Cotton Seed Meal MSDS 4708-97

CARGILL AUSTRALIA COTTONSEED MEAL
Chemwatch Independent Material Safety Data Sheet

Issue Date: 22-Apr-2010 CHEMWATCH 4708-97
NC317ECP Version No:5
CD 2010/1 Page 1 of 11
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
SYNONYMS
stock-feed, animal-feed
PROPER SHIPPING NAME

SEED CAKE with more than 1.5% oil and not more than 11% moisture
PRODUCT USE
Used for stock/ animal feed.
SUPPLIER
Company: Cargill Australia Limited
Address:
Level 11, Twenty8 Freshwater Place
Southbank
VIC, 3006
AUS
Telephone: +61 3 9268 7200
Emergency Tel: 1800 039 008 (24 hrs)
Fax: +61 3 9867 8774
WEB: http://cargill.com.au
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE

DANGEROUS GOODS. NON-HAZARDOUS SUBSTANCE. According to NOHSC Criteria, and ADG Code.
POISONS SCHEDULE
None
RISK
Risk Codes Risk Phrases
R07 ■ May cause fire.
R17 ■ Spontaneously flammable in air.
SAFETY
Safety Codes Safety Phrases
S22 ■ Do not breathe dust.
S24 ■ Avoid contact with skin.
S60 ■ This material and its container must be disposed of as
hazardous waste.
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
NAME CAS RN %
residue from crushing of cotton seeds >60
cottonseed oil 8001-29-4 0.5-5
water 7732-18-5 <12^
continued...
CD 2010/1 Page 2 of 11
Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
Section 4 - FIRST AID MEASURES
SWALLOWED
■ - Immediately give a glass of water.
- First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor.
EYE
■ If this product comes in contact with eyes:
- Wash out immediately with water.
- If irritation continues, seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.
SKIN
■ If skin or hair contact occurs:
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
INHALED
■ - If dust is inhaled, remove from contaminated area.
- Encourage patient to blow nose to ensure clear passage of breathing.
- If irritation or discomfort persists seek medical attention.
NOTES TO PHYSICIAN
■ Treat symptomatically.
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
■ - Jets of water.
- Water spray or fog.
- Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.
FIRE FIGHTING
■ - Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water courses.
- Use water delivered as a fine spray to control fire and cool adjacent area.
- DO NOT approach containers suspected to be hot.
- Cool fire exposed containers with water spray from a protected location.
- If safe to do so, remove containers from path of fire.
- Equipment should be thoroughly decontaminated after use.
When any large container (including road and rail tankers) is involved in a fire,
consider evacuation by 800 metres in all directions.
FIRE/EXPLOSION HAZARD
■ - May ignite on contact with air leading to spontaneous combustion
- May decompose explosively when heated or involved in fire.
- May REIGNITE after fire is extinguished.
- Gases generated in fire may be poisonous, corrosive or irritating.
- Containers may explode on heating.
- Runoff may create multiple fire or explosion hazard.
continued...
CD 2010/1 Page 3 of 11
Section 5 - FIRE FIGHTING MEASURES
May heat spontaneously.

Combustion products include: carbon monoxide (CO) and carbon dioxide (CO2).
Avoid creating dust - may present dust explosion hazard. Dry dust can be electrostatically charged by
turbulence, pneumatic transport, pouring, in exhaust ducts and during transport. Build-up of electrostatic
charge may be prevented by grounding.
May ignite spontaneously if wet or containing an excessive proportion of
unoxidised oil.
FIRE INCOMPATIBILITY
■ Avoid contamination with strong oxidising agents as ignition may result.
- Keep dry.
HAZCHEM
1Y
PERSONAL PROTECTION
Glasses: Gloves: Respirator:
Not normally required. When handling larger quantities: Type A- P Filter of sufficient
capacity
Section 6 - ACCIDENTAL RELEASE MEASURES
MINOR SPILLS
■ - Remove all ignition sources.
- Clean up all spills immediately.
- Avoid contact with skin and eyes.
- Control personal contact by using protective equipment.
- Use dry clean up procedures and avoid generating dust.
- Place in a suitable, labelled container for waste disposal.
MAJOR SPILLS
■ Remove all ignition sources.
- Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- Control personal contact by using protective equipment and dust respirator.
- Prevent spillage from entering drains, sewers or water courses.
- Avoid generating dust.
- Sweep, shovel up. Recover product wherever possible.
- Put residues in labelled plastic bags or other containers for disposal.
- If contamination of drains or waterways occurs, advise emergency services.
Personal Protective Equipment advice is contained in Section 8 of the MSDS.
Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING

■ - Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of overexposure occurs.
- Use in a well-ventilated area.
- Avoid contact with moisture.
- Avoid smoking, naked lights or ignition sources.
- Avoid contact with incompatible materials.
- When handling, DO NOT eat, drink or smoke.
- Keep containers securely sealed when not in use.
continued...
CD 2010/1 Page 4 of 11
Section 7 - HANDLING AND STORAGE
- Avoid physical damage to containers.

- Always wash hands with soap and water after handling.
- Work clothes should be laundered separately and before re-use
- Use good occupational work practice.
- Observe manufacturer's storing/handling recommendations.
- Atmosphere should be regularly checked against established exposure standards to ensure safe working
conditions are maintained.
SUITABLE CONTAINER
■ Multi-ply paper bag with sealed plastic liner or heavy gauge plastic bag.
NOTE: Bags should be stacked, blocked, interlocked, and limited in height so that they are stable and secure
against sliding or collapse. Check that all containers are clearly labelled and free from leaks. Packing as
recommended by manufacturer.
STORAGE INCOMPATIBILITY
■ Avoid storage with oxidisers.
STORAGE REQUIREMENTS
■ - Keep dry.
- Store under cover.
- Store in a well ventilated area.
- Store away from sources of heat or ignition.
- Observe manufacturer's storing and handling recommendations.
Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
Source Material TWA mg/m³
___________ ___________ _______
Australia Exposure Standards Cargill Australia Cottonseed Meal 4
(Grain dust (oats, wheat, barley))
The following materials had no OELs on our records

• cottonseed oil: CAS:8001- 29- 4
• water: CAS:7732- 18- 5
MATERIAL DATA
CARGILL AUSTRALIA COTTONSEED MEAL:
■ grain dust
TLV TWA: 4 mg/m3 (oat, wheat, barley) (total dust/particulate)
ES TWA: 4 mg/m3 (oat, wheat, barley)
MEL TWA: 10 mg/m3 (oat, wheat, barley, maize, rye) sensitiser
Exposure to grain dusts affects the upper and lower respiratory tract. Symptoms include running nose and
bronchitis. Irritant action, allergic reaction, or both, are thought to produce these symptoms. High
concentrations of the dusts are irritating to both eyes and skin and may produce "grain fever" characterised
by chest tightness and flu-like symptoms. Studies show a decline in lung function, in grain workers, exposed
to the dust over a period of six years. Inhalation of grain dusts may result in serious health effects
including occupational asthma, extrinsic alveolitis and chronic obstructive pulmonary disease. The nature of
the chemical agent(s) producing these effects is unknown but might include soils, microorganisms, pesticide
residues, naturally occurring toxins, insect parts, animal hairs, other proteins, and even small amounts of
free silica. [EH64 Summary Criteria for Occupational Exposure Limits- Health and Safety Executive, UK].
continued...
CD 2010/1 Page 5 of 11
COTTONSEED OIL:
■ vegetable oil mists (except castor, cashew nut and similar irritant oils)
TLV TWA: 10 mg/m3
ES TWA: 10 mg/m3
OSHA PEL TWA: 15 mg/m3, total particulate; 5 mg/m3, respirable particulate
The common vegetable oil mists are considered "nuisance" particulates which have little adverse effect on
the lung. They do not produce toxic effects or significant organic disease when exposures are kept under
reasonable control. Direct instillation of vegetable oils into rabbit lungs produces acute bronchitis whilst
high oral doses are laxatives.
PERSONAL PROTECTION
EYE
■ No special equipment for minor exposure i.e. when handling small quantities.
- OTHERWISE:
- Safety glasses with side shields.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A
written policy document, describing the wearing of lens or restrictions on use, should be created for each
workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals
in use and an account of injury experience. Medical and first-aid personnel should be trained in their
removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye
irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first
signs of eye redness or irritation - lens should be removed in a clean environment only after workers have
washed hands thoroughly. [CDC NIOSH Current Intelligence Bulletin 59].
HANDS/FEET
■ No special equipment needed when handling small quantities.
OTHERWISE: Wear general protective gloves, eg. light weight rubber gloves.
OTHER
■ No special equipment needed when handling small quantities.
- Overalls.
- Eyewash unit.
RESPIRATOR
■ Selection of the Class and Type of respirator will depend upon the level of breathing zone contaminant and
the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and
inside the mask) may also be important.
Breathing Zone Level Maximum Protection Half- face Respirator Full- Face Respirator
ppm (volume) Factor
1000 10 A- AUS P -
1000 50 - A- AUS P
5000 50 Airline * -
5000 100 - A- 2 P
10000 100 - A- 3 P
100+ Airline**
* - Continuous Flow ** - Continuous-flow or positive pressure demand.
The local concentration of material, quantity and conditions of use determine the type of personal protective
equipment required. For further information consult site specific CHEMWATCH data (if available), or your
Occupational Health and Safety Advisor.
continued...
CD 2010/1 Page 6 of 11
ENGINEERING CONTROLS
■ Use in a well-ventilated area.
- Local exhaust ventilation is required where solids are handled as powders or crystals; even when
particulates are relatively large, a certain proportion will be powdered by mutual friction.
- Exhaust ventilation should be designed to prevent accumulation and recirculation of particulates in the
workplace.
- If in spite of local exhaust an adverse concentration of the substance in air could occur, respiratory
protection should be considered. Such protection might consist of:
(a): particle dust respirators, if necessary, combined with an absorption cartridge;
(b): filter respirators with absorption cartridge or canister of the right type;
(c): fresh-air hoods or masks
- Build-up of electrostatic charge on the dust particle, may be prevented by bonding and grounding.
- Powder handling equipment such as dust collectors, dryers and mills may require additional protection
measures such as explosion venting.
Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Yellow and black flecked mixture of particles; dispersible in water.
PHYSICAL PROPERTIES
Solid.
Does not mix with water.
Floats on water.
State Divided solid Molecular Weight Not applicable

