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SHS Science Pocket Lesson in General Chemistry 1 2nd Quarter 1
SHS Science Pocket Lesson in General Chemistry 1 2nd Quarter 1
SHS Science Pocket Lesson in General Chemistry 1 2nd Quarter 1
Table of Contents
Science Pocket Lesson 3 Lewis Dot Structure and the Octet Rule…………………………..…….10
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
CHEMISTRY 1
Quantum Numbers
In your most creative way, draw the shape of the orbitals. After that, draw
one thing that resembles the orbital that you commonly see in your daily life.
(Example: Since s-orbital is spherical in shape, you can draw a tennis ball as
representation). You can copy the table below in a separate sheet.
s-orbital
p-orbital
d-orbital
f-orbital
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 1
The Quantum Mechanical Model of Atom
Niels Bohr (1885-1962) constructed a model of the
hydrogen atom with quantized energy levels. Bohr pictured the
electron moving in circular orbits corresponding to the various to
a different orbit by absorbing or emitting a photon of light with
exactly the correct energy content.
Niels Hendrik David Bohr Bohr’s Model of the Atom
Schrödinger’s equation required the use of quantum numbers to describe each electron
within an atom corresponding to the orbital size, shape, and orientation in space. Later it
was found that one needed a quantum number associated with the electron spin.
Orbital of Hydrogen Atom
2 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Principal Quantum Number
The first quantum number is the principal quantum number (n) that describes the size
and energy of the orbital and relative distance from the nucleus. The possible values of n are positive
integers (1, 2, 3, 4 and so on). The smaller the value of n, the lower the energy, and the closer to the
orbital is to the nucleus.
Things to remember:
(a) If l = 0, then the orbital is called an s-orbital and has a spherical shape.
(b) If l = 1, then the orbital is called a p-orbital with two lobes of high electron (c) d-orbital
density like an hourglass or dumbbell shape.
(c) If l = 2, then the orbital is a d-orbital with a variety of shapes.
(d) If l = 3, then the orbital is an f-orbital with more complex shapes.
(d) f-orbital
Magnetic Quantum Number
The third quantum number is the magnetic quantum number (ml). It describes the orientation
of the orbital sound around the nucleus. The possible values of ml depend upon the value of the l quantum
number. The allowed values for ml are -l though 0 to +l. For example, for l = 3, the possible values of ml
would be -3, -2, -1, 0, +1, +2, +3. This is why, for example if l = 1 (a p-orbital), there are three p-orbitals
(sublevels) corresponding to ml values of -1, 0, +1.
The fourth quantum number is the spin quantum number (ms) and indicates the direction the
electron is spinning. There are only two possible values for ms: +1/2 and -1/2. When two electrons are to
occupy the same orbital, then one must have an ms = +1/2 and the other electron must have an ms = -1/2.
These are spin paired electrons.
To assign the four quantum numbers for an electron, let’s have an example:
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 3
Instructions: Answer the following questions. Write your answer in a separate sheet of paper.
4. List the
four quantum
numbers.
1. If n = 6, What are the values
of l ?
2. If n = 7 and l = 5, then what are
the possible values of ml?
3. List all the possible combinations of a.
all four quantum numbers when b.
n =3, l =2, and ml = 1.
c.
d.
If you get a vapor of atoms hot, they emit light at a smallish number of discrete frequencies, with a
Answer to different pattern for every element. These "spectral lines" were quickly used to identify the
composition of unknown materials, and even to discover the presence of previously unknown
START-UP elements. The core idea of this is, electrons move between the special states inside atoms by
absorbing and emitting light of frequencies.
References:
4 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
CHEMISTRY 1
Electronic Configurations and
the Magnetic Properties
TCIELNOCRE GNICAORNTFOIU
Shows the distribution of electrons of an
atom or a molecule.
Refers to the magnetic state of an
atom with one or more unpaired ARGMSTEPNAMIA
electrons.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 5
What are Electronic Configurations?
An electronic configuration shows the distribution of electrons of an atom or a molecule. There is a
specific notation that can quickly show you where the electrons are likely to be located, so knowing this notation
is an essential part of knowing electron configurations. Reading these notations can tell you what element you’re
referring to and how many electrons it has.
Did you know that the structure of the periodic table (see
Figure 1) is based on electronic configuration? The periodic
table can be broken into blocks, corresponding to the
highest energy electrons. The alkali metals and alkaline
earth metals have one and two valence electrons
(electrons in the outer shell), respectively; because of this,
they lose electrons to form bonds easily and so are very
reactive. These elements comprise the s block of the
periodic table. The p block, on the right, contains common
non-metals, such as chlorine and helium. The d block,
which is the largest, consists of transition metals, such
as copper, iron, and gold. The f block, on the bottom,
contains rarer metals, including uranium.
Fig. 1 Blocking in the periodic table
The Aufbau principle: electrons We describe an electron configuration with a symbol that contains
fill orbitals starting at the lowest three pieces of information:
1 available energy state before filling
Name H 1
higher states (e.g., 1s before 2s). Number of electrons
s p d f
6 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Hund’s rule of maximum multiplicity: states Pauli’s exclusion principle: states that, in an
that when electrons occupy degenerate atom or molecule, no two electrons can have
2 orbitals (i.e. same n and l quantum numbers), the same four electronic quantum numbers. As
an orbital can contain a maximum of only two 3
they must first occupy the empty orbitals
electrons, the two electrons must have
before double occupying them.
opposing spins. This means if one is assigned
an up-spin (+1/2), the other must be down-spin
(-1/2).
