged on each
makes the residual oil amount in the treated soil reach screw pitch.
the national standards. Further, the reduction, harmless [0024] The thermally conductive pipes are hollow
and resource-based treatment and application of oil pipes.
sludge are realized without secondary pollution. The de- [0025] A solid heat carrier is dispersed in the inner cyl-
vice is economical, environmentally friendly and safe. 15 inder body.
[0026] The solid heat carrier is a metal sphere.
Description of figure [0027] A diameter of the metal sphere is 5-50mm.

[0011] Embodiment 4
20
Figure 1 is the structural diagram of the invention. [0028] An oil sludge pyrolysis device, comprising an
Figure 2 is the left view of Figure 1. outer cylinder body 1 and an inner cylinder body 2, a
spiral conveyor 3 being provided on an inner wall of the
[0012] Wherein, 1. the outer cylinder body, 2. the inner inner cylinder body 2, and thermally conductive pipes 4
cylinder body, 3. the spiral conveyor belt, 4. the thermally 25 being provided on the spiral conveyor belt 3.
conductive pipes, 5. the hot air chamber. [0029] Thermally conductive pipes 4 are evenly ar-
ranged on each screw pitch of the spiral conveyor belt 3.
Specific embodiments [0030] Three thermally conductive pipes 4 are evenly
arranged on each screw pitch, the thermally conductive
Embodiment 1 30 pipes 4 are arranged along the rotation direction of the
spiral conveyor belt.
[0013] An oil sludge pyrolysis device, comprising an [0031] The thermally conductive pipes 4 are hollow
outer cylinder body and an inner cylinder body, a spiral pipes.
conveyor belt being provided on an inner wall of the inner [0032] A solid heat carrier is dispersed in the inner cyl-
cylinder body, and thermally conductive pipes being pro- 35 inder body 2.
vided on the spiral conveyor belt. [0033] The solid heat carrier is a metal sphere.
[0014] The thermally conductive pipes are hollow [0034] A diameter of the metal sphere is 5-50mm.
pipes.
[0015] A solid heat carrier is dispersed in the inner cyl-
inder body. 40 Claims

Embodiment 2 1. An oil sludge pyrolysis device, comprising an outer


cylinder body (1) and an inner cylinder body (2), a
[0016] An oil sludge pyrolysis device, comprising an spiral conveyor belt (3) being provided on an inner
outer cylinder body and an inner cylinder body, a spiral 45 wall of the inner cylinder body (2), characterized in
conveyor belt being provided on an inner wall of the inner that thermally conductive pipes (4) are provided on
cylinder body, and thermally conductive pipes being pro- the spiral conveyor belt (3).
vided on the spiral conveyor belt.
[0017] Thermally conductive pipes are evenly ar- 2. The oil sludge pyrolysis device according to claim 1,
ranged on each screw pitch of the spiral conveyor belt. 50 characterized in that the thermally conductive
A thermally conductive pipe is arranged on each screw pipes (4) are evenly arranged on each screw pitch
pitch. of the spiral conveyor belt (3).
[0018] The thermally conductive pipes are hollow
pipes. 3. The oil sludge pyrolysis device according to claim 1,
[0019] A solid heat carrier is dispersed in the inner cyl- 55 characterized in that three or more thermally con-
inder body. ductive pipes (4) are evenly arranged on each screw
[0020] The solid heat carrier is a non-metal sphere. pitch, the thermally conductive pipes(4) are arranged
[0021] A diameter of the non-metal sphere is 5-25mm. along a rotation direction of the spiral conveyor belt.

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5 EP 3 838 850 A1 6

4. The oil sludge pyrolysis device according to claim 1,


characterized in that the thermally conductive
pipes (4) are hollow pipes.

5. The oil sludge pyrolysis device according to claim 1, 5


characterized in that a solid heat carrier is dis-
persed in the inner cylinder body (2).

6. The oil sludge pyrolysis device according to claim 1,


characterized in that the solid heat carrier is a metal 10
sphere or a non-metal sphere.

7. The oil sludge pyrolysis device according to claim 1,


characterized in that a diameter of the sphere is
5-50mm. 15

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