Melting Range (°C) Not applicable Viscosity Not Applicable
Boiling Range (°C) Not applicable Solubility in water (g/L) Immiscible
Flash Point (°C) Not applicable pH (1% solution) Not applica ble
Decomposition Temp (°C) Not Available pH (as supplied) Not a pplicable
Autoignition Temp (°C) Not available Vapour Pressure (kPa) Not applicable
Upper Explosive Limit (%) Not available Specific Gravity (water=1) 0.56
Lower Explosive Limit (%) Not available Relative Vapour Density Not applicable
(air=1)
Volatile Component (%vol) Not applicable Evaporation Rate Not applicable
Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY

■ May heat spontaneously.
- Presence of heat source and ignition source.
- Presence of incompatible materials.
Presence of water.
Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.
Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
continued...
CD 2010/1 Page 7 of 11
Section 11 - TOXICOLOGICAL INFORMATION
ACUTE HEALTH EFFECTS
SWALLOWED
■ Considered to be non toxic.
EYE
■ Although the material is not thought to be an irritant (as classified by EC Directives), direct contact
with the eye may produce transient discomfort characterised by tearing or conjunctival redness (as with
windburn).
SKIN
■ The material is not thought to be a skin irritant (as classified by EC Directives using animal models).
Temporary discomfort, however, may result from prolonged dermal exposures. Good hygiene practice requires
that exposure be kept to a minimum and that suitable gloves be used in an occupational setting.
INHALED
■ Generated dust may be discomforting.
CHRONIC HEALTH EFFECTS

■ There is some evidence that inhaling this product is more likely to cause a sensitisation reaction in some
persons compared to the general population.
There is limited evidence that, skin contact with this product is more likely to cause a sensitisation
reaction in some persons compared to the general population.
Dusts produced by proteins can sometimes sensitise workers like other foreign bodies. Symptoms include asthma
appearing soon after exposure, with wheezing, narrowing of the airways and breathing difficulties. There may
also be a chronic cough, phlegm, fever, muscle pains, fatigue and airway obstruction; chest X-rays may show a
characteristic net-like pattern or scarring at the tip and base. There may also be chest discomfort, headache,
stomachache and a general feeling of unwellness. Often the clinical picture is similar to "farmer's lung" and
other allergic lung inflammations. Prolonged contact with the skin can cause pain, redness, inflammation and
ulceration. Repeated attacks can cause loss of lung function due to scarring.
Sensitisation may give severe responses to very low levels of exposure, i.e. hypersensitivity. Sensitised
persons should not be allowed to work in situations where exposure may occur.
TOXICITY AND IRRITATION