In applying electrons to the boxes using the arrows,
you must first complete the “upward arrows” for all
boxes before applying the remaining “downward
arrows”.
The alkali metal, Sodium “Na” (atomic number 11) has one more electron than the Neon atom. This
electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1
configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called
valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core
electron shells correspond to noble gas electron configurations, we can abbreviate electron
configurations by writing the noble gas that matches the core electron configuration, along with the valence
electrons in a condensed format. For our Sodium example, the symbol [Ne] represents core electrons,
(1s22s22p6) and our abbreviated or condensed configuration is [Ne]3s1.
• Nitrogen (atomic number 7) fills the 1s and 2s subshells and has one electron in
each of the three 2p orbitals, in accordance with Hund’s rule. These three electrons
have unpaired spins. Oxygen (atomic number 8) has a pair of electrons in any one
of the 2p orbitals (the electrons have opposite spins) and a single electron in each
of the other two. Fluorine (atomic number 9) has only one 2p orbital containing an
unpaired electron. All of the electrons in the noble gas neon (atomic number 10)
are paired, and all of the orbitals in the n = 1 and the n = 2 shells are filled. The
electron configurations and orbital diagrams of these four elements are:
• Similarly, the abbreviated configuration of lithium can be represented as [He]2s1, where [He] represents the
configuration of the helium atom, which is identical to that of the filled inner shell of lithium. Writing the
configurations in this way emphasizes the similarity of the configurations of lithium and sodium. Both atoms,
which are in the alkali metal family, have only one electron in a valence s subshell outside a filled set of inner
shells.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 7
Magnetic Properties of Atoms based on their Electronic
Configurations
The magnetic moment of a system measures the strength and the direction of its magnetism. The term itself
usually refers to the magnetic dipole moment. Anything that is magnetic, like a bar magnet or a loop of electric
current, has a magnetic moment. A magnetic moment is a vector quantity, with a magnitude and a direction. An
electron has an electron magnetic dipole moment, generated by the electron's intrinsic spin property, making it an
electric charge in motion.
refers to the magnetic state of an atom with one or Diamagnetic substances are characterized by paired
more unpaired electrons. The unpaired electrons are electrons—except in the previously-discussed case of
attracted by a magnetic field due to the electrons' transition metals, there are no unpaired electrons.
magnetic dipole moments. Hund's Rule states that According to the Pauli Exclusion Principle which states
electrons must occupy every orbital singly before any that no two identical electrons may take up the same
orbital is doubly occupied. This may leave the atom quantum state at the same time, the electron spins are
with many unpaired electrons. Because unpaired oriented in opposite directions. This causes the magnetic
electrons can orient in either direction, they exhibit fields of the electrons to cancel out; thus there is no net
magnetic moments that can align with a magnet. This magnetic moment, and the atom cannot be attracted
capability allows paramagnetic atoms to be attracted into a magnetic field. In fact, diamagnetic substances
to magnetic fields. Diatomic oxygen, O2 is a good are weakly repelled by a magnetic field.
example of paramagnetism.
Question: Are chlorine atoms paramagnetic or Question: Are zinc atoms paramagnetic or
diamagnetic? diamagnetic?
Solution: Solution:
Ans.: Ans.:
Ignore the core electrons and focus on the valence Ignore the core electrons and focus on the valence
electrons only. electrons only.
Ans.: Since there is an unpaired electron, Cl Ans.: Because there are no unpaired electrons, Zn
atoms are paramagnetic (but weakly since only atoms are diamagnetic.
one electron is unpaired).
8 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Write the electronic configuration of the following elements and draw the correct arrows to represent
the electrons in each subshell.
1. Lithium (3)
2. Oxygen (8)
3. Sulfur (16)
4. Potassium (19)
Instructions: Tell whether the given substance in the problem is PARAMAGNETIC or DIAMAGNETIC
using the 4 steps of determining magnetic properties through electronic configurations. Show your
solution and illustration in a separate sheet of neat paper.
1. Boron (5)
2. Bromine (35) Note: You can always abbreviate and find the core electrons and valence
electrons! *wink*
A VIN or a vehicle identification number is a digit sequence that is stamped into the chassis of a car.
Answer to This serves as an identification code and is a must when registering a vehicle. Each and every car on
START-UP the road has a unique number, which is sometimes referred to as the body number. VIN numbers are
all different and you will never come across vehicles with the same VIN Number stamped on it. This is
also the reason it is referred to as the car’s DNA, because with this number you can identify the exact
model and details registered under it. Just like with the atoms, it has a unique electronic configuration
which will determine the accurate identity of the element.
References:
• https://education.jlab.org/qa/e
lectron_config.html
• https://opentextbc.ca/chemistry/c
hapter/6-4-electronic-structure-
of-atoms-electron-configurations/
• https://chem.libretexts.org
• https://byjus.com/chemistry/elect
ron-configuration/
• https://www.wikihow.com/Write-
Electron-Configurations-for-
Atoms-of-Any-Element
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 9
CHEMISTRY 1 Lewis Dot Structure
and the Octet Rule
Decipher the Mystery Word! Using the Morse Code, decode the unknown word below.
10 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Just what is a Lewis Dot Structure?
Fluorine, for example, with the electron configuration [He]2s22p5, has seven valence
electrons, so its Lewis dot symbol is constructed as follows:
1 2 3 4 5 6 7
Below shows the use of Lewis symbols to show the transfer of electrons during the formation of ionic compounds.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 11
Lewis Structure for Covalent Compounds
A single bond is formed when only one pair of the electron is shared
between the two participating atoms. It is represented by one dash (-). Although
this form of covalent bond has a smaller density and is weaker than a double and
triple bond, it is the most stable.
For example, HCl molecule has one Hydrogen atom with one valence electron and one
Chlorine atom with seven valence electrons. In this case, a single bond is formed between
hydrogen and chlorine by sharing one electron.
12 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
DOUBLE COVALENT BOND
A double bond is formed when two pairs of electrons are shared between the two
participating atoms. It is represented by two dashes (=). Double covalent bonds are much
stronger than a single bond, but they are less stable.
Example: Carbon dioxide molecule has one carbon atom with six valence electrons and two
oxygen atoms with four valence electrons.
To complete its octet, carbon shares two of its
valence electrons with one oxygen atom and two with another
oxygen atom. Each oxygen atom shares its two electrons with
carbon and therefore there are two double bonds in CO2.
1. Carbon has four electrons in its valence shell and it completes its octet
by sharing its four electrons with four chlorine atoms to form carbon
tetrachloride (CCl4) molecule as shown right:
2. Nitrogen has five electrons in its valence shell completes its octet by sharing its three
electrons with three hydrogen atoms to form NH3 (Ammonia).
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 13
Instructions: Answer the following questions. Write your answer in a separate sheet of paper.
1. Magnesium [Ne] 3s2 2. Carbon [He] 2s22p2 3. Sodium (Atomic No. 11)
B. Following the octet rule, form a correct Lewis Dot Structure of a molecule by connecting
the elements using dashes and applying the correct number of dots.
1. Oxygen (6 valence electrons) 2. Bromine (7 valence electrons); Phosphorus (5 valence electrons)
Br P Br
O O
Br
C. Write before the number if the molecules shown below follow the octet rule. If the
molecules’ structure do not follow octet rule, write .
The sound energy in your voice makes the diaphragm vibrate, moving the coil nearer to or further
Answer to from the magnet. This generates an electric current in the coil that corresponds to the sound of
START-UP your voice that generates directly into the communication wires, making a stable connection. In
Lewis Dot Structures, elements have their representation of their connection through dots and
dashes, forming a particular substance and understand its structure.
References:
• https://chem.libretexts.org/
• https://byjus.com/jee/covalent
-bond
• https://www.ck12.org/chemist
ry/Lewis-Electron-Dot-
Structures/rwa/A-Simple-
Code/
• https://electronics.howstuffwor
ks.com/telephone.htm
14 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
CHEMISTRY 1
Naming Compounds
Guess the scientific name! Connect the scientific names of the different flora
and fauna. Try it for fun!
Scientific Names
1. Philippine Eagle
• a. Homo Sapiens
2. Gumamela • b. Jasminum Sambac
3. Human • c. Hibiscus
4. Banana • d. Pithecophaga Jefferyi
5. Sampaguita • e. Musa acuminata
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 15
Nomenclature is the term referring to the naming of compounds.
In this section, we will learn how to write the formula of molecular
compounds formed by the nonmetallic elements. To name compounds
correctly, you will need to memorize certain elements and ions, and you will
need to apply a few rules. Let’s check it out as you go through in this
lesson.
First, we will use a limited set of elements and ions to our examples.
You will also need to learn additional names. Our limited set begins with
the following elements (see table at the right corner).
1 - mono* 6 - hexa
2 - di 7 - hepta
3 - tri 8 - octa
4 - tetra 9 - nona
5 - penta 10 - deca
16 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
To name the compounds correctly, a step-by-step guide will help. Refer to the
example below.
Let’s use the following compounds as examples: CS 2, ClF3, and N2O5. You should
locate the elements in each compound on the periodic table to confirm the order they
appear in the formula. The next step is to write the name of each element in the same
order that they appear in the formula:
CS2
ClF3
carbon sulfur
chlorine fluorine 1
N2O5 nitrogen oxygen
In each case, we need to change the name of the second element to one with an -ide
suffix:
Next, we need to add a prefix in those cases in which there is more than one of a particular
atom:
CS2 carbon disulfide
ClF3 chlorine trifluoride
N2O5 dinitrogen pentoxide
3
Reversing this procedure will allow us to write a formula from a name. Let’s try this
`
with carbon tetrachloride and oxygen difluoride. The formulas for these two compounds
are CCl4 and OF2, respectively.
Note:
• Generally, the less electronegative element is written first in the formula, though
there are a few exceptions. Carbon is always first in a formula and hydrogen is
after nitrogen in a formula such as NH3. The order of common nonmetals in
binary compound formulas is C, P, N, H, S, I, Br, Cl, O, F.