■ Not available. Refer to individual constituents.
COTTONSEED OIL:
■ No significant acute toxicological data identified in literature search.
Reproductive effector in rats.
Section 12 - ECOLOGICAL INFORMATION
CARGILL AUSTRALIA COTTONSEED MEAL:

■ Biodegradable.
COTTONSEED OIL:
■ Substances containing unsaturated carbons are ubiquitous in indoor environments. They result from many
sources (see below). Most are reactive with environmental ozone and many produce stable products which are
thought to adversely affect human health.The potential for surfaces in an enclosed space to facilitate
reactions should be considered.
Source of unsaturated substances Unsaturated substances (Reactive Major Stable Products produced
Emissions) following reaction with ozone.
continued...
CD 2010/1 Page 8 of 11
Occupants (exhaled breath, ski Isoprene, nitric oxide, Methacrolein, methyl vinyl
oils, personal care products) squalene, unsaturated sterols, ketone, nitrogen dioxide,
oleic acid and other unsaturated acetone, 6MHQ, geranyl acetone,
fatty acids, unsaturated 4OPA, formaldehyde, nonanol,
oxidation products decanal, 9- oxo- nonanoic acid,
azelaic acid, nonanoic acid.
Soft woods, wood flooring, Isoprene, limonene, alpha- Formaldehyde, 4- AMC,
including cypress, cedar and pinene, other terpenes and pinoaldehyde, pinic acid,
silver fir boards, houseplants sesquiterpenes pinonic acid, formic acid,
methacrolein, methyl vinyl
ketone, SOAs including ultrafine
particles
Carpets and carpet backing 4- Phenylcyclohexene, 4- Formaldehyde, acetaldehyde,
vinylcyclohexene, styrene, 2- benzaldehyde, hexanal, nonanal,
ethylhexyl acrylate, unsaturated 2- nonenal
fatty acids and esters
Linoleum and paints/polishes Linoleic acid, linolenic acid Propanal, hexanal, nonanal, 2-
containing linseed oil heptenal, 2- nonenal, 2-
decenal, 1- pentene- 3- one,
propionic acid, n- butyric acid
Latex paint Residual monomers Formaldehyde
Certain cleaning products, Limonene, alpha- pinene, Formaldehyde, acetaldehyde,
polishes, waxes, air fresheners terpinolene, alpha- terpineol, glycoaldehyde, formic acid,
linalool, linalyl acetate and acetic acid, hydrogen and
other terpenoids, longifolene organic peroxides, acetone,
and other sesquiterpenes benzaldehyde, 4- hydroxy- 4-
methyl- 5- hexen- 1- al, 5-
ethenyl- dihydro- 5- methyl-
2(3H)- furanone, 4- AMC, SOAs
including ultrafine particles
Natural rubber adhesive Isoprene, terpenes Formaldehyde, methacrolein,
methyl vinyl ketone
Photocopier toner, printed Styrene Formaldehyde, benzaldehyde
paper, styrene polymers
Environmental tobacco smoke Styrene, acrolein, nicotine Formaldehyde, benzaldehyde,
hexanal, glyoxal, N-
methylformamide,
nicotinaldehyde, cotinine
Soiled clothing, fabrics, Squalene, unsaturated sterols, Acetone, geranyl acetone, 6MHO,
bedding oleic acid and other saturated 40PA, formaldehyde, nonanal,
fatty acids decanal, 9- oxo- nonanoic acid,
azelaic acid, nonanoic acid
Soiled particle filters Unsaturated fatty acids from Formaldehyde, nonanal, and other
plant waxes, leaf litter, and aldehydes; azelaic acid;
other vegetative debris; soot; nonanoic acid; 9- oxo- nonanoic
diesel particles acid and other oxo- acids;
compounds with mixed functional
groups (=O, - OH, and - COOH)
Ventilation ducts and duct Unsaturated fatty acids and C5 to C10 aldehydes
liners esters, unsaturated oils,
neoprene
" Urban grime" Polycyclic aromatic hydrocarbons Oxidized polycyclic aromatic
hydrocarbons
Perfumes, colognes, essential Limonene, alpha- pinene, Formaldehyde, 4- AMC, acetone,
oils (e.g. lavender, eucalyptus, linalool, linalyl acetate, 4- hydroxy- 4- methyl- 5- hexen-
tea tree) terpinene- 4- ol, gamma- 1- al, 5- ethenyl- dihydro- 5-
terpinene methyl- 2(3H) furanone, SOAs
including ultrafine particles
continued...
CD 2010/1 Page 9 of 11
Overall home emissions Limonene, alpha- pinene, styrene Formaldehyde, 4- AMC,