• The a or o at the end of a prefix is usually dropped from the name when the
name of the element begins with a vowel. As an example, four oxygen atoms, is
tetroxide instead of tetraoxide.
• The prefix is "mono" is not added to the first element’s name if there is only
one atom of the first element in a molecule.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 17
Instructions: Answer the following questions. Write your answer in a separate sheet of paper.
Write the molecular formula for Write the name for each
each compound: compound:
All medicines have one generic name, and perhaps one or more brand names. For example, Advil and Motrin are
Answer to brand names for the generic medicine ibuprofen. When you are taking medicine, it is important to know both the
generic and the brand names. This information will prevent you from taking too much of the same medicine,
START-UP which can lead to an overdose. Just like in Chemistry, it is important to know the right names of the compounds
formed as well as its formula.
References:
• https://chem.libretexts.org/
• https://www.guinnessworld
records.com/
• https://consumermedsafety.
org/
• https://courses.lumenlearni
ng.com/
18 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
CHEMISTRY 1
Food that resembles hexagonal Square object you see in your house
shape
Rectangular object that can be found in Triangular object related to human history
school
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 19
The Lewis electron-pair approach can be used to predict the number and types of bonds
between the atoms in a substance, and it indicates which atoms have lone pairs of electrons. This
approach gives no information about the actual arrangement of atoms in space. We continue our
discussion of structure and bonding by introducing the valence-shell electron-pair repulsion
(VSEPR) model (pronounced “vesper”), which can be used to predict the shapes of simple molecules.
Fig. 1: Common Structures for Molecules that consist of a Central Atom Bonded to Two or Three Other Atoms
`
The four covalent bonds in CCl4 arrange themselves three dimensionally,
pointing toward the corner of a tetrahedron and making bond angles of
109.5°. CCl4 is said to have a tetrahedral shape:
Molecules with lone electron pairs around the central atom have a shape based
on the position of the atoms, not the electron pairs. For example, NH 3 has one
lone electron pair and three bonded electron pairs. These four electron pairs
repel each other and adopt a tetrahedral arrangement. However, the shape of
the molecule is described in terms of the positions of the atoms, not the lone
electron pairs. Thus, NH3 is said to have a trigonal pyramidal shape, not a
tetrahedral one.
20 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Similarly, H2O has two lone pairs of electrons around the central
oxygen atom and two bonded electron pairs. Although the four
electron pairs adopt a tetrahedral arrangement, the shape of the
molecule is described by the positions of the atoms only. The shape of
H2O is bent with an approximate 109.5° angle.
In summary…
To determine the molecular
geometry:
Example: What is the geometry of the ammonium ion, NH 4+? Its Lewis
` structure is shown below. How is this different from ammonia, NH 3?
Solution: In ammonium ion, the central atom N has 4 bonds and no lone pair. Based
on Table 1, this is tetrahedral. For representation, see picture below.
In ammonia (NH3), shown below, N has 3 bonds and one lone pair. Based on Table 1, it is
equivalent to the shape of trigonal pyramid.
Lone pair
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 21
Instructions: Identify the shape of the given simple molecules by analyzing its number of bonds
and lone pairs. Write your answer in a separate sheet of paper.
The hexagon - a shape with 6 sides - is one of the most common shapes in nature. From
Answer to honeycombs to snowflakes and patterns found on fruit skins, the hexagon is present everywhere!
START-UP The hexagonal honeycomb construction is so strong at such a light weight that it is commonly used
in human manufacturing.
References:
• https://byjus.com/
22 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
CHEMISTRY 1
Instructions: Study the different shapes below. Identify which shapes are symmetric
or asymmetric by writing its corresponding number to the table below.
5 8
10
4 7
Hint! If a figure can be folded or
divided into half so that the two
halves match exactly then such a
figure is called a symmetric figure.
6 9 2
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 23
Let us define polarity. Polarity is a
state or a condition of an atom or a molecule
having positive and also negative charges,
especially in case of magnetic or an electrical
pole. Polarity, in general, refers to the physical
properties of compounds such as boiling point,
melting points, and their solubilities. The polarity of bonds mainly arises from the act between
molecules and atoms with various electronegativities. Electronegativity is a chemical
property that describes the power of an atom in a molecule to attract electrons to itself. There
is a large difference in electronegativity for atoms from the left- and right-hand sides of the
periodic table. Electronegativity is an important quantity in determining the nature of bonds
between elements and will be considered as the main factor in chemical bonding.
24 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
A molecule is basically said to be either a polar molecule or non- polar molecule. But
how can we find out? Below are the most basic guidelines on how to determine a molecule’s
polarity.
1. Start by drawing its Lewis Structure. This rule applies to all molecules except
hydrocarbons and molecules with two atoms of the same element.
2. The Lewis Structure will help you analyze the shape of the molecule given to you, as
tackled in our previous lesson.
3. Determine which of the five categories of shapes your molecule falls into linear,
tetrahedral, trigonal planar, bent, trigonal pyramid. The first three are symmetric
shapes, and the last two are asymmetric shapes.
4. Remember, non-polar molecules are perfectly symmetrical while polar
molecules are not. This means that if the shape of the molecule given to you is a
bent or trigonal pyramid, it is a polar molecule.
5. Remember that asymmetry applies even if the outer atoms are the same. The
arrangement of the atoms matters more.
6. Now, let us dissect the symmetric molecules. All the atoms that are attached to the
central atom must be the same if it is a non-polar molecule. If different kinds of
atoms are attached to the central atom, the molecule is polar.
`
Non-Polar Molecules (By Shape) Polar Molecules (By Shape)
Bent
Linear
Trigonal Pyramid
Trigonal Planar Tetrahedral
A molecule may be polar or non-polar. A non-polar molecule has a structure of its atoms
lined up in a way that the orbital electrons in the outer region cancel out the
electronegativity.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 25
Instructions: Answer the following questions. Write your answer in a separate sheet of paper.
2. Draw the shape of the given molecules below and identify if its
polarity is polar or non-polar.
a. CO2
b. NH3
c. SO2
d. BCl3
A magnet has two ends called poles, one of which is called a north pole, while the other is called a south pole.
Answer to The north pole of one magnet attracts the south pole of a second magnet, while the north pole of one magnet
repels the other magnet's north pole. So, we have the common saying: like poles repel, unlike poles attract. When
START-UP atoms in a molecule share electron unequally, they create what is called a dipole moment. This occurs when one
atom is more electronegative than another, resulting in that atom pulling more tightly on the shared pair of
electrons, or when one atom has a lone pair of electrons.
References:
• https://byjus.com/chemistr
y/polarity/
• https://geometryofmolecule
s.com/how-to-determine-
molecule-polar-non-polar/
• https://www.explainthatstuf
f.com/
26 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
CHEMISTRY 1
Functional Groups
The following objects below are grouped. If you will describe the set of objects into
one or two words, what is it? Explain. Write your answer in a separate sheet of
paper.
1 3
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 27
The functional group can be defined as an
atom or a group of atoms that are joined together in
a specific manner which is responsible for the
characteristic of chemical properties of organic
compounds. Examples, in this case, are the
hydroxyl group -OH, aldehyde group -CHO, and
carboxylic acid group -COOH. Figure 1
The manner in which the functional groups indulge in a chemical reaction can be further
modified with the help of other functional groups, and these groups can also be interconverted. A few
functional groups involving carbon are illustrated in Figure 1.
Some more functional groups containing elements such
Figure 2 as nitrogen and oxygen featuring different hybridizations of the
carbon-nitrogen and the carbon-oxygen bonds are illustrated in
Figure 2.
The presence of functional groups in a molecule also
affects the solubility and the tendency to form complexes of the
molecule in question. If the functional groups of the solute and
the solvent interact well, the solubility increases. For example,
since sugar and water both contain the -OH (hydroxyl) group,
sugar can be easily dissolved in water.
The common functional groups, along with the prefix and the suffix which must be used in their
nomenclature are provided in this subsection. Additionally, a brief description of the constitution of each
of these groups is also provided.
Hydrocarbons
• Alkanes, alkenes, alkynes (and sometimes the derivatives of benzene) are represented by the symbol R.
these groups are also referred to as hydrocarbyl groups since they contain only carbon and hydrogen atoms.
However, they may vary in the types of bonds between two carbon atoms, such as double or triple bonds.
• The reactivity of these groups varies due to the nature of the carbon-carbon bond. Some groups are made up
of a long, branched alkane or a ring-structured alkane, which are assigned specific names. Examples include
names such as bornyl and cyclohexyl.
• The hydrocarbon functional groups may have an ionic charge on them. The positively charged structures are
referred to as carbocations whereas the negatively charged hydrocarbons are called carbanions.
Haloalkanes
• Haloalkanes, or alkyl halides, are the functional groups which contain a bond between a carbon atom
and a halogen. The prefix used to denote a halogen is ‘halo-’. For example, the compound CH3F can
be called fluoromethane, and the prefix here is fluoro.
28 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
• The suffix used to denote a halogen is the ‘halide’. For example, the same compound,
fluoromethane (CH3F) can also be referred to as methyl fluoride, the suffix being fluoride.
• The carbon-halogen bond varies in strength and stability based on the halogen. For
example, the carbon-iodine bond in alkyl iodides is quite weak but the carbon-fluorine bond
in alkyl fluorides is quite strong and stable.
• The properties of the functional groups containing a carbon-oxygen bond are entirely dependent on the
hybridization of the carbon-oxygen bond.
• This can be explained by the electron donating effect of the sp2 hybridization of oxygen which can
be observed in alcohols in sharp contrast with the electron withdrawing effect of the sp hybridized oxygen
which can be observed in the carbonyl groups which contain a carbon-oxygen double bond.
• The suffixes used in the nomenclature of compounds which have a functional group containing a C-O bond
are tabulated below along with examples.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 29
Based on the Functional Group table, what
is the suffix and functional group of:
1. Define functional group.
1. Ethanoic Acid?
2. What will happen if the functional 2. Methanol?
groups of the solute and the solvent 3. Trimethylamine?
interact well? 4. Ethanal?