pinonaldehyde, acetone, pinic
acid, pinonic acid, formic acid,
benzaldehyde, SOAs including
ultrafine particles
Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA, 4-oxopentanal, SOA,

Secondary Organic Aerosols
Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006.
■ Unsaturated vegetable oils are often used in paints which upon "drying" produce a polymeric network formed
of the constituent fatty acids.
During the drying process, a number of compounds are produced that do not contribute to the polymer network.
These include unstable hydroperoxide (ROOH) the major by-product of the reaction of oxygen with unsaturated
fatty acids. The hydroperoxides quickly decompose, forming carbon dioxide and water, as well as a variety of
aldehydes, acids and hydrocarbons. Many of these compounds are volatile, and in an unpigmented oil, they
would be quickly lost to the environment. However, in paints, such volatiles may react with lead, zinc,
copper or iron compounds in the pigment, and remain in the paint film as coordination complexes or salts. A
large number of the original ester bonds in the oil molecules undergo hydrolysis releasing individual fatty
acids. Some portion of the free fatty acids react with metals in the pigment, producing metal carboxylates.
Together, the various non-cross-linking substances associated with the polymer network constitute the mobile
phases. Unlike the molecules that are part of the network itself, they are capable of moving and diffusing
within the film, and can be removed using heat or a solvent. The mobile phase may play a role in plasticising
the paint film, preventing it from becoming too brittle.
One simple technique for monitoring the early stages of the drying process is to measure weight change in an
oil film over time. Initially, the film becomes heavier, as it absorbs large amounts of oxygen. Then oxygen
uptake ceases, and the weight of the film declines as volatile compounds are lost to the environment.
As the oil ages, a further transition occurs. Carboxyl groups in the polymers of the stationary phase lose a
hydrogen ion, becoming negatively charged, and form complexes with metal cations present in the pigment. The
original network, with its nonpolar, covalent bonds is replaced by an ionomeric structure, held together by
ionic interactions. At present, the structure of these ionomeric networks is not well understood.
■ DO NOT discharge into sewer or waterways.
Section 13 - DISPOSAL CONSIDERATIONS
■ - Recycle wherever possible or consult manufacturer for recycling options.

- Consult State Land Waste Authority for disposal.
- Bury or incinerate residue at an approved site.
- Recycle containers if possible, or dispose of in an authorised landfill.
Section 14 - TRANSPORTATION INFORMATION
Labels Required: SPONTANEOUSLY COMBUSTIBLE
HAZCHEM:
1Y (ADG7)
continued...
CD 2010/1 Page 10 of 11
Section 14 - TRANSPORTATION INFORMATION
ADG7:
Class or division: 4.2 Subsidiary risk: None
UN No.: 1386 UN packing group: III
Special provisions: 29 Packing Instructions: None
Limited quantities: 0 Portable tanks and bulk None
containers -
Instructions:
Portable tanks and bulk None Packagings and IBCs - P003; IBC08; LP02
containers - Special Packing instruction:
provisions:
Packagings and IBCs - PP20, B3, B6
Special packing
provisions:
Shipping Name:SEED CAKE with more than 1.5% oil and not more than 11%
moisture SEED CAKE
Land Transport UNDG:

Class or division: 4.2 Subsidiary risk: None
UN No.: 1386 UN packing group: III
Shipping Name:SEED CAKE with more than 1.5% oil and not more than 11%
moisture SEED CAKE
Air Transport IATA:

ICAO/IATA Class: 4.2 ICAO/IATA Subrisk: None
UN/ID Number: 1386 Packing Group: -
Special provisions: A2
Cargo Only
Packing Instructions: Forbidden Maximum Qty/Pack: Forbidden
Passenger and Cargo Passenger and Cargo
Packing Instructions: Forbidden Maximum Qty/Pack: Forbidden
Passenger and Cargo Passenger and Cargo
Limited Quantity Limited Quantity
Packing Instructions: - Maximum Qty/Pack: -
Shipping Name: SEED CAKE
Maritime Transport IMDG:

IMDG Class: 4.2 IMDG Subrisk: None
UN Number: 1386 Packing Group: III
EMS Number: F- A , S- J Special provisions: 29 929
Limited Quantities: 0
Shipping Name: SEED CAKE, containing vegetable oil (a) mechanically expelled seeds, containing more than 10%
of oil or more than 20% of oil and moisture combined
Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE
None
REGULATIONS
Regulations for ingredients
cottonseed oil (CAS: 8001-29-4) is found on the following regulatory lists;

"Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in
Listed medicines","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code Chapter 17: Summary of minimum requirements","IMO MARPOL 73/78 (Annex II) -
List of Noxious Liquid Substances Carried in Bulk","OECD Representative List of High Production Volume (HPV) Chemicals"
continued...
CD 2010/1 Page 11 of 11
Section 15 - REGULATORY INFORMATION
No data for Cargill Australia Cottonseed Meal (CW: 4708-97)
Section 16 - OTHER INFORMATION
■ Classification of the preparation and its individual components has drawn on official and authoritative
sources as well as independent review by the Chemwatch Classification committee using available literature
references.
A list of reference resources used to assist the committee may be found at:
www.chemwatch.net/references.
■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors
determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined
by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering
controls must be considered.
This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.
Issue Date: 22-Apr-2010

Print Date: 22-Apr-2010
This is the end of the MSDS.

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CARGILL AUSTRALIA COTTONSEED MEAL

Chemwatch Independent Material Safety Data Sheet

Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PROPER SHIPPING NAME

Section 2 - HAZARDS IDENTIFICATION

STATEMENT OF HAZARDOUS NATURE

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

Section 4 - FIRST AID MEASURES

Section 5 - FIRE FIGHTING MEASURES

May heat spontaneously.

Section 6 - ACCIDENTAL RELEASE MEASURES

Personal Protective Equipment advice is contained in Section 8 of the MSDS.

Section 7 - HANDLING AND STORAGE

PROCEDURE FOR HANDLING

- Avoid physical damage to containers.

Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

The following materials had no OELs on our records

TLV TWA: 4 mg/m3 (oat, wheat, barley) (total dust/particulate)

ES TWA: 4 mg/m3 (oat, wheat, barley)

MEL TWA: 10 mg/m3 (oat, wheat, barley, maize, rye) sensitiser

TLV TWA: 10 mg/m3

OSHA PEL TWA: 15 mg/m3, total particulate; 5 mg/m3, respirable particulate

* - Continuous Flow ** - Continuous-flow or positive pressure demand.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

State Divided solid Molecular Weight Not applicable

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION

CONDITIONS CONTRIBUTING TO INSTABILITY

Section 11 - TOXICOLOGICAL INFORMATION

POTENTIAL HEALTH EFFECTS

ACUTE HEALTH EFFECTS

CHRONIC HEALTH EFFECTS

TOXICITY AND IRRITATION

Section 12 - ECOLOGICAL INFORMATION

CARGILL AUSTRALIA COTTONSEED MEAL:

Overall home emissions Limonene, alpha- pinene, styrene Formaldehyde, 4- AMC,

Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA, 4-oxopentanal, SOA,

Section 13 - DISPOSAL CONSIDERATIONS

■ - Recycle wherever possible or consult manufacturer for recycling options.

Section 14 - TRANSPORTATION INFORMATION

Labels Required: SPONTANEOUSLY COMBUSTIBLE

Land Transport UNDG:

Air Transport IATA:

Shipping Name: SEED CAKE

Maritime Transport IMDG:

Section 15 - REGULATORY INFORMATION

cottonseed oil (CAS: 8001-29-4) is found on the following regulatory lists;

No data for Cargill Australia Cottonseed Meal (CW: 4708-97)

Section 16 - OTHER INFORMATION

Issue Date: 22-Apr-2010

This is the end of the MSDS.

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