5. Ethyl Butanoate?
Grouping ingredients will help you to put it in a cooking pan at its specific time (e.g., right time for
Answer to tenderness, avoid being saggy, extracting flavors at right temperature). Also, you don’t like your
preparation and cooking to be messy. In chemistry, atoms can be grouped in a specific manner
START-UP which is responsible for the characteristic of chemical properties of organic compounds, called
functional groups.
References:
• https://byjus.com/
30 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
CHEMISTRY 1
Structural Isomerism
Can You Solve This Matchstick Math Puzzle? Each of the numbers in this
equation is built from matchsticks. By moving only one matchstick, fix the equation
so that it is correct. (Keep moving 1 matchstick! Although we need only 1 answer,
there are at least three possible ways to make the equation work!)
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 31
in Organic Molecules
Isomers are molecules that have the same molecular formula, but have a different arrangement
of the atoms in space. That excludes any different arrangements which are simply due to the molecule
rotating as a whole, or rotating about particular bonds. Take a look at the example below. Both of the
following are the same molecule. They are not isomers. Both are butane.
Linear Branched
32 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Positional isomerism arises when there Position Isomerism
is a difference in the positions occupied by the
substituent atoms or a group of atoms or due to the unsaturation occurring in the chain. When the
position of the functional groups with respect to main chain atom changes, the phenomenon is
called as position isomerism. In simple words, the basic carbon skeleton remains unchanged,
but important groups are moved around on that skeleton. For example, there are two
structural isomers with the molecular formula C3H7Br. In one of them the bromine atom is on the
end of the chain, whereas in the other it's attached in the middle.
Functional group isomerism is a type of structural isomerism where isomers have same
molecular formula but differ in functional group. Thus, they belong to different families of compounds
or different homologous series. For example, there are two functional group isomers found with the
molecular formula C2H6O. Ethanol and dimethyl ether are those two functional group isomers. Here
`
ethanol contains alcohol as functional group and dimethyl ether contains ether.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 33
Identify which from the types of structural isomerism represent the
description or example below.
______________3.
Answer to Convertible dresses (or versatile dresses e.g., malong, sarong, customized fabrics) are those that
START-UP can be worn into different styles by tying or knotting the parts of the textile, forming as a whole
dress. The key takeaway here is that, atom arrangements of molecules may always differ.
References:
• https://chem.libretexts.org
• https://byjus.com
• https://www.thoughtco.com
• https://chemdictionary.org
34 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
CHEMISTRY 1
Organic Reactions
Me:
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 35
Types of Organic Reactions
Substitution Reaction
Elimination Reaction
There are some reactions which involve the elimination or
removal of the adjacent atoms. After these multiple bonds are formed
and there is a release of small molecules as products.
One of the examples of elimination reaction is the conversion of
ethyl chloride to ethylene.
CH3CH2Cl → CH2=CH2 + HCl
In the above reaction, the eliminated molecule is HCl, which is
formed by the combination of H+ from the carbon atom which is on the
left side and Cl– from the carbon atom which is on the right side.
Addition Reaction
Addition reaction is nothing but just the opposite of elimination
reaction. In an addition reaction, the components A and B are added to
the carbon-carbon multiple bonds and this is called addition reaction. In
the reaction given below when HCl is added to ethylene, it will give us
ethylene chloride.
HCl + CH2 CH2 → CH3CH2Cl
Rearrangement Reaction
36 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Instructions: Determine the organic reaction based on the description below. Write your answer
in a separate sheet of paper.
Traditionally, three reagents, potassium nitrate, carbon, and sulfur, make gunpowder. You’re doing
Answer to a combustion reaction out of those types of materials that creates this detonation explosion. Those
START-UP three reagents react to make solid potassium carbonate, solid potassium sulfate, nitrogen gas, and
carbon dioxide gas, so you have solid reagents reacting to make gases.
References:
• https://stillunfold.com/
• https://chem.libretexts.org/
• https://byjus.com/
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 37
CHEMISTRY 1
Polymers
Look around your surroundings. List some items that you consider as an example
of a polymer (either man-made e.g., plastics or polymers found in nature e.g.,
cotton). Give its function or uses.
POLYMER FUNCTION/USE
1. Sponge (Example) Sponges can be used for dishwashing.
3. ______________ _______________________________________
2. ______________ _______________________________________
4. ______________ _______________________________________
6. ______________ _______________________________________
5. ______________ _______________________________________
7. ______________ _______________________________________
9. ______________ _______________________________________
8. ______________ _______________________________________
38 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
What are Polymers?
In this lesson, we will explore polymers, which are found everywhere, from our food to our
clothes. You'll learn the definition of the term 'polymer,' and we'll look at the structure of it.
Polymers are very big molecules made up of many smaller molecules layered together in a
repeating pattern. In fact, the word polymer is Greek for 'many parts.' The smaller molecules that come
together to form polymers are called monomers--small units that link together over and over to form a
large polymer. Think of monomers like paper clips that link together to form a chain, and the chain is a
polymer.
Polymers can result in some very unique materials, both naturally occurring and man-made. Let's
explore some examples of man-made and natural polymers.
Polymers are formed by a process called polymerization, in which a chemical reaction of reacting
monomer molecules forms polymer chains in a variety of complexities.
• Addition Polymerization
• Condensation Polymerization
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 39
Ever wondered what is the shape of a
polymer molecule? Think spaghetti!
There are also classes of biological molecules may be grouped into the types of polymers
they form and the monomers that act as subunits:
1. Lipids - polymers called diglycerides, triglycerides; monomers are glycerol and fatty acids
2. Proteins - polymers are known as polypeptides; monomers are amino acids
3. Nucleic Acids - polymers are DNA and RNA; monomers are nucleotides, which are in
turn consist of a nitrogenous base, pentose sugar, and phosphate group
4. Carbohydrates - polymers are polysaccharides and disaccharides; monomers are
` monosaccharides (simple sugars)
Here we will list some of the important uses of polymers in our everyday life.
40 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Instructions: Answer the following questions. Write your answer in a separate sheet of paper.
Differentiate Addition
Polymerization and Write an essay on the important
Condensation Polymerization. uses of polymers in our daily lives.
The vast majority of plastic bags that we use everyday are made from an ever-present polymer
Answer to
substance, known as polyethylene. This consists of long chains of ethylene monomers.
START-UP
References:
• https://byjus.com/
• https://www.thoughtco.com/
• www.chem1.com
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 41
CHEMISTRY 1
Organic Compounds and
its General Classes
Identify and write which of the images below fall under a general class or a
major source of carbohydrates, lipids, proteins, and nucleic acids.
DNA Potatoes
4. __________________ 5. __________________
42 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
The chemical compounds of living things are known as organic compounds because of their association
with organisms and because they are carbon-containing compounds. Organic compounds, which are the
compounds associated with life processes, are the subject matter of organic chemistry.
What do you observe?
As shown in the table, two columns are divided – one is for organic
compounds and the other is for inorganic compounds. What did you notice
about all the compounds that are classified as examples of organic
compounds?
Did you observe carbon is always present and that hydrogen and
oxygen are commonly found in organic compounds? Great! Most organic
compounds contain carbon, hydrogen, and sometimes other elements such
as nitrogen, sulfur, oxygen, or phosphorus. All living organisms contain carbon—even bacteria. Our bodies
are composed mostly of water, H2O, and it is necessary for us to survive. However, water is an example of an
inorganic compound because it does not contain carbon and it was not formed by a living organism. Carbon
dioxide, CO2, is another example of an inorganic compound because it does not contain both carbon and
hydrogen. One molecule of CO2 contains one atom of carbon and two atoms of oxygen. There are a total of three
atoms in one molecule of carbon dioxide, CO2.
Carbohydrates
Carbohydrates are macronutrients and are one of the three main ways by which our body obtains its
energy. They are called carbohydrates as they comprise carbon, hydrogen, and oxygen at their chemical level.
Carbohydrates are essential nutrients which include sugars, fibers, and starches. They are found in grains,
vegetables, fruits, and in milk and other dairy products. They are the basic food groups which play an important
role in a healthy life. The carbohydrates are further classified into simple and complex which is mainly based on
their chemical structure and degree of polymerization.
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 43
• Glucose is an example of a carbohydrate monomer or monosaccharide. Other examples of
monosaccharides include mannose, galactose, fructose, etc.
• Two monosaccharides combine to form a disaccharide. Examples of carbohydrates having two monomers
include- Sucrose, Lactose, Maltose, etc.
• Polysaccharides are complex carbohydrates formed by the polymerization of a large number of monomers.
Examples: starch, glycogen, cellulose, etc. which exhibit extensive branching.
Functions of Carbohydrates
✓ The main function of carbohydrates is to provide energy and food to the body and to the nervous system.
✓ Carbohydrates are known as one of the basic components of food, including sugars, starch, and fiber which are
abundantly found in grains, fruits, and milk products.
✓ It is also involved in fat metabolism and prevents ketosis.
✓ Inhibits the breakdown of proteins for energy as they are the primary source of energy.
✓ An enzyme by name amylase assists in the breakdown of starch into glucose, finally to produce energy for metabolism.
Lipids
Lipids are a family of organic compounds, composed of
fats and oils. These molecules yield high energy and are
responsible for different functions within the human
body.
Types of Lipids
Proteins
Proteins consist of chains of amino
acids called peptides. A protein may be made
from a single polypeptide chain or may have a
more complex structure where polypeptide
subunits pack together to form a unit. Proteins
consist of hydrogen, oxygen, carbon, and
nitrogen atoms. Some proteins contain other
atoms, such as sulfur, phosphorus, iron,
copper, or magnesium.
Functions of Proteins
✓ Used to build structures, and as signal molecules to help cells communicate with each other.
✓ Store energy for long term
✓ Waterproof covering
44 SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Nucleic Acid
Nucleic acids are the molecules in our cells that direct and store
information for reproduction and cellular growth. There are two types of
nucleic acids:
1. Ribonucleic Acid (RNA)
2. Deoxyribonucleic Acid (DNA)
Both nucleic acids are unbranched organic polymers composed of
monomer units called nucleotides. These nucleotides are composed of a
sugar molecule, a nitrogen base, and phosphoric acid. A single DNA
molecule may contain several million of these nucleotides, while the
smaller RNA molecules may contain several thousand. The DNA carries
the genetic information for the cells. Sections of a DNA molecule called
genes contain the information to make a protein. DNA serves two main
functions. Molecules of DNA can produce other DNA molecules and RNA
molecules. RNA molecules are directly responsible for the synthesis of
proteins.
Functions of Nucleic Acids
✓ DNA’s function is the transmission of genetic information. It forms as a media for long-term storage.
✓ RNA’s function is the transmission of the genetic code that is necessary for the protein creation from
the nucleus to the ribosome.
Identify the following statements by writing the answer in the space provided.
After you workout, your body repairs or replaces damaged muscle fibers through a cellular process
Answer to where it fuses muscle fibers together to form new muscle protein strands or myofibrils. These
START-UP repaired myofibrils increase in thickness and number to create muscle hypertrophy (growth). It is
essential for us to have a right amount of intake of proteins and carbohydrates.
References:
• https://byjus.com/
• https://www.builtlean.com/
• https://healthfully.com/
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020 45
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
INSTANT TASK INSTANT TASK
1. D Mystery Word: F L U O R I N E
2. C
FLASH CHECK
3. A
4. E 1. Magnesium [Ne] 3s2
5. B 2. Carbon [He] 2s22p2
3. Sodium (Atomic No. 11)
FLASH CHECK
A. 1. PCl5 1. 2.
2. SO2
3. SiI4
4. S2C
B. 1. Bromine Pentafluoride
2. Disulfur Difluoride
1.
3. Carbon Monoxide 2.
4. Carbon Tetrafluoride 3.
.
SCIENCE POCKET LESSON 4 SCIENCE POCKET LESSON 3
Week 2
INSTANT TASK INSTANT TASK
1. Aufbau Principle (Answer may vary with the student’s
representation.)
2. Electronic Configuration
Shapes of the Orbitals:
3. Paramagnetism
4. Diamagnetism
FLASH CHECK
1. 1s22s1 -
2. 1s22s22p4 -
3. 1s22s22p63s23p4 -
4. 1s22s22p63s23p64s1 -
FLASH CHECK
1. l can have a value of 0, 1, 2, 3, 4, 5
2. -5, -4 ,-3, -2, -1, 0, 1, 2, 3, 4, 5
3. n = 3, l = 2, ml = 1, ms = +1/2 and
1. Boron - [He] 2s22p1 1 unpaired electron;
n = 3, l = 2, ml = 1, ms = -1/2
PARAMAGNETIC 4. A. principal quantum numbers
B. angular momentum quantum
2. Bromine - [Ar] 4s23d104p5 1 unpaired electron; number
PARAMAGNETIC C. magnetic quantum number
D. spin quantum number
SCIENCE POCKET LESSON 2 SCIENCE POCKET LESSON 1
Week 1
ANSWER KEY
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
INSTANT TASK INSTANT TASK
(Any of the three solutions.) (Answer may vary with the student’s representation.)
FLASH CHECK
(A)
1. Functional group - defined as an atom or a group of atoms
that are joined together in a specific manner which is responsible
for the characteristic of chemical properties of organic
compounds.
2. If the functional groups of the solute and the solvent interact
well, the solubility increases. For example, since sugar and
water both contain the -OH (hydroxyl) group, sugar can be
FLASH CHECK easily dissolved in water.
1. Position Isomerism (B)
2. Functional Group Isomerism
3. Chain Isomerism 1. -oic acid; Carboxlyic Acid
2. -ol; Alcohol
3. -amine; Tertiary Amine
4. -al, Aldehyde
5. Alkyl Alkanoate; Ester
SCIENCE POCKET LESSON 8 SCIENCE POCKET LESSON 7
Week 4
INSTANT TASK INSTANT TASK
(Answer may vary with the student’s
representation.)
FLASH CHECK
1. Linear
2. Tetrahedral
3. Bent
FLASH CHECK 4. Trigonal Planar
1. (Answer may vary depending on student’s insights.)
2. a. CO2; Non-polar b. NH3; Polar c. SO2; Polar d. BCl3; Non-Polar
SCIENCE POCKET LESSON 6 SCIENCE POCKET LESSON 5
Week 3
ANSWER KEY
SAN PEDRO RELOCATION CENTER NATIONAL HIGH SCHOOL – SCIENCE DEPARTMENT © 2020
Protein 5.
Lipids 4.
Carbohydrates 3.
Deoxyribonucleic Acid 2.
Polysaccharides 1.
FLASH CHECK
Carbohydrates 5.
Nucleic Acid 4.
Lipids 3.
Protein 2.
Carbohydrates 1.
INSTANT TASK
SCIENCE POCKET LESSON 11
Week 7
INSTANT TASK
(Objects listed should be an example of man-made or natural
polymers.)
FLASH CHECK
Difference of Addition and Condensation Polymerization:
(a) In addition polymerization, small monomer units are
combined to form a giant polymer, while in
condensation polymerization, small molecules of H2O,
CO, or NH3 are eliminated to form a resulting polymer.
(b) [Answer may vary.]
SCIENCE POCKET LESSON 10
Week 6
INSTANT TASK
(Answer may vary with the student’s representation.)
FLASH CHECK
1. Addition Reaction
2. Elimination Reaction
3. Substitution Reaction
4. Rearrangement Reaction
SCIENCE POCKET LESSON 9
Week 5
ANSWER KEY